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1. 发明授权

US5770737A Asymmetrical dyes with large two-photon absorption cross-sections 失效
标题翻译：具有大双光子吸收截面的不对称染料
公开(公告)号：US5770737A
公开(公告)日：1998-06-23
申请号：US933067
申请日：1997-09-18
申请人： Bruce A. Reinhardt , Jayprakash C. Bhatt , Lawrence L. Brott , Stephen J. Clarson
发明人： Bruce A. Reinhardt , Jayprakash C. Bhatt , Lawrence L. Brott , Stephen J. Clarson
IPC分类号： C07D213/38 , C07D409/10 , C07D213/02
CPC分类号： C07D213/38 , C07D409/10
摘要： A two-photon absorbing chromophore of the formula D--Ar--A wherein Ar is selected from the group consisting of ##STR1## D is selected from the group consisting of ##STR2## and A is selected from the group consisting of ##STR3## wherein R.sub.1 and R.sub.2 are alkyl groups having 8 to 12 carbon atoms, and wherein R.sub.1 and R.sub.2 are the same or different.
摘要翻译：式D-Ar-A的双光子吸收发色团，其中Ar选自＆lt; IMAGE＆gt; D＆lt; IMAGE＆gt; D＆lt; IMAGE＆gt;＆gt;选自＆lt; IMAGE＆gt; IMAGE>其中R1和R2是具有8至12个碳原子的烷基，并且其中R1和R2相同或不同。

2. 发明授权

US5594075A Acetylenic heterocyclic nonlinear optical thermoset monomers 失效
标题翻译：乙炔杂环非线性光学热固性单体
公开(公告)号：US5594075A
公开(公告)日：1997-01-14
申请号：US505715
申请日：1995-08-07
申请人： Bruce A. Reinhardt , Jayprakash C. Bhatt
发明人： Bruce A. Reinhardt , Jayprakash C. Bhatt
IPC分类号： C07D409/06 , C08G73/22 , C08G75/32 , G02F1/361 , C08L79/06
CPC分类号： C07D409/06 , C08G73/22 , C08G75/32 , G02F1/3614 , G02F1/3615 , Y10S525/909
摘要： The compound 2-ethynyl-5-(4-pyridyl)ethynyl thiophene: ##STR1## when incorporated into a thermoplastic polymer having repeating units of the formula: ##STR2## wherein X is --O-- or --S--, and R is selected from the group consisting of: ##STR3## and Ar is selected from the group consisting of: ##STR4## wherein X is as previously defined, poled to align the molecules and cured to crosslink at least the terminal acetylenic groups, has second-order nonlinear optical activity.
摘要翻译：化合物2-乙炔基-5-（4-吡啶基）乙炔基噻吩：当结合到具有下式的重复单元的热塑性聚合物中时：其中X是-O-或-S-，R选自来自由以下组成的组：和Ar选自由以下组成的组：和其中X如前所定义，极化以使分子对准并固化至少交联末端炔属基团，具有二阶非线性光学活性。

3. 发明授权

US06300502B1 Multi-armed chromophores with very large two-photon absorption cross-sections 有权
标题翻译：具有非常大的双光子吸收横截面的多臂发色团
公开(公告)号：US06300502B1
公开(公告)日：2001-10-09
申请号：US09731549
申请日：2000-12-08
申请人： Ramamurthi Kannan , Bruce A. Reinhardt , Loon-Seng Tan
发明人： Ramamurthi Kannan , Bruce A. Reinhardt , Loon-Seng Tan
IPC分类号： C07D27766
CPC分类号： C07D207/456
摘要： Provided are chromophores with very large two-photon absorption cross-sections. One group of these chromophores has the formula: (T—Q)n—N—Phm wherein Q is a single bond or 1,4-phenylene, Ph is a phenyl group, n has a value of 1-3 and m has a value of 3−n, and wherein T is wherein R1 and R2 are alkyl groups having 1 to 20 carbon atoms, provided that when Q is a single bond, the value of n is 2 or 3. Another group of these chromophores has the formula: (T—Q)n—G—Phm wherein T is as defined above, Q is a single bond or 1,4-phenylene, Ph is a phenyl group, n has a value of 1-4 and m has a value of 4−n, and wherein G is a 4-arm core unit. Yet another group of these chromophores has the formula: (T—Q)n—G—Phm wherein T is as described previously, Q is a single bond or 1,4-phenylene, Ph is a phenyl group, n has a value of 1-6 and m has a value of 6−n, and wherein G is a 6-arm core unit.
摘要翻译：提供了具有非常大的双光子吸收横截面的发色团。一组这些发色团具有下式：其中Q为单键或1,4-亚苯基，Ph为苯基，n为1-3，m为3-n的值，其中T为 R1和R2是具有1至20个碳原子的烷基，条件是当Q是单键时，n的值为2或3.这些发色团的另一组具有下式：其中T如上所定义，Q是单键或1,4-亚苯基，Ph为苯基，n为1-4，m为4-n的值，G为4-臂核心单元。另一组这些发色团具有下式：其中T如前所述，Q是单键或1,4-亚苯基，Ph是苯基，n的值为1-6，m的值为6-n，其中G 是一个6臂的核心单元。

4. 发明授权

US4667002A Phenylquinoxaline resin compositions 失效
标题翻译：苯基喹喔啉树脂组合物
公开(公告)号：US4667002A
公开(公告)日：1987-05-19
申请号：US819322
申请日：1986-01-16
申请人： Marilyn R. Unroe , Bruce A. Reinhardt , Fred E. Arnold
发明人： Marilyn R. Unroe , Bruce A. Reinhardt , Fred E. Arnold
IPC分类号： C07D241/42 , C08G73/06 , C08F26/06
CPC分类号： C07D241/42 , C08G73/0694
摘要： Phenylquinoxaline monomers containing sterically hindered ethynyl groups are provided. These monomers can be crosslinked to provide thermoset resins of the general formula ##STR1## wherein Pq is a phenylquinoxaline linking unit. Ar is an aromatic ether or thioether, and n has a value between 2 and 3.
摘要翻译：提供含空间位阻乙炔基的苯基喹喔啉单体。这些单体可以交联以提供通式为“IMAGE”的热固性树脂，其中Pq是苯基喹喔啉连接单元。 Ar为芳族醚或硫醚，n为2〜3。

5. 发明授权

US4220750A Thermally stable aromatic enyne polyimides 失效
标题翻译：热稳定的芳香族烯聚酰亚胺
公开(公告)号：US4220750A
公开(公告)日：1980-09-02
申请号：US032809
申请日：1979-04-24
申请人： Bruce A. Reinhardt , Fred E. Arnold
发明人： Bruce A. Reinhardt , Fred E. Arnold
IPC分类号： C08G73/10 , C08G73/12
CPC分类号： C08G73/1053 , C08G73/10 , C08G73/1064
摘要： High molecular weight aromatic enyne polyimide thermoplastics are prepared by reacting an aromatic dianhydride with (E)-3,3'-(1-buten-3-ynylene) dianiline alone or in admixture with an aromatic diamine. Because of the presence of the enyne moiety in the polymer backbone, the polymers can be lightly crosslinked to provide solvent-resistant thermoplastics. The polymers are particularly useful in fabricating graphite-reinforced, thermoplastic composites for structural applications.
摘要翻译：通过使芳族二酐与（E）-3,3' - （1-丁烯-3-亚炔基）二苯胺单独或与芳族二胺混合反应制备高分子量芳族烯丙聚酰亚胺热塑性塑料。由于在聚合物骨架中存在烯炔部分，聚合物可以轻度交联以提供耐溶剂的热塑性塑料。聚合物特别适用于制造用于结构应用的石墨增强的热塑性复合材料。

6. 发明授权

US06730793B1 Two-photon responsive chromophores containing electron accepting core units 有权
标题翻译：含有电子接受核心单元的双光子响应发色团
公开(公告)号：US06730793B1
公开(公告)日：2004-05-04
申请号：US10171566
申请日：2002-06-13
申请人： Ramamurthi Kannan , Loon-Seng Tan , Bruce A. Reinhardt , Richard A. Vaia
发明人： Ramamurthi Kannan , Loon-Seng Tan , Bruce A. Reinhardt , Richard A. Vaia
IPC分类号： C07D51302
CPC分类号： C07D513/04 , C07D277/66
摘要： Provided are chromophores of the formula Q—(—L—Z)x, wherein x is 2 or 3, wherein Q is selected from the group consisting of wherein L is wherein R is an alkyl group having 1 to 20 carbon atoms, and wherein Z is selected from the group consisting of
摘要翻译：提供的方解石x的发色团是2或3，其中Q选自其中L是其中R是具有1至20个碳原子的烷基，其中Z选自

7. 发明授权

US4931532A Method of synthesis of thermoplastic aromatic benzoxazole polymers 失效
标题翻译：热塑性芳族苯并唑混合物的合成方法
公开(公告)号：US4931532A
公开(公告)日：1990-06-05
申请号：US241645
申请日：1988-09-08
申请人： Bruce A. Reinhardt
发明人： Bruce A. Reinhardt
IPC分类号： C08G73/22
CPC分类号： C08G73/22
摘要： There is provided an aromatic benzoxazole polymer having repeating units of the formula ##STR1## wherein Ar is ##STR2## wherein R is an alkyl group having 8 to 12 carbon atoms. The polymers of this invention are prepared by the polycondensation of 4,4'-hexafluoroisopropylidene bis(2-aminophenol) with a dicarboxylic acid selected from the group consisting of isophthalic acid, terephthalic acid, 2,5-pyridine dicarboxylic acid, 2,6-pyridine dicarboxylic acid and a 2,5-bis(alkoxy) terephthalic acid of the formula ##STR3## wherein R is an alkyl group having 8 to 12 carbon atoms, in a suitable reaction medium containing a suitable dehydrating agent.
摘要翻译：提供具有下式的重复单元的芳族苯并恶唑聚合物，其中Ar是具有8至12个碳原子的烷基。本发明的聚合物通过4,4'-六氟异亚丙基双（2-氨基苯酚）与选自间苯二甲酸，对苯二甲酸，2,5-吡啶二羧酸，2,6 - 吡啶二羧酸和式为“IMAGE”的2,5-双（烷氧基）对苯二甲酸，其中R为含有8至12个碳原子的烷基，在合适的含有合适的脱水剂的反应介质中。

8. 发明授权

US4417039A Cis-enyne aromatic and aromatic heterocyclic polymers 失效
标题翻译：顺式芳族和芳族杂环聚合物
公开(公告)号：US4417039A
公开(公告)日：1983-11-22
申请号：US399661
申请日：1982-07-19
申请人： Bruce A. Reinhardt , Fred E. Arnold
发明人： Bruce A. Reinhardt , Fred E. Arnold
IPC分类号： C08G61/00 , C08F38/04
CPC分类号： C08G61/00
摘要： Aromatic and aromatic heterocyclic enyne polymers are prepared by reacting a di-.beta.-bromovinylbenzene and a diacetylenic compound. The polymers have relatively low glass transition temperatures for fabrication, and after heat treatment exhibit high glass transition temperatures, as well as low solvent susceptibility. Also provided is a new composition of matter 1,4-bis-(cis-.beta.-bromovinyl)benzene.
摘要翻译：芳族和芳族杂环烯烃聚合物通过使二β-乙烯基苯和二乙炔化合物反应来制备。聚合物具有相对低的玻璃化转变温度用于制造，并且在热处理后表现出高的玻璃化转变温度以及低的溶剂敏感性。还提供了物质1,4-双 - （顺式 - β-溴乙烯基）苯的新组合物。

9. 发明授权

US4082806A Preparation of tetraketones 失效
标题翻译：四氢呋喃的制备
公开(公告)号：US4082806A
公开(公告)日：1978-04-04
申请号：US641958
申请日：1975-12-18
申请人： Frank W. Harris , Bruce A. Reinhardt
发明人： Frank W. Harris , Bruce A. Reinhardt
IPC分类号： C07C45/28 , C07C45/30 , C07C49/784 , C07D213/50 , C07C49/76
CPC分类号： C07D213/50 , C07C45/28 , C07C45/30 , C07C49/784
摘要： A method of preparing tetraketone precursors which are useful in the production of high temperature resistant polyquinoxaline resins. Suitable diketones are oxidized with a halogenating agent, such as cupric halide or hydrogen bromide, and dimethylsulfoxide to produce the corresponding tetraketone. The tetraketones which can be produced by the instant process have the formula: ##STR1## wherein R is hydrogen or an aryl, substituted aryl, heterocyclic or substituted heterocyclic radical and R' is an aryl, substituted aryl, arylalkyl, arylether, arylthioether, arylsulfoxide, arylsulfone, heterocyclic or substituted heterocyclic radical.

10. 发明授权

US5991021A Nonlinear spectrophotometer 失效
公开(公告)号：US5991021A
公开(公告)日：1999-11-23
申请号：US241191
申请日：1999-02-01
申请人： Anadi Mukherjee , Nandini Mukherjee , Conrad S. Sarvis , Bruce A. Reinhardt
发明人： Anadi Mukherjee , Nandini Mukherjee , Conrad S. Sarvis , Bruce A. Reinhardt
IPC分类号： G01J3/42 , G01J3/44 , G01J3/453 , G01J3/457
CPC分类号： G01J3/4406 , G01J3/42 , G01J3/453
摘要： The purpose of the nonlinear spectrophotometer is to provide a simple instrument that can be used on a routine basis to accurately measure the two-photon absorption (TPA) coefficient and cross-section on a wide variety of materials. The instrument is capable of measuring: (1) both organic and inorganic materials, (2) solutions and thin film materials forms, and (3) materials which are fluorescent and nonfluorescent.

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