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1. 发明授权

US4709056A 4,4-dihalohexahydrophthalic anhydrides and 4-fluorotetrahydrophthalic anhydride, and process for their preparation 失效
标题翻译： 4,4-二卤代六氢邻苯二甲酸酐和4-氟四氢邻苯二甲酸酐，及其制备方法
公开(公告)号：US4709056A
公开(公告)日：1987-11-24
申请号：US604271
申请日：1984-05-02
申请人： Byron R. Cotter , Henry C. Lin , Joseph A. Pawlak
发明人： Byron R. Cotter , Henry C. Lin , Joseph A. Pawlak
IPC分类号： C07C61/15 , C07C61/40 , C07C61/09 , C07D307/89
CPC分类号： C07C61/40 , C07C61/15
摘要： 4,4-dihalohexahydrophthalic anhydrides of the formula ##STR1## where Y is chlorine or fluorine, are prepared by the reaction of hydrogen fluoride with 4-chlorotetrahydrophthalic anhydride.The 4,4-dihalohexahydrophthalic anhydrides of this invention can be dehydrohalogenated by reaction with basic alumina to prepare a mixture of 4-fluorotetrahydrophthalic anhydride isomers of the formula ##STR2## The 4-fluorotetrahydrophthalic anhydrides can then be dehydrogenated by reaction with a dehydrogenation catalyst to prepare 4-fluorophthalic anhydride.
摘要翻译：通过氟化氢与4-氯四氢邻苯二甲酸酐的反应制备式“IMAGE”的其中Y是氯或氟的4,4-二卤代六氢邻苯二甲酸酐。本发明的4,4-二卤代六氢邻苯二甲酸酐可以通过与碱性氧化铝反应脱卤化氢来制备下式的4-氟四氢邻苯二甲酸酐异构体的混合物。然后可以通过与脱氢催化剂反应将4-氟四氢邻苯二甲酸酐脱氢，制备4-氟邻苯二甲酸酐。

2. 发明授权

US4697023A Process for the preparation of oxy-diphthalic anhydrides 失效
标题翻译：氧基二邻苯二甲酸酐的制备方法
公开(公告)号：US4697023A
公开(公告)日：1987-09-29
申请号：US914955
申请日：1986-10-03
申请人： Willis T. Schwartz , Joseph A. Pawlak
发明人： Willis T. Schwartz , Joseph A. Pawlak
IPC分类号： C07D307/89 , C07C51/347 , C07C51/567 , C07C65/24
CPC分类号： C07C51/567
摘要： Oxy-diphthalic anhydrides are prepared by reacting a halophthalic anhydride with water and an alkali metal compound such as KF, CsF or K.sub.2 CO.sub.3 in the presence of a polar, aprotic solvent.

3. 发明授权

US5021168A Process for the preparation and recovery of oxydiphthalic anhydrides 失效
标题翻译：氧联二邻苯二甲酸酐的制备和回收方法
公开(公告)号：US5021168A
公开(公告)日：1991-06-04
申请号：US381345
申请日：1989-07-18
申请人： John R. Molinaro , Joseph A. Pawlak , Willis T. Schwartz
发明人： John R. Molinaro , Joseph A. Pawlak , Willis T. Schwartz
IPC分类号： C07C51/567
CPC分类号： C07C51/567
摘要： Oxydiphthalic anhydrides of the formula ##STR1## are prepared by reacting a halophthalic anhydride with potassium carbonate in:(1) a solvent-free reaction medium wherein the molar ratio of halophthalic anhydride:potassium carbonate is greater than 2:1; or(2) a high boiling solvent which improves the mixing of the components, and aids in subsequent purification of the product. The molar ratio of halophthalic anhydride to potassium carbonate is about 1.5:1 or greater.The oxydiphthalic anhydride can be purified by filtering or centrifuging a hot solution of the oxydiphthalic anhydride in a high boiling solvent to remove impurities, followed by cooling the solution to precipitate the oxydiphthalic anhydride, which can be removed from the solution by filtration or centrifuging.
摘要翻译：通过使卤代邻苯二甲酸酐与碳酸钾反应制备下式的氧邻二氢邻苯二甲酸酐：（1）卤代邻苯二甲酸酐：碳酸钾的摩尔比大于2:1的无溶剂反应介质; 或（2）高沸点溶剂，其改善了组分的混合，有助于随后的产物纯化。卤代邻苯二甲酸酐与碳酸钾的摩尔比为约1.5:1或更高。氧联二邻苯二甲酸酐可以通过在高沸点溶剂中过滤或离心氧联二邻苯二甲酸酐的热溶液以除去杂质，然后冷却溶液以沉淀氧联二邻苯二甲酸酐，从而可以通过过滤或离心从溶液中除去。

4. 发明授权

US4049629A Solution polycondensation method 失效
标题翻译：溶液缩聚法
公开(公告)号：US4049629A
公开(公告)日：1977-09-20
申请号：US542644
申请日：1975-01-20
申请人： Joseph A. Pawlak , Anthony L. Lemper , Victor A. Pattison
发明人： Joseph A. Pawlak , Anthony L. Lemper , Victor A. Pattison
IPC分类号： C08G63/00 , C08G63/19 , C08G63/40 , C08G63/22 , C08G63/18
CPC分类号： C08G63/40
摘要： High molecular weight, linear aromatic polyesters are produced in an improved solution polycondensation process in which the hydroxyl component is added to the acid halide.
摘要翻译：高分子量的线性芳族聚酯在其中将羟基成分加入到酰卤中的改进的溶液缩聚方法中制备。

5. 发明授权

US4009198A Antidegradant esters 失效
标题翻译：抗降解酯
公开(公告)号：US4009198A
公开(公告)日：1977-02-22
申请号：US537521
申请日：1974-12-30
申请人： Joseph A. Pawlak , Francis J. Bajer
发明人： Joseph A. Pawlak , Francis J. Bajer
IPC分类号： C08K5/18 , C07C93/26
CPC分类号： C08K5/18
摘要： Compounds of the formula ##STR1## wherein, X is from 1 to 12; Z is a member selected from the group consisting of --H, --NH.sub.4, alkali metal, lower alkyl and lower hydroxyalkyl; R is a member selected from the group consisting of ethylene, 1,2-propylene, 1,2-butylene, 2,3-butylene, styrylene and mixtures thereof; R' is selected from the group consisting of substituted or unsubstituted alkylene, alkenylene, cycloalkenylene, arylene and cycloalkylene moieties containing at least two nuclear carbon atoms and in which any substituent is selected from the group consisting of carboxy, halo and lower alkyl substituents; M is a member selected from the group consisting of hydrocarbon of 1-20 carbon atoms, --RO).sub.x H, and ##STR2## wherein R, X, R' and Z are as above defined; and P is an integer from 0-1, providing when p is 0, ##STR3## is hydrogen, are non-staining or slightly staining antioxidants possessing antiozonant properties for use as antidegradants in combination with oxidizable organic substrates.
摘要翻译：下式的化合物其中X为1至12; Z是选自-H，-NH4，碱金属，低级烷基和低级羟烷基的成员; R是选自乙烯，1,2-亚丙基，1,2-亚丁基，2,3-丁烯基，亚乙烯基及其混合物的成员; R'选自含有至少两个核碳原子的取代或未取代的亚烷基，亚烯基，亚环烯基，亚芳基和亚环烷基，其中任何取代基选自羧基，卤代和低级烷基取代基; M是选自1-20个碳原子的烃，-RO）xH和其中R，X，R'和Z如上定义的那些; 并且P为0-1的整数，当p为0时，为氢，是具有抗臭氧特性的无染色或微染色抗氧化剂，用作抗氧化可降解剂与可氧化有机底物结合使用。

6. 发明授权

US4006117A Amine phosphite antioxidants 失效
标题翻译：亚磷酸亚胺抗氧化剂
公开(公告)号：US4006117A
公开(公告)日：1977-02-01
申请号：US584445
申请日：1975-06-06
申请人： D. Bruce Merrifield , Joseph A. Pawlak , James G. Colson
发明人： D. Bruce Merrifield , Joseph A. Pawlak , James G. Colson
IPC分类号： C07F9/141 , C08K5/524 , C10M137/02 , C10M153/04 , C08K5/52
CPC分类号： C10M153/04 , C07F9/1411 , C08K5/524 , C10M137/02 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2209/103 , C10M2211/02 , C10M2223/04 , C10M2223/042 , C10M2225/00 , C10M2225/02 , C10M2227/02 , C10M2229/02 , C10M2229/05 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/401 , C10N2250/10 , Y10S524/925
摘要： Compounds of the formula ##STR1## WHEREIN R is selected from the group consisting of ethylene, 1,2 propylene, 1,2 butylene, 2,3 butylene, styrylene and mixtures thereof,x is an integer from 1 to 12,R.sup.1 is substituted or unsubstituted alkyl or aryl,n is an integer from 1 to 3,Each m is a member, selected independently from the group consisting of hydrocarbon of 1 to 20 carbon atoms, --RO-- , --RO-- H and --RO-- P(OR').sub.3.sup.-n,Wherein R, R', n and x are as above described, providing where m is --RO-- , the O-- bond thereof is attached to the phosphorus of an adjacent P(OR') moiety of a common nitrogen, andP is 0 or 1, providing that when p is ##STR2## IS HYDROGEN, ARE DISCLOSED HAVING UTILITY AS NON-STAINING ANTIOXIDANTS.
摘要翻译：下式的化合物，其中R选自乙烯，1,2-丙烯，1,2-亚丁基，2,3-亚丁基，亚乙烯基及其混合物，X为1至12的整数，R 1为取代基或未取代的烷基或芳基，N为1至3的整数，每个M为独立选自1至20个碳原子的烃的基团，-RO-，-RO-H和-RO-P（ OR'）3，n，其中R，R'，n和x如上所述，其中m是-RO-，其O-键连接到相邻P（OR'）部分的磷上的普通氮气，P为0或1，条件是当p为“氢”时，作为非污染抗氧化剂被公布为实用性。

7. 发明授权

US4051107A Microstructured high molecular weight-low viscosity polyester polymers 失效
标题翻译：微结构高分子量低粘度聚酯聚合物
公开(公告)号：US4051107A
公开(公告)日：1977-09-27
申请号：US542636
申请日：1975-01-20
申请人： Joseph A. Pawlak , Anthony L. Lemper , Victor A. Pattison
发明人： Joseph A. Pawlak , Anthony L. Lemper , Victor A. Pattison
IPC分类号： C08G63/00 , C08G63/19 , C08G63/40
CPC分类号： C08G63/40
摘要： High molecular weight, linear aromatic polyesters having an ordered microstructure are produced in an improved solution polycondensation process in which the hydroxyl component is added to the acid halide.
摘要翻译：具有有序微观结构的高分子量线性芳族聚酯在改进的溶液缩聚方法中制备，其中将羟基组分加入到酰卤中。

8. 发明授权

US4021474A Antidegradant esters 失效
标题翻译：抗降解酯
公开(公告)号：US4021474A
公开(公告)日：1977-05-03
申请号：US537472
申请日：1974-12-30
申请人： Joseph A. Pawlak , Francis J. Bajer
发明人： Joseph A. Pawlak , Francis J. Bajer
IPC分类号： C09K15/20 , C07C93/26
CPC分类号： C09K15/20
摘要： Compounds of the formula ##STR1## wherein, X is from 1 to 12; Z is a member selected from the group consisting of --H, --NH.sub.4, alkali metal, lower alkyl and lower hydroxyalkyl; R is a member selected from the group consisting of ethylene, 1,2-propylene, 1,2-butylene, 2,3-butylene, styrlene and mixtures thereof; R' is selected from the group consisting of substituted or unsubstituted alkylene, alkenylene, cycloalkenylene and cycloalkylene moieties containing at least two nuclear carbon atoms and in which any substituent is selected from the group consisting of carboxy, halo and lower alkyl substituents; M is a member selected from the group consisting of hydrocarbon of 1-20 carbon atoms --RO--H, and ##STR2## wherein R, X, R' and Z are as above defined; and p is an integer from 0-1, providing when p is 0, ##STR3## IS HYDROGEN, ARE NON-STAINING OR SLIGHTLY STAINING ANTIOXIDANTS POSSESSING ANTIOZONANT PROPERTIES FOR USE AS ANTIDEGRADANTS IN COMBINATION WITH OXIDIZABLE ORGANIC SUBSTRATES.
摘要翻译：下式的化合物其中X为1至12; Z是选自-H，-NH4，碱金属，低级烷基和低级羟烷基的成员; R是选自乙烯，1,2-丙烯，1,2-亚丁基，2,3-丁烯，苯乙烯及其混合物的成员; R'选自取代或未取代的亚烷基，亚烯基，亚环烯基和含有至少两个核碳原子的亚环烷基，其中任何取代基选自羧基，卤代和低级烷基取代基; M是选自1-20个碳原子的烃-RO-H的烃，和其中R，X，R'和Z如上所定义的并且p是0-1的整数，当p为0时，图像为氢，非污染或略微染色抗氧化剂，可用于与可氧化有机基质结合使用的抗病毒剂。

9. 发明授权

US4870194A Process for the preparation and recovery of oxdiphthalic anhydrides 失效
标题翻译：氧二邻苯二甲酸酐的制备和回收方法
公开(公告)号：US4870194A
公开(公告)日：1989-09-26
申请号：US160036
申请日：1988-02-24
申请人： John R. Molinaro , Joseph A. Pawlak , Willis T. Schwartz
发明人： John R. Molinaro , Joseph A. Pawlak , Willis T. Schwartz
IPC分类号： C07D307/89 , C07B61/00 , C07C51/567
CPC分类号： C07C51/567
摘要： Oxydiphthalic anhydrides of the formula ##STR1## are prepared by reacting a halophthalic anhydride with potassium carbonate in:(1) a solvent-free reaction medium wherein the molar ratio of halophthalic anhydride:potassium carbonate is greater than 2:1; or(2) a high boiling solvent which improves the mixing of the components, and aids in subsequent purification of the product. The molar ratio of halophthalic anhydride to potassium carbonate is about 1.5:1 or greater.The oxydiphthalic anhydride can be purified by filtering or centrifuging a hot solution of the oxydiphthalic anhydride in a high boiling solvent to remove impurities, followed by cooling the solution to precipitate the oxydiphthalic anhydride, which can be removed from the solution by filtration or centrifuging.
摘要翻译：通过使卤代邻苯二甲酸酐与碳酸钾反应制备：式（1）的无水反应介质，其中卤代邻苯二甲酸酐：碳酸钾的摩尔比大于2:1; 或（2）高沸点溶剂，其改善了组分的混合，有助于随后的产物纯化。卤代邻苯二甲酸酐与碳酸钾的摩尔比为约1.5:1或更高。氧联二邻苯二甲酸酐可以通过在高沸点溶剂中过滤或离心氧联二邻苯二甲酸酐的热溶液以除去杂质，然后冷却溶液以沉淀氧联二邻苯二甲酸酐，从而可以通过过滤或离心从溶液中除去。

10. 发明授权

US4680371A Preparation of aromatic polyester with improved stability by addition of phosphite during preparation 失效
标题翻译：通过在制备过程中加入亚磷酸酯制备具有改善的稳定性的芳族聚酯
公开(公告)号：US4680371A
公开(公告)日：1987-07-14
申请号：US833870
申请日：1986-02-25
申请人： Jerold C. Rosenfeld , Joseph A. Pawlak
发明人： Jerold C. Rosenfeld , Joseph A. Pawlak
IPC分类号： C08L67/00 , C08G63/18 , C08G63/19 , C08G63/692 , C08G63/78 , C08G63/87 , C08K5/52 , C08K5/526 , C08G63/22
CPC分类号： C08G63/87 , C08K5/526
摘要： A process for preparing an aromatic polyester derived from aromatic dicarboxylic acid and bisphenol includes adding a phosphite stabilizer to reduce coloration and reduce loss of intrinsic viscosity of the aromatic polyester to a molten mixture of the monomeric reactants or prepolymer.
摘要翻译：制备由芳族二羧酸和双酚衍生的芳族聚酯的方法包括加入亚磷酸酯稳定剂以减少着色并降低芳族聚酯对单体反应物或预聚物的熔融混合物的特性粘度的损失。

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