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1. 发明授权

US08784516B2 Process for the production of hydrogen with intermediate-pressure purging 失效
标题翻译：用中压清洗生产氢气的方法
公开(公告)号：US08784516B2
公开(公告)日：2014-07-22
申请号：US13187844
申请日：2011-07-21
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/24
CPC分类号： C01B3/384 , C01B3/48 , C01B3/52 , C01B3/56 , C01B2203/0227 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/0822 , C01B2203/0827 , C01B2203/148 , C01B2203/84 , C01B2203/86 , Y02P20/128 , Y02P30/30
摘要： This invention relates to a process for the production of hydrogen from a hydrocarbon feedstock and water vapor comprising: A stage for the production of a synthetic gas in a vapor reforming unit of the hydrocarbon feedstock in the presence of water vapor, with a fuel that provides the heat that is necessary to the reaction, A stage for conversion to vapor of the synthetic gas that is obtained in the preceding stage producing a hydrogen stream that contains methane and carbon dioxide, A stage for recovering carbon dioxide that is present in the stream that is obtained in the stage for conversion to vapor, making it possible to separate the carbon dioxide from the hydrogen stream, A stage for recovery and recycling to the vapor reforming stage of impurities that are present in the hydrogen stream, comprising a decompression phase.
摘要翻译：本发明涉及从烃原料和水蒸汽生产氢的方法，包括：在水蒸气存在下在烃原料的气相重整单元中生产合成气体的阶段，其中提供反应所需的热量，在前一阶段获得的合成气体的蒸发阶段，产生含有甲烷和二氧化碳的氢气流的阶段，用于回收存在于流中的二氧化碳的阶段在转化成蒸气的阶段中获得，使得可以将来自氢气流的二氧化碳，用于回收和再循环的阶段分离到存在于氢气流中的包含减压阶段的氢气流中的杂质的气相重整阶段。

2. 发明授权

US08671695B2 Process for the production of hydrogen with total recovery of CO2 and reduction of unconverted methane 有权
标题翻译：生产氢气的过程具有CO2的全部回收和未转化的甲烷的还原
公开(公告)号：US08671695B2
公开(公告)日：2014-03-18
申请号：US12700353
申请日：2010-02-04
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino
IPC分类号： F01K23/10
CPC分类号： C01B3/382 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/0811 , C01B2203/1241 , C01B2203/1258 , C01B2203/142 , C01B2203/84 , C01B2203/86 , Y02E20/16 , Y02P30/30
摘要： This invention relates to a process for the production of hydrogen from a hydrocarbon feedstock and water vapor comprising a stage in which a portion of the hydrocarbon feedstock is sent to a vapor-reforming unit and another portion of the hydrocarbon feedstock is sent directly to an autothermal reformer in a mixture with the effluent that is obtained from a vapor-reforming unit, a vapor-reforming stage of the hydrocarbon feedstock in a vapor-reforming unit, a stage for autothermal reforming of the stream that is obtained in the preceding stage as well as the hydrocarbon feedstock that is sent directly into an autothermal reformer, a vapor conversion stage of the synthesis gas that is obtained in the preceding stage, and a stage for recovering carbon dioxide that is present in the stream that is obtained in the vapor conversion stage.
摘要翻译：本发明涉及从烃原料和水蒸气生产氢气的方法，该方法包括将一部分烃原料送入气相重整单元并将另一部分烃原料直接送入自热与蒸气重整单元获得的流出物的混合物中的重整器，气相重整单元中的烃原料的蒸气重整阶段，以及前一阶段获得的流的自热重整阶段作为直接送入自热重整器的烃原料，前一阶段获得的合成气的蒸气转化阶段和回收存在于蒸汽转化阶段获得的料流中的二氧化碳的阶段。

3. 发明授权

US08790617B2 Process for producing hydrogen with complete capture of CO2 and recycling unconverted methane 有权
标题翻译：完全捕获二氧化碳并回收未转化甲烷生产氢气的方法
公开(公告)号：US08790617B2
公开(公告)日：2014-07-29
申请号：US12568317
申请日：2009-09-28
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/26
CPC分类号： C01B3/56 , B01D53/04 , B01D2253/102 , B01D2253/304 , B01D2253/308 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/7022 , B01D2259/4009 , C01B3/48 , C01B3/52 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0475 , C01B2203/0822 , C01B2203/0827 , C01B2203/1241 , C01B2203/148 , Y02C10/04 , Y02C10/08 , Y02E60/324 , Y02P20/128 , Y02P20/152 , Y02P30/30
摘要： The present invention concerns a process for producing hydrogen from a hydrocarbon feed and steam, comprising: a step for producing a synthesis gas in a unit for steam reforming the hydrocarbon feed in the presence of steam, with a fuel providing the heat necessary for the reaction; a step for steam converting synthesis gas obtained in the preceding step, producing a stream of hydrogen containing methane and carbon dioxide; a step for capturing carbon dioxide present in the stream obtained from the steam conversion step in order to separate the carbon dioxide from the stream of hydrogen; a step for capturing and recycling the methane and other impurities (CO, CO2) present in the stream of hydrogen to the steam reforming step.
摘要翻译：本发明涉及一种从烃类进料和蒸汽中生产氢气的方法，包括：在蒸汽存在下用于在烃类进料中蒸汽重整的单元中生产合成气的步骤，提供反应所需的热量 ; 在前述步骤中获得的蒸汽转化合成气的步骤，产生含有甲烷和二氧化碳的氢气流; 用于捕获从蒸汽转化步骤获得的物流中存在的二氧化碳以从二氧化碳流中分离二氧化碳的步骤; 将存在于氢气流中的甲烷和其它杂质（CO，CO 2）捕获并再循环到蒸汽重整步骤的步骤。

4. 发明申请

US20120017511A1 PROCESS FOR THE PRODUCTION OF HYDROGEN WITH INTERMEDIATE-PRESSURE PURGING 失效
标题翻译：用中间压力生产氢气的方法
公开(公告)号：US20120017511A1
公开(公告)日：2012-01-26
申请号：US13187844
申请日：2011-07-21
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino , Michel Thomas
IPC分类号： C01B3/34
CPC分类号： C01B3/384 , C01B3/48 , C01B3/52 , C01B3/56 , C01B2203/0227 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/0822 , C01B2203/0827 , C01B2203/148 , C01B2203/84 , C01B2203/86 , Y02P20/128 , Y02P30/30
摘要： This invention relates to a process for the production of hydrogen from a hydrocarbon feedstock and water vapor comprising: A stage for the production of a synthetic gas in a vapor reforming unit of the hydrocarbon feedstock in the presence of water vapor, with a fuel that provides the heat that is necessary to the reaction, A stage for conversion to vapor of the synthetic gas that is obtained in the preceding stage producing a hydrogen stream that contains methane and carbon dioxide, A stage for recovering carbon dioxide that is present in the stream that is obtained in the stage for conversion to vapor, making it possible to separate the carbon dioxide from the hydrogen stream, A stage for recovery and recycling to the vapor reforming stage of impurities that are present in the hydrogen stream, comprising a decompression phase.
摘要翻译：本发明涉及从烃原料和水蒸汽生产氢的方法，包括：在水蒸气存在下在烃原料的气相重整单元中生产合成气体的阶段，其中提供反应所需的热量，在前一阶段获得的合成气体的蒸发阶段，产生含有甲烷和二氧化碳的氢气流的阶段，用于回收存在于流中的二氧化碳的阶段在转化成蒸气的阶段中获得，使得可以将来自氢气流的二氧化碳，用于回收和再循环的阶段分离到存在于氢气流中的包含减压阶段的氢气流中的杂质的气相重整阶段。

5. 发明申请

US20100199682A1 PROCESS FOR THE PRODUCTION OF HYDROGEN WITH TOTAL RECOVERY OF CO2 AND REDUCTION OF UNCONVERTED METHANE 有权
标题翻译：生产二氧化碳总量恢复和还原甲烷的氢过程
公开(公告)号：US20100199682A1
公开(公告)日：2010-08-12
申请号：US12700353
申请日：2010-02-04
申请人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino
发明人： Beatrice Fischer , Fabrice Giroudiere , Jean-Louis Ambrosino
IPC分类号： F02C7/22 , C01B3/02
CPC分类号： C01B3/382 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/0811 , C01B2203/1241 , C01B2203/1258 , C01B2203/142 , C01B2203/84 , C01B2203/86 , Y02E20/16 , Y02P30/30
摘要： This invention relates to a process for the production of hydrogen from a hydrocarbon feedstock and water vapor comprising: A stage in which a portion of the hydrocarbon feedstock is sent to a vapor-reforming unit and another portion of the hydrocarbon feedstock is sent directly to an autothermal reformer in a mixture with the effluent that is obtained from a vapor-reforming unit, A vapor-reforming stage of the hydrocarbon feedstock in a vapor-reforming unit, A stage for autothermal reforming of the stream that is obtained in the preceding stage as well as the hydrocarbon feedstock that is sent directly into an autothermal reformer, A vapor conversion stage of the synthesis gas that is obtained in the preceding stage, A stage for recovering carbon dioxide that is present in the stream that is obtained in the vapor conversion stage.
摘要翻译：本发明涉及从烃原料和水蒸汽生产氢的方法，包括：其中将一部分烃原料送入气相重整单元并将另一部分烃原料直接送至与蒸气重整单元获得的流出物的混合物中的自热重整器，蒸气重整单元中的烃原料的蒸气重整阶段，前段获得的流的自热重整阶段为以及直接送入自热重整器的烃原料，在前一阶段获得的合成气的蒸气转化级，用于回收存在于在蒸汽转化级中获得的物流中的二氧化碳的A级。

6. 发明授权

US07449049B2 Method of purifying a natural gas by mercaptan adsorption 失效
标题翻译：通过硫醇吸附法净化天然气的方法
公开(公告)号：US07449049B2
公开(公告)日：2008-11-11
申请号：US11366581
申请日：2006-03-03
申请人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
发明人： Michel Thomas , Eszter Toth , Fabrice Lecomte , Peter Meyer , Jean-Louis Ambrosino
IPC分类号： B01D53/04 , B01D53/48 , C07C7/13
CPC分类号： C10L3/10 , B01D53/0462 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/306 , B01D2253/308 , B01D2256/24 , B01D2256/245 , B01D2257/304 , B01D2257/306 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40045 , B01D2259/40052 , B01D2259/40056 , B01D2259/40064 , B01D2259/4009 , B01D2259/403 , Y02C10/08
摘要： The raw natural gas is deacidized and dehydrated in units DA and DH. The treated gas is then purified by adsorption of the mercaptans in first enclosure A1. Part of the purified gas is heated in E1, then fed into second enclosure A2 so as to discharge the water adsorbed by the adsorbent material contained in this second enclosure. A steam-rich stream is fed into third enclosure A3 containing a mercaptan-laden adsorbent material. In A3, the mercaptans are desorbed and replaced by the steam.
摘要翻译：原始天然气在DA和DH单位脱酸脱水。然后经处理的气体通过吸附第一外壳A 1中的硫醇来纯化。净化气体的一部分在E 1中被加热，然后进料到第二外壳A 2中，以排出由第二外壳中包含的吸附材料吸附的水。富含蒸汽的料流进料到含有载有硫醇的吸附剂材料的第三壳体A 3中。在A 3中，硫醇解吸并用蒸汽代替。

7. 发明授权

US07727311B2 Installation and method for mixing and distributing a liquid phase and a gaseous phase 有权
标题翻译：用于混合和分配液相和气相的安装和方法
公开(公告)号：US07727311B2
公开(公告)日：2010-06-01
申请号：US11223142
申请日：2005-09-12
申请人： Ludovic Raynal , Eric Lemaire , Jean-Louis Ambrosino
发明人： Ludovic Raynal , Eric Lemaire , Jean-Louis Ambrosino
IPC分类号： B01D47/14 , B01D53/14
CPC分类号： B01D53/18
摘要： Installation for gas treatment by a liquid phase comprising a) a column (C) that comprises means (1) for introducing gas at one end of said column, means (9) for drawing off gas from the other end of column (C) and, from upstream to downstream in the direction of circulation of the liquid phase: a first internal (2) that comprises means for distribution of a liquid phase, a first bed (6) that comprises a packing or catalytic particles, a second internal (3) that comprises means for separating liquid/gas mixture (19, 20) that is obtained from first bed (6), first means (32, 4) for collecting and evacuating the separated liquid phase, means (100) for passing through internal (3) of the treated gas, and distribution means (31, 101) of a liquid phase with said gas, a second bed (8), second means (10) for collecting and evacuating the liquid phase at the lower outlet of column (C), b) Means for recycling the collected liquid phase.
摘要翻译：用于通过液相进行气体处理的装置包括a）柱（C），其包括用于在所述塔的一端引入气体的装置（1），用于从塔（C）的另一端排出气体的装置（9）和，从液相循环方向的上游到下游：包括用于分配液相的装置的第一内部（2），包括填料或催化颗粒的第一床（6），第二内部（3））包括用于分离从第一床（6）获得的液体/气体混合物（19,20）的装置，用于收集和抽空分离的液相的第一装置（32,4），用于通过内部（ 3）和与所述气体的液相的分配装置（31,101），第二床（8），第二装置（10），用于在塔的下部出口处收集和排出液相（C ），b）回收液相的方法。

8. 发明申请

US20060060083A1 Installation and method for mixing and distributing a liquid phase and a gaseous phase 有权
标题翻译：用于混合和分配液相和气相的安装和方法
公开(公告)号：US20060060083A1
公开(公告)日：2006-03-23
申请号：US11223142
申请日：2005-09-12
申请人： Ludovic Raynal , Eric Lemaire , Jean-Louis Ambrosino
发明人： Ludovic Raynal , Eric Lemaire , Jean-Louis Ambrosino
IPC分类号： B01D47/14
CPC分类号： B01D53/18
摘要： Installation for gas treatment by a liquid phase comprising a) a column (C) that comprises means (1) for introducing gas at one end of said column, means (9) for drawing off gas from the other end of column (C) and, from upstream to downstream in the direction of circulation of the liquid phase: a first internal (2) that comprises means for distribution of a liquid phase, a first bed (6) that comprises a packing or catalytic particles, a second internal (3) that comprises means for separating liquid/gas mixture (19, 20) that is obtained from first bed (6), first means (32, 4) for collecting and evacuating the separated liquid phase, means (100) for passing through internal (3) of the treated gas, and distribution means (31, 101) of a liquid phase with said gas, a second bed (8), second means (10) for collecting and evacuating the liquid phase at the lower outlet of column (C), b) Means for recycling the collected liquid phase.
摘要翻译：通过液相进行气体处理的安装包括

9. 发明授权

US06365791B1 Process for converting hydrocarbons by treatment in a distillation zone comprising extracting a hydrocarbon cut as a side stream, associated with a reaction zone, and its use for hydrogenating benzene 有权
标题翻译：通过在蒸馏区中处理来转化烃的方法，包括萃取与反应区相关的侧流的烃馏分及其用于苯化氢的用途
公开(公告)号：US06365791B1
公开(公告)日：2002-04-02
申请号：US09376054
申请日：1999-08-17
申请人： Jean-Louis Ambrosino , Jean-Charles Viltard , Blaise Didillon
发明人： Jean-Louis Ambrosino , Jean-Charles Viltard , Blaise Didillon
IPC分类号： C07C500
CPC分类号： C10G45/44
摘要： The invention provides a process for converting hydrocarbons in which said feed is treated in a distillation zone associated with a reaction zone, the feed for the reaction zone being drawn off at the height of at least one draw-off level, the effluent from the reaction zone being re-introduced into the distillation zone at the height of a re-introduction level, said process being characterized in that a liquid effluent is also withdrawn from the distillation zone at the height of a withdrawal level, said liquid effluent being treated in a gas-liquid side separation zone (splitter), the gaseous effluent being re-introduced into the distillation zone and the liquid effluent being recovered as an intermediate cut. This process can be used to reduce the benzene content of a hydrocarbon cut and to recover a naphtha cut.
摘要翻译：本发明提供了一种转化烃的方法，其中所述进料在与反应区相关的蒸馏区中处理，反应区的进料在至少一个排出水平的高度被排出，反应的流出物区域在再引入水平的高度被重新引入蒸馏区，所述方法的特征在于，在排出水平的高度处还从蒸馏区抽出液体流出物，所述液体流出物在气 - 液侧分离区（分流器），气态流出物被重新引入蒸馏区，液体流出物作为中间馏分被回收。该方法可用于降低烃馏分的苯含量并回收石脑油馏分。

10. 发明授权

US5863315A Process for the separation of isoalkanes/n-alkanes by gas phase adsorption using a pressure swing and four adsorbers 失效
标题翻译：使用压力摆动和四个吸附器通过气相吸附分离异烷烃/正烷烃的方法
公开(公告)号：US5863315A
公开(公告)日：1999-01-26
申请号：US900532
申请日：1997-07-25
申请人： Sophie Jullian , Jean-Louis Ambrosino , Alain Chansolme , Valerie Wiss-Henrard
发明人： Sophie Jullian , Jean-Louis Ambrosino , Alain Chansolme , Valerie Wiss-Henrard
IPC分类号： B01D53/04 , B01J20/18 , C07C7/13 , C10G25/03 , B01D53/047
CPC分类号： C10G25/03 , C07C7/13
摘要： Four adsorbers 1 to 4, each operating in a cycle comprising (described for adsorber 2): an adsorption step 1 wherein a feed from adsorber 2 is circulated to adsorber 2; an adsorption step 2 wherein feed is injected to the bottom of adsorber 2 and a product rich in isoparaffins is recovered from the head of adsorber 2; an adsorption step 3 wherein a portion of the fluid leaving adsorber 2 is sent to adsorber 3; an adsorption step 4 wherein the head of adsorber 2 receiving the feed is connected to the bottom of adsorber 3; a first depressurisation step 5 wherein adsorber 2 at high pressure is connected to adsorber 4 at a lower pressure; a second depressurisation step 6 wherein the head of adsorber 2 is closed; a stripping step 7 wherein the bottom of adsorber 2, which receives desorbent overhead, is connected to the top of adsorber 2; two principal stripping steps 8 and 9 wherein adsorber 2 alone is supplied with desorbent; a stripping finishing step 10 wherein adsorber 2 is continued to be supplied with desorbent and the outlet from the adsorber 2 is connected to adsorber 3; a first pressurisation step 11 to an intermediate pressure wherein the bottoms of adsorbers 2 and 4 are connected together; and a second pressurisation step 12 wherein a stream providing a portion of the effluent from adsorber 1 is introduced into the bottom of adsorber 2.
摘要翻译：四个吸附器1至4，每个在包括（对于吸附器2描述）的循环中操作：吸附步骤1，其中来自吸附器2的进料循环到吸附器2; 从吸附器2的头部回收吸附步骤2，其中将进料注入吸附器2的底部和富含异构烷烃的产物; 吸附步骤3，其中离开吸附器2的一部分流体被送到吸附器3; 吸附步骤4，其中接收进料的吸附器2的头部连接到吸附器3的底部; 第一减压步骤5，其中高压吸附器2以较低压力连接到吸附器4; 第二减压步骤6，其中吸附器2的头部关闭; 汽提步骤7，其中接收解吸塔顶的吸附器2的底部连接到吸附器2的顶部; 两个主要的汽提步骤8和9，其中单独的吸附器2被提供解吸剂; 剥离完成步骤10，其中吸附器2继续被提供解吸剂，并且吸附器2的出口连接到吸附器3; 第一加压步骤11到中间压力，其中吸附器2和4的底部连接在一起; 和第二加压步骤12，其中将提供一部分来自吸附器1的流出物的流引入吸附器2的底部。

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