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1. 发明授权

US4575516A Cyclopropylmethyl(ene) ethers and arthropocidal use thereof 失效
标题翻译：环丙基甲基（烯）醚及其联合作用
公开(公告)号：US4575516A
公开(公告)日：1986-03-11
申请号：US576073
申请日：1984-02-01
申请人： Bernd-Wieland Kruger , Uwe Priesnitz , Gerhard Jager , Wolfgang Behrenz
发明人： Bernd-Wieland Kruger , Uwe Priesnitz , Gerhard Jager , Wolfgang Behrenz
IPC分类号： C07C43/17 , A01N31/04 , A01N33/08 , C07C17/20 , C07C17/269 , C07C41/00 , C07C43/172 , C07C67/00 , C07C213/00 , C07C217/44 , C07C313/00 , C07C323/04 , C07C43/15 , A01N43/00 , C07C43/162 , C07C43/166
CPC分类号： C07C43/172 , A01N31/04 , C07C17/208 , C07C17/269
摘要： Substituted cyclopropylmethyl(ene) ethers of the formula ##STR1## in which X.sup.1 and X.sup.2 are identical or different and represent halogen,R.sup.1 represents hydrogen or alkyl,R.sup.2 and R.sup.3 are identical or different and represent hydrogen, alkyl, optionally substituted aryl, halogenoalkyl, hetero-alkyl, alkoxyalkyl, alkylthioalkyl, optionally substituted alkenoxyalkyl, optionally substituted alkinoxyalkyl or (di)alkylaminoalkyl,R.sup.4 represents hydrogen or alkyl,R.sup.5 and R.sup.6 are identical or different and represent hydrogen or optionally substituted radicals from the series comprising alkyl, aryl and aralkyl andR represents a trihalogenoalkenyl, alkinyl or iodoalkinyl radical,exhibit some arthropodicidal activity and synergize other known arthropodicides.
摘要翻译：取代的式“IMAGE”的环丙基甲基（烯）醚，其中X 1和X 2相同或不同并且表示卤素，R 1表示氢或烷基，R 2和R 3相同或不同，表示氢，烷基，任选取代的芳基，卤代烷基，杂烷基，烷氧基烷基，烷硫基烷基，任选取代的烯氧基烷基，任选取代的烷氧基烷基或（二）烷基氨基烷基，R 4表示氢或烷基，R 5和R 6相同或不同，代表氢或任选取代的基团，包括烷基，芳基和芳烷基 R代表三卤代烯基，炔基或碘链烯基，表现出一些节肢动物活性，并协同其他已知的节肢动物杀虫剂。

2. 发明授权

US4946850A Agents for repelling insects and mites 失效
标题翻译：用于排斥昆虫和螨虫的药剂
公开(公告)号：US4946850A
公开(公告)日：1990-08-07
申请号：US372801
申请日：1989-06-28
申请人： Bernd-Wieland Kruger , Klaus Sasse , Franz-Peter Hoever , Gunther Nentwig , Wolfgang Behrenz
发明人： Bernd-Wieland Kruger , Klaus Sasse , Franz-Peter Hoever , Gunther Nentwig , Wolfgang Behrenz
IPC分类号： C07D211/32 , A01N37/18 , A01N37/20 , A01N37/44 , A01N43/34 , A01N43/36 , A01N43/40 , A01N43/44 , A01N43/46 , A01N47/06 , C07C233/18 , C07D207/08 , C07D207/27 , C07D211/22
CPC分类号： C07D207/08 , A01N37/20 , A01N43/36 , A01N43/40 , A01N43/44 , A01N43/46 , A01N47/06 , C07D211/22
摘要： Repelling insects and mites with acylated .alpha.,.omega., aminoalcohol derivatives of the formula ##STR1## in which X represents hydrogen, COR.sup.11, COOR.sup.12 or R.sup.13,R.sup.1 represents optionally subsituted alkyl or alkenyl radicals,R.sup.2, R.sup.11, R.sup.12 and R.sup.13 are identical or different and represent optionally substituted alkyl or alkenyl radicals,R.sup.3 to R.sup.10 are identical or different and represent hydrogen, or represent optionally substituted alkyl radicals,and whereinR.sup.2 and R.sup.3, together with the atoms to which they are bonded, can also form an optionally subsituted monocyclic ring, andn and m are identical or different and denote 0 or 1,with the proviso that X does not represent hydrogen or R.sup.13 if n and m represent 0.Those compounds wherein R.sup.2 and R.sup.3 together are --(CH.sub.2).sub.4 -- and R.sup.1 is C.sub.2 -C.sub.6 -alkyl or C.sub.3 -C.sub.6 -alkenyl are new.

3. 发明授权

US4900834A Substituted .alpha.,.omega.-aminoalcohol derivatives 失效
标题翻译：取代的α，ω-氨基醇衍生物
公开(公告)号：US4900834A
公开(公告)日：1990-02-13
申请号：US183941
申请日：1988-04-20
申请人： Bernd-Wieland Kruger , Klaus Sasse , Franz-Peter Hoever , Gunther Nentwig , Wolfgang Behrenz
发明人： Bernd-Wieland Kruger , Klaus Sasse , Franz-Peter Hoever , Gunther Nentwig , Wolfgang Behrenz
IPC分类号： A01N20060101 , A01N47/10 , A01N47/12 , A01N47/16 , A01N47/18 , C07C20060101 , C07C67/00 , C07C239/00 , C07C269/04 , C07C269/06 , C07C271/12 , C07C271/16 , C07D20060101 , C07D211/22 , C07D227/04
CPC分类号： C07C271/16 , A01N47/12 , A01N47/16 , A01N47/18 , C07D211/22 , C07C2101/02 , C07C2101/14 , Y10S514/919
摘要： It has been found that the substituted .alpha.,.omega.-amino-alcohol derivatives, some of which are known, of the formula I ##STR1## in which X represents hydrogen, COR.sup.11, COOR.sup.12 or R.sup.13,R.sup.1 represents optionally substituted alkyl, alkenyl or alkinyl radicalsR.sup.2, R.sup.11, R.sup.12 and R.sup.13 are identical or different and represent optionally substituted alkyl or alkenyl radicals,R.sup.3 to R.sup.10 are identical or different and represent hydrogen, or represent optionally substituted alkyl radicals,and whereinR.sup.2 and R.sup.3 or R.sup.3 and R.sup.7 or R.sup.3 and R.sup.5 or R.sup.5 and R.sup.7, together with the atoms to which they are bonded, can also form an optionally substituted monocyclic ring, andn and m are identical or different and denote 0 or 1,with the proviso that X does not represent hydrogen or R.sup.13 if n and m represent 0,have a powerful insect- and mite-repelling action (repellent action).
摘要翻译：已经发现取代的α，ω-氨基醇衍生物，其中一些是已知的式I（I），其中X表示氢，COR 11，COOR 12或R 13，R 1表示任选取代的烷基，烯基或炔基R2，R11，R12和R13相同或不同，代表任选取代的烷基或烯基，R3至R10相同或不同，代表氢，或代表任选取代的烷基，其中R2和R3或R3和 R 7或R 3和R 5或R 5和R 7与它们所键合的原子一起也可以形成任选取代的单环，并且n和m相同或不同，表示0或1，条件是X不代表氢或R13，如果n和m代表0，具有强大的昆虫和螨虫排斥作用（驱避作用）。

4. 发明授权

US4695563A Arthropodicidal phosphorus-containing heterocycles 失效
标题翻译：类节肢动物的含磷杂环
公开(公告)号：US4695563A
公开(公告)日：1987-09-22
申请号：US870043
申请日：1986-06-03
申请人： Bernd-Wieland Kruger , Wolfgang Behrenz , Benedikt Becker , Bernhard Homeyer , Wilhelm Stendel
发明人： Bernd-Wieland Kruger , Wolfgang Behrenz , Benedikt Becker , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： A01N57/36 , C07F9/6571 , C07F9/6578 , C07F9/21
CPC分类号： C07F9/6578 , A01N57/36 , C07F9/657154 , C07F9/65785
摘要： Novel arthropodicidally active compounds of the formula ##STR1## in which R represents amino or optionally substituted radicals from the series comprising alkyl, alkylamino, methyl-alkylamino, alkoxy, alkenyloxy and alkylthio,R.sup.1 to R.sup.8 are identical or different and represent hydrogen or optionally halogen-substituted radicals from the series comprising alkyl, alkenyl, alkoxyalkyl and alkylthioalkyl, or represent halogen, nitro or dialkylaminoalkyl or represent optionally substituted phenyl or benzyl, and two of the radicals R.sup.1 to R.sup.8, together with the carbon atom or atoms to which they are bonded, may furthermore form an optionally substituted monocyclic or bicyclic ring, andn represents zero or 1.intermediates therefor wherein R is replaced by Cl are also novel.
摘要翻译：其中R表示包含烷基，烷基氨基，甲基 - 烷基氨基，烷氧基，烯氧基和烷硫基的系列中的氨基或任选取代的基团的新型节肢动物活性化合物，其中R代表氨基或任选取代的基团，R 1至R 8相同或不同，表示氢或任选的卤素或者代表任意取代的苯基或苄基，以及其中两个基团R 1 -R 8与它们所代表的碳原子或原子一起形成的烷基，链烯基，烷氧基烷基和烷硫基烷基，还可以形成任选取代的单环或双环，并且n表示0或1，其中R由Cl代替的中间体也是新的。

5. 发明授权

US4387060A 2-Thi-1,3,2-oxazaphospholanes 失效
公开(公告)号：US4387060A
公开(公告)日：1983-06-07
申请号：US202906
申请日：1980-11-03
申请人： Hellmut Hoffmann , Bernd-Wieland Kruger , Wolfgang Behrenz
发明人： Hellmut Hoffmann , Bernd-Wieland Kruger , Wolfgang Behrenz
IPC分类号： A01N57/36 , C07F9/6584 , C07F9/24 , A01N57/26
CPC分类号： C07F9/65844 , A01N57/36
摘要： In a synergistic pesticidal composition comprising (1) a pesticidally active compound and (2) a synergizing agent in amount sufficient to synergize the pesticidal activity of the pesticidally active compound, the improvement which comprises employing as the synergizing agent a 2-(thi)oxo-1,3,2-oxazaphospholane of the formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted alkyl, alkenyl, alkynyl, phenyl, alkoxy, alkenoxy, alkynoxy, alkylthio, aralkoxy, amino, mono- or di-alkylamino, heterocyclic amino, N-alkyl-N-aryl-amino, phenoxy or phenylthio radical,R.sup.1 represents hydrogen, optionally substituted alkyl, aralkyl, alkenyl, alkynyl or dialkylaminoalkyl,R.sup.2 represents hydrogen, alkylthioalkyl, or optionally substituted alkyl or aralkyl, or R.sup.1 and R.sup.2 together represent alkylene,R.sup.3 represents hydrogen or alkyl andR.sup.4 represents hydrogen, alkyl, or phenyl.
摘要翻译：在一种协同杀虫组合物中，其包含（1）农药活性化合物和（2）足以协同农药活性化合物杀虫活性的量的协同剂，其改进包括使用2-（硫代）氧代其中X表示氧或硫，R表示任选取代的烷基，烯基，炔基，苯基，烷氧基，链烯氧基，炔氧基，烷硫基，芳烷氧基，氨基，单或二烷氧基，二烷基氨基，杂环氨基，N-烷基-N-芳基 - 氨基，苯氧基或苯硫基，R 1表示氢，任选取代的烷基，芳烷基，烯基，炔基或二烷基氨基烷基，R 2表示氢，烷硫基烷基或任选取代的烷基或芳烷基，或者R 1和R 2一起表示亚烷基，R 3表示氢或烷基，R 4表示氢，烷基或苯基。

6. 发明授权

US4511562A (Thio)(dithio-phosphates(phosphonates), processes for their preparation, and their use in pest-combating agents 失效
标题翻译：（Thio）（二硫代磷酸酯（膦酸酯）），其制备方法及其在抗虫剂中的应用
公开(公告)号：US4511562A
公开(公告)日：1985-04-16
申请号：US404249
申请日：1982-08-02
申请人： Bernd-Wieland Kruger , Wolfgang Behrenz
发明人： Bernd-Wieland Kruger , Wolfgang Behrenz
IPC分类号： A01N57/02 , C07F9/09 , C07F9/165 , C07F9/20 , C07F9/24 , C07F9/26 , C07F9/40 , C07F9/42 , A01N57/00 , A01N57/16 , A01N57/26 , A01N65/00
CPC分类号： C07F9/425 , A01N57/02 , C07F9/091 , C07F9/1651 , C07F9/1653 , C07F9/20 , C07F9/2408 , C07F9/26 , C07F9/4075 , C07F9/4087
摘要： Pesticidal dicyanohydrin (thiono)(dithio)-phosphates(phosphonates) of the general formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted radical selected from alkyl, alkenyl, alkinyl, aryl, aralkyl, alkoxy, aryloxy, aralkoxy, alkylthio, arylthio, aralkylthio, alkylamino (mono- and dialkylamino), arylamino and aralkylamino, andR.sup.1 and R.sup.2 are identical or different and individually represent a hydrogen atom, an optionally substituted radical selected from alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl and aryl, or an optionally substituted heterocyclic radical,are new and are particularly effective in combating pests, such as insects and acarids, in synergistic combinations with other compounds which are active against arthropods.
摘要翻译：通式为（I）的农药二氰醇（二硫）磷酸酯（膦酸酯），其中X表示氧或硫，R表示任选取代的选自烷基，烯基，炔基，芳基，芳烷基，烷氧基，芳氧基，芳烷氧基，烷硫基，芳硫基，芳烷硫基，烷基氨基（单和二烷基氨基），芳基氨基和芳烷基氨基，R 1和R 2相同或不同，并且各自表示氢原子，任选取代的选自烷基，烯基，炔基，环烷基，环烯基，芳烷基，芳烯基和芳基，或任选取代的杂环基是新的，并且特别有效地与防治节肢动物活性的其它化合物协同组合地对抗害虫，例如昆虫和螨虫。

7. 发明授权

US4609646A 2-(thi)oxo-1,3,2-oxazaphospholanes as synergizing agents for pesticides 失效
标题翻译： 2-（thi）氧代-1,3,2-氧氮杂磷杂环己烷作为农药的协同作用剂
公开(公告)号：US4609646A
公开(公告)日：1986-09-02
申请号：US581470
申请日：1984-02-17
申请人： Hellmut Hoffmann , Bernd-Wieland Kruger , Wolfgang Behrenz
发明人： Hellmut Hoffmann , Bernd-Wieland Kruger , Wolfgang Behrenz
IPC分类号： A01N57/36 , C07F9/6584 , C07F9/24
CPC分类号： C07F9/65844 , A01N57/36
摘要： In a synergistic pesticidal composition comprising (1) a pesticidally active compound and (2) a synergizing agent in amount sufficient to synergize the pesticidal activity of the pesticidally active compound, the improvement which comprises employing as the syngerizing agent a 2-(thi)oxo-1,3,2-oxazaphospholane of the formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted alkyl, alkenyl, alkynyl, phenyl, alkoxy, alkenoxy, alkynoxy, alkylthio, aralkoxy, amino, mono- or di-alkylamino, heterocyclic amino, N-alky-N-aryl-amino, phenoxy or phenylthio radical,R.sup.1 represents hydrogen, optionally subsituted alkyl, aralkyl, alkenyl, alkynyl or dialkylaminoalkyl,R.sup.2 represents hydrogen, alkylthioalkyl; or optionally substituted alkyl or aralkyl, or R.sup.1 and R.sup.2 together represent alkylene,R.sup.3 represents hydrogen or alkyl andR.sup.4 represents hydrogen, alkyl, or phenyl.
摘要翻译：在一种协同杀虫组合物中，其包含（1）杀虫活性化合物和（2）足以协同杀虫活性化合物杀虫活性的量的协同剂，其改进包括使用2-（硫代）氧代其中X表示氧或硫，R表示任选取代的烷基，烯基，炔基，苯基，烷氧基，链烯氧基，炔氧基，烷硫基，芳烷氧基，氨基，单或二烷氧基，二烷基氨基，杂环氨基，N-烷基-N-芳基 - 氨基，苯氧基或苯硫基，R 1表示氢，任选取代的烷基，芳烷基，烯基，炔基或二烷基氨基烷基，R 2表示氢，烷硫基烷基; 或任选取代的烷基或芳烷基，或R 1和R 2一起表示亚烷基，R 3表示氢或烷基，R 4表示氢，烷基或苯基。

8. 发明授权

US4473558A 2-(Thi)oxo-1,3,2-oxazaphospholanes as synergizing agents for pesticides 失效
标题翻译： 2-（Thi）氧代-1,3,2-氧氮杂磷杂环己烷作为农药的协同作用剂
公开(公告)号：US4473558A
公开(公告)日：1984-09-25
申请号：US401461
申请日：1982-07-26
申请人： Hellmut Hoffmann , Bernd-Wieland Kruger , Wolfgang Behrenz
发明人： Hellmut Hoffmann , Bernd-Wieland Kruger , Wolfgang Behrenz
IPC分类号： A01N57/36 , C07F9/6584 , A01N65/00 , A01N57/00 , A01N57/26
CPC分类号： C07F9/65844 , A01N57/36
摘要： In a synergistic pesticidal composition comprising (1) a pesticidally active compound and (2) a synergizing agent in amount sufficient to synergize the pesticidal activity of the pesticidally active compound, the improvement which comprises employing as the synergizing agent a 2-(thi)oxo-1,3,2-oxazaphospholane of the formula ##STR1## in which X represents oxygen or sulphur,R represents an optionally substituted alkyl, alkenyl, alkynyl, phenyl, alkoxy, alkenoxy, alkynoxy, alkylthio, aralkoxy, amino, mono- or di-alkylamino, heterocyclic amino, N-alkyl-N-aryl-amino, phenoxy or phenylthio radical,R.sup.1 represents hydrogen, optionally substituted alkyl, aralkyl, alkenyl, alkynyl or dialkylaminoalkyl,R.sup.2 represents hydrogen, alkylthioalkyl, or optionally substituted alkyl or aralkyl, or R.sup.1 and R.sup.2 together represent alkylene,R.sup.3 represents hydrogen or alkyl andR.sup.4 represents hydrogen, alkyl, or phenyl.
摘要翻译：在一种协同杀虫组合物中，其包含（1）农药活性化合物和（2）足以协同农药活性化合物杀虫活性的量的协同剂，其改进包括使用2-（硫代）氧代其中X表示氧或硫，R表示任选取代的烷基，烯基，炔基，苯基，烷氧基，链烯氧基，炔氧基，烷硫基，芳烷氧基，氨基，单或二烷氧基，二烷基氨基，杂环氨基，N-烷基-N-芳基 - 氨基，苯氧基或苯硫基，R 1表示氢，任选取代的烷基，芳烷基，烯基，炔基或二烷基氨基烷基，R 2表示氢，烷硫基烷基或任选取代的烷基或芳烷基，或者R 1和R 2一起表示亚烷基，R 3表示氢或烷基，R 4表示氢，烷基或苯基。

9. 发明授权

US5008261A Agents for repelling insects and mites 失效
标题翻译：用于排斥昆虫和螨虫的药剂
公开(公告)号：US5008261A
公开(公告)日：1991-04-16
申请号：US423070
申请日：1989-10-18
申请人： Bernd-Wieland Kruger , Klaus Sasse , Franz-Peter Hoever , Gunther Nentwig , Wolfgang Behrenz
发明人： Bernd-Wieland Kruger , Klaus Sasse , Franz-Peter Hoever , Gunther Nentwig , Wolfgang Behrenz
IPC分类号： A01N20060101 , A01N47/10 , A01N47/12 , A01N47/16 , A01N47/18 , C07C20060101 , C07C67/00 , C07C239/00 , C07C269/04 , C07C269/06 , C07C271/12 , C07C271/16 , C07D20060101 , C07D211/22 , C07D227/04
CPC分类号： C07C271/16 , A01N47/12 , A01N47/16 , A01N47/18 , C07D211/22 , C07C2101/02 , C07C2101/14 , Y10S514/919
摘要： It has been found that the substituted .alpha.,.omega.-amino-alcohol derivatives, some of which are known, of the formula I ##STR1## in which X represents hydrogen, COR.sup.11, COOR.sup.12 or R.sup.13,R.sup.1 represents optionally substituted alkyl, alkenyl or alkinyl radicalsR.sup.2, R.sup.11, R.sup.12 and R.sup.13 are identical or different and represent optionally substituted alkyl or alkenyl radicals,R.sup.3 to R.sup.10 are identical or different and represent hydrogen, or represent optionally substituted alkyl radicals,and whereinR.sup.2 and R.sup.3 or R.sup.3 and R.sup.7 or R.sup.3 and R.sup.5 or R.sup.5 and R.sup.7, together with the atoms to which they are bonded, can also form an optionally substituted monocyclic ring, andn and m are identical or different and denote 0 or 1,with the proviso that X does not represent hydrogen or R.sup.13 if n and m represent 0,have a powerful insect- and mite-repelling action (repellent action).

10. 发明授权

US4678777A Pest-combating agents containing phosphorus-heterocyclic compounds 失效
标题翻译：含有磷杂环化合物的抗虫剂
公开(公告)号：US4678777A
公开(公告)日：1987-07-07
申请号：US762979
申请日：1985-08-06
申请人： Bernd-Wieland Kruger , Hellmut Hoffmann , Ernst Roos , Wolfgang Behrenz
发明人： Bernd-Wieland Kruger , Hellmut Hoffmann , Ernst Roos , Wolfgang Behrenz
IPC分类号： A01N57/36 , C07F9/6571
CPC分类号： C07F9/657181 , A01N57/36 , C07F9/657118 , C07F9/657127 , C07F9/657154
摘要： An arthropodicidal composition comprising an arthropodicidally effective amount of an arthropodicidally active compound and a synergistically effective amount of at least one compound of the formula ##STR1## in which A is amino, alkylamino, dialkylamino or N-alkyl-N-arylamino, or an optionally substituted alkyl, alkenyl, alkoxy, alkenyloxy, alkylthio, aralkyl, aralkoxy, phenyl, phenoxy or phenylthio radical,R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each independently is hydrogen, or an optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl or alkylthioalkyl radical, or is halogen, nitro or dialkylaminoalkyl, or is optionally substituted phenyl or benzyl, or two of the radicals R.sup.1 to R.sup.8, together with the carbon atom or atoms to which they are bonded form an optionally substituted monocyclic or bicyclic ring andn and m each independently is 0 or 1.
摘要翻译：一种节肢动物杀伤组合物，其包含节肢动物节肢动物有效量的节肢动物杀虫活性化合物和协同有效量的至少一种下式的化合物，其中A是氨基，烷基氨基，二烷基氨基或N-烷基-N-芳基氨基，或任选地取代的烷基，烯基，烷氧基，烯氧基，烷硫基，芳烷基，芳烷氧基，苯基，苯氧基或苯硫基，R1，R2，R3，R4，R5，R6，R7和R8各自独立地为氢或任选卤素取代的烷基，烯基，烷氧基烷基或烷硫基烷基，或为卤素，硝基或二烷基氨基烷基，或任选取代的苯基或苄基，或两个基团R 1至R 8与它们所连接的碳原子或原子一起形成任选取代的单环或双环，n和m各自独立地为0或1。

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