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    • 3. 发明授权
    • Base resistant FKM-TPV elastomers
    • 耐碱FKM-TPV弹性体
    • US07718736B2
    • 2010-05-18
    • US11171720
    • 2005-06-30
    • Edward Hosung ParkFrancis Joseph Walker
    • Edward Hosung ParkFrancis Joseph Walker
    • C08L27/12C08L27/18C08L25/02C08F214/26
    • C08L27/12C08L27/16C08L27/18C08L2205/02C08L2666/04
    • A processable rubber composition contains a double cured fluorocarbon elastomer dispersed in a matrix of a thermoplastic polymeric material. The cured elastomer contains repeating units derived from one or more fluorine-containing monomers, and further contains low levels of a peroxide cure site that contains at least one of a C—Cl bond, a C—Br bond, a C—I bond, and an olefin. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. In various embodiments, the processable compositions are thermally processed into molded articles that exhibit a high degree of base resistance, especially a high degree of resistance to degradation of physical properties upon exposure to fluids containing strong nucleophiles such as amines.
    • 可加工的橡胶组合物包含分散在热塑性聚合物材料的基质中的双重固化的碳氟化合物弹性体。 固化的弹性体含有衍生自一种或多种含氟单体的重复单元,并且还含有低含量的过氧化物固化位点,其含有C-Cl键,C-Br键,C-I键, 和烯烃。 在一个实施方案中,基质形成连续相,并且硫化的弹性体材料为形成非连续相的颗粒形式。 在各种实施方案中,将可加工组合物热处理成表现出高耐碱性的模塑制品,特别是在暴露于含有强亲核试剂如胺的流体时物理性能降低的高度抗性。
    • 6. 发明授权
    • Dynamic vulcanization with fluorocarbon processing aids
    • 用氟碳加工助剂进行动态硫化
    • US07449524B2
    • 2008-11-11
    • US11029770
    • 2005-01-05
    • Edward Hosung ParkFrancis Joseph Walker
    • Edward Hosung ParkFrancis Joseph Walker
    • C08L27/12
    • C08L27/12C08L27/16C08L2205/03C08L2205/22C08L2666/04
    • A curable fluorocarbon elastomer is dynamically cured in the presence of a major amount of a non-curing thermoplastic material and a minor amount of a second fluorocarbon elastomer that does not cure under the dynamic vulcanization conditions. The non-curing elastomer is preferably present at from 1 to 20 parts based on 100 parts of the curing fluorocarbon elastomer. Processable rubber compositions comprise a continuous phase of a thermoplastic material, particles of a cured fluorocarbon elastomer dispersed in the continuous phase, and an uncured fluorocarbon elastomer at a level of 10 parts or less per 100 parts of the cured fluorocarbon elastomer. Shaped articles such as gaskets and seals are produced by thermoplastic processing of the processable rubber compositions.
    • 可固化的氟碳弹性体在大量未固化的热塑性材料和少量在动态硫化条件下不固化的第二种氟碳弹性体的存在下动态固化。 基于100份固化氟碳弹性体,非固化弹性体优选以1至20份存在。 可加工橡胶组合物包含热塑性材料的连续相,分散在连续相中的固化碳氟化合物弹性体的颗粒和每100份固化的碳氟化合物弹性体10份或更少的未固化氟碳弹性体。 诸如垫圈和密封件的成形制品通过可加工橡胶组合物的热塑性加工制成。
    • 7. 发明授权
    • Fluorocarbon elastomer compositions containing wear reducing additives
    • 含有减磨添加剂的氟碳弹性体组合物
    • US07449523B2
    • 2008-11-11
    • US11022715
    • 2004-12-27
    • Edward Hosung Park
    • Edward Hosung Park
    • C08F259/08
    • C09K3/1009B29B7/7495C08L27/16C08L27/18C08L2205/02C08L2205/03C08L2666/04
    • Processable rubber compositions contain a vulcanized fluorocarbon elastomer and wear reducing additives dispersed in a matrix of a thermoplastic polymeric material. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a curative, an uncured fluorocarbon elastomer, a wear reducing additive and a thermoplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles such as seals, gaskets, O-rings, and hoses may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion.
    • 可加工橡胶组合物含有分散在热塑性聚合材料基体中的硫化氟碳弹性体和耐磨耗添加剂。 在一个实施方案中,基质形成连续相,并且硫化的弹性体材料为形成非连续相的颗粒形式。 组合物通过组合固化剂,未固化的氟碳弹性体,耐磨耗添加剂和热塑性材料制成,并在足以实现弹性体材料硫化的温度和时间下加热混合物,同时施加机械能以混合 该混合物在加热步骤期间。 根据常规热塑性方法如吹塑,注射成型和挤出,可以从橡胶组合物容易地形成诸如密封件,垫圈,O形环和软管的成型制品。
    • 9. 发明授权
    • Dynamic vulcanization of fluorocarbon elastomers containing peroxide cure sites
    • 含有过氧化物固化部位的氟碳弹性体的动态硫化
    • US07662886B2
    • 2010-02-16
    • US12241537
    • 2008-09-30
    • Edward Hosung Park
    • Edward Hosung Park
    • C08L27/12
    • C08F214/18Y10T428/139
    • Processable rubber compositions contain a vulcanized elastomeric material dispersed in a matrix of a thermoplastic polymeric material. The vulcanized elastomeric material is a peroxide cure polymeric material containing repeating units derived from fluorine-containing monomers and at least one peroxide cure site monomer. In one embodiment the matrix forms a continuous phase and the vulcanized elastomeric material is in the form of particles forming a non-continuous phase. The compositions are made by combining a radical curing system, a fluorocarbon elastomer material, and a fluoroplastic material, and heating the mixture at a temperature and for a time sufficient to effect vulcanization of the elastomeric material, while mechanical energy is applied to mix the mixture during the heating step. Shaped articles may be readily formed from the rubber compositions according to conventional thermoplastic processes such as blow molding, injection molding, and extrusion. Examples of useful articles include seals, gaskets, O-rings, and hoses.
    • 可加工橡胶组合物含有分散在热塑性聚合材料基体中的硫化弹性体材料。 硫化弹性体材料是含有衍生自含氟单体和至少一种过氧化物固化位点单体的重复单元的过氧化物固化聚合材料。 在一个实施方案中,基质形成连续相,并且硫化的弹性体材料为形成非连续相的颗粒形式。 组合物通过组合自由基固化体系,氟碳弹性体材料和氟塑料材料制成,并在足以实现弹性体材料硫化的温度和时间下加热混合物,同时施加机械能以混合混合物 在加热步骤期间。 成型制品可以根据常规的热塑性方法如吹塑,注模和挤出由橡胶组合物容易地形成。 有用的物品的实例包括密封件,垫圈,O型圈和软管。