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1. 发明授权

US5367012A Stabilizer for glass/polymer alloys 失效
标题翻译：玻璃/聚合物合金稳定剂
公开(公告)号：US5367012A
公开(公告)日：1994-11-22
申请号：US100835
申请日：1993-08-09
申请人： Bruce G. Aitken , Dana C. Bookbinder , James E. Dickinson, Jr. , Brent M. Wedding
发明人： Bruce G. Aitken , Dana C. Bookbinder , James E. Dickinson, Jr. , Brent M. Wedding
IPC分类号： C03C3/16 , C03C14/00 , C08K3/00 , C08K3/22 , C08K3/26 , C08K3/40 , C08L101/00 , C08K3/32 , C08L23/00 , C08L67/00 , C08L71/00
CPC分类号： C03C14/00 , C08K3/22 , C08K3/26 , C08K3/40 , C03C2214/12
摘要： This invention is directed to an alloy, and a method of producing an alloy, of increased resistance to moisture, comprising a melt mixture of at least one phosphate glass, at least one organic thermoplastic or thermosetting polymer, and an amount of a water soluble stabilizer component which provides a source of metal cations having a valency of 2.sup.+ or higher The amount of the stabilizer component added is that amount effective to improve the alloy's resistance to moisture. Preferably, the alloy is comprised of: (a) 5-80% of the matrix material; (b) 15-90% of the phosphate glass; and, (c) 0.1 to 40% of the stabilizer component. Additionally, the metal cations which are found in the stabilizer component and which form part of the insoluble surface layer are preferably selected from the group consisting of Ba.sup.2+, Mg.sup.2+, Ca.sup.2+, Al.sup.3+, Zn.sup.2+, Sr.sup.+2 and Fe.sup.3+.
摘要翻译：本发明涉及一种具有增加的抗水分性的合金和合金的制造方法，包括至少一种磷酸盐玻璃，至少一种有机热塑性或热固性聚合物的熔融混合物和一定量的水溶性稳定剂提供具有2+或更高价态的金属阳离子源的组分。添加的稳定剂组分的量是有效改善合金耐湿性的量。优选地，该合金由以下组成：（a）5-80％的基质材料; （b）15-90％的磷酸盐玻璃; 和（c）0.1〜40％的稳定剂成分。此外，在稳定剂组分中发现并形成不溶性表面层的一部分的金属阳离子优选选自Ba2 +，Mg2 +，Ca2 +，Al3 +，Zn2 +，Sr +2和Fe3 +。

2. 发明授权

US5246890A Non-lead sealing glasses 失效
标题翻译：非铅密封眼镜
公开(公告)号：US5246890A
公开(公告)日：1993-09-21
申请号：US924107
申请日：1992-08-03
申请人： Bruce G. Aitken , Dana C. Bookbinder , Margaret E. Greene , Robert M. Morena
发明人： Bruce G. Aitken , Dana C. Bookbinder , Margaret E. Greene , Robert M. Morena
IPC分类号： C03C3/062 , C03C3/16 , C03C3/17 , C03C3/19 , C03C8/08 , C03C8/24 , C03C10/00 , H01J9/26
CPC分类号： C03C10/00 , C03C3/062 , C03C3/16 , C03C3/17 , C03C3/19 , C03C8/24
摘要： Lead-free, SnO-ZnO-P.sub.2 O.sub.5 glasses contain 25-50 mole percent P.sub.2 O.sub.5 and SnO and ZnO in amounts such that the mole ratio of SnO:ZnO is in the range of 1:1 to 5:1. Optionally, the glasses may contain up to 20 mole percent of modifying oxides including up to 5 mole percent SiO.sub.2, up to 20 mole percent B.sub.2 O.sub.3 and up to 5 mole percent Al.sub.2 O.sub.3, as well as one or more crystallization promoters selected from 1-5 mole percent zircon and/or zirconia and 1-15 mole percent R.sub.2 O. The glasses are particularly useful as sealing glass frits in sealing material to join component parts in articles such as cathode ray tubes. The sealing glass material may contain mill additions to reduce the effective coefficient of thermal expansion in a seal.

3. 发明授权

US08148179B2 Hermetically sealed glass package and method of fabrication 有权
标题翻译：密封玻璃包装及其制造方法
公开(公告)号：US08148179B2
公开(公告)日：2012-04-03
申请号：US12725648
申请日：2010-03-17
申请人： Bruce G. Aitken , Paul S. Danielson , James E. Dickinson, Jr. , Stephan L. Logunov , Robert Morena , Mark L. Powley , Kamjula P. Reddy , Joseph F. Schroeder, III , Alexander Streltsov
发明人： Bruce G. Aitken , Paul S. Danielson , James E. Dickinson, Jr. , Stephan L. Logunov , Robert Morena , Mark L. Powley , Kamjula P. Reddy , Joseph F. Schroeder, III , Alexander Streltsov
IPC分类号： H01L21/00
CPC分类号： C03B23/245 , C03C3/091 , C03C3/093 , C03C3/108 , C03C8/04 , C03C8/10 , C03C8/24 , C03C27/06 , H01L51/524 , H01L51/5246
摘要： A hermetically sealed glass package and method for manufacturing the hermetically sealed glass package are described herein using an OLED display as an example. In one embodiment, the hermetically sealed glass package is manufactured by providing a first substrate plate and a second substrate plate. The second substrate contains at least one transition or rare earth metal such as iron, copper, vanadium, manganese, cobalt, nickel, chromium, neodymium and/or cerium. A sensitive thin-film device that needs protection is deposited onto the first substrate plate. A laser is then used to heat the doped second substrate plate in a manner that causes a portion of it to swell and form a hermetic seal that connects the first substrate plate to the second substrate plate and also protects the thin film device. The second substrate plate is doped with at least one transition metal such that when the laser interacts with it there is an absorption of light from the laser in the second substrate plate, which leads to the formation of the hermetic seal while avoiding thermal damage to the thin-film device. Another embodiment of the hermetically sealed glass package and a method for manufacturing that hermetically sealed glass package are also described herein.
摘要翻译：这里使用OLED显示器作为示例来描述气密密封的玻璃封装和制造密封玻璃封装的方法。在一个实施例中，通过提供第一基板和第二基板制造密封的玻璃封装。第二基板包含至少一种过渡金属或稀土金属，例如铁，铜，钒，锰，钴，镍，铬，钕和/或铈。需要保护的敏感薄膜器件沉积到第一衬底板上。然后使用激光器以使其一部分膨胀并形成将第一衬底板连接到第二衬底板的气密密封件并且还保护薄膜器件的方式来加热掺杂的第二衬底板。第二衬底板掺杂有至少一种过渡金属，使得当激光与其相互作用时，吸收来自第二衬底板中的激光的光，这导致气密密封的形成，同时避免对薄膜装置。本文还描述了密封玻璃封装的另一个实施例以及密封玻璃封装的制造方法。

4. 发明授权

US5529961A Cuprous pyrophosphate glasses 失效
标题翻译：焦磷酸铜眼镜
公开(公告)号：US5529961A
公开(公告)日：1996-06-25
申请号：US367465
申请日：1994-12-30
申请人： Bruce G. Aitken , George H. Beall , James E. Dickinson, Jr.
发明人： Bruce G. Aitken , George H. Beall , James E. Dickinson, Jr.
IPC分类号： C03C3/16 , C03C3/17 , C03C3/19 , C03C3/21
CPC分类号： C03C3/16
摘要： The subject invention is directed at glasses wherein either a portion of the ZnO or alkali metals, or both, is replaced by Cu.sub.2 O, i.e., monovalent copper. Specifically, the present invention is directed at a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, 28-42% P.sub.2 O.sub.5, 15-30% Cu.sub.2 O, 10-30% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-15% Li.sub.2 O, 0-20% Na.sub.2 O, and 0-10% K.sub.2 O, and up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-2% Ln.sub.2 O.sub.3, 0-10 Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3, 0-10 Fe.sub.2 O.sub.3 0-10% Al.sub.2 O.sub.3 +B.sub.2 O.sub.3 +Fe.sub.2 O.sub.3, 0-7% MoO.sub.3 0-7% WO.sub.3 0-7% MoO.sub.3 +WO.sub.3, and 0-8% F, the latter as analyzed in weight percent. In addition, it is necessary that the predominate proportion of the copper in the glass is present in the cuprous or Cu.sup.+ oxidation state. These inventive glasses exhibit a transition temperature normally below about 300.degree. C., a working temperature below about 400.degree. C., while, at the same time, exhibiting excellent resistance to attack by water.
摘要翻译：本发明涉及其中一部分ZnO或碱金属或两者都被Cu 2 O替代的玻璃，即一价铜。具体地说，本发明涉及基本上由以氧化物为基准的摩尔百分数表示的玻璃，28-42％的P2O5，15-30％的Cu2O，10-30％的R2O，其中R2O选自由0-15％的Li 2 O，0〜20％的Na 2 O和0〜10％的K 2 O组成，最多可以以指定的比例选择总量为45％的选自0-10％的Al 2 O 3， 15％MgO，0-20％CaO，0-20％SrO，0-20％BaO，0-25％MgO + CaO + SrO + BaO，0-35％ZnO，0-10％MnO，0-2％ CeO2,0-2％Ln2O3,0-10Al2O3 0-10％B2O3,0-10Fe2O3 0-10％Al2O3 + B2O3 + Fe2O3,0-7％MoO3 0-7％WO3 0-7％MoO3 + WO3，和0-8％F，后者以重量百分比分析。此外，玻璃中铜的主要比例必须以亚铜或Cu +氧化态存在。这些本发明的玻璃的转变温度通常低于约300℃，工作温度低于约400℃，同时表现出优异的耐水侵蚀性。

5. 发明授权

US5529960A Cuprous metaphosphate glasses 失效
标题翻译：亚硫酸偏磷酸盐眼镜
公开(公告)号：US5529960A
公开(公告)日：1996-06-25
申请号：US367466
申请日：1994-12-30
申请人： Bruce G. Aitken , George H. Beall , James E. Dickinson, Jr.
发明人： Bruce G. Aitken , George H. Beall , James E. Dickinson, Jr.
IPC分类号： C03C3/17 , C03C3/21 , C03C3/16 , C03C3/19
CPC分类号： C03C3/21 , C03C3/17
摘要： The subject invention is directed at wherein either a portion of the ZnO or alkali metals, or both, found in prior art glasses, is replaced by Cu.sub.2 O, i.e., cuprous or monovalent copper. In addition to the Cu.sub.2 O substitution, the inventive glass contains a required metal oxide constituent which is necessary to enhance durability. More specifically, the present invention discloses a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, of about 42-54% P.sub.2 O.sub.5, 10-30% Cu.sub.2 O, 10-30% R.sub. O and 3-12% of a component selected from the group consisting of 0-7% MoO.sub.3, 0-10 Fe.sub.2 O.sub.3, 0-10% Al.sub.2 O.sub.3 and 0-7%WO.sub.3. In addition, the composition includes up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-10% B.sub.2 O.sub.3, 0-2% Ln.sub.2 O.sub.3 , 0-8% F, the latter as analyzed in weight percent. The R.sub.2 O constituent is selected from the group consisting of 0-15% Li.sub.2 O, 0-20% Na.sub.2 O, and 0-10% K.sub.2 O. Furthermore, the Al.sub.2 O.sub.3 +Fe.sub.2 O.sub.3 does not exceed 10% and the MoO.sub.3 +WO.sub.3 does not exceed 7%. One final requirement of the glass is that the predominate proportion of the copper is present in the Cu.sup.+ or monovalent oxidation state.
摘要翻译：本发明涉及其中在现有技术的玻璃中发现的ZnO或碱金属的一部分或两者的一部分被Cu 2 O替代，即亚铜或一价铜。除了Cu2O的取代之外，本发明的玻璃还含有必要的金属氧化物成分，这是提高耐久性所必需的。更具体地说，本发明公开了一种玻璃，其基本上由以氧化物为基准的摩尔百分数表示，约42-54％的P 2 O 5，10-30％的Cu 2 O，10-30％的RO和3-12％的选自0-7％MoO 3，0-10 Fe 2 O 3，0-10％Al 2 O 3和0-7％WO 3的组分。此外，该组合物包含至多总计45％的任选成分，所指定的比例选自0-15％MgO，0-20％CaO，0-20％SrO，0-20％BaO， 0-25％MgO + CaO + SrO + BaO，0-35％ZnO，0-10％MnO，0-2％CeO 2，0-10％B 2 O 3，0-2％Ln 2 O 3，0-8％F 按重量百分比分析。 R2O成分选自0-15％Li2O，0-20％Na2O和0-10％K2O。此外，Al2O3 + Fe2O3不超过10％，MoO3 + WO3不超过7％。玻璃的一个最终要求是铜的主要比例存在于Cu +或一价氧化态中。

6. 发明申请

US20100186449A1 HERMETICALLY SEALED GLASS PACKAGE AND METHOD OF FABRICATION 有权
标题翻译：密封玻璃包装和制造方法
公开(公告)号：US20100186449A1
公开(公告)日：2010-07-29
申请号：US12725648
申请日：2010-03-17
申请人： Bruce G. Aitken , Paul S. Danielson , James E. Dickinson, JR. , Stephan L. Longunov , Robert Morena , Mark L. Powley , Kamjula P. Reddy , Joseph F. Schroeder, III , Alexander Streltsov
发明人： Bruce G. Aitken , Paul S. Danielson , James E. Dickinson, JR. , Stephan L. Longunov , Robert Morena , Mark L. Powley , Kamjula P. Reddy , Joseph F. Schroeder, III , Alexander Streltsov
IPC分类号： C03B29/00
CPC分类号： C03B23/245 , C03C3/091 , C03C3/093 , C03C3/108 , C03C8/04 , C03C8/10 , C03C8/24 , C03C27/06 , H01L51/524 , H01L51/5246
摘要： A hermetically sealed glass package and method for manufacturing the hermetically sealed glass package are described herein using an OLED display as an example. In one embodiment, the hermetically sealed glass package is manufactured by providing a first substrate plate and a second substrate plate. The second substrate contains at least one transition or rare earth metal such as iron, copper, vanadium, manganese, cobalt, nickel, chromium, neodymium and/or cerium. A sensitive thin-film device that needs protection is deposited onto the first substrate plate. A laser is then used to heat the doped second substrate plate in a manner that causes a portion of it to swell and form a hermetic seal that connects the first substrate plate to the second substrate plate and also protects the thin film device. The second substrate plate is doped with at least one transition metal such that when the laser interacts with it there is an absorption of light from the laser in the second substrate plate, which leads to the formation of the hermetic seal while avoiding thermal damage to the thin-film device. Another embodiment of the hermetically sealed glass package and a method for manufacturing that hermetically sealed glass package are also described herein.
摘要翻译：这里使用OLED显示器作为示例来描述气密密封的玻璃封装和制造密封玻璃封装的方法。在一个实施例中，通过提供第一基板和第二基板制造密封的玻璃封装。第二基板包含至少一种过渡金属或稀土金属，例如铁，铜，钒，锰，钴，镍，铬，钕和/或铈。需要保护的敏感薄膜器件沉积到第一衬底板上。然后使用激光器以使其一部分膨胀并形成将第一衬底板连接到第二衬底板的气密密封件并且还保护薄膜器件的方式来加热掺杂的第二衬底板。第二衬底板掺杂有至少一种过渡金属，使得当激光与其相互作用时，吸收来自第二衬底板中的激光的光，这导致气密密封的形成，同时避免对薄膜装置。本文还描述了密封玻璃封装的另一个实施例以及密封玻璃封装的制造方法。

7. 发明申请

US20100099546A1 TRANSPARENT, COLORLESS TITANIA-FREE BETA-QUARTZ GLASS-CERAMIC 有权
标题翻译：透明，无色TITANIA-FREE BETA-QUARTZ玻璃陶瓷
公开(公告)号：US20100099546A1
公开(公告)日：2010-04-22
申请号：US12516892
申请日：2006-11-29
申请人： Bruce G. Aitken , Marie Jacqueline Monique Comte , Lothar Wondraczek
发明人： Bruce G. Aitken , Marie Jacqueline Monique Comte , Lothar Wondraczek
IPC分类号： C03C10/14 , C03C3/097 , C03C3/095 , C03C3/083 , C03C3/085 , C03B5/00 , C03B19/00
CPC分类号： C03C10/0027
摘要： The invention relates to a transparent and essentially colorless β-quartz glass-ceramic material which is free of TiO2, As2O3, Sb2O3 and phosphates; articles formed from said glass-ceramic material; lithium aluminosilicate glasses, precursors for said glass-ceramic material; and methods of producing said glass-ceramic material and said articles formed from said glass-ceramic material.
摘要翻译：本发明涉及透明且基本上无色的石英玻璃陶瓷材料，其不含TiO 2，As 2 O 3，Sb 2 O 3和磷酸盐; 由所述玻璃 - 陶瓷材料形成的制品; 铝硅酸锂玻璃，所述玻璃 - 陶瓷材料的前体; 以及由所述玻璃 - 陶瓷材料制成所述玻璃 - 陶瓷材料和所述制品的方法。

8. 发明授权

US06656859B2 Tellurite glasses and optical components 有权
公开(公告)号：US06656859B2
公开(公告)日：2003-12-02
申请号：US10016337
申请日：2001-12-06
申请人： Bruce G. Aitken , Adam J. G. Ellison , Randall E. Youngman
发明人： Bruce G. Aitken , Adam J. G. Ellison , Randall E. Youngman
IPC分类号： C03C312
CPC分类号： C03C4/12 , C03C3/122 , C03C13/048 , G02B6/02 , H01S3/177
摘要： A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.

9. 发明授权

US06503859B1 Molecular, inorganic glasses 有权
标题翻译：分子，无机眼镜
公开(公告)号：US06503859B1
公开(公告)日：2003-01-07
申请号：US09894587
申请日：2001-06-28
申请人： Bruce G. Aitken
发明人： Bruce G. Aitken
IPC分类号： C03C332
CPC分类号： C03C3/321 , C03C4/10
摘要： The invention resides in a molecular, inorganic glass and a method of making the glass, the glass being vitreous and resistant to devitrification, that is composed, in substantial part at least, of thermally-stable, zero-dimensional clusters or molecules, composed of four atoms of arsenic and three atoms of sulfur, the glass further containing up to 12 atomic percent of germanium, adjoining clusters being bonded to each other primarily by van der Waals forces, and at least 95% of the glass composition consisting of 42-60% arsenic, 37-48% sulfur plus selenium, the selenium being 0-14%.
摘要翻译：本发明在于一种分子，无机玻璃和一种制造玻璃，玻璃是玻璃体并且耐失透的方法，其至少部分地由热稳定的零维簇或分子组成，其由四个原子的砷和三个原子的硫，玻璃还含有最多12原子％的锗，相邻的簇主要通过范德华力彼此结合，并且至少95％的玻璃组合物由42-60 ％砷，37-48％硫加硒，硒为0-14％。

10. 发明授权

US5021366A Fluorine-free phosphate glasses 失效
标题翻译：无氟磷酸盐玻璃
公开(公告)号：US5021366A
公开(公告)日：1991-06-04
申请号：US599751
申请日：1990-10-19
申请人： Bruce G. Aitken
发明人： Bruce G. Aitken
IPC分类号： C03C3/16 , C03C3/17
CPC分类号： C03C3/17 , C03C3/16 , Y10S501/90 , Y10S501/903
摘要： This invention is drawn particularly to the production of glasses having essentially fluorine-free compositions consisting essentially, in mole percent, of:______________________________________ Li.sub.2 O 5-10 P.sub.2 O.sub.5 30-36 Na.sub.2 O 5-15 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-6 CeO.sub.2 0-2 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 15-25 SnO 0-20 ZnO 10-33 PbO 0-20 CaO 0-20 Sb.sub.2 O.sub.3 0-12 SrO 0-20 Bi.sub.2 O.sub.3 0-6 BaO 0-20 SnO + PbO + 0-20. Sb.sub.2 O.sub.3 + Bi.sub.2 O.sub.3 CaO + SrO + BaO 12-25 ______________________________________

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