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1. 发明授权

US6045661A Process and apparatus for recovering diluent, monomer, and comonomer from a polymerization reactor effluent 失效
标题翻译：用于从聚合反应器流出物回收稀释剂，单体和共聚单体的方法和设备
公开(公告)号：US6045661A
公开(公告)日：2000-04-04
申请号：US82398
申请日：1998-05-20
申请人： Bruce E. Kreischer , Donald W. Verser , James E. Hein
发明人： Bruce E. Kreischer , Donald W. Verser , James E. Hein
IPC分类号： B01D3/06 , B01D3/14 , C08F6/00
CPC分类号： C08F6/003 , B01D3/06 , B01D3/146
摘要： A process and apparatus are provided for recovering diluent, unreacted monomer, and unreacted comonomer from a polymerization reactor effluent. The comonomer has a boiling point higher than the boiling point of the monomer and the diluent has a boiling point between the boiling points of the monomer and comonomer. The process and apparatus employ at least one flash tank, a first fractionation stage including a first column and operating at a first fractionation pressure, and a second fraction stage including a second column and operating at a higher second fractionation pressure. Comonomer is withdrawn from the first column as a fractionation product, and overhead vapor containing diluent and monomer is substantially condensed to yield a substantially condensed overhead stream. Liquid and vapor from the stream are separated in an accumulator. Vapor and liquid from the accumulator are compressed and pumped, respectively, for delivery to the second fractionation stage at approximately the second fractionation pressure. The pumped liquid is a major portion by weight of the total flow of pumped liquid and compressed vapor to the second fractionation stage. Diluent and monomer are withdrawn from the second column as fractionation products.
摘要翻译：提供了从聚合反应器流出物中回收稀释剂，未反应单体和未反应的共聚单体的方法和装置。共聚单体的沸点高于单体的沸点，稀释剂的沸点在单体和共聚单体的沸点之间。该方法和装置使用至少一个闪蒸罐，包括第一塔并在第一分馏压力下操作的第一分馏阶段和包含第二塔并在较高的第二分馏压力下运行的第二馏分级。共聚单体作为分馏产物从第一塔排出，并且含有稀释剂和单体的塔顶蒸气基本上冷凝以产生基本上冷凝的塔顶馏出物流。来自流的液体和蒸汽在蓄液器中分离。来自蓄能器的蒸汽和液体分别被压缩和泵送，以在大约第二分馏压力下输送到第二分馏级。泵送的液体是泵送液体和压缩蒸气到第二分馏级的总流量的主要部分。稀释剂和单体作为分馏产物从第二塔排出。

2. 发明申请

US20080177122A1 Methods of Preparation of an Olefin Oligomerization Catalyst 有权
标题翻译：烯烃低聚催化剂的制备方法
公开(公告)号：US20080177122A1
公开(公告)日：2008-07-24
申请号：US12057853
申请日：2008-03-28
申请人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges
发明人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges
IPC分类号： C07C2/08
CPC分类号： B01J31/143 , B01J31/0244 , B01J31/2226 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C11/02
摘要： A method of making a catalyst for use in oligomerizing an olefin, comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the pyrrole-containing compound, a composition comprising a non-metal halide-containing compound, a composition comprising the solvent, or combinations thereof prior to contact thereof with a composition comprising a metal halide-containing compound.
摘要翻译：一种制备用于低聚烯烃的催化剂的方法，包括含铬化合物，含吡咯的化合物，金属烷基，含卤化合物和任选的溶剂，所述方法包括减少全部或部分包含含铬化合物的组合物，包含含吡咯的化合物的组合物，包含非金属卤化物的化合物的组合物，包含溶剂的组合物或其接触前的组合的组合物，水，酸性质子或两者其包含含有金属卤化物的化合物的组合物。

3. 发明授权

US07910670B2 Methods of preparation of an olefin oligomerization catalyst 有权
标题翻译：制备烯烃低聚催化剂的方法
公开(公告)号：US07910670B2
公开(公告)日：2011-03-22
申请号：US12534536
申请日：2009-08-03
申请人： Ronald D. Knudsen , Ronald G. Abbott , Bruce E. Kreischer , Eduardo J. Baralt , Brooke L. Small
发明人： Ronald D. Knudsen , Ronald G. Abbott , Bruce E. Kreischer , Eduardo J. Baralt , Brooke L. Small
IPC分类号： C08F4/69
CPC分类号： C07C2/32 , B01J31/04 , B01J31/128 , B01J31/143 , B01J31/18 , B01J31/181 , B01J31/2226 , B01J31/4092 , B01J2231/20 , B01J2531/62 , C07C2527/125 , C07C2531/22 , C08F10/00 , Y02P20/584 , C08F4/69
摘要： A method of making an olefin oligomerization catalyst, comprising contacting a chromium-containing compound, a heteroatomic ligand, and a metal alkyl, wherein the chromium-containing compound comprises less than about 5 weight percent chromium oligomers. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising adding a composition comprising the chromium-containing compound to a composition comprising the metal alkyl. A method of making an olefin oligomerization catalyst comprising a chromium-containing compound, a nitrogen-containing compound, and a metal alkyl, the method comprising abating all or a portion of water, acidic protons, or both from a composition comprising the chromium-containing compound, a composition comprising the nitrogen-containing compound, or combinations thereof prior to or during the preparation of the catalyst. Methods of oligomerizing olefins by contacting such catalysts with an alpha olefin.
摘要翻译：一种制备烯烃低聚催化剂的方法，包括使含铬化合物，杂原子配体和金属烷基接触，其中所述含铬化合物包含小于约5重量％的铬低聚物。一种制备包含含铬化合物，含氮化合物和金属烷基的烯烃低聚催化剂的方法，所述方法包括将含有所述含铬化合物的组合物加入到包含所述金属烷基的组合物中。一种制备包含含铬化合物，含氮化合物和金属烷基的烯烃低聚催化剂的方法，该方法包括从包含含铬化合物的组合物中减少全部或一部分水，酸性质子或两者化合物，包含含氮化合物的组合物或其组合在制备催化剂之前或期间。通过使这种催化剂与α-烯烃接触来使烯烃低聚的方法。

4. 发明申请

US20100113851A1 System and Method of Deactivating and Quenching an Oligomerization Catalyst 有权
标题翻译：灭活和淬灭低聚催化剂的系统和方法
公开(公告)号：US20100113851A1
公开(公告)日：2010-05-06
申请号：US12609631
申请日：2009-10-30
申请人： Bruce E. Kreischer , Orson L. Sydora , Ronald D. Knudsen
发明人： Bruce E. Kreischer , Orson L. Sydora , Ronald D. Knudsen
IPC分类号： C07C2/34 , C07C2/08 , C07C7/00
CPC分类号： B01J31/122 , B01J31/0237 , B01J31/0239 , B01J31/0244 , B01J31/143 , B01J2231/20 , B01J2531/62 , Y02P20/582 , Y10S585/903
摘要： A method of deactivate a catalyst system is described. The method may include contacting a reactor effluent comprising a catalyst system, an oligomerized olefin, and diluent with a kill agent to at least partially deactivate the catalyst system, separating the reactor effluent into one or more first streams comprising oligomerized olefin and diluent, the one or more first streams being substantially devoid of the at least partially deactivated catalyst, and a second stream comprising the deactivated catalyst; and contacting the second stream with a quench agent.
摘要翻译：描述了使催化剂体系失活的方法。该方法可以包括将包含催化剂体系，低聚烯烃和稀释剂的反应器流出物与杀灭剂接触以使催化剂体系至少部分失活，将反应器流出物分离成一个或多个包含低聚烯烃和稀释剂的第一流，或更多的第一物流基本上不含至少部分失活的催化剂，以及包含失活的催化剂的第二物流; 并使第二流与骤冷剂接触。

5. 发明申请

US20090270567A1 Olefin Oligomerization 有权
标题翻译：烯烃低聚
公开(公告)号：US20090270567A1
公开(公告)日：2009-10-29
申请号：US12480384
申请日：2009-06-08
申请人： Brooke L. Small , Bruce E. Kreischer
发明人： Brooke L. Small , Bruce E. Kreischer
IPC分类号： C08F2/01 , C08F4/42 , C08F4/52
CPC分类号： C07C2/32 , C07C2531/28 , C07C2531/30 , C07C11/02
摘要： Provided is a method of oligomerizing alpha olefins. In an embodiment, an oligomerization catalyst system is contacted in at least one continuous reactor with a feed comprising olefins; an effluent comprising product olefins having at least four carbon atoms is withdrawn from the reactor; the oligomerization catalyst system comprises iron or cobalt, or combinations thereof; and the single pass conversion of ethylene is at least about 40 weight percent among product olefins having at least four carbon atoms. In another embodiment, the single pass conversion of ethylene comprises at least about 65 weight percent among product olefins having at least four carbon atoms. In another embodiment, product olefins of the effluent having twelve carbon atoms comprise at least about 95 weight percent 1-dodecene. In another embodiment, product olefins comprise at least about 80 weight percent linear 1-alkenes. In another embodiment, product olefins comprise at least about 20 weight percent alpha olefins having from about 8 to about 20 carbon atoms. In another embodiment, the oligomerization catalyst system provided comprises a selective 1-hexene (S1H) catalyst.
摘要翻译：提供了一种使α-烯烃低聚的方法。在一个实施方案中，低聚催化剂体系在至少一个连续反应器中与包含烯烃的进料接触; 含有至少四个碳原子的产物烯烃的流出物从反应器中排出; 所述低聚催化剂体系包含铁或钴，或其组合; 并且在具有至少四个碳原子的产物烯烃中乙烯的单程转化率至少为约40重量％。在另一个实施方案中，乙烯的单程转化在具有至少四个碳原子的产物烯烃中包含至少约65重量％。在另一个实施方案中，具有十二个碳原子的流出物的产物烯烃包含至少约95重量％的1-十二碳烯。在另一个实施方案中，产物烯烃包含至少约80重量％的直链1-烯烃。在另一个实施方案中，产物烯烃包含至少约20重量％的具有约8至约20个碳原子的α-烯烃。在另一个实施方案中，提供的低聚催化剂体系包括选择性1-己烯（S1H）催化剂。

6. 发明授权

US07994376B2 Olefin oligomerization 有权
标题翻译：烯烃低聚
公开(公告)号：US07994376B2
公开(公告)日：2011-08-09
申请号：US12480384
申请日：2009-06-08
申请人： Brooke L. Small , Bruce E. Kreischer
发明人： Brooke L. Small , Bruce E. Kreischer
IPC分类号： C07C2/30
CPC分类号： C07C2/32 , C07C2531/28 , C07C2531/30 , C07C11/02
摘要： Provided is a method of oligomerizing alpha olefins. In an embodiment, an oligomerization catalyst system is contacted in at least one continuous reactor with a feed comprising olefins; an effluent comprising product olefins having at least four carbon atoms is withdrawn from the reactor; the oligomerization catalyst system comprises iron or cobalt, or combinations thereof; and the single pass conversion of ethylene is at least about 40 weight percent among product olefins having at least four carbon atoms. In another embodiment, the single pass conversion of ethylene comprises at least about 65 weight percent among product olefins having at least four carbon atoms. In another embodiment, product olefins of the effluent having twelve carbon atoms comprise at least about 95 weight percent 1-dodecene. In another embodiment, product olefins comprise at least about 80 weight percent linear 1-alkenes. In another embodiment, product olefins comprise at least about 20 weight percent alpha olefins having from about 8 to about 20 carbon atoms. In another embodiment, the oligomerization catalyst system provided comprises a selective 1-hexene (S1H) catalyst.
摘要翻译：提供了一种使α-烯烃低聚的方法。在一个实施方案中，低聚催化剂体系在至少一个连续反应器中与包含烯烃的进料接触; 含有至少四个碳原子的产物烯烃的流出物从反应器中排出; 所述低聚催化剂体系包含铁或钴，或其组合; 并且在具有至少四个碳原子的产物烯烃中乙烯的单程转化率至少为约40重量％。在另一个实施方案中，乙烯的单程转化在具有至少四个碳原子的产物烯烃中包含至少约65重量％。在另一个实施方案中，具有十二个碳原子的流出物的产物烯烃包含至少约95重量％的1-十二碳烯。在另一个实施方案中，产物烯烃包含至少约80重量％的直链1-烯烃。在另一个实施方案中，产物烯烃包含至少约20重量％的具有约8至约20个碳原子的α-烯烃。在另一个实施方案中，提供的低聚催化剂体系包括选择性1-己烯（S1H）催化剂。

7. 发明申请

US20110021343A1 Methods of Preparation of an Olefin Oligomerization Catalyst 有权
标题翻译：烯烃低聚催化剂的制备方法
公开(公告)号：US20110021343A1
公开(公告)日：2011-01-27
申请号：US12897296
申请日：2010-10-04
申请人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges , Eduardo J. Baralt , Brooke Small
发明人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges , Eduardo J. Baralt , Brooke Small
IPC分类号： B01J37/04 , B01J37/03 , B01J31/02
CPC分类号： B01J31/0244 , B01J31/128 , B01J31/143 , B01J31/2208 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C2531/02 , C07C11/02
摘要： A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.
摘要翻译：一种制备用于低聚烯烃的催化剂的方法，所述催化剂包含含铬化合物，含吡咯的化合物，金属烷基，含卤化合物和任选的溶剂，所述方法包括使包含铬 - 含有金属烷基的组合物，其中将包含含铬化合物的组合物加入到包含金属烷基的组合物中。

8. 发明授权

US07384886B2 Methods of preparation of an olefin oligomerization catalyst 有权
标题翻译：制备烯烃低聚催化剂的方法
公开(公告)号：US07384886B2
公开(公告)日：2008-06-10
申请号：US10783737
申请日：2004-02-20
申请人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges , Eduardo J. Baralt
发明人： Ronald D. Knudsen , Bruce E. Kreischer , Ronald G. Abbott , Steven D. Bridges , Eduardo J. Baralt
IPC分类号： B01J31/18
CPC分类号： B01J31/0244 , B01J31/128 , B01J31/143 , B01J31/2208 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C2531/02 , C07C11/02
摘要： A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.
摘要翻译：一种制备用于低聚烯烃的催化剂的方法，所述催化剂包含含铬化合物，含吡咯的化合物，金属烷基，含卤化合物和任选的溶剂，所述方法包括使包含铬 - 含有金属烷基的组合物，其中将包含含铬化合物的组合物加入到包含金属烷基的组合物中。

9. 发明授权

US5641842A Ethylene copolymerization process 失效
标题翻译：乙烯共聚方法
公开(公告)号：US5641842A
公开(公告)日：1997-06-24
申请号：US471894
申请日：1995-06-07
申请人： Max P. McDaniel , Rickey D. Badley , Bruce E. Kreischer , Joseph S. Shveima
发明人： Max P. McDaniel , Rickey D. Badley , Bruce E. Kreischer , Joseph S. Shveima
IPC分类号： C08F4/22 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/24
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , Y10S526/908
摘要： A process is provided comprising copolymerizing, under copolymerizing conditions, ethylene with one or more alpha-olefins, using a catalyst system, where said catalyst system has been sized, to produce a lower-density-copolymer, where said lower-density-copolymer has a density lower than a similar copolymer produced by copolymerizing, under said copolymerizing conditions, ethylene with said one or more alpha-olefins, using said catalyst system, where said catalyst system has not been sized, where said catalyst system that has been sized has had substantially all particles removed that produce, under said copolymerizing conditions, a higher-density-copolymer, where said higher-density-copolymer has a density higher than said similar copolymer.
摘要翻译：提供了一种方法，包括在共聚合条件下使乙烯与一种或多种α-烯烃共聚，使用催化剂体系，其中所述催化剂体系的尺寸被制成低密度共聚物，其中所述低密度共聚物具有通过使用所述催化剂体系在所述共聚条件下共聚乙烯和所述一种或多种α-烯烃，其中所述催化剂体系未被大小化，其中所述催化剂体系的尺寸已经达到规定尺寸基本上所有去除的颗粒在所述共聚条件下产生高密度共聚物，其中所述高密度共聚物的密度高于所述类似的共聚物。

10. 发明授权

US08344198B2 Process to decrease or eliminate corrosion from the decomposition of halide containing olefin catalysts 有权
标题翻译：减少或消除含卤化烯烃催化剂分解腐蚀的方法
公开(公告)号：US08344198B2
公开(公告)日：2013-01-01
申请号：US10800471
申请日：2004-03-15
申请人： Warren M. Ewert , Bruce E. Kreischer , Ronald D. Knudsen
发明人： Warren M. Ewert , Bruce E. Kreischer , Ronald D. Knudsen
IPC分类号： C07C2/08 , B08B9/00
CPC分类号： C07C7/005 , B01J31/0244 , B01J31/143 , B01J31/181 , B01J31/4015 , B01J2231/20 , B01J2531/62 , C08F110/14 , C10G50/00 , C10G2300/1092 , C10G2300/44 , C10G2300/802 , C10G2400/22 , Y02P20/582 , Y02P20/584 , C08F2500/02
摘要： A processes is provided to inhibit or limit the decomposition of a halide-containing olefin oligomerization catalyst system during recovery of an oligomerization product. The process includes deactivation of an olefin oligomerization catalyst system present in an olefin oligomerization reactor effluent stream by contact with an alcohol under conditions that minimize potential for deactivated catalyst system decomposition. Such conditions include minimization of the water content of the deactivation agent and concentration of the deactivation agent.
摘要翻译：提供了在回收低聚产物期间抑制或限制含卤烯烃低聚催化剂体系的分解的方法。该方法包括使烯烃低聚反应器流出物流中存在的烯烃低聚催化剂体系通过与醇的接触来使在失活的催化剂体系分解的潜力最小化的条件下失活。这些条件包括减活化剂的水含量的最小化和失活剂的浓度。

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