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1. 发明授权

US5145625A Method of preparing shaped articles from a mineral aggregate and a polyacrylate binder 失效
标题翻译：从矿物骨料和聚丙烯酸酯粘合剂制备成型制品的方法
公开(公告)号：US5145625A
公开(公告)日：1992-09-08
申请号：US714346
申请日：1991-06-12
申请人： Bernhard Dotzauer , Wilhelm F. Beckerle , Hans-Juergen Denu , Kurt Wendel , Manfred Schwartz
发明人： Bernhard Dotzauer , Wilhelm F. Beckerle , Hans-Juergen Denu , Kurt Wendel , Manfred Schwartz
IPC分类号： B27N3/04 , C04B26/06 , C08K3/00 , C08K7/02 , C08L33/04 , C08L33/12 , D21J1/00
CPC分类号： C08K3/0033 , C08K7/02 , Y10S264/19
摘要： Shaped articles are produced from a finely particulate material as aggregate and an aqueous binder preparation containing an acrylate polymer by moistening the aggregate with the binder preparation, making it into the desired shape and then drying it, using a binder preparation whose binder is an acrylate polymer whose glass transition range is relatively high and which is formed from (A) a predominant amount of methyl methacrylate, (B) a minor amount of (meth) acrylic acid, (C) a minor amount of an optional alkyl acrylate and (D) a small optional amount of another specific polymerizable compound.
摘要翻译：成型制品由作为骨料的细颗粒材料和含有丙烯酸酯聚合物的水性粘合剂制剂通过用粘合剂制剂润湿聚集体制成，使其成为所需形状，然后使用其粘合剂为丙烯酸酯聚合物的粘合剂制剂其玻璃化转变范围相对较高并且由（A）主要量的甲基丙烯酸甲酯，（B）少量的（甲基）丙烯酸，（C）少量的任选的丙烯酸烷基酯和（D）另一种特定的可聚合化合物的选择量很小。

2. 发明授权

US5061556A Shaped articles 失效
标题翻译：形状文章
公开(公告)号：US5061556A
公开(公告)日：1991-10-29
申请号：US482986
申请日：1990-02-22
申请人： Bernhard Dotzauer , Wilhelm F. Beckerle , Hans-Juergen Denu , Kurt Wendel , Manfred Schwartz
发明人： Bernhard Dotzauer , Wilhelm F. Beckerle , Hans-Juergen Denu , Kurt Wendel , Manfred Schwartz
IPC分类号： C04B41/48 , C04B41/63
CPC分类号： C04B41/009 , C04B41/483 , C04B41/63
摘要： A shaped article is obtainable by impregnating or coating a preform composed in the main of mineral fibers, nonfibrous mineral fillers and starch with a composition which contains a binder comprising a copolymer composed ofa) 60-95% by weight of methyl methacrylate (monomer I),b) 5-40% by weight of acrylic or methacrylic acid (monomer II)c) 0-35% by weight of one or more acrylic esters of a C.sub.1 -C.sub.8 -alkanol (monomer III),d) 0-5% by weight of a copolymerizable olefinically polyunsaturated monomer (monomer IV), ande) 0-5% by weight of another copolymerizable monomer (monomer V)in polymerized form, the weight percentages of monomers I, II, III and V having been selected within the stated limits in such a way that a polymer composed of these monomers only would have a glass transition temperature of from 60.degree. to 125.degree. C.
摘要翻译：可以通过浸渍或涂覆以矿物纤维，非纤维矿物填料和淀粉为主成分的预型体，其中含有包含由以下组成的共聚物的组合物的组合物可获得成型制品：a）60-95重量％的甲基丙烯酸甲酯（单体I ），b）5-40重量％的丙烯酸或甲基丙烯酸（单体II）c）0-35重量％的一种或多种C1-C8-链烷醇（单体III）的丙烯酸酯，d）0-5 可共聚的烯属多不饱和单体（单体IV）的重量％，以及e）0-5重量％的聚合形式的其它可共聚单体（单体V），已经选择了单体I，II，III和V的重量百分数在所述限度内，使得由这些单体组成的聚合物仅具有60至125℃的玻璃化转变温度。

3. 发明授权

US5215827A Polymer-coated precast concrete 失效
标题翻译：聚合物涂层预制混凝土
公开(公告)号：US5215827A
公开(公告)日：1993-06-01
申请号：US802397
申请日：1991-12-04
申请人： Bernhard Dotzauer , Eckehardt Wistuba , Manfred Schwartz , Rolf Petri , Bertold Bechert , Hans-Juergen Denu
发明人： Bernhard Dotzauer , Eckehardt Wistuba , Manfred Schwartz , Rolf Petri , Bertold Bechert , Hans-Juergen Denu
IPC分类号： C04B41/48 , C04B41/63 , C09D133/06
CPC分类号： C04B41/009 , C04B41/483 , C04B41/63 , C09D133/062 , C04B2111/00586 , C04B2111/21 , Y10T428/31855
摘要： Precast concrete which is coated with a copolymer A with a glass transition temperature of rom -25.degree. to +30.degree. C. and composed ofa) from 0.1 to 10% by weight of a monomer of the formula I ##STR1## where R.sup.1 and R.sup.2 are each --H or C.sub.1 -C.sub.4 -alkyl, R.sup.3 is a bridge of from 1 to 20 carbons,R.sup.4 is --C(O)R.sup.6, --C(O)OR.sup.6 or -CNR.sup.5 is --H, --C(OR)R.sup.9, --C(O)OR.sup.9 or --CNX is --O-- or --NR.sup.7 --,Z is a single bond, --CH.sub.2 --, --O--, --NR.sup.8 -- or --O--C(O)-- andR.sup.6, R.sup.7, R.sup.8 and R.sup.9 are each --H, alkyl, aryl, alkaryl or aralkyl of up to 12 carbons,b) from 85 to 99.9% by weight of at least two monomers selected from the group comprising esters of acrylic and methacrylic acid with alcohols containing from 1 to 24 carbons, vinyl esters of carboxylic acids containing from 1 to 20 carbons, vinylaromatic compounds containing up to 20 carbons, ethylenically unsaturated nitriles containing from 3 to 6 carbons, vinyl halides, non-aromatic hydrocarbons containing from 2 to 8 carbons and at least one olefinic double bond andc) from 0 to 10% by weight of other copolymerizable tin-free monomers,is produced as described.
摘要翻译：涂有共聚物A的预制混凝土，其玻璃化转变温度为-25℃至+ 30℃，并由a）0.1至10重量％的式I的单体组成，其中R 1 且R 2为-C（O）R 6，-C（O）OR 6或-CN R 5为-H，-C（O）或）R 9，-C（O）OR 9或-CN X为-O-或-NR 7 - ，Z为单键，-CH 2 - ， - O - ， - NR 8 - 或-OC（O） R 7，R 8和R 9各自为至多12个碳的-H，烷基，芳基，烷芳基或芳烷基，b）85至99.9重量％的至少两种选自丙烯酸和甲基丙烯酸的酯与含有醇的组的单体 1至24个碳原子，含有1-20个碳原子的羧酸乙烯基酯，含有至多20个碳的乙烯基芳族化合物，含有3-6个碳原子的烯键式不饱和腈，卤代乙烯，含有2-8个碳原子的非芳族烃，和至少一个烯属双键和c）0至10 其他可共聚的无锡单体的重量％如上所述制备。

4. 发明授权

US5512629A Aqueous polymer dispersions 失效
公开(公告)号：US5512629A
公开(公告)日：1996-04-30
申请号：US246828
申请日：1994-05-20
申请人： Wilhelm F. Beckerle , Rolf Petri , Bernhard Dotzauer , Manfred Schwartz , Maximilian Angel
发明人： Wilhelm F. Beckerle , Rolf Petri , Bernhard Dotzauer , Manfred Schwartz , Maximilian Angel
IPC分类号： C04B24/26 , C04B28/02 , C08F2/22 , C08F220/12 , C08L35/06
CPC分类号： C08F220/12 , C04B24/2641 , C04B24/2688 , C04B28/02 , C04B2103/0057
摘要： Aqueous dispersions of polymers which have a high glass transition temperature and a low average molecular weight and contain a specific amount of methacrylic acid as polymerized units are suitable, in liquid or dried form, as additives for improving the flow behavior of cement-containing mineral building materials having binding properties.

5. 发明授权

US5576404A Aqueous polymer dispersions 失效
标题翻译：聚合物水分散体
公开(公告)号：US5576404A
公开(公告)日：1996-11-19
申请号：US572740
申请日：1995-12-14
申请人： Wilhelm F. Beckerle , Rolf Petri , Bernhard Dotzauer , Manfred Schwartz , Maximilian Angel
发明人： Wilhelm F. Beckerle , Rolf Petri , Bernhard Dotzauer , Manfred Schwartz , Maximilian Angel
IPC分类号： C04B24/26 , C04B28/02 , C08F2/22 , C08F220/12 , C08L35/06
CPC分类号： C08F220/12 , C04B24/2641 , C04B24/2688 , C04B28/02 , C04B2103/0057
摘要： Aqueous dispersions of polymers which have a high glass transition temperature and a low average molecular weight and contain a specific amount of methacrylic acid as polymerized units are suitable, in liquid or dried form, as additives for improving the flow behavior of cement-containing mineral building materials having binding properties.
摘要翻译：具有高玻璃化转变温度和低平均分子量并含有特定量的甲基丙烯酸作为聚合单元的聚合物的水分散体适合于液体或干燥形式，作为用于改善含水泥矿物建筑物的流动行为的添加剂具有结合性的材料。

6. 发明授权

US4587278A Sound-insulating boards based on mineral fibers and thermoplastic binders 失效
标题翻译：基于矿物纤维和热塑性粘合剂的隔音板
公开(公告)号：US4587278A
公开(公告)日：1986-05-06
申请号：US599575
申请日：1984-04-12
申请人： Bernhard Dotzauer , Hans Kast , Gernot Franzmann , Gregor Ley , Wilhelm F. Beckerle , Wolfgang Schilder
发明人： Bernhard Dotzauer , Hans Kast , Gernot Franzmann , Gregor Ley , Wilhelm F. Beckerle , Wolfgang Schilder
IPC分类号： D21H13/36 , C04B26/06 , C08K7/04 , D21H17/37 , D21H19/16 , C08K7/12 , C08K7/10 , C08K9/02
CPC分类号： C04B26/06 , C08K7/04 , C04B2103/63 , C04B2103/65 , C04B2111/52
摘要： Sound-insulating boards which are based on mineral fibers and thermoplastic binders and may or may not additionally contain fillers, flameproofing agents and water repellants contain, as the binder, from 4 to 20%, based on the weight of the mineral fibers, of polymers having a glass transition temperature of from 30.degree. to 80.degree. C. and consisting of not less than 60% by weight, based on the copolymer, of (meth)acrylates of 1 to 4 carbon atoms and as much as 40% by weight of acrylonitrile and/or styrene.
摘要翻译：基于矿物纤维和热塑性粘合剂的绝缘板，可以或可以不另外含有填充剂，防火剂和防水剂作为粘合剂，以矿物纤维的重量为基准含有4至20％的聚合物玻璃化转变温度为30至80℃，并且由基于共聚物的不小于60重量％的由（甲基）丙烯酸酯组成的含有1至4个碳原子的（甲基）丙烯酸酯和40重量％丙烯腈和/或苯乙烯。

7. 发明授权

US4925529A Light-weight building boards based on mineral fibers and thermoplastic binders 失效
标题翻译：基于矿物纤维和热塑性粘合剂的轻质建筑板材
公开(公告)号：US4925529A
公开(公告)日：1990-05-15
申请号：US788574
申请日：1985-10-17
申请人： Bernhard Dotzauer , Hans Kast , Wilhelm F. Beckerle , Rainer Hummerich
发明人： Bernhard Dotzauer , Hans Kast , Wilhelm F. Beckerle , Rainer Hummerich
IPC分类号： C04B26/06 , C08K5/098
CPC分类号： C04B26/06 , C08K5/098 , C04B2103/0065
摘要： Light-weight building boards which are based on mineral fibers and thermoplastic binders, may furthermore contain fillers, fireproofing agents and water repellents, contain, as the binder, from 4 to 20%, based on the weight of the mineral fibers, of polymers having a glass transition temperature of from 60.degree. to 110.degree. C., and consisting of not less than 60% by weight, based on the copolymer, of (meth)acrylates of alcohols of 1 to 4 carbon atoms and not more than 40% by weight of (meth)acrylonitrile and/or styrene, and additionally contain salts of polyvalent metals with carboxylic acids of 12 to 36 carbon atoms are distinguished by low water absorption and excellent sound-insulating characteristics, are flame-retardant and exhibit dimensional stability even in the tropics.
摘要翻译：基于矿物纤维和热塑性粘合剂的轻质建筑板还可以含有填充剂，防火剂和防水剂，其含有基于矿物纤维重量的4至20％的具有玻璃化转变温度为60〜110℃，由不低于60重量％的共聚物组成，含有1至4个碳原子的醇的（甲基）丙烯酸酯和不超过40％的（甲基）丙烯腈和/或苯乙烯的重量，另外含有碳原子数为12〜36的羧酸的多价金属盐的特征在于低吸水性和优良的隔音特性，阻燃性，即使在热带地区

8. 发明授权

US5696185A Aqueous polymer dispersions 失效
标题翻译：聚合物水分散体
公开(公告)号：US5696185A
公开(公告)日：1997-12-09
申请号：US682167
申请日：1996-07-17
申请人： Wilhelm Friedrich Beckerle , Rolf Petri , Bernhard Dotzauer , Manfred Schwartz , Maximilian Angel
发明人： Wilhelm Friedrich Beckerle , Rolf Petri , Bernhard Dotzauer , Manfred Schwartz , Maximilian Angel
IPC分类号： C04B24/26 , C04B28/02 , C08F2/22 , C08F220/12 , C08L35/06
CPC分类号： C08F220/12 , C04B24/2641 , C04B24/2688 , C04B28/02 , C04B2103/0057
摘要： Aqueous dispersions of polymers which have a high glass transition temperature and a low average molecular weight and contain a specific amount of methacrylic acid as polymerized units are suitable, in liquid or dried form, as additives for improving the flow behavior of cement-containing mineral building materials having binding properties.
摘要翻译：具有高玻璃化转变温度和低平均分子量并含有特定量的甲基丙烯酸作为聚合单元的聚合物的水分散体适合于液体或干燥形式，作为用于改善含水泥矿物建筑物的流动行为的添加剂具有结合性的材料。

9. 发明授权

US5047295A Concrete roof tile 失效
标题翻译：混凝土屋顶瓦
公开(公告)号：US5047295A
公开(公告)日：1991-09-10
申请号：US461916
申请日：1990-01-08
申请人： Bernhard Dotzauer , Rolf Dersch , Johannes Vinke , Harutyun Hanciogullari , Manfred Schwartz , Volkmar Berg
发明人： Bernhard Dotzauer , Rolf Dersch , Johannes Vinke , Harutyun Hanciogullari , Manfred Schwartz , Volkmar Berg
IPC分类号： C04B41/64 , C04B41/48 , C04B41/63 , C09D5/00 , C09D5/14 , E04D1/28
CPC分类号： C04B41/009 , C04B41/4857 , C04B41/63 , C09D5/00 , E04D1/28 , Y10T428/31855
摘要： A concrete roof tile is coated with an unfilled or aggregate- and/or pigment-filled film of a copolymer containing (a) from 0.03 to 2% by weight of tin in the form of a polymerizable organotin compound (b) from 0.5 to 5% by weight of (meth)acrylic acid, (meth)acrylamide and/or vinylsulfonic acid and (c) from 0.1 to 5% by weight of carbonyl-containing monomers crosslinked with certain dicarboxodihydrazides, besides (d) at least two (meth)acrylic esters of C.sub.1 -C.sub.8 alkanols and/or styrene as copolymerized units in such an amount and such mixing ratios that the copolymer has a glass transition temperature of -15 to +10.degree. C. prior to crosslinking.
摘要翻译：涂有混合屋面瓦片，其中未填充或聚集和/或颜料填充的共聚物薄膜包含（a）0.03至2重量％的可聚合有机锡化合物（b）形式的锡0.5至5 （甲基）丙烯酸，（甲基）丙烯酰胺和/或乙烯基磺酸的重量％，（c）0.1〜5重量％的与特定二羧酸酰肼交联的含羰基单体，（d）至少两个（甲基） C1-C8链烷醇和/或苯乙烯的丙烯酸酯作为共聚单元，其量为这样的混合比，使得共聚物在交联之前的玻璃化转变温度为-15至+10℃。

10. 发明授权

US5314936A Aqueous polymer dispersions containing organic compounds having carbonate groups and carbonyl groups and paints and coating systems produced therewith 失效
标题翻译：含有具有碳酸酯基团和羰基的有机化合物的水性聚合物分散体以及由其制备的油漆和涂料体系
公开(公告)号：US5314936A
公开(公告)日：1994-05-24
申请号：US834206
申请日：1992-02-12
申请人： Manfred Schwartz , Reinhard Baecher , Bernhard Dotzauer , Eckehardt Wistuba , Andreas Boettcher
发明人： Manfred Schwartz , Reinhard Baecher , Bernhard Dotzauer , Eckehardt Wistuba , Andreas Boettcher
IPC分类号： C08K5/13 , C04B41/46 , C04B41/48 , C04B41/62 , C04B41/63 , C08K5/10 , C08K5/109 , C08L25/00 , C08L25/14 , C08L33/04 , C08L33/06 , C09D133/04 , C09D133/06 , C08K5/45
CPC分类号： C04B41/009 , C04B41/46 , C04B41/483 , C04B41/62 , C04B41/63 , C08K5/109 , C09D133/062 , C04B2111/00586
摘要： The invention relates to an aqueous polymer dispersion which may optionally contain mineral additives and/or pigments and which essentially consists of a mixture ofA) a 20% to 65% w/w aqueous dispersion of a copolymer of(a) an olefinically unsaturated compound containing one or more carboxyl groups and/or amide groups, and(b) at least two monomers selected from the group consisting of acrylates and methacrylates and vinylaromatic compounds, andB) from 0.1 to 5% w/w, based on the weight of the copolymer contained in component (A), of at least one aromatic ketone of the general formula (I) ##STR1## in which R stands for an alkyl or aryl radical and R.sup.1 stands for an aryl radical containing from 1 to 3 radicals of the formula --O--C(O)--O-- attached to one or more oxaalkylene groups.Such polymer dispersions are suitable for the manufacture of paints and coating systems.
摘要翻译：本发明涉及一种水性聚合物分散体，其可以任选地含有矿物添加剂和/或颜料，并且其基本上由A）20％至65％w / w的（a）烯属不饱和化合物含有一个或多个羧基和/或酰胺基团，和（b）至少两种选自丙烯酸酯和甲基丙烯酸酯和乙烯基芳族化合物的单体，和B）0.1至5％w / w，基于包含在组分（A）中的至少一种通式（I）芳基酮的芳族基团的共聚物，R 1代表含有1-3个式-OC（O）-O-基团的芳基，所述基团连接到一个或多个氧杂亚烷基。这种聚合物分散体适用于制造涂料和涂料体系。

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