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    • 2. 发明申请
    • STABILIZATION OF CARBON NANOTUBE COATINGS TO MOISTURE
    • 碳纳米管涂料对水分的稳定性
    • US20160137854A1
    • 2016-05-19
    • US14936308
    • 2015-11-09
    • Battelle Memorial Institute
    • Amy M. HeintzChad M. CuckseyAnthony D. DuongRandy L. JonesMichael D. Crenshaw
    • C09D5/24C01B31/02
    • A method of making CNT films is described in which the film is washed with a mild acid treatment. The method generates a CNT film that is not sensitive to moisture or fluctuations in moisture. The method involves the use of anionic polysaccharides or anionic glycosaminoglycans such as hyaluronic acid, sodium salt, as aqueous dispersing agents and their modification to a hydrophobic matrix after deposition. In the course of conducting the work described here, we made the surprising discovery that washing with an aqueous acidic solution resulted in a decrease in resistance through the material. The invention also includes CNT composites made by the inventive methods and a CNT composite comprising CNTs and anionic polysaccharides or anionic glycosaminoglycans further characterized by a low cationic content and a high conductivity and/or small CNT particle size as measured by SEM.
    • 描述制造CNT膜的方法,其中用温和酸处理洗涤该膜。 该方法产生对水分不敏感或湿度波动的CNT膜。 该方法包括使用阴离子多糖或阴离子糖胺聚糖如透明质酸钠盐作为水性分散剂,并在沉积后对疏水性基质进行改性。 在进行这里描述的工作的过程中,我们惊奇地发现用酸性水溶液洗涤导致材料的电阻降低。 本发明还包括通过本发明方法制备的CNT复合材料和包含CNT和阴离子多糖或阴离子糖胺聚糖的CNT复合材料,其进一步的特征在于通过SEM测量的低阳离子含量和高导电性和/或小的CNT颗粒尺寸。