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1. 发明授权

US4211637A FCC Catalyst section control 失效
标题翻译： FCC催化剂部分控制
公开(公告)号：US4211637A
公开(公告)日：1980-07-08
申请号：US931600
申请日：1978-08-07
申请人： Benjamin Gross , Wooyoung Lee
发明人： Benjamin Gross , Wooyoung Lee
IPC分类号： B01J8/26 , C10G11/18
CPC分类号： C10G11/187 , B01J8/26 , Y10S208/01
摘要： In the fluid catalytic cracking process, improved adaptive behavior of the catalyst section with the regenerator operating in the complete CO-burning mode is achieved by including within the regenerator, as an element of control, variable recycle of regenerated to spent catalyst. In response to excursions of the regenerated catalyst temperature, such as would be caused by change of feedstock, the recycle ratio is altered in a direction to restore the temperature to a predetermined value. The improved control system extends the useful control range, and it also diminishes counterproductive changes in severity induced by disturbances such as change of feedstock quality.
摘要翻译：在流化催化裂化过程中，通过在再生器内包含作为对照元素的可再循环再生到废催化剂来实现具有以完全CO燃烧模式操作的再生器的催化剂部分的改进的适应行为。响应于再生催化剂温度的偏移，例如由原料变化引起的再循环比例，在使温度恢复到预定值的方向上改变再循环比。改进的控制系统延伸了有用的控制范围，并且还减少了干扰引起的严重性的反作用变化，例如原料质量的变化。

2. 发明授权

US4282084A Catalytic cracking process 失效
标题翻译：催化裂化过程
公开(公告)号：US4282084A
公开(公告)日：1981-08-04
申请号：US137877
申请日：1980-04-07
申请人： Benjamin Gross , Wooyoung Lee
发明人： Benjamin Gross , Wooyoung Lee
IPC分类号： C10G11/18
CPC分类号： C10G11/18 , C10G11/187 , Y02P30/446 , Y10S208/01
摘要： An improved catalytic process wherein trace amounts of a metal of period 5 and 6 of Group VIII or rhenium is added to the total catalyst inventory for cracking of gas oil is disclosed. With this improved process, the yield of gasoline, fuel oil, total cracked products, or predetermined combinations thereof, is maximized for the fluid catalytic cracking of any predetermined feed, usually a gas oil. The process employs a kinetic predictive or a correlative model of the cracking process to identify proper operating conditions, including CO.sub.2 /CO ratio in the effluent from the regenerator, and also requires control of the metal activity to achieve optimal conversion of CO to CO.sub.2 in the regenerator.Also disclosed is an improved method for control of a fluid catalytic process wherein the cracking catalyst comprises trace amounts of a metal selected from the group Pt, Pd, Rh, Ru, Ir, Os and Re.
摘要翻译：公开了一种改进的催化方法，其中将痕量的VIII族或铼的第5和6周期的金属加入到用于瓦斯油裂化的总催化剂库存中。通过这种改进的方法，对于任何预定进料（通常为瓦斯油）的流化催化裂化，汽油，燃料油，总裂化产物或其预定组合的产率最大化。该过程采用裂解过程的动力学预测或相关模型来识别合适的操作条件，包括来自再生器的流出物中的CO 2 / CO比，并且还需要控制金属活性以实现CO在CO 2中的最佳转化再生器。还公开了用于控制流体催化方法的改进方法，其中裂化催化剂包含痕量的选自Pt，Pd，Rh，Ru，Ir，Os和Re的金属。

3. 发明授权

US4211636A FCC Catalyst section control 失效
标题翻译： FCC催化剂部分控制
公开(公告)号：US4211636A
公开(公告)日：1980-07-08
申请号：US931573
申请日：1978-08-07
申请人： Benjamin Gross , Wooyoung Lee
发明人： Benjamin Gross , Wooyoung Lee
IPC分类号： B01J8/26 , C10G11/18
CPC分类号： B01J8/26 , C10G11/187 , Y10S208/01
摘要： In the fluid catalytic cracking process, improved adaptive behavior of the catalyst section with the regenerator operating in the complete CO-burning mode is achieved by including, as elements of control, variable preheat of the oil feed and variable recycle of regenerated catalyst to spent catalyst. In response to excursions of the regenerated catalyst temperature, such as would be caused by change of feedstock, the oil preheat temperature and recycle ratio are altered in a direction to restore the regenerated catalyst temperature to a predetermined value. The improved control system extends the useful control range, and it also diminishes counterproductive changes in severity induced by disturbances such as change of feedstock quality.
摘要翻译：在流化催化裂化过程中，催化剂部分与再生器在完全CO燃烧模式下运行的改进的适应行为通过包括作为控制元素的油进料可变预热和再生催化剂可再循环到废催化剂。响应于再生催化剂温度的偏移，例如由原料变化引起的油的预热温度和再循环率在一个方向上改变，以将再生催化剂温度恢复到预定值。改进的控制系统延伸了有用的控制范围，并且还减少了干扰引起的严重性的反作用变化，例如原料质量的变化。

4. 发明授权

US4093537A FCC Catalyst section control 失效
标题翻译： FCC催化剂部分控制
公开(公告)号：US4093537A
公开(公告)日：1978-06-06
申请号：US769639
申请日：1977-02-17
申请人： Benjamin Gross , Wooyoung Lee
发明人： Benjamin Gross , Wooyoung Lee
IPC分类号： B01J8/26 , C10G11/18 , C10G13/18
CPC分类号： B01J8/26 , C10G11/187 , Y10S208/01
摘要： In the fluid catalytic cracking process, improved adaptive behavior of the catalyst section with the regenerator operating in the complete CO-burning mode is achieved by including, as elements of control, variable preheat of the air feed and variable recycle of regenerated catalyst to spent catalyst. In response to excursions of the regenerated catalyst temperature, such as would be caused by change of feedstock, the air preheat temperature and recycle ratio are altered in a direction to restore the regenerated catalyst temperature to a predetermined value. The improved control system extends the useful control range, and it also diminishes counterproductive changes in severity induced by disturbances such as change of feedstock quality.
摘要翻译：在流化催化裂化过程中，催化剂段与采用完全CO燃烧模式工作的再生器的改进的适应行为是通过将作为控制元件的空气进料的可变预热和再生催化剂可再循环到废催化剂。响应于再生催化剂温度的偏移，例如由原料变化引起的空气预热温度和再循环比在沿再生催化剂温度恢复到预定值的方向上改变。改进的控制系统延伸了有用的控制范围，并且还减少了干扰引起的严重性的反作用变化，例如原料质量的变化。

5. 发明授权

US4304951A Hydrotreating of bottoms fractions resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate 失效
$Hydrotreating of bottoms fractions resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate$
标题翻译：加氢处理从甲醇转化成汽油产生的塔底馏分，以减少杜烯并产生馏出物
公开(公告)号：US4304951A
公开(公告)日：1981-12-08
申请号：US225061
申请日：1981-01-14
申请人： William E. Garwood , Wooyoung Lee , Hans J. Schoennagel
发明人： William E. Garwood , Wooyoung Lee , Hans J. Schoennagel
IPC分类号： C10G3/00 , C10G45/44 , C10G45/58 , C10G45/60 , C10G45/62 , C10G47/12 , C10G47/16 , C10G47/20 , C07C1/20
CPC分类号： C10G45/44 , C10G45/58 , Y02P30/20
摘要： A durene-containing gasoline obtained from the catalytic conversion of methanol after removal of at least the light olefinic fraction is subjected to hydrotreating by contact with hydrogen over a hydrogenation metal on an acidic or non-acidic support.
摘要翻译：在除去至少轻的烯属馏分之后，从甲醇的催化转化得到的含有杜烯的汽油通过在酸性或非酸性载体上的氢化金属上与氢接触进行加氢处理。

6. 发明授权

US4413153A Integrated process for making transportation fuels and lubes from wet natural gas 失效
标题翻译：从湿天然气制造运输燃料和润滑油的综合过程
公开(公告)号：US4413153A
公开(公告)日：1983-11-01
申请号：US436158
申请日：1982-10-22
申请人： William E. Garwood , Wooyoung Lee
发明人： William E. Garwood , Wooyoung Lee
IPC分类号： C10G3/00 , C10G50/00 , C10G57/02 , F02B3/06 , C07C1/04
CPC分类号： C10G50/00 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , F02B3/06 , Y02P30/20
摘要： The synthetic fuel slate of products derived from wet natural gas is expanded to include both aromatic gasoline from the methane rich dry gas portion via steam reforming to synthesis gas, the production of methanol from synthesis gas and the conversion of methanol to gasoline over a ZSM-5 type catalyst, plus high quality jet fuel, diesel fuel and lubricating oils from the C.sub.3.sup.+ paraffin rich fraction of wet natural gas via thermal cracking of the paraffin rich fraction to olefins and the conversion of the olefins to gasoline and distillate boiling range hydrocarbons over a ZSM-5 type catalyst. Methane separated from the thermal cracked product can be mixed with the dry gas fraction for synthesis gas production and a portion of the hydrogen from the synthesis gas may be used to hydrogenate the distillate fraction from the catalytic conversion of the thermal cracked product.
摘要翻译：来自湿天然气的产品的合成燃料石板膨胀，包括从富甲烷干燥部分通过蒸汽重整到合成气的芳香族汽油，从合成气生产甲醇，通过ZSM- 5型催化剂，加上高品质的喷气燃料，柴油燃料和润滑油，通过富含馏分的烯烃的热裂解将烯烃转化为汽油和馏出物沸点烃，来自富含天然气的C3 +石蜡馏分 ZSM-5型催化剂。与热裂解产物分离的甲烷可以与用于合成气生产的干燥气体馏分混合，并且可以使用来自合成气的一部分氢气从热裂化产物的催化转化中氢化馏出物馏分。

7. 发明授权

US4227992A Process for separating ethylene from light olefin mixtures while producing both gasoline and fuel oil 失效
标题翻译：在轻质烯烃混合物中分离乙烯同时生产汽油和燃油的方法
公开(公告)号：US4227992A
公开(公告)日：1980-10-14
申请号：US41843
申请日：1979-05-24
申请人： William E. Garwood , Wooyoung Lee
发明人： William E. Garwood , Wooyoung Lee
IPC分类号： B01J29/40 , C07C7/148 , C10G29/16 , C10G35/095 , C10G35/06
CPC分类号： C10G35/095 , B01J29/40 , C07C7/148 , C10G29/16 , Y02P20/52
摘要： A process is disclosed for separating ethylene in admixture with light olefins by contacting said olefinic mixture under very critical reaction conditions over a special catalyst, such as a zeolite of the ZSM-5 type so as to selectively react the C.sub.3 and higher olefins and convert the same to both gasoline and fuel oil.
摘要翻译：公开了一种用于通过在非常临界的反应条件下使所述烯烃混合物在特殊催化剂如ZSM-5型沸石上接触来分离乙烯与轻质烯烃混合的方法，以选择性地使C3和更高级烯烃反应，并将与汽油和燃油相同。

8. 发明授权

US4197418A Heat disposed in lower alcohols and derivatives conversion to gasoline hydrocarbons in a crystaline zeolite fluidized bed 失效
标题翻译：放置在低级醇中的热量和衍生物转化为结晶沸石流化床中的汽油烃
公开(公告)号：US4197418A
公开(公告)日：1980-04-08
申请号：US16596
申请日：1979-03-01
申请人： Wooyoung Lee , Sergei Yurchak
发明人： Wooyoung Lee , Sergei Yurchak
IPC分类号： B01J8/18 , B01J8/34 , B01J8/38 , B01J21/12 , B01J29/00 , C07B61/00 , C07C1/00 , C07C1/20 , C07C67/00 , C10G3/00 , C07C11/00 , C07C15/02
CPC分类号： C10G3/57 , B01J8/1836 , B01J8/34 , B01J8/388 , C07C1/20 , C10G3/49 , C10G3/62 , B01J2208/00141 , C07C2529/40 , C10G2300/4006 , C10G2400/02 , C10G2400/30 , Y02P20/584 , Y02P30/20
摘要： A method and means for disposing of undesired heat in the conversion of lower alcohols and their derivatives to higher boiling gasoline hydrocarbons in a crystalline zeolite fluidized bed.
摘要翻译：在结晶沸石流化床中将低级醇及其衍生物转化成较高沸点汽油烃的方法和方法。

9. 发明授权

US4211640A Process for the treatment of olefinic gasoline 失效
标题翻译：烯烃汽油的处理方法
公开(公告)号：US4211640A
公开(公告)日：1980-07-08
申请号：US41844
申请日：1979-05-24
申请人： William E. Garwood , Wooyoung Lee
发明人： William E. Garwood , Wooyoung Lee
IPC分类号： C10G57/02 , B01J21/12 , B01J29/40 , C10G29/16 , C10G35/095 , C10G50/00 , C10G25/04
CPC分类号： B01J29/40 , C10G29/16
摘要： A process is disclosed for the treatment of highly olefinic gasoline containing at least about 50% by weight of olefins by contacting said olefinic gasoline with a special group of acidic crystalline aluminosilicate zeolites, such as those of the ZSM-5 type in order to enhance the gum stability of said gasoline and produce products comprising both gasoline and fuel oil.
摘要翻译：公开了一种用于处理含有至少约50重量％的烯烃的高度烯烃汽油的方法，其中所述烯烃汽油与特殊的一组酸性结晶硅铝酸盐沸石（例如ZSM-5型沸石）相接触，以增强所述汽油的胶稳定性并且产生包含汽油和燃料油的产品。

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