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1. 发明申请

US20070260086A1 Process for the Preparation of Dinitriles 有权
标题翻译：制备二腈的方法
公开(公告)号：US20070260086A1
公开(公告)日：2007-11-08
申请号：US10556629
申请日：2004-05-07
申请人： Cecile Rosier , Philippe Leconte , Damien Bourgeois
发明人： Cecile Rosier , Philippe Leconte , Damien Bourgeois
IPC分类号： C07C253/08
CPC分类号： C07C253/10 , C07C253/34 , Y02P20/584 , C07C255/04
摘要： The present invention relates to a process for the preparation of dinitriles by hydrocyanation of unsaturated nitrile compounds in the presence of a catalyst based on a metal element in the zero oxidation state and on organophosphorus ligands;the invention relates more particularly to a process for the recovery from the hydrocyanation medium of a catalyst for the hydrocyanation of unsaturated nitrites to dinitriles. It consists in controlling the concentration of unsaturated nitrites in the reaction medium resulting from the hydrocyanation reaction in order to obtain a concentration by weight of unsaturated nitrites of less than 20% in the said medium, and in then feeding the said medium to a stage of settling into two upper and lower phases. The lower phase comprises most of the catalytic system, while the upper phase is composed essentially of the dinitriles.
摘要翻译：本发明涉及一种通过在基于零氧化态的金属元素和有机磷配体的催化剂存在下，通过不饱和腈化合物的氢氰化来制备二腈的方法;本发明更具体地涉及一种回收方法来自用于将不饱和亚硝酸盐氢化成二腈的催化剂的氢化细胞培养基。它包括控制由氢氰化反应产生的反应介质中的不饱和亚硝酸盐的浓度，以便在所述介质中获得小于20％的不饱和亚硝酸盐的重量浓度，然后将所述介质供给到沉入两个上下相。较低的相包含大部分催化体系，而上部相基本上由二腈组成。

2. 发明授权

US07612223B2 Process for the hydrocyanation of unsaturated compounds 有权
标题翻译：不饱和化合物的氢化方法
公开(公告)号：US07612223B2
公开(公告)日：2009-11-03
申请号：US10556628
申请日：2004-05-07
申请人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
发明人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
IPC分类号： C07C253/00
CPC分类号： C07C253/34 , C07C255/04
摘要： The present invention relates to a process for the hydrocyanation of unsaturated compounds to unsaturated mononitrile compounds or to dinitrile compounds; It relates more particularly to a process for the manufacture of dinitriles by double hydrocyanation of diolefins, such as butadiene, comprising a recovery and separation of the catalytic system. The process for the manufacture of dinitriles of the invention by hydrocyanation of unsaturated compounds, comprising at least one stage of hydrocyanation in the presence of a catalytic system comprising an organometallic complex formed by one or more monodentate organophosphite ligands and one or more bidentate organophosphorus ligands and optionally a promoter of Lewis acid type, comprises at least one stage of separation by distillation of a reactant used in the process or of a compound formed by the reaction from a medium comprising the said catalytic system.
摘要翻译：本发明涉及不饱和化合物氢化成不饱和单腈化合物或二腈化合物的方法; 更具体地涉及通过二烯烃如丁二烯的双氢氰化制备二腈的方法，其包括催化体系的回收和分离。通过氢化不饱和化合物的方法制备本发明的二腈的方法，该方法在包含由一个或多个单齿有机亚磷酸酯配体和一个或多个二齿有机磷配体形成的有机金属络合物的催化体系存在下包含至少一个氢化氰化阶段，以及任选的路易斯酸型助催化剂包括通过蒸馏在该方法中使用的反应物或由包含所述催化体系的介质通过反应形成的化合物的至少一个阶段分离。

3. 发明申请

US20070155979A1 Process for the hydrocyanation of unsaturated compounds 有权
标题翻译：不饱和化合物的氢化方法
公开(公告)号：US20070155979A1
公开(公告)日：2007-07-05
申请号：US10556628
申请日：2004-05-07
申请人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
发明人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
IPC分类号： C07C255/06 , C07C253/10
CPC分类号： C07C253/34 , C07C255/04
摘要： The present invention relates to a process for the hydrocyanation of unsaturated compounds to unsaturated mononitrile compounds or to dinitrile compounds; It relates more particularly to a process for the manufacture of dinitriles by double hydrocyanation of diolefins, such as butadiene, comprising a recovery and separation of the catalytic system. The process for the manufacture of dinitriles of the invention by hydrocyanation of unsaturated compounds, comprising at least one stage of hydrocyanation in the presence of a catalytic system comprising an organometallic complex formed by one or more monodentate organophosphite ligands and one or more bidentate organophosphorus ligands and optionally a promoter of Lewis acid type, comprises at least one stage of separation by distillation of a reactant used in the process or of a compound formed by the reaction from a medium comprising the said catalytic system.
摘要翻译：本发明涉及不饱和化合物氢化成不饱和单腈化合物或二腈化合物的方法; 更具体地涉及通过二烯烃如丁二烯的双氢氰化制备二腈的方法，其包括催化体系的回收和分离。通过氢化不饱和化合物的方法制备本发明的二腈的方法，该方法在包含由一个或多个单齿有机亚磷酸酯配体和一个或多个二齿有机磷配体形成的有机金属络合物的催化体系存在下包含至少一个氢化氰化阶段，以及任选的路易斯酸型助催化剂包括通过蒸馏在该方法中使用的反应物或由包含所述催化体系的介质通过反应形成的化合物的至少一个阶段进行分离。

4. 发明授权

US07897801B2 Process for the preparation of dinitriles 有权
标题翻译：制备二腈的方法
公开(公告)号：US07897801B2
公开(公告)日：2011-03-01
申请号：US10556629
申请日：2004-05-07
申请人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
发明人： Cécile Rosier , Philippe Leconte , Damien Bourgeois
IPC分类号： C07C253/08
CPC分类号： C07C253/10 , C07C253/34 , Y02P20/584 , C07C255/04
摘要： The present invention relates to a process for the preparation of dinitriles by hydrocyanation of unsaturated nitrile compounds in the presence of a catalyst based on a metal element in the zero oxidation state and on organophosphorus ligands;the invention relates more particularly to a process for the recovery from the hydrocyanation medium of a catalyst for the hydrocyanation of unsaturated nitrites to dinitriles. It consists in controlling the concentration of unsaturated nitrites in the reaction medium resulting from the hydrocyanation reaction in order to obtain a concentration by weight of unsaturated nitrites of less than 20% in the said medium, and in then feeding the said medium to a stage of settling into two upper and lower phases. The lower phase comprises most of the catalytic system, while the upper phase is composed essentially of the dinitriles.
摘要翻译：本发明涉及一种通过在基于零氧化态的金属元素和有机磷配体的催化剂存在下，通过不饱和腈化合物的氢氰化来制备二腈的方法;本发明更具体地涉及一种回收方法来自用于将不饱和亚硝酸盐氢化成二腈的催化剂的氢化细胞培养基。它包括控制由氢氰化反应产生的反应介质中的不饱和亚硝酸盐的浓度，以便在所述介质中获得小于20％的不饱和亚硝酸盐的重量浓度，然后将所述介质供给到沉入两个上下相。较低的相包含大部分催化体系，而上部相基本上由二腈组成。

5. 发明申请

US20140012045A1 PREPARATION OF DIAMINE VIA THE PREPARATION OF AMINONITRILE 有权
标题翻译：通过制备氨基酸制备DIAMINE
公开(公告)号：US20140012045A1
公开(公告)日：2014-01-09
申请号：US13982694
申请日：2012-02-03
申请人： Philippe Leconte
发明人： Philippe Leconte
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C253/30 , Y02P20/582 , C07C211/11 , C07C255/24
摘要： A continuous method (P) for preparing diamine is described. The method includes reacting the corresponding alkene nitrile with the corresponding monoamine in order to form the corresponding aminonitrile. The monoamine can be introduced in molecular excess with respect to the alkene nitrile, wherein the unreacted monoamine is recirculated to the reaction; followed by reducing the aminonitrile produced by hydrogen in the presence of at least one alkali-metal hydroxide, water, and a hydrogenation catalyst; and purifying the diamine.
摘要翻译：描述了制备二胺的连续方法（P）。该方法包括使相应的烯腈与相应的单胺反应以形成相应的氨基腈。单胺可以相对于烯腈分子过量引入，其中未反应的单胺再循环到反应中; 然后在至少一种碱金属氢氧化物，水和氢化催化剂的存在下还原氢气产生的氨基腈; 并纯化二胺。

6. 发明授权

US07973192B2 Preparation of both hexamethylene diamine and aminocapronitrile 有权
标题翻译：六亚甲基二胺和氨基己腈的制备
公开(公告)号：US07973192B2
公开(公告)日：2011-07-05
申请号：US12090125
申请日：2006-10-16
申请人： Philippe Leconte
发明人： Philippe Leconte
IPC分类号： C07C255/00
CPC分类号： C07C253/32 , C07C209/48 , C07C209/82 , C07C209/86 , C07C253/30 , C07C211/12 , C07C255/24
摘要： Hexamethylenediamine and aminocapronitrile are simultaneoussly produced by hemihydrogenation of adiponitrile, which includes a stage of separation of the hexamethylenediamine from the hydrogenate by distillation of the hexamethylenediamine, the distillation of the hexamethylenediamine being carried out from the hydrogenate containing a free acid and/or an alkali metal or ammonium acid salt, whereby a top fraction A recovered at the column top of the stage of distillation of the hexamethylenediamine is essentially crude hexamethylenediamine and a small amount of THA; the amount of THA (tetrahydroazepine) present in the crude hexamethylenediamine constitutes a small proportion of the THA present in the hydrogenate.
摘要翻译：六亚甲基二胺和氨基己腈通过己二腈的半氢化同时产生，其包括通过蒸馏六亚甲基二胺将六亚甲基二胺与氢化物分离的阶段，从含有游离酸和/或碱金属的氢化物中进行的六亚甲基二胺的蒸馏或铵盐，由此在六亚甲基二胺的蒸馏阶段的塔顶回收的顶馏分A基本上是粗己二胺和少量的THA; 存在于粗六亚甲基二胺中的THA（四氢氮杂）的量占氢化物中存在的THA的一小部分。

7. 发明申请

US20090234115A1 Production of Lactams 失效
标题翻译：内华达州的生产
公开(公告)号：US20090234115A1
公开(公告)日：2009-09-17
申请号：US11884883
申请日：2006-02-14
申请人： Philippe Leconte
发明人： Philippe Leconte
IPC分类号： C07D201/02
CPC分类号： C07D201/08 , Y02P20/52
摘要： Lactams, notably ε-caprolactam, are prepared from alkyl cyanovalerates, themselves obtained from unsaturated nitrile compounds, by contacting same, in gaseous state, with hydrogen in the presence of hydrogenation/cyclization catalysts, and then condensing the gas stream thus formed, without intermediate separation of any alkyl aminocaproate, and recovering lactam produced therefrom.
摘要翻译：内酰胺，特别是ε-己内酰胺，由本身由不饱和腈化合物获得的烷基氰基戊酸酯通过在氢化/环化催化剂存在下以气态与氢气接触而制备，然后将如此形成的气流冷凝而无中间体分离任何烷基氨基己酸酯，并回收由其制备的内酰胺。

8. 发明授权

US07501045B2 Method of producing and separating dinitrile compounds 有权
标题翻译：二腈化合物的生产和分离方法
公开(公告)号：US07501045B2
公开(公告)日：2009-03-10
申请号：US10565483
申请日：2004-07-23
申请人： Jérôme Gerber , Philippe Leconte , Daniel Amoros
发明人： Jérôme Gerber , Philippe Leconte , Daniel Amoros
IPC分类号： B01D3/14 , B01D3/42 , C07C253/34 , C07C253/10
CPC分类号： C07C253/34 , B01D3/14 , Y10S203/20 , C07C255/04
摘要： The present invention relates to a process for the manufacture and separation of dinitrile compounds.It relates more particularly to a process for the manufacture and separation of dinitrile compounds from a medium originating from the hydrocyanation of unsaturated mononitriles.The invention consists in feeding the medium comprising the dinitriles to a distillation column and then recovering the purified dinitriles as intermediate fraction, the heavy products being removed as column tail fraction and the light products, including the unsaturated mononitriles, being recovered as top fraction.
摘要翻译：本发明涉及二腈化合物的制造和分离方法。更具体地涉及从不饱和单腈的氢氰化的介质中制备和分离二腈化合物的方法。本发明包括将包含二腈的培养基送入蒸馏塔，然后回收纯化的二腈作为中间馏分，将重产物作为塔尾馏分除去，轻产物（包括不饱和单腈）作为最高馏分回收。

9. 发明授权

US07453012B2 Continuous process for the hydrogenation of nitriles or nitro compounds to amines 有权
标题翻译：将腈或硝基化合物氢化成胺的连续方法
公开(公告)号：US07453012B2
公开(公告)日：2008-11-18
申请号：US10502179
申请日：2003-01-20
申请人： Gérald Bocquenet , André Chesnais , Jean-Michel Desire , Philippe Leconte , Lionel Sever
发明人： Gérald Bocquenet , André Chesnais , Jean-Michel Desire , Philippe Leconte , Lionel Sever
IPC分类号： C07C209/32 , C07C209/48
CPC分类号： C07C253/30 , C07C209/48 , Y02P20/582 , Y02P20/584 , C07C211/09 , C07C211/12 , C07C255/24
摘要： A process for the hydrogenation of compounds comprising nitrile or nitro functional groups to amine, aminonitrile or aminonitro compounds is provided. The process can be a continuous process conducted in the presence of a heterogeneous hydrogenation catalyst in divided form and a basic compound. The reaction can be conducted in a stirred reactor comprising an external loop for circulating the reaction mixture, allowing one portion of the hydrogenated products to be separated without withdrawing the catalyst, by using tangential filtration. The process may be especially useful in the hydrogenation of adiponitrile to an aminocapronitrile/hexamethylenediamine mixture.
摘要翻译：提供了将含有腈或硝基官能团的化合物氢化成胺，氨基腈或氨基硝基化合物的方法。该方法可以是在分散形式的非均相氢化催化剂和碱性化合物的存在下进行的连续方法。反应可以在包含用于使反应混合物循环的外部循环的搅拌反应器中进行，允许一部分氢化产物通过使用切向过滤分离而不抽出催化剂。该方法可以特别用于己二腈加氢到氨基己腈/六亚甲基二胺混合物中。

10. 发明申请

US20080230368A1 Process for the purification of lactams 有权
标题翻译：内酰胺纯化方法
公开(公告)号：US20080230368A1
公开(公告)日：2008-09-25
申请号：US12155065
申请日：2008-05-29
申请人： Daniel Amoros , Philippe Leconte , Pierre Coqueret
发明人： Daniel Amoros , Philippe Leconte , Pierre Coqueret
IPC分类号： B01D3/34
CPC分类号： C07D201/16 , C07D201/08 , Y10S203/90
摘要： A method and a plant are disclosed for purifying lactams, particularly lactams obtained by cyclizing hydrolysis of aminonitrile. The purification of ε-caprolactam obtained by cyclizing hydrolysis of aminocapronitrile is described which includes eliminating the ammonia from the reaction medium of the hydrolysis, then recovering the lactam from said medium in purified form. The recovery is carried out by performing at least a distillation of the lactam in the presence of a base producing optionally a fronts fraction comprising compounds more volatile than the lactam, a fraction comprising the lactam to be recovered to the degree of desired purity and a distillation tails comprising the lactam and compounds less volatile than the lactam. The distillation tails are treated by various processes such as evaporation in thin layers to recover the major part of the caprolactam and recycling the latter in the purification process.
摘要翻译：公开了一种用于纯化内酰胺，特别是通过环化氨基腈水解获得的内酰胺的方法和设备。描述了通过环化氨基己腈水解获得的ε-己内酰胺的纯化，其包括从水解反应介质中除去氨，然后以纯化形式从所述介质中回收内酰胺。回收是通过在碱的存在下至少进行内消旋而进行的，所述碱生产任选地含有比内酰胺更易挥发的化合物的前列馏分，包含待回收的内酰胺至所需纯度的馏分和蒸馏尾部包含内酰胺和化合物比内酰胺更不易挥发。蒸馏尾部通过各种方法处理，例如在薄层中蒸发以回收大部分己内酰胺并在纯化过程中回收己内酰胺。

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