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    • 8. 发明授权
    • Process for preparing oil-extending rubber
    • 制备加油橡胶的方法
    • US3687889A
    • 1972-08-29
    • US3687889D
    • 1969-07-22
    • BAYER AG
    • WITTE JOSEFHAAS FRIEDRICHMARWEDE GUNTER
    • C08F4/64C08F136/08C08K5/17C08C11/22B01J11/84
    • C08F136/08C08K5/17C08F2/42C08L9/00
    • An oil-extended polyisoprene composition which comprises A. 100 PARTS BY WEIGHT OF A SYNTHETIC CIS-1,4-POLYISOPRENE WHICH HAS BEEN PREPARED BY POLYMERIZING ISOPRENE IN SOLUTION IN A HYDROCARBON WITH AN ORGANOMETALLIC MIXED CATALYST OF TITANIUM TETRACHLORIDE, AN ALUMINUM TRIALKYL AND/OR AN ALUMINUM TRIALKYL ETHERATE AND STOPPING THE POLYMER SOLUTION CONTAINING THE MIXED CATALYST WITH AN ALIPHATIC OR CYCLOALIPHATIC DIAMINE OR POLYAMINE AND AN ALIPHATIC OR CYCLOALIPHATIC SECONDARY AMINE CONTAINING AT LEAST 10 CARBON ATOMS, OPTIONALLY IN ADMIXTURE WITH A LOWER ALIPHATIC ALCOHOL, FOLLOWED BY STABILIZATION WITH A CONVENTIONAL ANTI-AGER, AND B. FROM 15 TO 50 PARTS BY WEIGHT OF A RUBBER EXTENDING OIL AND A PROCESS FOR PRODUCING SAID MIXTURE.
    • 一种含油聚异戊二烯组合物,其包含A. 100份合成的单体-1,4-聚异戊二烯的重量份,其通过在溶剂中的溶液中聚合异丙苯与四氯化钛的有机金属混合催化剂,铝三聚物和/ 或铝酸铝酸钠,并且将含有混合催化剂的聚合物溶液与含有至少10个碳原子的惰性或环状二胺或多胺以及包含至少10个碳原子的惰性或环状二次胺一起停止,与下列醇溶液相似,在与A的稳定作用下进行 常规抗菌剂和B.从15至50份橡胶扩展油重量份和生产混合物的方法。