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    • 4. 发明授权
    • Vapor-permeable, waterproof bicomponent structure
    • 透气性,防水双组分结构
    • US4725481A
    • 1988-02-16
    • US18338
    • 1987-02-24
    • George J. Ostapchenko
    • George J. Ostapchenko
    • B32B7/02B32B27/08B32B27/12B32B27/36
    • B32B27/08Y10T428/2495Y10T428/31797Y10T442/679Y10T442/699
    • (A) A continuous layer of a hydrophobic elastomer having a water vapor transmission rate of 400-2500 gm.mil/m.sup.2 /24 hrs., said hydrophobic elastomer is a copolyetherester having a multiplicity of recurring long-chain ester units and short-chain ester units, said long-chain ester units being represented by the formula ##STR1## and said short-chain ester units being represented by the formula ##STR2## where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide)glycol having an average molecular weight of about 400-3500, the amount of ethylene oxide groups incorporated in the copolyetherester by the poly(alkylene oxide)glycol is not greater than about 20 weight percent; R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight less than 300; D is a divalent radical remaining after removal of hydroxyl groups from a diol having a molecular weight less than about 250;(B) a continuous layer of a hydrophilic elastomer having a water vapor transmission rate of at least 3500 gm.mil/m.sup.2 /24 hrs. said hydrophilic elastomer is a copolyetherester having a multiplicity of long-chain ester units and short-chain ester units represented by formulae (I) and (II) above and having the values given above with the proviso that the amount of ethylene oxide groups incorporated in the copolyetherester by the poly(alkylene oxide)glycol is from about 25-68 weight percent andsaid bicomponent film has a separation ratio for water vapor of at least 1.2.
    • (A)疏水性弹性体的连续层,其水蒸汽透过率为400-2500gm.mil / m2 / 24小时,所述疏水性弹性体是具有多个重复长链酯单元和短链的共聚醚酯 酯单元,所述长链酯单元由式(I)表示,所述短链酯单元由式(II)表示,其中G是除去末端后残留的二价基团 来自平均分子量为约400-3500的聚(环氧烷)二醇的羟基,由聚(环氧烷)二醇引入共聚醚酯中的环氧乙烷基团的量不大于约20重量%; R是从分子量小于300的二羧酸除去羧基后剩余的二价基团; D是从分子量小于约250的二醇中除去羟基后剩余的二价基团; (B)具有至少3500gm.mil / m 2/24小时的水蒸气透过率的亲水性弹性体的连续层。 所述亲水性弹性体是具有多个长链酯单元和由上述式(I)和(II)表示的短链酯单元的共聚醚酯,并且具有上述给出的值,条件是环氧乙烷基团的量加入 聚(环氧烷)二醇的共聚醚酯为约25-68重量%,所述双组分膜的水蒸汽分离比至少为1.2。
    • 5. 发明授权
    • Extrusion coating process
    • 挤出涂装工艺
    • US06645336B1
    • 2003-11-11
    • US09670528
    • 2000-09-27
    • Yannick AlbertoneGeorge J. Ostapchenko
    • Yannick AlbertoneGeorge J. Ostapchenko
    • B32B3130
    • B32B27/12B32B37/153B32B2262/0253B32B2307/724B32B2307/7265B32B2323/04B32B2323/10B32B2419/06B32B2437/00B32B2555/02
    • A process for the preparation of a laminate, particularly a waterproof moisture vapor permeable laminate, comprising a substrate having on a surface thereof a thermoplastic polymer resin coating and further comprising a peelable release layer in contact with the surface of said thermoplastic polymer resin remote from the substrate, and optionally further comprising a tie layer between the substrate and the thermoplastic polymer resin, said process comprising the steps of forming or providing a substrate layer and providing on a surface thereof a thermoplastic polymer resin coating and a peelable release layer and optionally providing a tie layer between the substrate and the thermoplastic polymer resin coating, characterized in that the thermoplastic polymer resin has a viscosity less than about 3000 Pa.s measured according to the standard ISO11443.
    • 一种用于制备层压体,特别是防水透湿层压材料的方法,其包括在其表面上具有热塑性聚合物树脂涂层的基底,并且还包括与所述热塑性聚合物树脂的远离所述热塑性聚合物树脂的表面接触的可剥离的隔离层 衬底,并且任选地还包括在所述基底和所述热塑性聚合物树脂之间的连接层,所述方法包括以下步骤:形成或提供基底层,并在其表面上提供热塑性聚合物树脂涂层和可剥离释放层,并且任选地提供 基底和热塑性聚合物树脂涂层之间的粘结层,其特征在于热塑性聚合物树脂的粘度小于根据标准ISO11443测量的约3000Pa.s。