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    • 6. 发明申请
    • PROCESS FOR PREPARING HIGH-PERFORMANCE POLYPROPYLENES
    • 制备高性能聚丙烯的方法
    • US20150246986A1
    • 2015-09-03
    • US14710007
    • 2015-05-12
    • China Petroleum & Chemical CorporationBeijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    • Wenbo SongMeifang GuoJinliang QiaoZhichao YangShijun ZhangLuqiang Yu
    • C08F110/02
    • The invention discloses a process for preparing high-performance propylene polymers, the process utilizing a high activity, highly stereoselective Ziegler-Natta catalyst and two or more stages of polymerization carried out under different hydrogen concentrations to prepare propylene polymers having broad molecular weight distribution, wherein non-uniformness of isotacticity of molecular chains of the final propylene polymers is improved by adjusting or controlling stereoselectivity of catalytic active sites under different hydrogen concentrations, namely, making the low molecular weight fraction of the polymers having a higher isotacticity and making the high molecular weight fraction of the polymers having a lower isotacticity, thereby overcoming the drawbacks of the propylene polymers having broad molecular weight distribution known in the art. The resulting final polymers have excellent combined properties, in particular, remarkably improved mechanical properties.
    • 本发明公开了一种制备高性能丙烯聚合物的方法,该方法利用高活性,高立体选择性齐格勒 - 纳塔催化剂和在不同氢气浓度下进行的两个或多个阶段的聚合,以制备具有宽分子量分布的丙烯聚合物,其中 通过在不同的氢浓度下调节或控制催化活性位点的立体选择性,即使聚合物的低分子量分数具有更高的全同立构规整度并使其具有高分子量,从而提高了最终丙烯聚合物分子链的全同立构规整度的不均匀性 具有较低全同立构规整度的聚合物部分,从而克服了本领域已知的具有宽分子量分布的丙烯聚合物的缺点。 所得的最终聚合物具有优异的组合性能,特别是显着提高的机械性能。