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1. 发明授权

US06355757B2 Processing olefin copolymers 失效
公开(公告)号：US06355757B2
公开(公告)日：2002-03-12
申请号：US09020270
申请日：1998-02-06
申请人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
发明人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
IPC分类号： C08F21000
CPC分类号： C08L23/0815 , C08F110/02 , C08F255/00 , C08F255/02 , C08F257/02 , C08F279/02 , C08F290/042 , C08F290/044 , C08F290/06 , C08F297/08 , C08L23/02 , C08L51/06 , C08L55/00 , C08L55/005 , C08L2666/02 , C08L2666/24 , C08L2666/04 , C08F2500/03 , C08F2500/09 , C08F2500/12
摘要： The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain, B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and a MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (&eegr;0) at 190° C. at least 50% greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer, B) a ratio of the rubbery plateau modulus at 190° C. to that of a linear polymer of the same chemical composition less than 0.5, preferably

2. 发明授权

US06391998B1 Processing olefin copolymers 有权
标题翻译：加工烯烃共聚物
公开(公告)号：US06391998B1
公开(公告)日：2002-05-21
申请号：US09943540
申请日：2001-08-30
申请人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
发明人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
IPC分类号： C08F29900
CPC分类号： C08L23/0815 , C08F110/02 , C08F255/00 , C08F255/02 , C08F257/02 , C08F279/02 , C08F290/042 , C08F290/044 , C08F290/06 , C08F297/08 , C08L23/02 , C08L51/06 , C08L55/00 , C08L55/005 , C08L2666/02 , C08L2666/24 , C08L2666/04 , C08F2500/03 , C08F2500/09 , C08F2500/12
摘要： The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain, B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and a MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (&eegr;0) at 190° C. at least 50% greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer, B) a ratio of the rubbery plateau modulus at 190° C. to that of a linear polymer of the same chemical composition less than 0.5, preferably
摘要翻译：本发明涉及基本上饱和的烃聚合物组合物，其包含基本上饱和的烃聚合物，其具有A）主链，B）与A）连接的多个基本上烃基的侧链，所述侧链的数均分子量为2500道尔顿至 125,000道尔顿和SEC的MWD为1.0-3.5; 并且具有A）在190℃下的牛顿极限粘度（eta0）比具有相同化学组成和重均分子量的线性烯烃聚合物的牛顿极限粘度（eta0）至少大50％，优选至少是所述线性聚合物，B）190℃下的橡胶平稳度模量与相同化学组成小于0.5，优选<0.3的线性聚合物的比率，C）牛顿极限粘度（η）与绝对值的比率振荡剪切下的复数粘度值（eta *）在190℃下在100rad / sec下的值至少为5，D）在应变速率1秒-1，190℃下测量的拉伸粘度比，时间= 3秒（即3的应变）与在相同温度和时间为2或更大的线性粘弹性预测的时间。通过阴离子聚合和氢化制备的乙烯 - 丁烯和通过配位聚合制备的乙烯 - 己烯共聚说明了本发明。本发明聚合物表现出改进的加工特性，因为剪切稀化行为与理想聚合物的剪切变稀行为密切相关，并表现出改进的应变增厚。

3. 发明授权

US06417281B1 Processing olefin copolymers 失效
公开(公告)号：US06417281B1
公开(公告)日：2002-07-09
申请号：US09939269
申请日：2001-08-23
申请人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
发明人： Cesar A. Garcia-Franco , David J. Lohse , Robert A. Mendelson , Lewis J. Fetters , Scott T. Milner , Nikos Hadjichristidis , David W. Mead
IPC分类号： C08L2306
CPC分类号： C08L23/0815 , C08F110/02 , C08F255/00 , C08F255/02 , C08F257/02 , C08F279/02 , C08F290/042 , C08F290/044 , C08F290/06 , C08F297/08 , C08L23/02 , C08L51/06 , C08L55/00 , C08L55/005 , C08L2666/02 , C08L2666/24 , C08L2666/04 , C08F2500/03 , C08F2500/09 , C08F2500/12
摘要： The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain; B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and a MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (&eegr;0) at 190° C. at least 50% greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer, B) a ratio of the rubbery plateau modulus at 190° C. to that of a linear polymer of the same chemical composition less than 0.5, preferably

4. 发明申请

US20100227977A1 Synthesis and use of well-defined, highly-branched saturated hydrocarbon polymers 有权
标题翻译：明确定义的高度支化的饱和烃聚合物的合成和使用
公开(公告)号：US20100227977A1
公开(公告)日：2010-09-09
申请号：US12658567
申请日：2010-02-05
申请人： David J. Lohse , César Garcia-Franco , Nikos Hadjichristidis
发明人： David J. Lohse , César Garcia-Franco , Nikos Hadjichristidis
IPC分类号： C08L23/04 , C08F236/00 , C08F110/02
CPC分类号： C08C19/44 , C08C19/02 , C08F36/04 , C08F110/02 , C08F236/10 , C08F255/02 , C08G83/003 , C08L9/00 , C08L23/0815 , C08L51/06 , C08L101/005 , C08L2205/14 , C08L2205/16 , C08L2666/06 , C08L2666/02 , C08L2666/04 , C08F4/48 , C08F2500/09
摘要： The present invention relates to a method to produce highly branched polymers with a polyolefin backbone structure of ethylene and precise control of the nature of the branching. In particular, the distribution of branch length and number of branches can be more precisely controlled via the polymerization method of the present invention. The method comprises using anionic chemistry to make unsaturated polydienes with a well-defined, highly-branched structure, and then hydrogenating these polydienes to form highly branched or dendritic saturated hydrocarbon polymers. Highly branched or dendritic polyethylene, ethylene-propylene copolymer and atactic polypropylene are among the saturated hydrocarbon polymers that can be anionically synthesized via the proper selection of diene monomer type, coupling agent, and hydrogenation conditions. The highly branched or dendritic saturated hydrocarbon polymers of the present invention find application in injection molding and extrusion processes as a minor additive for improving processability of linear polyolefins by delaying the onset of melt fracture, and correspondingly increasing melt throughput rates. An additional benefit is that the mechanical properties of the polyolefinic film, sheet, pipe or fiber produced with minor amounts of highly branched or dendritic saturated hydrocarbon polymers of the present disclosure are not negatively impacted.
摘要翻译：本发明涉及一种生产具有乙烯聚烯烃骨架结构的高度支化聚合物的方法，并且精确控制了支化性质。特别地，可以通过本发明的聚合方法更精确地控制分支长度和分支数的分布。该方法包括使用阴离子化学制备具有明确定义的高支化结构的不饱和聚二烯，然后将这些聚二烯氢化形成高度支化或树枝状饱和烃聚合物。高分支或树枝状聚乙烯，乙烯 - 丙烯共聚物和无规立构聚丙烯是通过二烯单体类型，偶联剂和氢化条件的适当选择可阴离子合成的饱和烃聚合物之一。本发明的高度支化或树枝状饱和烃聚合物可用于注射成型和挤出方法，作为通过延迟熔体破裂开始并改善熔体通过速率来改善线性聚烯烃的加工性的次要添加剂。另外的好处是，用本发明的少量高支化或树枝状饱和烃聚合物生产的聚烯烃膜，片，管或纤维的机械性能不会受到负面影响。

5. 发明授权

US07687580B2 Synthesis and use of well-defined, highly-branched saturated hydrocarbon polymers 有权
标题翻译：明确定义的高度支化的饱和烃聚合物的合成和使用
公开(公告)号：US07687580B2
公开(公告)日：2010-03-30
申请号：US11296999
申请日：2005-12-08
申请人： David J. Lohse , César Garcia-Franco , Nikos Hadjichristidis
发明人： David J. Lohse , César Garcia-Franco , Nikos Hadjichristidis
IPC分类号： C08F10/00 , C08F36/08 , C08F8/42 , C08F36/04
CPC分类号： C08C19/44 , C08C19/02 , C08F36/04 , C08F110/02 , C08F236/10 , C08F255/02 , C08G83/003 , C08L9/00 , C08L23/0815 , C08L51/06 , C08L101/005 , C08L2205/14 , C08L2205/16 , C08L2666/06 , C08L2666/02 , C08L2666/04 , C08F4/48 , C08F2500/09
摘要： The present invention relates to a method to produce highly branched polymers with a polyolefin backbone structure of ethylene and precise control of the nature of the branching. In particular, the distribution of branch length and number of branches can be more precisely controlled via the polymerization method of the present invention. The method comprises using anionic chemistry to make unsaturated polydienes with a well-defined, highly-branched structure, and then hydrogenating these polydienes to form highly branched or dendritic saturated hydrocarbon polymers. Highly branched or dendritic polyethylene, ethylene-propylene copolymer and atactic polypropylene are among the saturated hydrocarbon polymers that can be anionically synthesized via the proper selection of diene monomer type, coupling agent, and hydrogenation conditions. These polymers find application in injection molding and extrusion processes as a minor additive for improving processability of linear polyolefins by delaying the onset of melt fracture, and correspondingly increasing melt throughput rates.
摘要翻译：本发明涉及一种生产具有乙烯聚烯烃骨架结构的高度支化聚合物的方法，并且精确控制了支化性质。特别地，可以通过本发明的聚合方法更精确地控制分支长度和分支数的分布。该方法包括使用阴离子化学制备具有明确定义的高支化结构的不饱和聚二烯，然后将这些聚二烯氢化形成高度支化或树枝状饱和烃聚合物。高分支或树枝状聚乙烯，乙烯 - 丙烯共聚物和无规立构聚丙烯是通过二烯单体类型，偶联剂和氢化条件的适当选择可阴离子合成的饱和烃聚合物之一。这些聚合物可用作注射成型和挤出方法，作为通过延迟熔融破裂开始以及相应地提高熔体流动速率来改善线性聚烯烃的加工性的次要添加剂。

6. 发明授权

US08168724B2 Synthesis and use of well-defined, highly-branched saturated hydrocarbon polymers 有权
标题翻译：明确定义的高度支化的饱和烃聚合物的合成和使用
公开(公告)号：US08168724B2
公开(公告)日：2012-05-01
申请号：US12658567
申请日：2010-02-05
申请人： David J. Lohse , César Garcia-Franco , Nikos Hadjichristidis
发明人： David J. Lohse , César Garcia-Franco , Nikos Hadjichristidis
IPC分类号： C08F10/00 , C08F36/08 , C08F8/42 , C08F36/04
CPC分类号： C08C19/44 , C08C19/02 , C08F36/04 , C08F110/02 , C08F236/10 , C08F255/02 , C08G83/003 , C08L9/00 , C08L23/0815 , C08L51/06 , C08L101/005 , C08L2205/14 , C08L2205/16 , C08L2666/06 , C08L2666/02 , C08L2666/04 , C08F4/48 , C08F2500/09
摘要： The present invention relates to a method to produce highly branched polymers with a polyolefin backbone structure of ethylene and precise control of the nature of the branching. In particular, the distribution of branch length and number of branches can be more precisely controlled via the polymerization method of the present invention. The method comprises using anionic chemistry to make unsaturated polydienes with a well-defined, highly-branched structure, and then hydrogenating these polydienes to form highly branched or dendritic saturated hydrocarbon polymers. Highly branched or dendritic polyethylene, ethylene-propylene copolymer and atactic polypropylene are among the saturated hydrocarbon polymers that can be anionically synthesized via the proper selection of diene monomer type, coupling agent, and hydrogenation conditions.
摘要翻译：本发明涉及一种生产具有乙烯聚烯烃骨架结构的高度支化聚合物的方法，并且精确控制了支化性质。特别地，可以通过本发明的聚合方法更精确地控制分支长度和分支数的分布。该方法包括使用阴离子化学制备具有明确定义的高支化结构的不饱和聚二烯，然后将这些聚二烯氢化形成高度支化或树枝状饱和烃聚合物。高分支或树枝状聚乙烯，乙烯 - 丙烯共聚物和无规立构聚丙烯是通过二烯单体类型，偶联剂和氢化条件的适当选择可阴离子合成的饱和烃聚合物之一。

7. 发明申请

US20130261264A1 BRANCHED SATURATED HYDROCARBON POLYMERS AS EXTENSIONAL RHEOLOGY MODIFIERS WITHOUT IMPACTING SHEAR PROPERTIES 有权
标题翻译：分散式饱和烃聚合物作为不影响剪切性能的扩展流变学改性剂
公开(公告)号：US20130261264A1
公开(公告)日：2013-10-03
申请号：US13855181
申请日：2013-04-02
申请人： Johannes Mattieu Soulages , David John Lohse , Andy Haishung Tsou , Thomas Sun , Pamela Jean Wright , Nikos Hadjichristidis , Pradeep Pandurang Shirodkar
发明人： Johannes Mattieu Soulages , David John Lohse , Andy Haishung Tsou , Thomas Sun , Pamela Jean Wright , Nikos Hadjichristidis , Pradeep Pandurang Shirodkar
IPC分类号： C08F110/02 , C08L23/06
CPC分类号： C08F110/02 , C08L23/06 , C08L2205/025 , C08L2207/07
摘要： Provided are blends of branched hydrocarbon comb polymers having tailored branching and molecular weight parameters, with substantially linear polymers. Such blends have been found to have improved extensional rheological properties, while maintaining nearly the viscosity of the substantially linear polymers. The blends of the hydrocarbon comb polymers with the substantially linear polymers thus maintain the extrusion processing characteristics of the linear polymer alone, but have improved extensional flow processability, with strain hardening ratios (SHR) greater than 1. The blends are effective in blown film processing. Also disclosed are related methods for improving extensional flow processability using the branched hydrocarbon comb polymers, as well as the branched hydrocarbon comb polymers themselves, including as a property enhancing additive for such substantially linear polymers.
摘要翻译：提供具有定制的支化和分子量参数的支链烃梳聚合物的混合物，具有基本上线性的聚合物。已发现这种共混物具有改进的拉伸流变性能，同时保持基本上线性聚合物的粘度。烃梳聚合物与基本上线性的聚合物的共混物因此保持单独的线性聚合物的挤出加工特性，但具有改进的拉伸流动加工性能，应变硬化率（SHR）大于1.该共混物在吹塑薄膜加工中是有效的。还公开了使用支链烃梳聚合物以及支链烃梳聚合物本身提高拉伸流加工性的相关方法，包括作为这种基本上线性的聚合物的性能增强添加剂。

8. 发明授权

US08623980B2 Process for making a saturated dendritic hydrocarbon polymer 有权
标题翻译：制备饱和树枝状烃聚合物的方法
公开(公告)号：US08623980B2
公开(公告)日：2014-01-07
申请号：US13329559
申请日：2011-12-19
申请人： David John Lohse , Nikos Hadjichristidis , Andy Haishung Tsou , Pamela J. Wright , Suzzy Chen Hsi Ho , Paul Edward Schuenzel
发明人： David John Lohse , Nikos Hadjichristidis , Andy Haishung Tsou , Pamela J. Wright , Suzzy Chen Hsi Ho , Paul Edward Schuenzel
IPC分类号： C08L9/00 , C08L23/00 , C08F36/00 , C08F136/00 , C08F136/06
CPC分类号： C08L9/00 , C08C19/02 , C08F36/04 , C08G83/002 , C08L19/00 , C08L23/06 , C08L2207/07 , C08F4/486
摘要： A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of a first alkadiene monomer under anionic conditions in the presence of a first organic monolithium initiator to produce a linear polyalkadiene having a lithiated chain end; (b) reacting the linear polyalkadiene with an amount of a second organic monolithium initiator in the presence of tetramethylethylene diamine to form a multilithiated polyalkadiene; (c) reacting the multilithiated polyalkadiene with an amount of a second alkadiene monomer to form a branched polyalkadiene; (d) repeating steps (b) and (c) with the branched polyalkadiene one or more times to prepare a dendritic polyalkadiene; and (e) hydrogenating the dendritic polyalkadiene to form the substantially saturated dendritic hydrocarbon polymer.
摘要翻译：制备基本上饱和的树枝状烃聚合物的方法。该方法具有以下步骤：（a）在阴离子条件下在第一有机单锂引发剂的存在下聚合一定量的第一链烯二烯单体以产生具有锂化链端的直链聚二烯二醇; （b）在四甲基乙二胺的存在下使直链多聚二烯与一定量的第二有机单锂引发剂反应，形成多元化的聚链二烯; （c）使多元化多聚二烯与一定量的第二链烯二烯单体反应以形成支链聚二烯; （d）用支链聚链二烯重复步骤（b）和（c）一次或多次以制备树枝状聚二烯; 和（e）氢化树枝状聚亚烷基二醇以形成基本饱和的树枝状烃聚合物。

9. 发明申请

US20110118420A1 Process for Making Dendritic Hydrocarbon Polymers 有权
标题翻译：制备树枝状烃聚合物的方法
公开(公告)号：US20110118420A1
公开(公告)日：2011-05-19
申请号：US12904428
申请日：2010-10-14
申请人： David John Lohse , Nikos Hadjichristidis , Andy Haishung Tsou , Suzzy C.H. Ho , Paul Edward Schuenzel
发明人： David John Lohse , Nikos Hadjichristidis , Andy Haishung Tsou , Suzzy C.H. Ho , Paul Edward Schuenzel
IPC分类号： C08F8/04 , C08J3/24
CPC分类号： C08G83/003 , C08C19/02 , C08C19/44 , C08F8/04 , C08F36/04 , C08F297/023 , C08G81/022 , C08G83/004 , C08F4/488
摘要： A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of one or more alkadiene monomers and/or one or more alkenylaromatic polymers under anionic conditions in the presence of a di- or tri-functional organic lithium initiator to produce a polyalkadiene defining a multiplicity of lithiated chain ends; (b) reacting the polyalkadiene with an amount of a tri- or di-functional silane coupling agent to form a dendritic polyalkadiene; and (c) hydrogenating the dendritic polyalkadiene to form a substantially saturated dendritic hydrocarbon polymer. Also a process for process for making a dendritic hydrocarbon polymer, comprising: (a) polymerizing an amount of one or more alkadiene monomers and/or one or more alkenylaromatic polymers under anionic conditions in the presence of a di- or tri-functional organic lithium initiator to produce a hydrocarbon polymer defining a multiplicity of lithiated chain ends; and (b) reacting the hydrocarbon polymer with an amount of a tri- or di-functional silane coupling agent to form a dendritic hydrocarbon polymer.
摘要翻译：制备基本上饱和的树枝状烃聚合物的方法。该方法具有以下步骤：（a）在二 - 或三官能有机锂引发剂的存在下，在阴离子条件下聚合一定量的一种或多种链烯二烯单体和/或一种或多种链烯基芳族聚合物，以产生限定锂化链末端的多重性; （b）使聚二烯与一定量的三官能或二官能硅烷偶联剂反应以形成树枝状聚二烯; 和（c）氢化树枝状聚亚烷基二醇以形成基本饱和的树枝状烃聚合物。还有一种用于制备树枝状烃聚合物的方法，其包括：（a）在二 - 或三官能有机锂存在下，在阴离子条件下聚合一定量的一种或多种链烯二烯单体和/或一种或多种链烯基芳族聚合物引发剂以产生限定多个锂化链端的烃聚合物; 和（b）使烃聚合物与一定量的三官能或二官能的硅烷偶联剂反应以形成树枝状烃聚合物。

10. 发明申请

US20130324447A1 LUBRICANT COMPOSITIONS AND PROCESSES FOR PREPARING SAME 有权
标题翻译：润滑剂组合物及其制备方法
公开(公告)号：US20130324447A1
公开(公告)日：2013-12-05
申请号：US13486345
申请日：2012-06-01
申请人： Andy Haishung Tsou , Vera Minak-Bernero , Martin N. Webster , Nikos Hadjichristidis
发明人： Andy Haishung Tsou , Vera Minak-Bernero , Martin N. Webster , Nikos Hadjichristidis
IPC分类号： C10M125/02 , C10M143/10 , B82Y30/00
CPC分类号： C10M161/00 , C10M2201/041 , C10M2203/1025 , C10M2205/028 , C10M2205/0285 , C10M2205/04 , C10M2205/06 , C10M2205/22 , C10M2205/223 , C10N2220/021 , C10N2230/06 , C10N2230/70 , C10N2240/10 , C10N2220/022
摘要： Provided is a method for stabilizing a dispersion of a carbon nanomaterial in a lubricating oil basestock. The method includes providing a lubricating oil basestock; dispersing a carbon nanomaterial in the lubricating oil basestock; and adding at least one block copolymer thereto. The at least one block copolymer has two or more blocks includes at least one alkenylbenzene block and at least one linear alpha olefin block. The at least one block copolymer is present in an amount sufficient to stabilize the dispersion of the carbon nanomaterial in the lubricating oil basestock. Also provided is a lubricating engine oil having a composition including: a lubricating oil base stock; a carbon nanomaterial dispersed in the lubricating oil basestock; and at least one block copolymer.
摘要翻译：提供一种稳定碳纳米材料在润滑油基础油料中的分散体的方法。该方法包括提供润滑油基础油; 将碳纳米材料分散在润滑油基础油料中; 并向其中加入至少一种嵌段共聚物。所述至少一种嵌段共聚物具有两个或更多个嵌段包括至少一个烯基苯嵌段和至少一个直链α-烯烃嵌段。至少一种嵌段共聚物的存在量足以使碳纳米材料在润滑油基础油料中的分散稳定。还提供了具有以下成分的润滑发动机油：润滑油基础油; 分散在润滑油基础油料中的碳纳米材料; 和至少一种嵌段共聚物。

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