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1. 发明申请

US20050228080A1 Halogen containing epoxy compositions and their preparation 有权
标题翻译：含卤素环氧组合物及其制备方法
公开(公告)号：US20050228080A1
公开(公告)日：2005-10-13
申请号：US11103947
申请日：2005-04-12
申请人： Bryan Bilyeu , Witold Brostow , Kevin Menard
发明人： Bryan Bilyeu , Witold Brostow , Kevin Menard
IPC分类号： C08G59/18 , C08G59/50 , C08G59/56 , C08L63/00 , C09D163/00
CPC分类号： C08G59/18 , C08G59/5006 , C08G59/504 , C09D163/00
摘要： One aspect of the current invention is a halogen containing epoxy composition and a method of producing the same. A functional halogen group, fluorine in one case, is incorporated into an epoxy coating by using a functionalized amine curing agent in small amounts. Functionalized amine curing agents are cheaper and easier to produce from small amine precursors when compared to the cost and complexity of functionalizing bulky epoxy resins. Amine curing agents are incorporated into a cured epoxy network. However, many functional groups will affect the reactivity of the curing reaction due to electronegativity effects. By using small amounts of functionalized amines with a large amount of non-functionalized agent, the effect is small and in the case of migration, it can be advantageous for tribological, mechanical and other properties of epoxies and epoxy-containing materials. Additionally, in stratified coatings, it is advantageous to use smaller functionalized amine molecules that can migrate more quickly into the composition before the composition becomes fully cured.
摘要翻译：本发明的一个方面是含卤素的环氧组合物及其制造方法。通过使用官能化的胺固化剂少量将功能性卤素基团，一种氟化合物引入到环氧涂料中。与官能化的大型环氧树脂的成本和复杂性相比，官能化胺固化剂比小胺前体更便宜，更容易生产。胺固化剂掺入固化环氧树脂网络中。然而，由于电负性效应，许多官能团将影响固化反应的反应性。通过使用少量的官能化胺与大量的非官能化试剂，其效果很小，而在迁移的情况下，可能有利于环氧树脂和含环氧材料的摩擦学，机械性能和其它性能。另外，在分层涂层中，使用较小的官能化胺分子是有利的，其可以在组合物完全固化之前更快地迁移到组合物中。

2. 发明授权

US07868067B2 Composition of epoxy resin, aliphatic amine curing agent and halogenated amine 有权
标题翻译：环氧树脂，脂族胺固化剂和卤代胺的组成
公开(公告)号：US07868067B2
公开(公告)日：2011-01-11
申请号：US12401431
申请日：2009-03-10
申请人： Bryan Bilyeu , Witold Brostow , Kevin Menard
发明人： Bryan Bilyeu , Witold Brostow , Kevin Menard
IPC分类号： C08K7/02 , C08K7/14 , C08G59/50 , C08L63/02 , C08L63/04
CPC分类号： C08G59/18 , C08G59/5006 , C08G59/504 , C09D163/00
摘要： One aspect of the current invention is a halogen containing epoxy composition and a method of producing the same. A functional halogen group, fluorine in one case, is incorporated into an epoxy coating by using a functionalized amine curing agent in small amounts. Functionalized amine curing agents are cheaper and easier to produce from small amine precursors when compared to the cost and complexity of functionalizing bulky epoxy resins. Amine curing agents are incorporated into a cured epoxy network. However, many functional groups will affect the reactivity of the curing reaction due to electronegativity effects. By using small amounts of functionalized amines with a large amount of non-functionalized agent, the effect is small and in the case of migration, it can be advantageous for tribological, mechanical and other properties of epoxies and epoxy-containing materials. Additionally, in stratified coatings, it is advantageous to use smaller functionalized amine molecules that can migrate more quickly into the composition before the composition becomes fully cured.
摘要翻译：本发明的一个方面是含卤素的环氧组合物及其制造方法。通过使用官能化的胺固化剂少量将功能性卤素基团，一种氟化合物引入到环氧涂料中。与官能化的大型环氧树脂的成本和复杂性相比，官能化胺固化剂比小胺前体更便宜，更容易生产。胺固化剂掺入固化环氧树脂网络中。然而，由于电负性效应，许多官能团将影响固化反应的反应性。通过使用少量的官能化胺与大量的非官能化试剂，其效果很小，而在迁移的情况下，可能有利于环氧树脂和含环氧材料的摩擦学，机械性能和其它性能。另外，在分层涂层中，使用较小的官能化胺分子是有利的，其可以在组合物完全固化之前更快地迁移到组合物中。

3. 发明申请

US20090176932A1 Halogen containing epoxy compositions and their preparation 有权
标题翻译：含卤素环氧组合物及其制备方法
公开(公告)号：US20090176932A1
公开(公告)日：2009-07-09
申请号：US12401431
申请日：2009-03-10
申请人： Bryan Bilyeu , Witold Brostow , Kevin Menard
发明人： Bryan Bilyeu , Witold Brostow , Kevin Menard
IPC分类号： C08L71/02 , C08G59/14 , C08L61/06
CPC分类号： C08G59/18 , C08G59/5006 , C08G59/504 , C09D163/00
摘要： One aspect of the current invention is a halogen containing epoxy composition and a method of producing the same. A functional halogen group, fluorine in one case, is incorporated into an epoxy coating by using a functionalized amine curing agent in small amounts. Functionalized amine curing agents are cheaper and easier to produce from small amine precursors when compared to the cost and complexity of functionalizing bulky epoxy resins. Amine curing agents are incorporated into a cured epoxy network. However, many functional groups will affect the reactivity of the curing reaction due to electronegativity effects. By using small amounts of functionalized amines with a large amount of non-functionalized agent, the effect is small and in the case of migration, it can be advantageous for tribological, mechanical and other properties of epoxies and epoxy-containing materials. Additionally, in stratified coatings, it is advantageous to use smaller functionalized amine molecules that can migrate more quickly into the composition before the composition becomes fully cured.
摘要翻译：本发明的一个方面是含卤素的环氧组合物及其制造方法。通过使用官能化的胺固化剂少量将功能性卤素基团，一种氟化合物引入到环氧涂料中。与官能化的大型环氧树脂的成本和复杂性相比，官能化胺固化剂比小胺前体更便宜，更容易生产。胺固化剂掺入固化环氧树脂网络中。然而，由于电负性效应，许多官能团将影响固化反应的反应性。通过使用少量的官能化胺与大量的非官能化试剂，其效果很小，而在迁移的情况下，可能有利于环氧树脂和含环氧材料的摩擦学，机械性能和其它性能。另外，在分层涂层中，使用较小的官能化胺分子是有利的，其可以在组合物完全固化之前更快地迁移到组合物中。

4. 发明授权

US07501461B2 Composition of epoxy resin, aliphatic amine curing agent and halogenated amine 有权
标题翻译：环氧树脂，脂族胺固化剂和卤代胺的组成
公开(公告)号：US07501461B2
公开(公告)日：2009-03-10
申请号：US11103947
申请日：2005-04-12
申请人： Bryan Bilyeu , Witold Brostow , Kevin Menard
发明人： Bryan Bilyeu , Witold Brostow , Kevin Menard
IPC分类号： C08G59/50 , C08K7/14 , C08L63/00 , C08L63/02 , C08L63/04
CPC分类号： C08G59/18 , C08G59/5006 , C08G59/504 , C09D163/00
摘要： One aspect of the current invention is a halogen containing epoxy composition and a method of producing the same. A functional halogen group, fluorine in one case, is incorporated into an epoxy coating by using a functionalized amine curing agent in small amounts. Functionalized amine curing agents are cheaper and easier to produce from small amine precursors when compared to the cost and complexity of functionalizing bulky epoxy resins. Amine curing agents are incorporated into a cured epoxy network. However, many functional groups will affect the reactivity of the curing reaction due to electronegativity effects. By using small amounts of functionalized amines with a large amount of non-functionalized agent, the effect is small and in the case of migration, it can be advantageous for tribological, mechanical and other properties of epoxies and epoxy-containing materials. Additionally, in stratified coatings, it is advantageous to use smaller functionalized amine molecules that can migrate more quickly into the composition before the composition becomes fully cured.
摘要翻译：本发明的一个方面是含卤素的环氧组合物及其制造方法。通过使用官能化的胺固化剂少量将功能性卤素基团，一种氟化合物引入到环氧涂料中。与官能化的大型环氧树脂的成本和复杂性相比，官能化胺固化剂比小胺前体更便宜，更容易生产。胺固化剂掺入固化环氧树脂网络中。然而，由于电负性效应，许多官能团将影响固化反应的反应性。通过使用少量的官能化胺与大量的非官能化试剂，其效果很小，而在迁移的情况下，可能有利于环氧树脂和含环氧材料的摩擦学，机械性能和其它性能。另外，在分层涂层中，使用较小的官能化胺分子是有利的，其可以在组合物完全固化之前更快地迁移到组合物中。

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