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    • 1. 发明授权
    • Copper complexes for optoelectronic applications
    • 用于光电子应用的铜络合物
    • US09530974B2
    • 2016-12-27
    • US14572919
    • 2014-12-17
    • CYNORA GMBH
    • Hartmut YersinUwe MonkowiusTobias FischerThomas HofbeckThomas BaumannTobias Grab
    • H01L51/00C07F1/00C07F9/58C07F9/62C07F9/6512H01L51/50H01L51/42
    • H01L51/0091C07F1/005C07F9/58C07F9/62C07F9/6512H01L51/009H01L51/4253H01L51/5012H01L51/5072Y02E10/52Y02E10/549Y02P70/521
    • The invention relates to an optoelectronic component having a copper(I) complex of the formula: wherein X is independently selected from Cl, Br and I; N*∩E or E∩N* is a bidentate ligand connected to a first Cu atom via an N atom and connected to a second Cu atom via an E group, or a monodentate ligand connected to a Cu atom via an E group, wherein E is R2As or R2P, wherein R is selected from alkyl, aryl, alkoxy, and phenoxy; N* is a part of an aromatic group comprising an imine functional group, wherein the aromatic group is selected from pyridyl, pyrimidyl, pyridazinyl, triazinyl, oxazolyl, thiazolyl, imidazolyl, and fused N-heteroaromatics, and wherein the imine functional group comprises the N atom double bonded to a carbon atom of the aromatic group; and ∩ is a carbon atom, which is likewise part of the aromatic group, connected to the N atom of said aromatic group and also connected to the E group via the As or P atom of the E group.
    • 铜(I)复合物(I),是新的。 式(I)的铜(I)络合物是新的。 X:Cl,Br和/或I; ZAE:二价配体(任选地表现出至少一个用于提高铜(I)络合物在有机溶剂中的溶解度的取代基); Z:(R)2E形式的膦基或亚砷酰基; R:烷基,芳基,烷氧基,苯氧基或酰胺; Z:亚胺功能,其为包含吡啶基,嘧啶基,哒嗪基,三嗪基,恶唑基,噻唑基或咪唑基的芳族基团的组分; 和A:至少一个C,其也是芳族基团的组分,其中C直接邻近亚胺和P或As两者。 还包括独立权利要求:(1)使用(I)作为光电子部件的发射器或吸收体; (2)显示(I)的光电子成分; (3)制造包含使用(I)的光电子部件; (4)修改电子部件的发射和/或吸收特性,包括将(I)插入用于在光电子部件中传导电子或空穴的基质材料。 [图片]。
    • 9. 发明申请
    • COPPER COMPLEXES FOR OPTOELECTRONIC APPLICATIONS
    • 用于光电应用的铜复合材料
    • US20150194617A1
    • 2015-07-09
    • US14572919
    • 2014-12-17
    • CYNORA GMBH
    • Hartmut YersinUwe MonkowiusTobias FischerThomas HofbeckThomas BaumannTobias Grab
    • H01L51/00
    • H01L51/0091C07F1/005C07F9/58C07F9/62C07F9/6512H01L51/009H01L51/4253H01L51/5012H01L51/5072Y02E10/52Y02E10/549Y02P70/521
    • The invention relates to an optoelectronic component having a copper(I) complex of the formula: wherein X is independently selected from Cl, Br and I; N*∩E or E∩N* is a bidentate ligand connected to a first Cu atom via an N atom and connected to a second Cu atom via an E group, or a monodentate ligand connected to a Cu atom via an E group, wherein E is R2As or R2P, wherein R is selected from alkyl, aryl, alkoxy, and phenoxy; N* is a part of an aromatic group comprising an imine functional group, wherein the aromatic group is selected from pyridyl, pyrimidyl, pyridazinyl, triazinyl, oxazolyl, thiazolyl, imidazolyl, and fused N-heteroaromatics, and wherein the imine functional group comprises the N atom double bonded to a carbon atom of the aromatic group; and ∩ is a carbon atom, which is likewise part of the aromatic group, connected to the N atom of said aromatic group and also connected to the E group via the As or P atom of the E group.
    • 本发明涉及具有下式的铜(I)配合物的光电子部件:其中X独立地选自Cl,Br和I; N *∩E或E∩N*是通过N原子连接到第一Cu原子并经由E基团连接到第二Cu原子的二齿配体,或经由E基团连接到Cu原子的单齿配体,其中 E是R2As或R2P,其中R选自烷基,芳基,烷氧基和苯氧基; N *是包含亚胺官能团的芳族基团的一部分,其中芳族基团选自吡啶基,嘧啶基,哒嗪基,三嗪基,恶唑基,噻唑基,咪唑基和稠合的N-杂芳族化合物,其中亚胺官能团包括 N原子与芳基的碳原子双键键合; ∩是与所述芳族基团的N原子相连的芳族基团的一部分的碳原子,并且也通过E基团的As或P原子与E基团连接。