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1. 发明授权

US4847429A Synthesis of phenylhydroquinones 失效
标题翻译：苯基氢醌的合成
公开(公告)号：US4847429A
公开(公告)日：1989-07-11
申请号：US81209
申请日：1987-08-03
申请人： Carl M. Lentz , Bruce L. Gustafson , Dale E. Van Sickle , Joseph S. Bowers, Jr.
发明人： Carl M. Lentz , Bruce L. Gustafson , Dale E. Van Sickle , Joseph S. Bowers, Jr.
IPC分类号： B01J27/12 , B01J27/125 , B01J27/16 , B01J29/06 , B01J31/02 , B01J31/04 , B01J31/08 , C07B61/00 , C07C37/06 , C07C37/11 , C07C37/14 , C07C39/15 , C07C39/17 , C07C41/18 , C07C41/30 , C07C43/205 , C07C43/21 , C07C69/017 , C07C69/28 , C07C205/00 , C07C205/21 , C07C205/36 , C07C321/00
CPC分类号： C07C37/11 , C07C37/06 , C07C37/14 , C07C2101/14
摘要： Process is disclosed for the preparation of phenylhydroquinones by the alkylation of hydroquinone (or derivatives thereof) with the cyclohexyl moieties, cyclohexanol or cyclohexene (or derivatives thereof), followed by dehydrogenation of the intermediate cyclohexylhydroquinone.
摘要翻译：公开了通过用环己基部分，环己醇或环己烯（或其衍生物）烷基化氢醌（或其衍生物），然后中间体环己基氢醌脱氢来制备苯基氢醌的方法。

2. 发明授权

US4713472A Preparation of dimethyl 4,4'-stilbenedicarboxylate and intermediates therefor 失效
标题翻译：制备4,4'-二苯乙烯二甲酸二甲酯及其中间体
公开(公告)号：US4713472A
公开(公告)日：1987-12-15
申请号：US863274
申请日：1986-05-15
申请人： Dale E. Van Sickle
发明人： Dale E. Van Sickle
IPC分类号： C07C69/76 , C07C67/313 , C07C67/32
CPC分类号： C07C69/76
摘要： The preparation of 4,4'-dimethylstilbenedicarboxylate by acetylating 4,4'-bis(methoxycarbonyl)benzoin to give 4,4'-bis(methoxycarbonyl)benzoin acetate, selectively reducing 4,4'-bis(methoxycarbonyl)benzoin acetate with hydrogen to give 1,2-bis(4-methoxycarbonylphenyl)ethanol, and subjecting the 1,2-bis(4-methoxycarbonylphenyl)ethanol to either (1) dehydration or (2) acetylation to 1,2-bis(4-carbomethoxyphenyl)-1-acetoxy ethane followed by pyrolysis thereof to give the 4,4'-dimethylstilbenedicarboxylate. In this process, the new compounds 4,4'-bis(methoxycarbonyl)benzoin acetate, 1,2-bis(4-methoxycarbonylphenyl)ethanol, and 1,2-bis(4-carbomethoxyphenyl)-1-acetoxy ethane are produced and the novel preparations thereof are performed.
摘要翻译：通过乙酰化4,4'-双（甲氧基羰基）苯偶姻制备4,4'-二（甲氧基羰基）苯偶姻乙酸乙酯，通过氢气选择性还原4,4'-双（甲氧基羰基）苯偶姻乙酸酯，制备4,4'-二甲基二苯乙烯二酸二乙酯得到1,2-双（4-甲氧基羰基苯基）乙醇，并使1,2-双（4-甲氧基羰基苯基）乙醇（1）脱水或（2）乙酰化为1,2-双（4-甲氧基苯基） -1-乙酰氧基乙烷，然后热解，得到4,4'-二甲基二苯乙烯二羧酸酯。在该方法中，制备新化合物4,4'-双（甲氧基羰基）苯偶姻乙酸酯，1,2-双（4-甲氧基羰基苯基）乙醇和1,2-双（4-甲酯基苯基）-1-乙酰氧基乙烷，进行其新型制备。

3. 发明授权

US4484011A Process for preparation of 4-isopropylphenol 失效
标题翻译： 4-异丙基苯酚的制备方法
公开(公告)号：US4484011A
公开(公告)日：1984-11-20
申请号：US557691
申请日：1983-12-02
申请人： Dale E. Van Sickle
发明人： Dale E. Van Sickle
IPC分类号： C07C37/48 , C07C39/06
CPC分类号： C07C37/48 , Y02P20/582
摘要： The process for preparing 4-isopropylphenol (4-IPP) from 2-isopropylphenol (2-IPP) comprising contacting phenol with 2-IPP in the presence of a catalyst system selected from: (1) the combination of sulfuric acid on comminuted acid clay and a molecular sieve; and (2) trifluoromethane sulfonic acid (TFMSA); at a temperature of from about 90.degree. C. to about 250.degree. C., preferably from about 110.degree. C. to about 200.degree. C., wherein the initial mole ratio of phenol/2-IPP is from about 6 to about 2, preferably from about 4 to about 2.5, for a sufficient period to give a mole ratio of 4-IPP/2-IPP in the reaction system of from about 0.6 to about 1.5, and preferably from about 0.8 to about 1.2, without significant meta-isopropylphenol formation, i.e., less than about 10 mole %. In the isolation procedure, distillation separates the reaction mixture into phenol, 2-IPP, and 4-IPP.
摘要翻译：由2-异丙基苯酚（2-IPP）制备4-异丙基苯酚（4-IPP）的方法，包括在催化剂体系存在下使苯酚与2-IPP接触，所述催化剂体系选自：（1）硫酸在粉碎酸性粘土和分子筛; 和（2）三氟甲磺酸（TFMSA）; 在约90℃至约250℃的温度下，优选约110℃至约200℃，其中苯酚/ 2 -IPP的初始摩尔比为约6至约2，优选约4至约2.5，持续足够的时间以使反应体系中的4-IPP / 2-IPP的摩尔比为约0.6至约1.5，优选约0.8至约1.2，异丙基苯酚形成，即小于约10摩尔％。在分离过程中，蒸馏将反应混合物分离成苯酚，2-IPP和4-IPP。

4. 发明授权

US4468356A Diketene chlorination method 失效
标题翻译：二氯乙烯氯化法
公开(公告)号：US4468356A
公开(公告)日：1984-08-28
申请号：US436540
申请日：1982-10-25
申请人： Dale E. Van Sickle , Gordon C. Newland , Jeffrey J. Siirola , Steven L. Cook
发明人： Dale E. Van Sickle , Gordon C. Newland , Jeffrey J. Siirola , Steven L. Cook
IPC分类号： C07C51/58 , C07C67/46
CPC分类号： C07C51/58 , C07C67/46
摘要： Disclosed is a process and apparatus for the chlorination of diketene, by contacting the diketene in nebulized form with chlorine gas, which contacting can be in the absence of a solvent or diluent, in an essentially uncooled reaction zone of short residence time followed by a cooling zone wherein at least a portion of the heat of reaction is removed from the product without the need for refrigeration.
摘要翻译：公开了一种用于氯化双烯酮的方法和装置，通过使雾化形式的双烯酮与氯气气体接触，该氯气可在不存在溶剂或稀释剂的情况下在基本上未冷却的短停留时间的反应区中，然后冷却其中至少一部分反应热从产品中除去而不需要冷藏。

5. 发明授权

US5990321A Monoesters and macrocyclic diester of phthalic acid and synthesis thereof 失效
公开(公告)号：US5990321A
公开(公告)日：1999-11-23
申请号：US313653
申请日：1999-05-18
申请人： Dale E. Van Sickle
发明人： Dale E. Van Sickle
IPC分类号： C07C69/76 , C07C69/80 , C07D321/00 , C08G63/08 , C08G63/181 , C08G63/78 , C08G63/85 , C03C17/00 , C07D321/10 , C07D323/00 , C08G63/02
CPC分类号： C07C69/76 , C07C69/80 , C07D321/00 , C08G63/181 , C08G63/78 , C08G63/85 , Y10S526/915
摘要： Monoesters and macrocyclic diesters of 2,2,4-trimethyl-1,3-pentanediol and phthalic acid or a derivative thereof are described. Methods by which such monoesters and diesters may be prepared are also described. The mono- and diesters according to the invention are useful in the preparation of clear, hard thermoplastic polymers. The thermoplastic polymers are useful in coatings, inks, reinforced plastics and packaging materials.

6. 发明授权

US4876378A Recovery of dialkyl naphthalene-2,6-dicarboxylates from naphthalene-2,6-dicarboxylic acid-containing polyesters 失效
标题翻译：从萘-2,6-二羧酸的聚酯回收萘-2,6-二甲酸二烷基酯
公开(公告)号：US4876378A
公开(公告)日：1989-10-24
申请号：US197232
申请日：1988-05-23
申请人： Dale E. Van Sickle
发明人： Dale E. Van Sickle
IPC分类号： C07C67/03 , C07C69/76
CPC分类号： C07C67/03 , C07C69/76
摘要： A process for the formation and recovery of dialkyl naphthalene-2,6-dicarboxylates from poly-(alkylene naphthalene-2,6-dicarboxylate) polyesters. Alcoholysis of poly(ethylene naphthalene-2,6-dicarboxylate) in the presence of a transesterification catalyst on cooling yields solid dialkyl naphthalene-2,6-dicarboxylate which may be collected by filtration and further purified by recrystallization from xylenes. Novel alkyl hydroxyalkyl naphthalene-2,6-dicarboxylate compounds may be isolated from the filtrate and either reconverted to polyester or further alcoholized to dialkyl naphthalene-2,6-dicarboxylate.
摘要翻译：从聚（亚烷基萘-2,6-二甲酸酯）聚酯形成和回收萘-2,6-二羧酸二烷基酯的方法。聚酯（2,6-萘二甲酸乙烯酯）在酯交换催化剂存在下，在冷却条件下进行醇解，得到固体二烷基萘-2,6-二甲酸二苯酯，其可通过过滤收集并通过从二甲苯重结晶进一步纯化。新的烷基羟基烷基萘-2,6-二甲酸酯化合物可以从滤液中分离出来，并且再转化成聚酯或进一步醇化成萘-2,6-二羧酸二烷基酯。

7. 发明授权

US5994564A Monoesters and macrocyclic diester of phthalic acid and synthesis thereof 失效
标题翻译：单酯和邻苯二甲酸的大环二酯及其合成
公开(公告)号：US5994564A
公开(公告)日：1999-11-30
申请号：US136452
申请日：1998-08-19
申请人： Dale E. Van Sickle
发明人： Dale E. Van Sickle
IPC分类号： C07C69/76 , C07C69/80 , C07D321/00 , C08G63/08 , C08G63/181 , C08G63/78 , C08G63/85
CPC分类号： C07C69/76 , C07C69/80 , C07D321/00 , C08G63/181 , C08G63/78 , C08G63/85 , Y10S526/915
摘要： Monoesters and macrocyclic diesters of 2,2,4-trimethyl-1,3-pentanediol and phthalic acid or a derivative thereof are described. Methods by which such monoesters and diesters may be prepared are also described. The mono- and diesters according to the invention are useful in the preparation of clear, hard thermoplastic polymers. The thermoplastic polymers are useful in coatings, inks, reinforced plastics and packaging materials.
摘要翻译：描述了2,2,4-三甲基-1,3-戊二醇和邻苯二甲酸或其衍生物的单酯和大环二酯。还描述了可以制备这种单酯和二酯的方法。根据本发明的单酯和二酯可用于制备透明硬的热塑性聚合物。热塑性聚合物可用于涂料，油墨，增强塑料和包装材料。

8. 发明授权

US5118823A Oxidation of dihydroxyaromatic compounds to quinones 失效
标题翻译：将二羟基芳族化合物氧化成醌
公开(公告)号：US5118823A
公开(公告)日：1992-06-02
申请号：US628957
申请日：1990-12-13
申请人： Dale E. Van Sickle , Garry L. Myers , William D. Nottingham , Glenn C. Jones
发明人： Dale E. Van Sickle , Garry L. Myers , William D. Nottingham , Glenn C. Jones
IPC分类号： C07C46/08
CPC分类号： C07C46/08
摘要： Disclosed is a process for making quinones by oxidation of dihydroxyaromatic compounds in the presence of oxygen using supported platinum catalysts.
摘要翻译：公开了一种通过使用负载的铂催化剂在氧气存在下氧化二羟基芳族化合物来制备醌的方法。

9. 发明授权

US4789755A Process for the preparation of stilbenedicarboxylate derivatives 失效
标题翻译：二苯乙烯二羧酸酯衍生物的制备方法
公开(公告)号：US4789755A
公开(公告)日：1988-12-06
申请号：US105416
申请日：1987-10-07
申请人： Dale E. Van Sickle , John C. Morris , Marvin A. McCall , Jean C. Fleischer , Ted R. Walker, Jr.
发明人： Dale E. Van Sickle , John C. Morris , Marvin A. McCall , Jean C. Fleischer , Ted R. Walker, Jr.
IPC分类号： C07C67/343 , C07C67/52 , C07C69/76 , C07C69/773 , C07C67/39
CPC分类号： C07C67/52
摘要： Disclosed is a process for producing dimethyl or novel diphenyl derivatives of stilbenedicarboxylic acids from dimethyl toluates or diphenyl toluates and sulfur. The reaction requires an excess of toluate to sulfur of at least about 5:1. In addition hydrogen sulfide is removed from the reaction zone.
摘要翻译：公开了由甲苯甲酸甲酯或二苯甲酸甲酯和硫生成二苯乙烯二羧酸的二甲基或二苯基衍生物的方法。该反应需要至少约5:1的过量的甲苯甲酸酯与硫。此外，从反应区除去硫化氢。

10. 发明授权

US5210279A Process for manufacturing aromatic diacetates 失效
标题翻译：制备芳香族二乙酸酯的方法
公开(公告)号：US5210279A
公开(公告)日：1993-05-11
申请号：US551662
申请日：1990-07-12
申请人： Dale E. Van Sickle , Brad W. Overturf
发明人： Dale E. Van Sickle , Brad W. Overturf
IPC分类号： C07C67/05
CPC分类号： C07C67/05 , Y02P20/582
摘要： A continuous process for the production of diacetate derivatives of aromatic compounds, comprising feeding at any convenient temperature an oxygen-containing gas and feedstock comprising a diisopropyl ring substituted aromatic compound and the recycled monoisopropyl-monoacetate derivative thereof, to an oxidizer operated, for example, at from about 10.degree. C. to about 150.degree. C. and oxygen partial pressures of from about 0.05 to 10 atmospheres to form an oxidizer product comprising the mono- and dihydroperoxides of the feedstock, feeding the oxidizer product to a rearrangement-esterification zone containing acetic anhydride at from about 0.degree. C. to 150.degree. C. to form an ester product comprising the diacetate and monoisopropyl-monoacetate derivatives of the feedstock, distilling the ester product to separate the diacetate and monoisopropyl-monoacetate derivatives, and recycling the monoisopropyl-monoacetate derivative back to the oxidizer.
摘要翻译：一种用于生产芳族化合物的二乙酸酯衍生物的连续方法，包括在任何适宜的温度下将含氧气体和包含二异丙基环取代的芳族化合物的原料和其再循环的单异丙基 - 一乙酸酯衍生物进料到氧化剂中，在约10℃至约150℃，氧分压为约0.05至10个大气压，以形成包含原料的单氢化合物和二氢过氧化物的氧化剂产物，将氧化剂产物进料至含有乙酸酐在约0℃至150℃下反应以形成包含原料的二乙酸酯和单异丙基 - 一乙酸酯衍生物的酯产物，蒸馏酯产物以分离二乙酸酯和单异丙基 - 一乙酸酯衍生物，并将单异丙基 - 单乙酸酯衍生物回到氧化剂。

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