专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US06984749B2 Method for inhibiting polymerization during the recovery and purification of unsaturated mononitriles 失效
标题翻译：在不饱和单腈回收和纯化期间抑制聚合的方法
公开(公告)号：US06984749B2
公开(公告)日：2006-01-10
申请号：US10309962
申请日：2002-12-04
申请人： Bruce I. Rosen , Bruce E. Firth
发明人： Bruce I. Rosen , Bruce E. Firth
IPC分类号： C07C255/03
CPC分类号： C07C253/26 , C07C253/32 , C07C255/08
摘要： Economical processes are disclosed for recovery and refining of valuable nitrogen-containing organic compounds formed by catalytic oxidation of least one feed compound selected from the group consisting of propane, propylene, isobutane and isobutylene in the presence of ammonia to produce a gaseous. Processes of the invention include quenching the gaseous reactor effluent with an aqueous quench liquid; forming an aqueous solution comprising the corresponding unsaturated mononitrile, hydrogen cyanide and other organic co-products; and using an integrated sequence of distillations and phase separations to recover for recycle of a useful aqueous liquid, and obtain the desired nitrogen-containing products. According to the invention aqueous solutions are fractionated in an integrated system of multi-stage columns while an effective polymerization inhibiting amount of at least one member of a preselected class of p-phenylenediamine compounds is maintained therein.
摘要翻译：公开了经济方法用于在氨的存在下通过催化氧化选自丙烷，丙烯，异丁烷和异丁烯的至少一种进料化合物形成的有价值的含氮有机化合物来回收和精炼以产生气体。本发明的方法包括用水淬火液淬火气态反应器流出物; 形成包含相应的不饱和单腈，氰化氢和其它有机副产物的水溶液; 并使用一体化的蒸馏和相分离序列来回收有用的含水液体的再循环，并获得所需的含氮产物。根据本发明，水溶液在多级柱的一体化系统中分级，同时保持有效聚合抑制量的至少一种预选类对苯二胺化合物。

2. 发明授权

US07282600B2 Method for inhibiting polymerization during the recovery and purification of unsaturated mononitriles 失效
标题翻译：在不饱和单腈回收和纯化期间抑制聚合的方法
公开(公告)号：US07282600B2
公开(公告)日：2007-10-16
申请号：US10852277
申请日：2004-05-24
申请人： Bruce I. Rosen , Bruce E. Firth
发明人： Bruce I. Rosen , Bruce E. Firth
IPC分类号： C07C255/08
CPC分类号： C07C253/26 , C07C253/32 , C07C255/08
摘要： Economical processes are disclosed for recovery and refining of valuable nitrogen-containing organic compounds formed by catalytic oxidation of least one feed compound selected from the group consisting of propane, propylene, isobutane and isobutylene in the presence of ammonia to produce a gaseous. Processes of the invention include quenching the gaseous reactor effluent with an aqueous quench liquid; forming an aqueous solution comprising the corresponding unsaturated mononitrile, hydrogen cyanide and other organic co-products; and using an integrated sequence of distillations and phase separations to recover for recycle of a useful aqueous liquid, and obtain the desired nitrogen-containing products. According to the invention aqueous solutions are fractionated in an integrated system of multi-stage columns while an effective polymerization inhibiting amount of at least one member of a preselected class of p-phenylenediamine compounds is maintained therein.
摘要翻译：公开了经济方法用于在氨的存在下通过催化氧化选自丙烷，丙烯，异丁烷和异丁烯的至少一种进料化合物形成的有价值的含氮有机化合物来回收和精炼以产生气体。本发明的方法包括用水淬火液淬火气态反应器流出物; 形成包含相应的不饱和单腈，氰化氢和其它有机副产物的水溶液; 并使用一体化的蒸馏和相分离序列来回收有用的含水液体的再循环，并获得所需的含氮产物。根据本发明，水溶液在多级柱的一体化系统中分级，同时保持有效聚合抑制量的至少一种预选类对苯二胺化合物。

3. 发明授权

US06284920B1 Aromatic acid monomers, polymers, products and processes for their manufacture 有权
标题翻译：芳香族酸单体，聚合物，产品及其制造方法
公开(公告)号：US06284920B1
公开(公告)日：2001-09-04
申请号：US09412458
申请日：1999-10-04
申请人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W. Bauer , Gary T. Brooks
发明人： Edward E. Paschke , Bruce I. Rosen , David A. Peterson , David E. James , Melvin L. Luetkens, Jr. , Charles W. Bauer , Gary T. Brooks
IPC分类号： C07C5109
CPC分类号： C08G63/189 , C07C51/265 , C07C51/42 , C07C63/38 , Y10T428/1352 , Y10T428/29 , Y10T428/2913
摘要： Processes for producing aromatic monomers useful for forming polyesters are disclosed. Cost effective steps employed in the processes permit small amounts of process-related materials typically removed from monomer to remain in an aromatic monomer product. In many cases, the presence of the process-related materials left in the monomer product by the cost effective process steps can enhance the performance of the monomer in certain applications. Aromatic monomer products and polymers produced therefrom having these advantages also are disclosed, as well as products such as pasteurizable bottles made from these polymers.
摘要翻译：公开了用于制备用于形成聚酯的芳族单体的方法。在该方法中使用的成本有效的步骤允许通常从单体中除去残留在芳族单体产物中的少量与工艺相关的材料。在许多情况下，通过成本有效的工艺步骤留在单体产品中的工艺相关材料的存在可以在某些应用中提高单体的性能。还公开了具有这些优点的芳族单体产物和由其制备的聚合物，以及由这些聚合物制成的诸如可巴氏消毒瓶的产品。

4. 发明授权

US4608215A Preparation of ceramics 失效
标题翻译：陶瓷的制备
公开(公告)号：US4608215A
公开(公告)日：1986-08-26
申请号：US565077
申请日：1983-12-23
申请人： Stephen T. Gonczy , Randy J. Lawson , Bruce I. Rosen
发明人： Stephen T. Gonczy , Randy J. Lawson , Bruce I. Rosen
IPC分类号： C01B33/22 , C04B35/20 , C04B35/14
CPC分类号： C04B35/20 , C01B33/22
摘要： Ceramic materials comprising steatite or forsterite which are highly dense in nature may be prepared by admixing a hydrolyzed alcoholic solution of a silicon alkoxide with a solution prepared by adding an organomagnesium compound to an alcohol at gelation conditions. Following the formation of the gel, it is then dried at an elevated temperature of from about 300.degree. to about 500.degree. C. to remove volatile compounds as well as to decompose any remaining organic compounds and thereafter the powder is pressed into a desired shape. The formed shape is then sintered at a temperature in the range of from about 850.degree. to about 950.degree. C. to form a densified ceramic.
摘要翻译：包含高密度性质的滑石或镁橄榄石的陶瓷材料可以通过将硅醇盐的水解醇溶液与通过在凝胶化条件下向醇中加入有机镁化合物而制备的溶液混合来制备。在形成凝胶之后，然后在约300℃至约500℃的高温下干燥以除去挥发性化合物以及分解任何剩余的有机化合物，然后将粉末压制成所需形状。然后将形成的形状在约850℃至约950℃的温度下烧结以形成致密的陶瓷。

5. 发明授权

US4424163A Selective reduction of edible fats and oils 失效
标题翻译：选择性还原食用油脂
公开(公告)号：US4424163A
公开(公告)日：1984-01-03
申请号：US338736
申请日：1982-01-11
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C11C3/12
CPC分类号： C11C3/123
摘要： Selective reductions of fatty materials occur using a catalyst consisting of essentially of zerovalent nickel dispersed on a support which shows strong metal, support interaction. A particularly desirable catalyst is one where the nickel is dispersed on titania which is subsequently activated in hydrogen at a temperature above about 325.degree. C. The catalyst is sufficiently selective so as to permit continuous reduction of fatty material using a fixed bed of catalyst.
摘要翻译：脂肪物质的选择性还原使用分散在显示强金属，载体相互作用的载体上的基本上由零价镍组成的催化剂发生。特别理想的催化剂是其中镍分散在二氧化钛上的催化剂，其随后在氢气中在约325℃以上的温度下活化。催化剂是充分选择性的，以便允许使用固定床催化剂连续还原脂肪材料。

6. 发明授权

US06747171B2 Low temperature purification of naphthalene dicarboxylic acids 有权
标题翻译：萘二羧酸的低温纯化
公开(公告)号：US06747171B2
公开(公告)日：2004-06-08
申请号：US09775025
申请日：2001-02-01
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C07C5142
CPC分类号： C07C51/487 , C07C63/38
摘要： A process for purifying a naphthalenic carboxylic acid comprising contacting at a temperature below about 575° F. a mixture comprising an impure naphthalenic carboxylic acid and a solvent in the presence of hydrogen gas with a noble metal on carbon catalyst. The process results in reduced amounts of organic impurities in the purified acid when compared to other purification processes.
摘要翻译：一种纯化萘羧酸的方法，包括在低于约575°F的温度下将含有不纯的萘甲酸和溶剂的混合物在氢气存在下与贵金属在碳催化剂上接触。与其他纯化方法相比，该方法导致纯化酸中有机杂质的量减少。

7. 发明授权

US5453538A Process for the manufacture of aromatic dicarboxylic acids utilizing cerium to facilitate a low bromine to metals catalyst ratio 失效
标题翻译：利用铈制造芳族二羧酸的方法，以促进低溴与金属的催化比
公开(公告)号：US5453538A
公开(公告)日：1995-09-26
申请号：US195274
申请日：1994-02-14
申请人： Jeffrey L. Broeker , Walter Partenheimer , Bruce I. Rosen
发明人： Jeffrey L. Broeker , Walter Partenheimer , Bruce I. Rosen
IPC分类号： B01J31/04 , C07C51/265 , B01J31/00
CPC分类号： B01J31/0231 , B01J31/04 , C07C51/265 , B01J2231/70 , B01J2531/38 , B01J2531/72 , B01J2531/845
摘要： A process for the manufacture of aromatic dicarboxylic acids is disclosed using a low bromine to metals ratio facilitated by the use of cerium along with the cobalt and manganese catalyst. Aromatic dicarboxylic acids such as terephthalic acid are useful in the manufacture of fiber, films, bottles and molded products.
摘要翻译：公开了一种制备芳族二羧酸的方法，其中通过使用铈以及钴和锰催化剂促进了低溴与金属的比例。芳族二羧酸如对苯二甲酸可用于制造纤维，薄膜，瓶子和模制产品。

8. 发明授权

US5095145A Preparation of purified terephthalic acid from waste polyethylene terephthalate 失效
标题翻译：从废聚对苯二甲酸乙二醇酯制备纯化的对苯二甲酸
公开(公告)号：US5095145A
公开(公告)日：1992-03-10
申请号：US609202
申请日：1990-11-05
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C07C51/09
CPC分类号： C07C51/09 , C08J11/14 , C08J2367/02 , Y02W30/704
摘要： A process is disclosed for producing fiber-grade terephthalic acid from waste polyethylene terephthalate film, fiber, bottles, manufacturing residues, and other manufactured articles. The process comprises depolymerizing waste polyethylene terephthalate in an aqueous mixture to obtain crude terephthalic acid having a b*-value less than 10.00 and an RFCVIS value of about 5000, or greater, which is thereupon hydrogenated in aqueous solution for a period of up to 8 hours. Organic and inorganic impurities are retained in the aqueous components. The purified terephthalic acid has a b*-value less than 2.00, a relative fluorescence concentration in visible light (RFCVIS) of less than 2500, metals content less than 100 ppmw and total organic impurities of less than 1000 ppmw.
摘要翻译：公开了一种从废聚对苯二甲酸乙二醇酯膜，纤维，瓶，制造残余物和其它制品制造纤维级对苯二甲酸的方法。该方法包括将废聚对苯二甲酸乙二醇酯解聚在水性混合物中以获得具有小于10.00的ab *值的粗对苯二甲酸和约5000或更大的RFCVIS值，然后在水溶液中氢化至多8小时。有机和无机杂质保留在水性组分中。纯化的对苯二甲酸具有小于2.00的b *值，可见光（RFCVIS）中的相对荧光浓度小于2500，金属含量小于100ppmw，总有机杂质小于1000ppmw。

9. 发明授权

US4510092A Continuous reduction of edible oils 失效
标题翻译：持续减少食用油
公开(公告)号：US4510092A
公开(公告)日：1985-04-09
申请号：US360114
申请日：1982-03-19
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： B01J21/04 , B01J23/755 , C11C3/12
CPC分类号： C11C3/123 , B01J21/04 , B01J23/755 , B01J35/1009 , B01J35/108
摘要： A method of continuously hydrogenating fatty materials over a fixed catalyst bed utilizes zerovalent nickel on alpha-alumina. Partial hydrogenation of soybean oil to an IV of about 110 can be successfully performed using alpha-alumina of surface area less than about 5 m.sup.2 /g to afford a product whose SFI is acceptable for end product use.
摘要翻译：在固定催化剂床上连续氢化脂肪材料的方法在α-氧化铝上使用零价镍。可以使用表面积小于约5m 2 / g的α-氧化铝成功地进行大豆油部分氢化至约110的IV，以得到SFI对于最终产品使用是可接受的产品。

10. 发明授权

US4401639A Preparation of carbonyl cyanide 失效
标题翻译：羰基氰的制备
公开(公告)号：US4401639A
公开(公告)日：1983-08-30
申请号：US391752
申请日：1982-06-24
申请人： Bruce I. Rosen
发明人： Bruce I. Rosen
IPC分类号： C01C3/14
CPC分类号： C01C3/14
摘要： Carbonyl cyanide may be prepared by reacting a solution of a trihalomethyl haloformate in an organic solvent with a cyanide salt in the presence of a phase transfer catalyst. Carbonyl cyanide may be prepared by this method in good yield and with great convenience.
摘要翻译：羰基氰化物可以通过在相转移催化剂存在下使卤代甲酸三卤甲酯在有机溶剂中与氰化物盐的溶液反应来制备。羰基氰可以通过该方法以良好的产率和极大的方便性制备。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式