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    • 4. 发明授权
    • Device and method for separating oxygen isotopes
    • 用于分离氧同位素的装置和方法
    • US4437958A
    • 1984-03-20
    • US868586
    • 1978-01-11
    • Stephen D. RockwoodRobert K. Sander
    • Stephen D. RockwoodRobert K. Sander
    • B01J19/12C01B13/02
    • B01J19/121C01B13/0233C01B2210/0026
    • A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.
    • 用于在约193nm处产生相干辐射的ArF激光器分离氧同位素的装置和方法。 ArF激光器的输出在自然空气中过滤并施加到照射电池,其中其优先地使包含17O或18O氧化核素的氧气分子分解。 使用诸如O 2,CO或乙烯的清除剂来收集优先离解的氧原子并再循环以产生同位素富集的分子氧气体。 其他实施例利用与棱镜或衍射光栅进行狭窄调谐的ArF激光器,以优先光解所需同位素。 类似地,期望的同位素气体混合物可用作过滤器以使富氧预选的氧同位素光解离。
    • 6. 发明授权
    • Resonantly enhanced method for generation of tunable, coherent vacuum
ultraviolet radiation
    • 共振增强的可调谐,相干真空紫外线辐射的方法
    • US4529944A
    • 1985-07-16
    • US393251
    • 1982-06-29
    • James H. GlowniaRobert K. Sander
    • James H. GlowniaRobert K. Sander
    • G02F1/355H03F7/00H01S3/00
    • G02F1/355
    • Carbon Monoxide vapor is used to generate coherent, tunable vacuum ultraviolet radiation by third-harmonic generation using a single tunable dye laser. The presence of a nearby electronic level resonantly enhances the nonlinear susceptibility of this molecule allowing efficient generation of the vuv light at modest pump laser intensities, thereby reducing the importance of a six-photon multiple-photon ionization process which is also resonantly enhanced by the same electronic level but to higher order. By choosing the pump radiation wavelength to be of shorter wavelength than individual vibronic levels used to extend tunability stepwise from 154.4 to 124.6 nm, and the intensity to be low enough, multiple-photon ionization can be eliminated. Excitation spectra of the third-harmonic emission output exhibit shifts to shorter wavelength and broadening with increasing CO pressure due to phase matching effects. Increasing the carbon monoxide pressure, therefore, allows the substantial filling in of gaps arising from the stepwise tuning thereby providing almost continuous tunability over the quoted range of wavelength emitted.
    • 一氧化碳蒸气用于通过使用单个可调谐染料激光器的三次谐波产生相干,可调谐的真空紫外线辐射。 附近电子水平的存在共振地增强了该分子的非线性磁化率,允许在适度的泵浦激光强度下有效地产生vuv光,从而降低六光子多光子电离过程的重要性,其也被同样地共振地增强 电子级别,但更高级。 通过将泵浦辐射波长选择为比从单个的振荡电平来的波长更短的波长,从154.4到124.6nm逐步延伸可调性,并且强度足够低,可以消除多光子电离。 由于相位匹配效应,三次谐波发射输出的激发光谱表现出转变为较短的波长并随着CO压力的增加而变宽。 因此,增加一氧化碳压力允许基本上填充由逐步调谐产生的间隙,从而在引用的波长发射范围上提供几乎连续的可调谐性。