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1. 发明授权

US5198325A Photopolymerizable mixture, copying material containing same and process for producing highly heat-resistant relief structures wherein a trihalomethyl is the photoinitiator 失效
标题翻译：光聚合性混合物，复合材料及其制造方法，用于生产三氯甲烷是光敏剂的高耐热性缓冲结构
公开(公告)号：US5198325A
公开(公告)日：1993-03-30
申请号：US199296
申请日：1988-05-26
申请人： Bernd Hupfer , Gerhard Buhr , Charlotte Eckes
发明人： Bernd Hupfer , Gerhard Buhr , Charlotte Eckes
IPC分类号： C08F2/48 , C08F2/50 , G03F7/029
CPC分类号： G03F7/0295
摘要： A photopolymerizable mixture for producing relief structures composed of highly heat-resistant polymers is described which is composed essentially of a soluble prepolymer containing photosensitive radicals bound in an ester-like manner to carboxyl groups, monomers and a photoinitiator, wherein the photoinitiator carries at least one trihalomethyl group which reacts when exposed to light. Of advantage is the fact that, even after exposure times which are by a factor of 4 to 5 shorter compared with conventional photopolymerizable mixtures, sharp-edged resist images can be obtained with a resolution of less than 3 .mu.m.
摘要翻译：描述了一种用于生产由高耐热聚合物组成的浮雕结构的可光聚合混合物，其基本上由含有以类似羧基的光敏基团结合的可溶性预聚物，单体和光引发剂组成，其中光引发剂携带至少一种当暴露于光时反应的三卤代甲基。其优点在于，与常规的可光聚合混合物相比，即使曝光时间比4至5倍更短的事实，可以以小于3μm的分辨率获得锐利边缘的抗蚀剂图像。

2. 发明授权

US5725992A Process for the production of a multicolored image and photosensitive material for carrying out this process 失效
标题翻译：用于生产多彩图像和感光材料以进行该过程的方法
公开(公告)号：US5725992A
公开(公告)日：1998-03-10
申请号：US20829
申请日：1993-02-19
申请人： Stephan J. W. Platzer , Wojciech A. Wilczak , Gerhard Buhr , Dieter Mohr
发明人： Stephan J. W. Platzer , Wojciech A. Wilczak , Gerhard Buhr , Dieter Mohr
IPC分类号： G03C1/675 , C08F2/50 , G03F3/10 , G03F7/004 , G03F7/027 , G03F7/029 , G03F7/105 , G03F7/34 , G03C1/795
CPC分类号： G03F3/106 , G03F7/0295 , Y10S430/121 , Y10S430/126 , Y10S430/127
摘要： A photosensitive material for the production of color proofing films for multicolor printing, having (A) a transparent, flexible film support, (B) a photopolymerizable layer which contains (B1) a polymeric binder, (B2) a free-radical-polymerizable compound, (B3) a substituted bistrihalomethyl-s-triazine having an absorption maximum in the range from 300 to 380 nm and an absorbance of greater than 11,000 at the absorption maximum, and an absorbance of less than 1400 at 400 nm and above, as photoinitiator, and (B4) a dye or a colored pigment in a primary color of multicolor printing, and (C) a thermoplastic adhesive layer on the photo-sensitive layer. The material is processed by lamination onto an image-receiving material, exposure of the material and peeling apart of film support and image-receiving material, leaving the unexposed layer areas on the image-receiving material together with the adhesive layer. To produce a multicolored image, these steps are repeated with at least one further single-color sheet. The material has increased photosensitivity and gives color prints with lower background discoloration.
摘要翻译：一种用于生产多色印刷用彩色印刷膜的感光材料，其具有（A）透明柔性膜载体，（B）含有（B1）聚合物粘合剂的可光聚合层，（B2）可自由基聚合的化合物，（B3）作为光引发剂，吸收最大值为300〜380nm，吸收最大吸光度为11000以上，400nm以上的吸光度小于1400的取代双三甲基-s-三嗪，和（B4）多色印刷原色的染料或着色颜料，（C）感光层上的热塑性粘合剂层。该材料通过层压到图像接收材料上，曝光材料并剥离薄膜载体和图像接收材料，将图像接收材料上的未曝光层区域与粘合剂层一起留下。为了产生多色图像，这些步骤与至少一个另外的单色片重复。该材料具有增加的光敏性，并且具有较低背景变色的彩色印刷品。

3. 发明授权

US5529883A Photosensitive material for the production of a colored image utilizing adhesion promoting layer 失效
标题翻译：用于生产利用粘附促进层的彩色图像的感光材料
公开(公告)号：US5529883A
公开(公告)日：1996-06-25
申请号：US288323
申请日：1994-08-10
申请人： Stephan J. W. Platzer , Andrea Buchmann , Gerhard Buhr
发明人： Stephan J. W. Platzer , Andrea Buchmann , Gerhard Buhr
IPC分类号： G03F7/004 , G03F3/10 , G03F7/11 , G03F7/34 , G03F7/105
CPC分类号： G03F3/10
摘要： A photosensitive material comprising (A) a flexible transparent film support, (B) a colored photosensitive layer which contains an organic binder (B1) a dye or a colored pigment (B2), a compound (B3), which forms a strong acid on exposure to radiation, and a compound (B4) which has at least one group cleavable by the acid, and (C) an adhesion-promoting layer which contains a thermoplastic polymer which has a softening temperature in the range from 40.degree. to 200.degree. C., wherein the adhesion (a.sub.1) of the unexposed photosensitive layer (B) to the adhesion-promoting layer (C) is less than the adhesion (a.sub.3) of the unexposed photosensitive layer (B) to the film support (A) and than the cohesions of the layers (B) and (C), and the adhesion (a.sub.3 ') of the exposed photosensitive layer (B) to the film support (A) is less than the adhesion (a.sub.1 ') of the exposed photosensitive layer (B) to the adhesion-promoting layer (C) and than the cohesions of the adhesion-promoting layer (C) and of the exposed photosensitive layer (B) is useful for the production of a colored image, in particular, is useful in a color proofing method for multicolor printing, which process gives images having high resolution.
摘要翻译：一种感光材料，其包含（A）柔性透明膜载体，（B）含有有机粘合剂（B1）染料或着色颜料（B2）的着色感光层，在其上形成强酸的化合物（B3）以及具有至少一个可被酸裂解的基团的化合物（B4），和（C）含有软化温度在40〜200℃的热塑性聚合物的粘合促进层其中未曝光的感光层（B）对粘合促进层（C）的粘合力（a1）小于未曝光的感光层（B）对膜载体（A）的粘附（a3），而不是层（B）和（C）的粘合力和曝光的感光层（B）对膜支撑体（A）的粘合力（a3'）小于曝光的感光层（ B）与粘附促进层（C）的粘合力和粘附促进层（C）和暴露的ph 感光层（B）对于彩色图像的制备是有用的，特别是在多色打印的彩色打样方法中是有用的，该方法给出具有高分辨率的图像。

4. 发明授权

US5162190A 1,2-naphthoquinone-2-diazide-sulfonic acid amides and photosensitive compositions containing these compounds 失效
标题翻译：含有这些化合物的1,2-萘磺酸-2-二亚磺酸 - 酰胺类和感光性组合物
公开(公告)号：US5162190A
公开(公告)日：1992-11-10
申请号：US373036
申请日：1989-06-29
申请人： Wolfgang Zahn , Gerhard Buhr , Hartmut Steppan
发明人： Wolfgang Zahn , Gerhard Buhr , Hartmut Steppan
IPC分类号： C07C311/14 , C07C311/17 , G03F7/022 , G03F7/023
CPC分类号： C07C311/14 , C07C311/17 , G03F7/022
摘要： A compound of the general formula I ##STR1## in which D denotes a 1,2-naphthoquinone-2-diazide-4-sulfonyl or - 5-sulfonyl radical,R.sup.1 denotes an alkylene group andR.sup.2 denotes a hydrogen atom, an alkyl group or a group R.sup.1 --OH,or of the general formula II ##STR2## in which X denotes an alkylene group, an arylene group or a group of the formulaNH--Y--NH, wherein Y is an alkylene group or an arylene group,R.sup.3 denotes an alkylene group, which may be interrupted by ether oxygen atoms,n is a number from 1 to 40 andm is a number from 0 to 50,the ratio m:(m+n) being from 0:100 to 95:100 and R.sup.1 and D having the above-indicated meaning, are disclosed. The compounds may be used in positive-working photosenitive materials for the production of printing plates and photoresists. Compounds according to formula II do not require an addition of polymeric binders.
摘要翻译：其中D表示1,2-萘醌-2-重氮基-4-磺酰基或-5-磺酰基的通式I（I）的化合物，R 1表示亚烷基，R 2表示氢原子，烷基或基团R 1 -OH，或通式II其中X表示亚烷基，亚芳基或式NH-Y-NH基，其中Y 是亚烷基或亚芳基，R3表示可被醚氧原子间隔的亚烷基，n为1〜40的数，m为0〜50的数，m：（m + n ）为0：100〜95：100，R1和D为上述含义。这些化合物可用于生产印刷板和光致抗蚀剂的正性光敏材料。根据式II的化合物不需要加入聚合物粘合剂。

5. 发明授权

US4914721A Safety device 失效
公开(公告)号：US4914721A
公开(公告)日：1990-04-03
申请号：US266483
申请日：1988-11-02
申请人： Karl C. Glaeser , Gerhard Buhr , Joachim Cardinal , Klaus Genuit , Detlef Lohmuller , Heinz Tilmans
发明人： Karl C. Glaeser , Gerhard Buhr , Joachim Cardinal , Klaus Genuit , Detlef Lohmuller , Heinz Tilmans
IPC分类号： B24C5/02 , B24C7/00 , F16P3/12 , H03K17/94
CPC分类号： B24C7/00 , B24C5/02 , F16P3/12 , H03K17/94 , H01H2009/0221 , H01H2223/04 , H01H2300/026 , Y10S200/02 , Y10T307/76 , Y10T307/766
摘要： A safety device for an apparatus to be manipulated by an operator. The apparatus is connected via a supply line for a supply means to a supply means source. A handgrip is provided to be grasped by the operator for controlling the operation of the apparatus. An operating sensor is actuated by the operator and is connected to the control device. The operating sensor may be an electric proximity switch provided so that it is possible to shut off the apparatus when the operator ceases to actuate the operating sensor. The operating sensor, or at least one indiciator element of the operating sensor, is disposed on the hand of the operator, particularly integrated into a protective glove for the hand of the operator.

6. 发明授权

US4774171A Bis-1,2-naphthoquinone-2-diazide-sulfonic acid amides, their use in a radiation-sensitive mixture, and radiation-sensitive copying material 失效
标题翻译：双-1,2-萘醌-2-二叠氮磺酸酰胺，它们在辐射敏感混合物中的用途和辐射敏感性复制材料
公开(公告)号：US4774171A
公开(公告)日：1988-09-27
申请号：US10640
申请日：1987-02-04
申请人： Wolfgang Zahn , Gerhard Buhr
发明人： Wolfgang Zahn , Gerhard Buhr
IPC分类号： G03C1/72 , C07C67/00 , C07C301/00 , C07C311/29 , C07C311/37 , G03C1/73 , G03F7/022 , G03C1/54 , C07C113/00
CPC分类号： G03F7/022
摘要： Novel bis-1,2-naphthoquinone-2-diazide-sulfonic acid amides of secondary diamines, which amides are represented by the formula ##STR1## in which R is a straight-chain or branched, unsubstituted or hydroxyl-substituted alkyl, cycloalkyl or aralkyl radical which has 1 to 14 carbon atoms and which includes a carbon chain that can be interrupted by either oxygen atoms,R.sub.1 is an alkylene radical which has 2 to 12 carbon atoms and which includes a carbon chain that can be interrupted by ether oxygen atoms, or a mononuclear or polynuclear aralkylene radical which has 8 to 18 carbon atoms and which can, when it is a polynuclear radical, comprise aromatic members that are linked by a single bond, by --O--, --S--, --CO-- or --CR.sub.2 R.sub.3 --, --N[C.sub.1-3 -alkyl]CO-- or a C.sub.2-5 -alkyl group which can be interrupted by ether oxygen atoms, andR.sub.2 and R.sub.3 can be identical or different, and are separately hydrogen or an alkyl radical which is unsubstituted or substituted and which has 1 or 2 carbon atoms, orR and R.sub.1 together form a cycloalkyl radical which has 4 to 16 carbon atoms and which can, when it is a polynuclear radical, comprise cycloaliphatic moieties that are linked by a carbon chain having 1 to 6 carbon atoms,andD.sub.1 and D.sub.2 are identical or different and are 1,2-naphthoquinone-2-diazide-4- or -5-sulfonyl radicals.The compounds can be used as radiation-sensitive components in radiation-sensitive mixtures for copying materials, as they are characterized by good absorption in the range from 300 to 350 nm.
摘要翻译：次酰胺的新型双-1,2-萘醌-2-二叠氮化物 - 磺酸酰胺由式（I）表示，其中R是直链或支链，未取代或羟基取代的烷基，具有1至14个碳原子的环烷基或芳烷基，并且包括可以被氧原子间隔的碳链，R 1是具有2至12个碳原子的亚烷基，并且包括可以被醚氧原子或具有8至18个碳原子的单核或多核亚芳基，当其为多核基团时，其可以包含通过单键连接的芳族成员，-O - ， - S - ， - CO-或-CR 2 R 3 - ， - N [C 1-3 - 烷基] CO-或可被醚氧原子间隔的C 2-5 - 烷基，R 2和R 3可以相同或不同，并且分别为氢或未取代或取代且具有1或2个碳原子的烷基，或R和R 1 其形成具有4至16个碳原子的环烷基，并且当其为多核基团时，其可以包含通过具有1至6个碳原子的碳链连接的脂环族部分，并且D1和D2相同或不同，并且是 1,2-萘醌-2-二叠氮-4-或5-磺酰基。这些化合物可以用作用于复印材料的辐射敏感混合物中的辐射敏感组分，因为它们的特征在于在300至350nm范围内的良好吸收。

7. 发明授权

US4101323A Radiation-sensitive copying composition 失效
标题翻译：辐射敏感复印组合物
公开(公告)号：US4101323A
公开(公告)日：1978-07-18
申请号：US669892
申请日：1976-03-24
申请人： Gerhard Buhr , Hans Ruckert , Hans Werner Frass
发明人： Gerhard Buhr , Hans Ruckert , Hans Werner Frass
IPC分类号： G03F7/039 , G01T1/04 , G03C1/72 , G03C1/73 , G03F3/10 , G03F7/004 , G03F7/016 , G03F7/022 , G03C5/00 , G03C1/00 , G03C1/52
CPC分类号： G03F7/0045 , G01T1/04 , G03F3/10 , G03F7/016 , G03F7/022
摘要： This invention relates to a radiation-sensitive copying composition comprising a compound (1) which splits-off an acid upon irradiation and a compound (2) having at least one group selected from the group consisting of a carboxylic ortho acid ester group and a carboxylic acid amide acetal group, which composition, upon irradiation, forms an exposure product having a higher solubility in a liquid developer than the non-irradiated composition.
摘要翻译：本发明涉及一种辐射敏感复印组合物，其包含在照射时分解酸的化合物（1）和具有至少一个选自羧酸原酸酯基和羧酸的基团的化合物（2）酰胺缩醛基，该组合物在照射时形成与未照射组合物相比在液体显影剂中具有更高溶解度的曝光产品。

8. 发明授权

US5998567A Radiation-sensitive mixture 失效
标题翻译：辐射敏感混合物
公开(公告)号：US5998567A
公开(公告)日：1999-12-07
申请号：US932964
申请日：1997-09-18
申请人： Mathias Eichhorn , Gerhard Buhr
发明人： Mathias Eichhorn , Gerhard Buhr
IPC分类号： G03F7/004 , G03F7/039 , C08G63/02
CPC分类号： G03F7/0045
摘要： A radiation-sensitive mixture which contains (a) a compound of the formula (I) ##STR1## where R.sup.1 is an optionally substituted alkyl radical, R.sup.2 is a hydrogen atom or an optionally substituted alkyl radical containing 1 to 4 carbon atoms, R.sup.3 is an n-valent, optionally polymeric aliphatic or aromatic radical and n is a number from 1 to 100; and b) a compound which forms a strong acid on exposure to actinic radiation.
摘要翻译：一种辐射敏感性混合物，其包含（a）式（I）的化合物，其中R 1是任选取代的烷基，R 2是氢原子或任选取代的含有1至4个碳原子的烷基，任选的聚合的脂族或芳族基，n是1至100的数; 和b）在暴露于光化辐射下形成强酸的化合物。

9. 发明授权

US5879852A Positive-working radiation-sensitive mixture 失效
标题翻译：正面工作的辐射敏感混合物
公开(公告)号：US5879852A
公开(公告)日：1999-03-09
申请号：US841659
申请日：1997-04-30
申请人： Mathias Eichhorn , Gerhard Buhr
发明人： Mathias Eichhorn , Gerhard Buhr
IPC分类号： G03F7/004 , G03F7/00 , G03F7/016 , G03F7/039 , H01L21/027 , C08F8/14 , C08F8/10 , G03C1/52
CPC分类号： G03F7/0045 , G03F7/039 , Y10S430/111
摘要： The invention relates to a positive-working radiation-sensitive mixture containing a) a polymeric binder having acid-labile groups and b) a compound which forms a strong acid on irradiation, in which the binder simultaneously contains units of the formulae I, II and IIIR.sup.1 --OH (I),R.sup.1 --O--CO.sub.2 R.sup.2 (II)R.sup.1 --O--CH.sub.2 --CHR.sup.3 --OH (III).The mixture is used to coat radiation-sensitive recording material which can be used to produce printing plates and photoresists.
摘要翻译：本发明涉及一种正性工作辐射敏感性混合物，其包含a）具有酸不稳定基团的聚合物粘合剂，和b）在照射下形成强酸的化合物，其中所述粘合剂同时含有式I，II和 IIIR1-OH（I），R1-O-CO2R2（II）R1-O-CH2-CHR3-OH（III）。该混合物用于涂覆可用于制备印刷版和光致抗蚀剂的辐射敏感记录材料。

10. 发明授权

US5563018A (1,2-naphthoquinone 2-diazide) sulfonic acid esters, radiation-sensitive mixture prepared therewith and radiation-sensitive recording material 失效
标题翻译：（1,2-萘醌2-二叠氮化物）磺酸酯，其制备的辐射敏感性混合物和辐射敏感记录材料
公开(公告)号：US5563018A
公开(公告)日：1996-10-08
申请号：US32276
申请日：1993-03-17
申请人： Gerhard Buhr , Wolfgang Zahn , Fritz Erdmann , Siegfried Scheler
发明人： Gerhard Buhr , Wolfgang Zahn , Fritz Erdmann , Siegfried Scheler
IPC分类号： C07C309/71 , C07C309/74 , G03F7/022 , H01L21/027 , G03F7/023
CPC分类号： C07C309/71 , G03F7/022
摘要： The invention relates to 2,3,4-trihydroxy-3'-methyl-, -ethyl-, -propyl- or -isopropylbenzophenone which is completely esterified with (1,2-naphthoquinone 2-diazide)-4-sulfonic acid and/or (7-methoxy-1,2-naphthoquinone 2-diazide)-4-sulfonic acid, a radiation-sensitive mixture prepared therewith, and a radiation-sensitive recording material comprising a substrate and a radiation-sensitive layer which is composed of the mixture according to the invention.
摘要翻译：本发明涉及用（1,2-萘醌-2-二叠氮化物）-4-磺酸和/或其盐完全酯化的2,3,4-三羟基-3'-甲基 - ， - 乙基 - ， - 丙基 - 异丙基二苯甲酮和/ 或（7-甲氧基-1,2-萘醌-2-二叠氮化物）-4-磺酸，其制备的辐射敏感性混合物，以及包含基材和辐射敏感层的辐射敏感记录材料，其由混合物。

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