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1. 发明授权

US08404843B2 Chiral phosphorus compound 有权
标题翻译：手性磷化合物
公开(公告)号：US08404843B2
公开(公告)日：2013-03-26
申请号：US13531986
申请日：2012-06-25
申请人： Brian Adger , Alan Dyke , Giancarlo Francio , Frederick Ernest Hancock , Walter Leitner , Thomas Pullmann , Andreas Seger , Antonio Zanotti-Gerosa
发明人： Brian Adger , Alan Dyke , Giancarlo Francio , Frederick Ernest Hancock , Walter Leitner , Thomas Pullmann , Andreas Seger , Antonio Zanotti-Gerosa
IPC分类号： C07F9/60
CPC分类号： C07F9/60 , C07B53/00 , C07F9/657154 , C07F15/0073
摘要： The present invention relates to novel chiral phosphorus compounds which can be readily prepared from quinoline derivatives as inexpensive starting compounds and have the general formula (I) wherein R1, R2, R3, R4, R5 are chiral or achiral organic residues which are derived from substituted or unsubstituted straight or branched chain or cyclic aliphatic or aromatic groups and which, in the case of the pairs R1/R2 and R4/R5, may be interconnected. Further, the invention relates to methods for the synthesis of chiral phosphorus compounds of general formula (I) and their use as catalyst components in processes for the preparation of optically active products.
摘要翻译：本发明涉及可以容易地由喹啉衍生物制备的新颖的手性磷化合物，并且具有通式（I），其中R 1，R 2，R 3，R 4，R 5是衍生自取代基的手性或非手性有机残基或未取代的直链或支链或环状脂族或芳族基团，并且在配对R1 / R2和R4 / R5的情况下可以互连。此外，本发明涉及用于合成通式（I）的手性磷化合物的方法及其在制备光学活性产物的方法中作为催化剂组分的用途。

2. 发明申请

US20120264940A1 CHIRAL PHOSPHORUS COMPOUND 有权
标题翻译： CHIRAL PHOSPHORUS化合物
公开(公告)号：US20120264940A1
公开(公告)日：2012-10-18
申请号：US13531986
申请日：2012-06-25
申请人： Brian Adger , Alan Dyke , Giancarlo Francio , Frederick Ernest Hancock , Walter Leitner , Thomas Pullmann , Andreas Seger , Antonio Zanotti-Gerosa
发明人： Brian Adger , Alan Dyke , Giancarlo Francio , Frederick Ernest Hancock , Walter Leitner , Thomas Pullmann , Andreas Seger , Antonio Zanotti-Gerosa
IPC分类号： C07F9/60
CPC分类号： C07F9/60 , C07B53/00 , C07F9/657154 , C07F15/0073
摘要： The present invention relates to novel chiral phosphorus compounds which can be readily prepared from quinoline derivatives as inexpensive starting compounds and have the general formula (I) wherein R1, R2, R3, R4, R5 are chiral or achiral organic residues which are derived from substituted or unsubstituted straight or branched chain or cyclic aliphatic or aromatic groups and which, in the case of the pairs R1/R2 and R4/R5, may be interconnected. Further, the invention relates to methods for the synthesis of chiral phosphorus compounds of general formula (I) and their use as catalyst components in processes for the preparation of optically active products.
摘要翻译：本发明涉及可以容易地由喹啉衍生物制备的新颖的手性磷化合物，并且具有通式（I），其中R 1，R 2，R 3，R 4，R 5是衍生自取代基的手性或非手性有机残基或未取代的直链或支链或环状脂族或芳族基团，并且在配对R1 / R2和R4 / R5的情况下可以互连。此外，本发明涉及用于合成通式（I）的手性磷化合物的方法及其在制备光学活性产物的方法中作为催化剂组分的用途。

3. 发明授权

US08222415B2 Chiral phosphorus compound 有权
标题翻译：手性磷化合物
公开(公告)号：US08222415B2
公开(公告)日：2012-07-17
申请号：US12444289
申请日：2007-10-01
申请人： Brian Adger , Alan Dyke , Giancarlo Francio , Frederick Ernest Hancock , Walter Leitner , Thomas Pullman , Andreas Seger , Antonio Zanotti-Gerosa
发明人： Brian Adger , Alan Dyke , Giancarlo Francio , Frederick Ernest Hancock , Walter Leitner , Thomas Pullman , Andreas Seger , Antonio Zanotti-Gerosa
IPC分类号： C07F9/00 , C07F9/60
CPC分类号： C07F9/60 , C07B53/00 , C07F9/657154 , C07F15/0073
摘要： The present invention relates to novel chiral phosphorus compounds which can be readily prepared from quinoline derivatives as inexpensive starting compounds and have the general formula (I) wherein R1, R2, R3, R4, R5 are chiral or achiral organic residues which are derived from substituted or unsubstituted straight or branched chain or cyclic aliphatic or aromatic groups and which, in the case of the pairs R1/R2 and R4/R5, may be interconnected. Further, the invention relates to methods for the synthesis of chiral phosphorus compounds of general formula (I) and their use as catalyst components in processes for the preparation of optically active products.
摘要翻译：本发明涉及可以容易地由喹啉衍生物制备的新颖的手性磷化合物，并且具有通式（I），其中R 1，R 2，R 3，R 4，R 5是衍生自取代基的手性或非手性有机残基或未取代的直链或支链或环状脂族或芳族基团，并且在配对R1 / R2和R4 / R5的情况下可以互连。此外，本发明涉及用于合成通式（I）的手性磷化合物的方法及其在制备光学活性产物的方法中作为催化剂组分的用途。

4. 发明授权

US6020285A Calcium aluminate cement based catalyst 失效
标题翻译：铝酸钙水泥基催化剂
公开(公告)号：US6020285A
公开(公告)日：2000-02-01
申请号：US983581
申请日：1998-01-22
申请人： Frederick Ernest Hancock
发明人： Frederick Ernest Hancock
IPC分类号： C02F1/70 , B01J23/02 , B01J23/78 , B01J35/10 , B01J21/08 , B01J23/00 , B01J23/70 , C07C5/10
CPC分类号： B01J23/02 , B01J23/78 , B01J35/0026 , B01J35/10 , B01J35/1014 , B01J35/108
摘要： Shaped particles suitable for use as a catalyst, or precursor thereto, particularly for the decomposition of hypohalite ions in aqueous solution, comprising a high alumina cement having an aluminium to calcium atomic ratio above 2.5 and at least one oxide of a Group VIII metal M selected from nickel and cobalt, said particles containing 10 to 70% by weight of said Group VIII metal oxide and having a porosity in the range of 30 to 60%, in which at least 10% of the pore volume is in the form of pores of size in the range 15 to 35 nm and less than 65% of the pore volume is in the form of pores of diameter greater then 35 nm are disclosed.
摘要翻译： PCT No.PCT / GB96 / 01698 Sec。 371日期：1998年1月22日 102（e）1998年1月22日PCT PCT 1996年7月16日PCT公布。公开号WO97 / 04870 日期1997年2月13日适用于催化剂或其前体的形状颗粒，特别是用于在水溶液中分解次卤酸盐离子，其包含铝与钙原子比高于2.5的高铝水泥和至少一种氧化铝选自镍和钴的VIII族金属M，所述颗粒含有10至70重量％的所述VIII族金属氧化物，其孔隙率为30至60％，其中至少10％的孔体积为公开了尺寸在15至35nm且小于孔体积的65％的孔的形式为直径大于35nm的孔的形式。

5. 发明授权

US5859070A Catalytic process 失效
标题翻译：催化过程
公开(公告)号：US5859070A
公开(公告)日：1999-01-12
申请号：US624454
申请日：1996-07-22
申请人： Samuel David Jackson , Frederick Ernest Hancock , Bernard John Crewdson
发明人： Samuel David Jackson , Frederick Ernest Hancock , Bernard John Crewdson
IPC分类号： B01J37/00 , C07B59/00 , C07C1/12 , C07C29/156 , C07C27/00
CPC分类号： C07C1/12 , B01J37/00 , C07B59/001 , C07C29/156 , C07C2523/755
摘要： Synthesis of small quantities of compounds such as methanol from reagents, especially radio-labelled reagents such as .sup.11 C oxides, in a carrier gas by a catalytic reaction using a catalyst that has been pre-conditioned for the reaction by previous use for the desired reaction and has then been passivated, or has been maintained in the pre-conditioned state, until contacted with said carrier gas. Where the product is adsorbed by the catalyst, it may be desorbed by heating or displaced by contacting the catalyst with a material, e.g. a catalyst poison that is more strongly adsorbed. Such a more strongly adsorbed material may react with the adsorbed catalytic product to produce a desired product.
摘要翻译： PCT No.PCT / GB94 / 02204 Sec。 371日期：1996年7月22日 102（e）日期1996年7月22日PCT 1994年10月10日PCT PCT。公开号WO95 / 11080 PCT 日期1995年04月27日通过催化反应使用已经通过先前使用的反应预处理的催化剂，在载气中合成少量化合物如甲醇，特别是放射性标记试剂如11C氧化物进行所需的反应，然后被钝化，或者已经保持在预处理状态，直到与所述载气接触。当产物被催化剂吸附时，其可以通过加热或取代而被解吸，通过使催化剂与材料接触，例如，更强烈吸附的催化剂毒物。这种更强吸附的材料可以与吸附的催化产物反应以产生所需的产物。

6. 发明授权

US5772897A Continuous oxidation process using a hypochlorite solution 失效
标题翻译：使用次氯酸盐溶液进行连续氧化处理
公开(公告)号：US5772897A
公开(公告)日：1998-06-30
申请号：US716271
申请日：1996-12-23
申请人： Frederick Ernest Hancock
发明人： Frederick Ernest Hancock
IPC分类号： B01J23/72 , B01J23/755 , B01J23/80 , C02F1/72 , C02F1/76
CPC分类号： C02F1/76 , C02F1/722 , C02F1/725
摘要： A process of continuous decomposition of oxidizable materials in aqueous media, e.g. pollutants in effluents, by catalytic reaction with an oxidant, e.g. hypochlorite or hydrogen peroxide, in aqueous solution using a fixed bed of a particulate catalyst of at least 1% of nickel or copper oxide, optionally plus a basic oxide, e.g. zinc oxide, on a porous support is disclosed.
摘要翻译： PCT No.PCT / GB95 / 00522 Sec。 371日期：1996年12月23日 102（e）日期1996年12月23日PCT 1995年3月10日PCT PCT。 WO95 / 26318 PCT公开日期1995年10月5日在水介质中的可氧化材料的连续分解过程，例如污水中的污染物，通过与氧化剂的催化反应，例如次氯酸盐或过氧化氢，使用固定床的至少1％的镍或氧化铜的颗粒催化剂，任选加上碱性氧化物，例如，公开了一种多孔载体上的氧化锌。

7. 发明授权

US07262299B2 Catalysts 失效
标题翻译：催化剂
公开(公告)号：US07262299B2
公开(公告)日：2007-08-28
申请号：US10495004
申请日：2002-10-31
申请人： Neil Aubrey Caplan , Frederick Ernest Hancock
发明人： Neil Aubrey Caplan , Frederick Ernest Hancock
IPC分类号： C07D221/02 , C07D413/00
CPC分类号： C07D307/77 , B01J29/072 , B01J29/146 , B01J29/46 , B01J31/1805 , B01J31/2208 , C07C51/567 , C07C315/04 , C07C2602/44 , C07D263/22 , C07C61/29 , C07C317/14
摘要： A process for performing a catalytic Diels-Alder reaction by reacting a diene with a dienophile in the presence of a heterogeneous catalyst comprising a zeolitic material exchanged or impregnated with ions of a Lewis acidic metal is described. The catalyst, for example, copper-exchanged zeolite Y, may be treated with chiral bis(imine) compounds to direct the chirality of the reaction products. The catalyst can be separated from the reaction mixture and re-used in further Diels Alder reactions.
摘要翻译：描述了在包含交换或浸渍有路易斯酸性金属的离子的沸石材料的非均相催化剂存在下使二烯与亲二烯体反应进行催化Diels-Alder反应的方法。催化剂，例如铜交换沸石Y，可用手性双（亚胺）化合物处理以引导反应产物的手性。催化剂可以与反应混合物分离，并再次用于进一步的Diels Alder反应。

8. 发明授权

US07074960B2 Catalysts 失效
标题翻译：催化剂
公开(公告)号：US07074960B2
公开(公告)日：2006-07-11
申请号：US10487384
申请日：2002-08-05
申请人： Frederick Ernest Hancock , Graham John Hutchings , Neil Aubrey Caplan
发明人： Frederick Ernest Hancock , Graham John Hutchings , Neil Aubrey Caplan
IPC分类号： C07C45/72
CPC分类号： C07C227/32 , B01J29/146 , B01J31/1616 , B01J31/1805 , B01J31/182 , B01J31/403 , B01J2229/186 , B01J2229/34 , B01J2531/16 , C07B41/04 , C07B43/04 , C07B53/00 , C07B2200/07 , C07C67/343 , C07C209/52 , Y02P20/584 , Y02P20/588 , C07C69/732 , C07C211/28 , C07C229/36
摘要： A zeolite-immobilized Lewis acid e.g. copper catalyst for performing carbonyl-ene and iminoene reactions is described. The catalyst can readily be separated from the reaction mixture and re-used in further reactions with minimal reduction in activity.
摘要翻译：固定有沸石的路易斯酸例如描述了用于进行羰基和亚胺基反应的铜催化剂。催化剂可以容易地从反应混合物中分离出来，并且在进一步的反应中重新使用，活性降低最小。

9. 发明授权

US06409981B1 Process for removing chlorine from gas stream 失效
标题翻译：从气流中除去氯的方法
公开(公告)号：US06409981B1
公开(公告)日：2002-06-25
申请号：US09329412
申请日：1999-06-10
申请人： Edmund Hugh Stitt , Frederick Ernest Hancock
发明人： Edmund Hugh Stitt , Frederick Ernest Hancock
IPC分类号： B01D5368
CPC分类号： B01D53/68 , B01D53/1425
摘要： A process for the scrubbing of chlorine is scrubbed from a chlorine-containing gas using an aqueous feed liquor containing an excess of alkali to give an effluent liquor containing chloride and hypochlorite ions is disclosed. The effluent liquor is recycled as part or all of the aqueous feed liquor. For at least part of the time, at least part of the effluent liquor is passed through a fixed bed of a catalyst for the decomposition of hypochlorite ions whereby hypochlorite ions are decomposed to oxygen gas and chloride ions. The resultant catalyst-treated liquor is mixed with the remainder, if any, of the effluent liquor and recycled, optionally together with added fresh alkali solution, as the aqueous feed liquor. Part of the effluent liquor is optionally discharged as a purge stream before or after passage through catalyst bed. The process may be operated in a continuous mode or in a semi-continuous mode wherein a reservoir holding the liquor to be recycled is periodically discharged, preferably through the catalyst bed, and then recharged with fresh alkali solution. Alternatively two reservoirs may be employed with one supplying the aqueous feed liquor while the other is being discharged and replenished. In the latter case, the reservoir being discharged may have its liquor discharged through the catalyst bed.
摘要翻译：使用含有过量碱的含水原料液从含氯气体中洗涤氯的洗涤方法，得到含有氯化物和次氯酸根离子的流出液。流出液被回收作为部分或全部含水进料液。在至少部分时间内，至少部分废液通过催化剂的固定床，以分解次氯酸根离子，从而将次氯酸根离子分解成氧气和氯离子。将得到的催化剂处理的液体与其余的（如果有的话）的流出液混合，并且任选地与添加的新鲜碱溶液一起再循环，作为含水进料液。在通过催化剂床之前或之后，部分流出液可任选地作为吹扫流排出。该方法可以以连续模式或半连续模式操作，其中储存待循环液体的储存器周期性地排出，优选通过催化剂床，然后用新鲜碱溶液再充电。或者，可以使用两个储存器，一个供应水性进料液，另一个储存器被排出并补充。在后一种情况下，被排出的储存器可以使其液体通过催化剂床排出。

10. 发明授权

US06261465B1 Calcium aluminate based catalyst and use of the catalyst 失效
标题翻译：铝酸钙基催化剂和催化剂的使用
公开(公告)号：US06261465B1
公开(公告)日：2001-07-17
申请号：US09271647
申请日：1999-03-18
申请人： Frederick Ernest Hancock
发明人： Frederick Ernest Hancock
IPC分类号： C02F100
CPC分类号： C02F1/725 , B01J23/78 , B01J37/0009 , C02F2303/185
摘要： Shaped units suitable for use as a catalyst, e.g. for the decomposition of hypochlorite, comprise a compacted particulate mixture of at least one oxide of a Group VIII metal M selected from nickel and cobalt, a calcium aluminate cement, and alumina and/or magnesia, the shaped units having (after ignition in air at 900° C.) a content of a Group VIII metal oxide of 10 to 50% by weight (expressed as the divalent oxide, MO), a calcium oxide content of 1 to 10% by weight, an alumina content by weight that is at least four times the weight of calcium oxide, a total content of alumina plus magnesia of at least 40% by weight, a silica content of less than 1% by weight, and the shaped units having a pore volume in the range 0.2 to 0.5 ml/g and having a pore size distribution such that from 5 to 25% of the total pore volume is in the form of pores of diameter in the range 15 to 35 nm, at least 30% of the total pore volume is in the form of pores of diameter greater than 35 nm, and 10 to 20% of the total pore volume is in the form of pores of diameter greater than 1500 nm.
摘要翻译：适合用作催化剂的成形单元，例如为了分解次氯酸盐，包含至少一种选自镍和钴的第Ⅷ族金属M的氧化物，铝酸钙水泥和氧化铝和/或氧化镁的至少一种氧化物的压实颗粒混合物，所述成形单元具有（在空气中点燃 900℃），第Ⅷ族金属氧化物的含量为10〜50重量％（二价氧化物表示为MO），氧化钙含量为1〜10重量％，氧化铝含量为至少四倍于氧化钙的重量，氧化铝和氧化镁的总含量至少为40重量％，二氧化硅含量小于1重量％，成孔单元的孔体积为0.2-0.5毫升 / g，并且具有孔尺寸分布，使得总孔体积的5至25％是直径为15至35nm的孔的形式，总孔体积的至少30％为直径大于35nm的孔和总孔体积的10〜20％为d孔的形式直径大于1500nm。

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