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1. 发明授权

US06617478B2 Process for preparing a 1,3-alkandiol from 3-hydroxyester 失效
标题翻译：从3-羟基酯制备1,3-链二醇的方法
公开(公告)号：US06617478B2
公开(公告)日：2003-09-09
申请号：US10212671
申请日：2002-08-06
申请人： Byeong No Lee , In Sun Jung , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han
发明人： Byeong No Lee , In Sun Jung , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han
IPC分类号： C07C2700
CPC分类号： B01J23/72 , B01J21/08 , B01J23/8892 , B01J37/0009 , B01J37/03 , B01J37/18 , C07C29/149 , C07C31/205
摘要： A process for preparing a 1,3-alkandiol from a 3-hydroxyester, comprises preparing a catalyst by adding an alkaline precipitator to an aqueous copper salt solution to form copper hydroxide particles, and aging the particles following the addition of a colloidal silica thereto; activating the catalyst by reduction with a H2 gas or a H2-containing gas and applying a pressure of about 5 psig to about 2000 psig at a temperature of about 100° C. to about 250° C. in the presence of an activation solvent; and hydrogenating a 3-hydroxyester in a liquid phase slurry with a H2 gas or a H2-containing gas and applying a pressure of about 50 psig to about 3000 psig at a temperature of about 100° C. to about 250° C. in the presence of the activated catalyst and a reaction solvent, whereby a 1,3-alkanediol can be selectively prepared from a 3-hydroxyester with a high yield.
摘要翻译：从3-羟基酯制备1,3-二醇的方法包括通过向铜盐水溶液中加入碱性沉淀器来制备催化剂以形成氢氧化铜颗粒，并且在加入胶体二氧化硅后使颗粒老化; 通过用H 2气体或含H 2气体还原并在约100psi至约250℃的温度下在活化溶剂的存在下施加约5psig至约2000psig的压力来活化催化剂; 并用氢气或含H 2气体在液相浆料中氢化3-羟基酯，并在约100℃至约250℃的温度下施加约50psig至约3000psig的压力存在活化的催化剂和反应溶剂，从而可以高产率从3-羟基酯选择性地制备1,3-链烷二醇。

2. 发明授权

US06617477B2 Process for preparing 1,3-alkanediols from 3-hydroxyesters 失效
公开(公告)号：US06617477B2
公开(公告)日：2003-09-09
申请号：US09995798
申请日：2001-11-29
申请人： Byeong No Lee , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han , Hyun Kwan Shin , Ho Sun Lee
发明人： Byeong No Lee , Eun Joo Jang , Jung Ho Lee , Hyung Rok Kim , Yo Han Han , Hyun Kwan Shin , Ho Sun Lee
IPC分类号： C07C2700
CPC分类号： C07C29/149 , B01J23/72 , C07C31/205
摘要： A process for preparing an 1,3-alkanediol from a 3-hydroxyester includes hydrogenating a 3-hydroxyester in an alcohol-containing solvent in the presence of a hydrogenation catalyst prepared by adding an alkaline precipitator to an aqueous solution containing a copper salt to form particles, and then aging the particles following addition of colloidal silica thereto. Novel hydrogenation catalysts so prepared are also disclosed.

3. 发明授权

US06465680B2 Process for preparing malonate derivatives or &bgr;-keto esters from epoxide derivatives 失效
标题翻译：由环氧化物衍生物制备丙二酸酯衍生物或β-酮酯的方法
公开(公告)号：US06465680B2
公开(公告)日：2002-10-15
申请号：US09884440
申请日：2001-06-20
申请人： Byeong No Lee , In-Sun Jung , Eun Joo Jang
发明人： Byeong No Lee , In-Sun Jung , Eun Joo Jang
IPC分类号： C07C6966
CPC分类号： C07C67/313 , C07C67/37 , C07C69/38 , C07C69/716 , C07C69/675
摘要： A process for preparing a malonic acid monoester or &bgr;-ketoester from an epoxide includes the steps of reacting an epoxide with carbon monoxide and an alcohol in the presence of a catalytic amount of a cobalt compound and at least one promoter to produce a &bgr;-hydroxyester, separating the &bgr;-hydroxyester from the cobalt compound and the promoter, and oxidizing the &bgr;-hydroxyester to produce a malonic acid monoester or &bgr;-ketoester.
摘要翻译：从环氧化物制备丙二酸单酯或β-酮酯的方法包括以下步骤：在催化量的钴化合物和至少一种助催化剂的存在下使环氧化物与一氧化碳和醇反应，生成β-羟基酯将β-羟基酯与钴化合物和助催化剂分离，并氧化β-羟基酯以产生丙二酸单酯或β-酮酯。

4. 发明授权

US06600065B2 Process for preparing 3-hydroxyesters from epoxide derivatives 失效
标题翻译：从环氧化物衍生物制备3-羟基酯的方法
公开(公告)号：US06600065B2
公开(公告)日：2003-07-29
申请号：US10272380
申请日：2002-10-17
申请人： Byeong No Lee , Eun Joo Jang , Hyung Soo Cho , Byung Soon Chun
发明人： Byeong No Lee , Eun Joo Jang , Hyung Soo Cho , Byung Soon Chun
IPC分类号： C07C6966
CPC分类号： C07C67/37 , C07C69/675
摘要： Disclosed herein is a novel process for preparing 3-hydroxyesters, comprising: (a) reacting an epoxide derivative with carbon monoxide and alcohol in a solvent at a temperature of 30˜150° C. under a pressure of 50˜3000 psig by using a catalyst system consisting of a catalytic amount of a cobalt compound and optionally an effective amount of a promoter to produce a 3-hydroxyester or a derivative thereof; (b) separating the resulting product and the solvent from the cobalt compound and the promoter in a stripping column at a temperature of −30˜200° C. in an atmosphere of a stabilizing gas; and (c) recycling a part or all of the separated cobalt compound and promoter to the step (a) and repeating the steps (a) through (c).
摘要翻译：本文公开了一种制备3-羟基酯的新方法，其包括：（a）使环氧化物衍生物与一氧化碳和醇在溶剂中在30〜150℃的温度下在50〜3000psig的压力下反应，催化剂体系由催化量的钴化合物和任选的有效量的助催化剂组成，以产生3-羟基酯或其衍生物; （b）在稳定气体的气氛中，在-30〜200℃的温度下，将得到的产物和溶剂与汽提塔中的钴化合物和助催化剂分离; 和（c）将部分或全部分离的钴化合物和促进剂再循环到步骤（a）并重复步骤（a）至（c）。

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