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    • 9. 发明授权
    • Low molecular weight mesophase pitch
    • 低分子量中间相沥青
    • US4209500A
    • 1980-06-24
    • US838963
    • 1977-10-03
    • Stephen Chwastiak
    • Stephen Chwastiak
    • C10C3/02C01B31/02C10C3/00D01F9/12D01F9/145D01F9/15D01F9/155D01F9/14
    • D01F9/15C01B31/02C10C3/002D01F9/145D01F9/155
    • A low molecular weight, anisotropic pitch consisting of essentially 100 percent mesophase and suitable for spinning into continuous filaments can be prepared by passing an inert gas through an isotropic carbonaceous pitch at a rate of at least 4.0 scfh. per pound of pitch while heating the pitch at a temperature of from about 380.degree. C. to about 430.degree. C. to produce mesophase and simultaneously agitating the pitch so as to produce a homogeneous emulsion of the mesophase produced and the remaining non-mesophase portion of the pitch, said heating and agitation being continued until the pitch has been essentially completely converted to mesophase and the emulsion has been transformed into an essentially single phase system. When examined under polarized light, the pitches of the present invention are seen to consist of a single phase which is essentially completely anisotropic. The fibers spun from such pitch are also essentially completely anisotropic and can be further processed to produce carbon and graphite fibers having a high Young's modulus of elasticity and high tensile strength.
    • 可以通过使惰性气体以至少4.0scfh的速率通过各向同性的碳质沥青来制备由基本上100%的中间相组成并适于纺丝成连续长丝的低分子量各向异性沥青。 每磅沥青,同时在约380℃至约430℃的温度下加热沥青,以产生中间相,同时搅拌沥青,以产生所产生的中间相的均相乳液和剩余的非中间相部分 所述加热和搅拌继续进行,直到沥青基本上完全转化为中间相,并且乳液已经转变成基本上单相系统。 当在偏振光下检查时,可以看出本发明的间距由基本完全各向异性的单相组成。 从这种沥青纺丝的纤维也基本上完全是各向异性的,并且可以进一步加工以生产具有高杨氏弹性模量和高拉伸强度的碳和石墨纤维。