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1. 发明申请

US20070146971A1 Electrochemical-electrolytic capacitor and method of making the same 有权
标题翻译：电化学电解电容器及其制作方法
公开(公告)号：US20070146971A1
公开(公告)日：2007-06-28
申请号：US11316416
申请日：2005-12-22
申请人： Badawi Dweik , John Forchione , Mourad Manoukian , John Kosek , Anthony LaConti , David Evans
发明人： Badawi Dweik , John Forchione , Mourad Manoukian , John Kosek , Anthony LaConti , David Evans
IPC分类号： H01G9/04
CPC分类号： H01G9/15 , H01G9/042 , H01G9/0425 , Y10T29/41 , Y10T29/417
摘要： A high-voltage electrochemical-electrolytic capacitor. The capacitor includes a cathode comprising a plurality of electrically-conductive particles in intimate electrical contact with one another and disposed in a proton-conductive, electrically-non-conductive, solid ionomer matrix. The capacitor also includes an anode comprising a plurality of electrically-conductive particles in intimate electrical contact with one another and disposed in a proton-conductive, electrically-non-conductive solid ionomer matrix, the electrically-conductive particles of the anode differing in composition from the electrically-conductive particles of said cathode. The capacitor further includes a proton-conducting dielectric positioned between and in contact with each of the cathode and the anode, the proton-conducting dielectric comprising a solid ionomer. Preferably, the capacitor is assembled by constructing a first portion and a second portion, the first portion comprising the cathode and an extra thickness of solid ionomer on its inner surface, the second portion comprising the anode and an extra thickness of solid ionomer on its inner surface. When the first and second portions are brought together, the extended thicknesses of the solid ionomer jointly form the proton-conducting dielectric.
摘要翻译：高压电化学电解电容器。电容器包括阴极，其包括彼此紧密地电接触并设置在质子传导的非导电固体离聚物基质中的多个导电颗粒。电容器还包括阳极，其包括彼此紧密地电接触并设置在质子传导的非导电固体离聚物基质中的多个导电颗粒，阳极的导电颗粒的组成不同于所述阴极的导电颗粒。电容器还包括位于阴极和阳极之间并与之接触的质子传导电介质，质子传导电介质包含固体离聚物。优选地，通过构造第一部分和第二部分来组装电容器，第一部分包括阴极和在其内表面上具有额外厚度的固体离聚物，第二部分包括阳极和在其内部具有额外厚度的固体离聚物表面。当第一和第二部分合在一起时，固体离聚物的延伸厚度共同形成质子传导电介质。

2. 发明申请

US20060096871A1 Electrochemical carbon dioxide sensor 有权
标题翻译：电化学二氧化碳传感器
公开(公告)号：US20060096871A1
公开(公告)日：2006-05-11
申请号：US11252090
申请日：2005-10-17
申请人： Mourad Manoukian , Anthony LaConti , Linda Tempelman , John Forchione
发明人： Mourad Manoukian , Anthony LaConti , Linda Tempelman , John Forchione
IPC分类号： G01N27/26 , G01F1/64
CPC分类号： G01N27/4074
摘要： An electrochemical sensor is provided for the detection of carbon dioxide gas. The sensor includes a non-conductive solid substrate and at least one each of a metal oxide sensing electrode, a reference electrode and a counter electrode positioned on the substrate. A solid polymer electrolyte anion-exchange membrane is in intimate contact with the sensing electrode, reference electrode and counter electrode. The sensor is highly sensitive and selective to carbon dioxide and has very rapid response time.
摘要翻译：提供了一种用于检测二氧化碳气体的电化学传感器。传感器包括非导电固体基板和位于基板上的金属氧化物感测电极，参考电极和对置电极中的至少一个。固体聚合物电解质阴离子交换膜与感测电极，参比电极和对电极紧密接触。传感器对二氧化碳具有高度敏感性和选择性，响应时间非常快。

3. 发明授权

US07811433B2 Electrochemical carbon dioxide sensor 有权
标题翻译：电化学二氧化碳传感器
公开(公告)号：US07811433B2
公开(公告)日：2010-10-12
申请号：US11252090
申请日：2005-10-17
申请人： Mourad Manoukian , Anthony B. LaConti , Linda A. Tempelman , John Forchione
发明人： Mourad Manoukian , Anthony B. LaConti , Linda A. Tempelman , John Forchione
IPC分类号： G01N27/40
CPC分类号： G01N27/4074
摘要： An electrochemical sensor is provided for the detection of carbon dioxide gas. The sensor includes a non-conductive solid substrate and at least one each of a metal oxide sensing electrode, a reference electrode and a counter electrode positioned on the substrate. A solid polymer electrolyte anion-exchange membrane is in intimate contact with the sensing electrode, reference electrode and counter electrode. The sensor is highly sensitive and selective to carbon dioxide and has very rapid response time.
摘要翻译：提供了一种用于检测二氧化碳气体的电化学传感器。传感器包括非导电固体基板和位于基板上的金属氧化物感测电极，参考电极和对置电极中的至少一个。固体聚合物电解质阴离子交换膜与感测电极，参比电极和对电极紧密接触。传感器对二氧化碳具有高度敏感性和选择性，响应时间非常快。

4. 发明授权

US08361308B2 Electrochemical carbon dioxide sensor 有权
标题翻译：电化学二氧化碳传感器
公开(公告)号：US08361308B2
公开(公告)日：2013-01-29
申请号：US12878504
申请日：2010-09-09
申请人： Mourad Manoukian , Anthony B. Laconti , Linda A. Tempelman , John Forchione
发明人： Mourad Manoukian , Anthony B. Laconti , Linda A. Tempelman , John Forchione
IPC分类号： G01N27/417
CPC分类号： G01N27/4074
摘要： A method for the detection of carbon dioxide gas using an electrochemical sensor. The method includes exposing a gas to a sensor, which includes a non-conductive solid substrate and at least one each of a metal oxide sensing electrode, a reference electrode and a counter electrode positioned on the substrate. A solid polymer electrolyte anion-exchange membrane is in intimate contact with the sensing electrode, reference electrode and counter electrode. The method is highly sensitive and selective to carbon dioxide with a very rapid response time.
摘要翻译：一种使用电化学传感器检测二氧化碳气体的方法。该方法包括将气体暴露于传感器，该传感器包括非导电固体基底和位于基底上的金属氧化物感测电极，参考电极和对置电极中的至少一个。固体聚合物电解质阴离子交换膜与感测电极，参比电极和对电极紧密接触。该方法对二氧化碳具有高度敏感性和选择性，反应时间非常快。

5. 发明申请

US20050126930A1 Hybrid film type sensor 失效
公开(公告)号：US20050126930A1
公开(公告)日：2005-06-16
申请号：US10987825
申请日：2004-11-12
申请人： Otto Prohaska , Anthony LaConti , Jose Giner , Mourad Manoukian
发明人： Otto Prohaska , Anthony LaConti , Jose Giner , Mourad Manoukian
IPC分类号： G01N27/30 , G01N27/26 , G01N27/333 , G01N27/404 , G01N27/407 , G01N27/416 , G01N27/49 , G01N33/00
CPC分类号： G01N27/4045 , G01N27/4074 , G01N33/004
摘要： A miniaturized gas sensor comprised of thick- or thin-film type electrodes, on a non-conductive supportive substrate, and in contact with a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive substrate. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a constant-voltage, potentiostatic or potentiodynamic mode. A high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which provides contact with the solid ionomer electrolyte, as well as the gas sample via diffusion openings or holes that penetrate through the supportive substrate.

6. 发明授权

US5964992A Reference electrode for monitoring steel-in-concrete potentials 失效
标题翻译：用于监测钢铁混凝土电位的参比电极
公开(公告)号：US5964992A
公开(公告)日：1999-10-12
申请号：US119224
申请日：1998-07-20
申请人： Larry L. Swette , Mourad Manoukian , Monjid Hamdan , Anthony LaConti , Ali Akbar Sohanghpurwala , William T. Scannell
发明人： Larry L. Swette , Mourad Manoukian , Monjid Hamdan , Anthony LaConti , Ali Akbar Sohanghpurwala , William T. Scannell
IPC分类号： G01N17/02 , G01N27/30 , C25B11/00
CPC分类号： G01N27/301 , G01N17/02
摘要： A graphite reference electrode for use in the cathodic protection of steel embedded in concrete has been produced with a stable catalyzed structure that when equilibrated with air or oxygen and an electrolyte reaches a reproducible and reversible redox potential. This stable device is produced by exposure to hydrogen peroxide, impregnating with a metal oxide followed by a coating treatment. The embedded catalyzed graphite reference electrodes can be used in impressed cathodic protection systems or monitoring the corrosion condition of embedded steel to provide an early warning of impending damage.
摘要翻译：已经生产了用于在混凝土中嵌入的钢的阴极保护中的石墨参比电极，其具有稳定的催化结构，当用空气或氧气和电解质达到可再现和可逆的氧化还原电位时平衡。该稳定装置通过暴露于过氧化氢，用金属氧化物浸渍，然后进行涂覆处理来生产。嵌入式催化石墨参比电极可用于外加阴极保护系统或监测嵌入式钢的腐蚀状况，以提供即将发生的损坏的预警。

7. 发明申请

US20110005928A1 ELECTROCHEMICAL CARBON DIOXIDE SENSOR 有权
标题翻译：电化学二氧化碳传感器
公开(公告)号：US20110005928A1
公开(公告)日：2011-01-13
申请号：US12878504
申请日：2010-09-09
申请人： Mourad Manoukian , Anthony B. LaConti , Linda A. Tempelman , John Forchione
发明人： Mourad Manoukian , Anthony B. LaConti , Linda A. Tempelman , John Forchione
IPC分类号： G01N27/26
CPC分类号： G01N27/4074
摘要： A method for the detection of carbon dioxide gas using an electrochemical sensor. The method includes exposing a gas to a sensor, which includes a non-conductive solid substrate and at least one each of a metal oxide sensing electrode, a reference electrode and a counter electrode positioned on the substrate. A solid polymer electrolyte anion-exchange membrane is in intimate contact with the sensing electrode, reference electrode and counter electrode. The method is highly sensitive and selective to carbon dioxide with a very rapid response time.
摘要翻译：一种使用电化学传感器检测二氧化碳气体的方法。该方法包括将气体暴露于传感器，该传感器包括非导电固体基底和位于基底上的金属氧化物感测电极，参考电极和对置电极中的至少一个。固体聚合物电解质阴离子交换膜与感测电极，参比电极和对电极紧密接触。该方法对二氧化碳具有高度敏感性和选择性，反应时间非常快。

8. 发明申请

US20080264789A1 Film-Type Solid Polymer Ionomer Sensor And Sensor Cell 失效
标题翻译：膜型固体聚合物离聚物离子传感器和传感器单元
公开(公告)号：US20080264789A1
公开(公告)日：2008-10-30
申请号：US12147019
申请日：2008-06-26
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/26
CPC分类号： G01N27/4045 , G01N2030/125 , G01N2030/645
摘要： A miniaturized gas sensor including film type electrodes, and a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive material. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a potentiostatic or potentiodynamic mode. The unique feature of the sensor cell is that high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which is easily accessible to the gas sample via small diffusion openings or holes that penetrate through the solid polymer ionomer membrane layer above the sensing electrode. A significant signal to background noise enhancement is achieved for these film type sensor cells by processes that increase the three-phase contact area
摘要翻译：描述了一种用于检测有毒气体即一氧化碳和其它可氧化或可还原的气体和蒸气的薄膜型电极和固体离聚物电解质的微型气体传感器。全固体平面传感器单元具有布置在支撑材料的非导电平面上的两个或多个薄膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器电池不含液体电解质，并以恒电位或电位动力学模式运行。传感器单元的独特之处在于，通过用于感应电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，该设计可以通过穿透该气体样本的小扩散开口或孔容易接近气体样品固体聚合物离聚物膜层感应电极上方。通过增加三相接触面积的工艺，对这些膜型传感器单元实现对背景噪声增强的显着信号

9. 发明授权

US07404882B2 Film-type solid polymer ionomer sensor and sensor cell 失效
标题翻译：薄膜型固体聚合物离子交联聚合物传感器和传感器单元
公开(公告)号：US07404882B2
公开(公告)日：2008-07-29
申请号：US10738858
申请日：2003-12-17
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/407
CPC分类号： G01N27/4045 , G01N2030/125 , G01N2030/645
摘要： A miniaturized gas sensor including film type electrodes, and a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive material. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a potentiostatic or potentiodynamic mode. The unique feature of the sensor cell is that high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which is easily accessible to the gas sample via small diffusion openings or holes that penetrate through the solid polymer ionomer membrane layer above the sensing electrode. A significant signal to background noise enhancement is achieved for these film type sensor cells by processes that increase the three-phase contact area.
摘要翻译：描述了一种用于检测有毒气体即一氧化碳和其它可氧化或可还原的气体和蒸气的薄膜型电极和固体离聚物电解质的微型气体传感器。全固体平面传感器单元具有布置在支撑材料的非导电平面上的两个或多个薄膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器电池不含液体电解质，并以恒电位或电位动力学模式运行。传感器单元的独特之处在于，通过用于感应电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，该设计可以通过穿透该气体样品的小扩散开口或孔容易接近气体样品固体聚合物离聚物膜层感应电极上方。通过增加三相接触面积的工艺，对这些膜型传感器单元实现对背景噪声增强的显着信号。

10. 发明授权

US08123923B2 Film-type solid polymer ionomer sensor and sensor cell 失效
标题翻译：薄膜型固体聚合物离子交联聚合物传感器和传感器单元
公开(公告)号：US08123923B2
公开(公告)日：2012-02-28
申请号：US12147019
申请日：2008-06-26
申请人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
发明人： Otto J. Prohaska , Anthony B. LaConti , Jose D. Giner , Mourad Manoukian
IPC分类号： G01N27/407
CPC分类号： G01N27/4045 , G01N2030/125 , G01N2030/645
摘要： A miniaturized gas sensor including film type electrodes, and a solid ionomer electrolyte, for the detection of toxic gases, i.e., carbon monoxide, and other oxidizable or reducible gases and vapors is described. The all-solid planar sensor cell has two or more film type electrodes arranged on a non-conductive planar surface of a supportive material. The electrodes are discrete and in intimate contact with the same solid polymer ionomer membrane. The sensor cell contains no liquid electrolyte and is operated in a potentiostatic or potentiodynamic mode. The unique feature of the sensor cell is that high sensitivity to a select gas or vapor is achieved by a novel three-phase contact area design for a sensing electrode which is easily accessible to the gas sample via small diffusion openings or holes that penetrate through the solid polymer ionomer membrane layer above the sensing electrode. A significant signal to background noise enhancement is achieved for these film type sensor cells by processes that increase the three-phase contact area.
摘要翻译：描述了一种用于检测有毒气体即一氧化碳和其它可氧化或可还原的气体和蒸气的薄膜型电极和固体离聚物电解质的微型气体传感器。全固体平面传感器单元具有布置在支撑材料的非导电平面上的两个或多个薄膜型电极。电极是离散的并且与相同的固体聚合物离聚物膜紧密接触。传感器电池不含液体电解质，并以恒电位或电位动力学模式运行。传感器单元的独特之处在于，通过用于感应电极的新颖的三相接触面积设计来实现对选择气体或蒸气的高灵敏度，该设计可以通过穿透该气体样品的小扩散开口或孔容易接近气体样品固体聚合物离聚物膜层感应电极上方。通过增加三相接触面积的工艺，对这些膜型传感器单元实现对背景噪声增强的显着信号。

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