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1. 发明申请

US20210363348A1 FLAME-RETARDANT GRAY POLYAMIDE COMPOSITIONS AND USE THEREOF 有权
公开(公告)号：US20210363348A1
公开(公告)日：2021-11-25
申请号：US16630493
申请日：2018-07-06
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C08L77/06 , C08K7/14 , C08K5/5313 , C08K5/5317 , C08K5/3492 , C08K5/521 , C08K3/013 , C08K3/32
摘要： The invention relates to flame-retardant polyamide compositions comprising polyamide having a melting point of not more than 290° C. as component A, fillers and/or reinforcers as component B, phosphinic salt of the formula (I) as component C in which R1 and R2 are ethyl, M is Al, Fe, TiOp or Zn, m is 2 to 3, and p=(4−m)/2 compound selected from the group of the Al, Fe, TiOp and Zn salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid as component D phosphonic salt of the formula as component E in which R3 is ethyl, Met is Al, Fe, TiOq or Zn, n is 2 to 3, and q=(4−n)/2 melamine polyphosphate having an average degree of condensation of 2 to 200 as component F, and gray colorant as component G.

2. 发明申请

US20200165416A1 ADDITIVE MIXTURES FOR PLASTICS, LASER-MARKABLE POLYMER COMPOSITIONS COMPRISING THEM AND THE USE THEREOF 审中-公开
公开(公告)号：US20200165416A1
公开(公告)日：2020-05-28
申请号：US16630509
申请日：2018-07-06
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C08K5/5313 , C08K5/5317 , C08K9/02 , C08K5/00 , C08K3/08 , C08K3/24 , C08K3/32 , C08K7/14 , B41M5/26
摘要： The invention relates to additive mixtures for plastics containing phosphinic acid salt of formula (I) as component A, where R1 and R2 mean ethyl, M is Al, Fe, TiOp or Zn, m means 2 to 3, preferably 2 or 3, and p=(4−m)/2 is a compound selected from the group of Al salts, Fe salts, TiOp salts or Zn salts of ethylbutylphosphinic acid, dibutylphosphinic acid, ethylhexylphosphinic acid, butylhexylphosphinic acid and/or dihexylphosphinic acid as component B, phosphonic acid salt of formula (II) as component C, where R3 means ethyl, Met is Al, Fe, TiOq or Zn, n means 2 to 3, preferably 2 or 3, and q=(4−n)/2, and copper as component D.

3. 发明申请

US20200277491A1 FLAME-RETARDANT AND COLOR-STABLE POLYAMIDE MOLDING COMPOUNDS 审中-公开
公开(公告)号：US20200277491A1
公开(公告)日：2020-09-03
申请号：US16756210
申请日：2018-10-09
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Sebastian HÖROLD , Elke SCHLOSSER , Eva-Maria LEUSCHNER
IPC分类号： C08L77/06
摘要： The invention relates to a flame-retardant polyamide composition containing: as component A) 1 to 96 wt. % of one or more thermoplastic polyamides; as component B) 2 to 25 wt. % of a diorganylphosphinic acid salt of formula (I), wherein R1 and R2 are the same or different and C1-C18 alkyl is linear, branched or cyclical, C6-C18 aryl, C7-C18 arylalkyl and/or C7-C18 alkylaryl; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; as component C) 2 to 20 wt. % of at least a further polymer component, selected from the classes of thermoplastic polyester and polyester elastomers; as component D) 0 to 20 wt. % of a salt of the phosphorous acid of general formula (II), [HP(═O)O2]2−Mm+ (II) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; as component E) 0 to 20 wt. % of one or more condensation products of melamine and/or reaction products of melamine with phosphoric acids and/or melamine cyanurate; as component F) 0 to 50 wt. % of a filler and/or reinforcing agent; as component G) 0 to 5 wt. % of a compatibilizing agent for the polymer components; as component H) 0 to 2 wt. % of a phosphite or phosphonite or mixtures thereof; and as component I) 0 to 2 wt. % of an ester or salt of long-chained aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, wherein the sum of the components always amounts to 100 wt. %.

4. 发明申请

US20200172709A1 FLAME-RETARDANT POLYAMIDE COMPOSITIONS AND USE THEREOF 审中-公开
公开(公告)号：US20200172709A1
公开(公告)日：2020-06-04
申请号：US16637833
申请日：2018-08-08
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C08K13/04 , C08K5/5313 , C08K5/5317 , C08K5/529 , C08K5/18 , C08K5/524 , C08K7/14 , C08K3/40 , C08L77/06 , C08J5/18 , C09K21/12
摘要： The invention relates to flame-retardant polyamide compositions comprising polyamide having a melting point of not more than 290° C. as component A, fillers and/or reinforcers as component B, phosphinic salt of the formula (I) as component C in which R1 and R2 are ethyl, M is Al, Fe, TiOp or Zn, m is 2 to 3, and p=(4−m)/2 compound selected from the group of the Al, Fe, TiOp and Zn salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid as component D phosphonic salt of the formula (II) as component E in which R3 is ethyl, Met is Al, Fe, TiOq or Zn, n is 2 to 3, and q=(4−n)/2 melamine polyphosphate having an average degree of condensation of 2 to 200 as component F, sterically hindered phenolic antioxidant as component G, and/or organic phosphite and/or organic phosphonite as component H. The polyamide compositions can be used for production of fibers, films and shaped bodies, especially for applications in the electricals and electronics sector.

5. 发明申请

US20190225773A1 Flame Retardant-Stabilizer Combination for Thermoplastic Polymers 审中-公开
公开(公告)号：US20190225773A1
公开(公告)日：2019-07-25
申请号：US16333227
申请日：2017-09-06
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C08K5/5399 , C08K5/52 , C08K3/32 , C08K5/3492 , C08K5/3472 , C08K5/00 , C08K3/22
摘要： The invention relates to a novel flame retardant-stabilizer combination for thermoplastic polymers, comprising, as component A, from 25 to 99.9% by weight of a phosphinic acid salt of the formula (I) wherein R1, R2 are the same or different and are each C1-C18-alkyl, linear or branched, C6-C18-aryl, C7-C18-arylalkyl or C7-C18-alkylaryl, or R1 and R2 form one or more rings with each other, M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; as component B, from 0 to 75% by weight of a synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 50% by weight of magnesium oxide, zinc oxide, manganese oxide, tin oxide, dihydrotalcite, hydrocalumite, magnesium hydroxide, calcium hydroxide, zinc hydroxide, tin oxide hydrate, manganese hydroxide, zinc borate, basic zinc silicate, zinc stannate or mixtures of these substances, the sum of the component s always being 100% by weight, and wherein the angle of repose of said flame retardant-stabilizer combination is between 5° and 45°.

6. 发明申请

US20210147676A1 FLAME-RETARDANT POLYAMIDE COMPOSITIONS AND USE THEREOF 有权
公开(公告)号：US20210147676A1
公开(公告)日：2021-05-20
申请号：US16637802
申请日：2018-08-08
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C08L77/06 , C08L77/02 , C08K5/52 , C08K5/3492 , C08K5/098 , C08K5/101 , C08K3/32 , C08K7/14
摘要： The invention relates to flame-retardant polyamide compositions comprising polyamide having a melting point of not more than 290° C. as component A, fillers and/or reinforcers as component B, phosphinic salt of the formula (I) as component C in which R1 and R2 are ethyl, M is Al, Fe, TiOp or Zn, m is 2 to 3, and p=(4−m)/2 compound selected from the group of the Al, Fe, TiOp and Zn salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid as component D phosphonic salt of the formula (II) as component E in which R3 is ethyl, Met is Al, Fe, TiOq or Zn, n is 2 to 3, and q=(4−n)/2 melamine polyphosphate having an average degree of condensation of 2 to 200 as component F, and wax selected from the group of the polyolefin waxes, amide waxes, natural waxes, long-chain aliphatic carboxylic acids and/or the esters or salts thereof as component G. The polyamide compositions can be used for production of fibers, films and shaped bodies, especially for applications in the electricals and electronics sector.

7. 发明申请

US20210061990A1 FLAME-RETARDANT POLYESTER COMPOSITIONS AND THE USE THEREOF 有权
公开(公告)号：US20210061990A1
公开(公告)日：2021-03-04
申请号：US16644591
申请日：2018-08-29
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C08L67/02 , C08K5/00 , C08K5/5313 , C08K5/5317 , C08K7/14 , C08K3/32 , C08K3/08 , C08L91/06 , C08K5/3492 , C08G63/183
摘要： The invention relates to flame-retardant polyester compositions comprising thermoplastic polyester as component A, fillers and/or reinforcers as component B, phosphinic salt of the formula (I) as component C in which R1 and R2 are ethyl, M is Al, Fe, TiOp or Zn, m is 2 to 3, and p=(4−m)/2 compound selected from the group of the Al, Fe, TiOp and Zn salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid as component D phosphonic salt of the formula II as component E in which R3 is ethyl, Met is Al, Fe, TiOq or Zn, n is 2 to 3, and q=(4−n)/2, inorganic phosphonate as component F, and wax selected from the group consisting of the polyolefin waxes, amide waxes, natural waxes, long-chain aliphatic carboxylic acids and/or esters or salts thereof as component G. The polyester compositions can be used for production of fibers, films and moldings, especially for uses in the electricals and electronics sector.

8. 发明申请

US20190316039A1 FLAME RETARDANT MIXTURES, THE PRODUCTION AND THE USE THEREOF 审中-公开
公开(公告)号：US20190316039A1
公开(公告)日：2019-10-17
申请号：US16318526
申请日：2017-07-12
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C09K21/12 , C09K21/04 , C08J3/20 , C08K5/5377 , C08K5/5393 , C08K3/32
摘要： The invention relates to a flame retardant mixture comprising99.9999% to 87% by weight of diorganylphosphinic acid salts as component A) and 0.0001% to 13% by weight of iron as component B), where the sum total of A) and B) is 100% by weight. The invention likewise relates to processes for producing the aforementioned flame retardant mixture and to the use thereof.

9. 发明申请

US20190153322A1 FLAME PROTECTION AGENT MIXTURES, THEIR PREPARATION AND THEIR USE 审中-公开
公开(公告)号：US20190153322A1
公开(公告)日：2019-05-23
申请号：US16317702
申请日：2017-07-12
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C09K21/12 , C09K21/02 , C08K5/5313 , C08K3/30 , C08K13/02
摘要： Flame retardant mixtures and the production and use thereofThe invention relates to a flame retardant mixture comprising 99.9999% to 87% by weight of diorganylphosphinic salts as component A) and 0.0001% to 13% by weight of iron as component B), where the sum total of A) and B) is 100% by weight; and to processes for preparation thereof and to the use thereof.

10. 发明申请

US20210363349A1 FLAME-RETARDANT POLYAMIDE COMPOSITIONS WITH A HIGH GLOW WIRE IGNITION TEMPERATURE AND USE THEREOF 有权
公开(公告)号：US20210363349A1
公开(公告)日：2021-11-25
申请号：US16637815
申请日：2018-08-08
申请人： CLARIANT PLASTICS & COATINGS LTD
发明人： Harald BAUER , Sebastian HÖROLD , Martin SICKEN
IPC分类号： C08L77/06 , C08G69/26 , C08K3/40 , C08K7/14 , C08K5/5333 , C08K5/5313 , C08K5/524 , C08K5/52 , C08K13/04
摘要： The invention relates to flame-retardant polyamide compositions with a glow wire ignition temperature of not less than 775° C., comprising polyamide having a melting point of not more than 290° C. as component A, fillers and/or reinforcers as component B, phosphinic salt of the formula (I) as component C in which R1 and R2 are ethyl, M is Al, Fe, TiOp or Zn, m is 2 to 3, and p=(4−m)/2 compound selected from the group of the Al, Fe, TiOp and Zn salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid as component D phosphonic salt of the formula (II) as component E in which R3 is ethyl, Met is Al, Fe, TiOq or Zn, n is 2 to 3, and q=(4−n)/2, and melamine polyphosphate having an average degree of condensation of 2 to 200 as component F. The polyamide compositions can be used for production of fibers, films and shaped bodies, especially for applications in the electricals and electronics sector.

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