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    • 3. 发明授权
    • Infrared transparent selenide glasses
    • 红外透明硒化物眼镜
    • US5846889A
    • 1998-12-08
    • US818204
    • 1997-03-14
    • Barry B. HarbisonJasbinder S. SangheraJohn A. MoonIshwar D. Aggarwal
    • Barry B. HarbisonJasbinder S. SangheraJohn A. MoonIshwar D. Aggarwal
    • C03C3/32C03C13/04
    • C03C13/043C03C3/321C03C4/10C03C4/12Y10S501/904
    • A selenide glass with improved mechanical and optical properties such as ended transmission in the infrared region of radiation having wavelengths beyond 15 microns; Tg in the region of 363.degree.-394.degree. C.; and thermal stability of 85.degree.-145.degree. C. based on the difference between T.sub.g and T.sub.x, comprising, on mol basis, 20-70% germanium selenide, 0.5-25% gallium selenide, indium selenide or mixtures thereof; and 5-50% of at least one alkaline earth in selenide form is described. A process for improving mechanical and optical properties of a selenide glass based on germanium selenide comprises the steps of mixing glass components, including a modifier in elemental or selenide form; melting the glass components to form a molten mixture; cooling the molten glass mixture to a solid state; annealing the solid glass; and cooling the annealed glass to about room temperature is also described. The glass components can be in elemental form or in the form of selenides, and if in elemental form, then sufficient amount of selenium is added to form selenides of the glass components.
    • 具有改善的机械和光学性能的硒化物玻璃,例如在具有超过15微米的波长的辐射的红外区域中的扩展传输; 在363°-394℃的范围内的Tg。 和基于Tg和Tx之间的差异的85°-145℃的热稳定性,包括基于摩尔计的20-70%硒化锗,0.5-25%硒化镓,硒化铟或其混合物; 并描述了5-50%的至少一种硒化物形式的碱土金属。 用于改善基于硒化硒的硒化物玻璃的机械和光学性能的方法包括以下步骤:将元素或硒化物形式的包含改性剂的玻璃组分混合; 熔化玻璃组分以形成熔融混合物; 将熔融玻璃混合物冷却至固态; 退火固体玻璃; 并且还描述了将退火玻璃冷却至约室温。 玻璃组分可以是元素形式或以硒化物的形式,如果以元素形式,则加入足量的硒以形成玻璃组分的硒化物。
    • 4. 发明授权
    • Gas filled hollow core chalcogenide photonic bandgap fiber Raman device and method
    • 气体填充中空硫族化合物光子带隙光纤拉曼装置及方法
    • US07283712B2
    • 2007-10-16
    • US11122203
    • 2005-05-03
    • L. Brandon ShawJasbinder S. SangheraIshwar D. AggarwalPeter A. Thielen
    • L. Brandon ShawJasbinder S. SangheraIshwar D. AggarwalPeter A. Thielen
    • G02B6/32
    • G02B6/02328C03B2201/86C03B2203/16C03B2203/42G02B6/02347G02B6/032H01S3/06741H01S3/302
    • This invention pertains to a glass fiber, a Raman device and a method. The fiber is a hollow core photonic bandgap chalcogenide glass fiber that includes a hollow core for passing light therethrough, a Raman active gas disposed in said core, a microstructured region disposed around said core, and a solid region disposed around said microstructured region for providing structural integrity to said microstructured region. The device includes a coupler for introducing at least one light signal into a hollow core of a chalcogenide photonic bandgap fiber; a hollow core chalcogenide photonic bandgap glass fiber; a microstructured fiber region disposed around said core; a solid fiber region disposed around said microstructured region for providing structural integrity to said microstructured region; and a Raman active gas disposed in the hollow core. The method includes the steps of introducing a light beam into a hollow core chalcogenide photonic bandgap glass fiber filled with a Raman active gas disposed in the core, conveying the beam through the core while it interacts with the gas to form a Stokes beam of a typically higher wavelength, and removing the Stokes beam from the core of the fiber.
    • 本发明涉及玻璃纤维,拉曼装置和方法。 纤维是中空核光子带隙硫族化物玻璃纤维,其包括用于使光通过的中空芯,布置在所述芯中的拉曼活性气体,围绕所述芯设置的微结构化区域,以及设置在所述微结构区域周围的固体区域,用于提供结构 对所述微结构区域的完整性。 该装置包括耦合器,用于将至少一个光信号引入到硫族化物光子带隙光纤的中空芯中; 空心核硫属元素光子带隙玻璃纤维; 设置在所述芯周围的微结构化纤维区域; 设置在所述微结构区域周围的固体纤维区域,用于向所述微结构化区域提供结构完整性; 和设置在中空芯中的拉曼活性气体。 该方法包括以下步骤:将光束引入到填充有设置在芯中的拉曼活性气体的中空核心硫族化物光子带隙玻璃纤维中,在与气体相互作用的同时将光束传送通过核心,以形成典型的斯托克斯光束 更高的波长,并从纤芯的核心去除斯托克斯光束。