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    • 1. 发明申请
    • PROCESS FOR PREPARING ACETYLENE AND SYNTHESIS GAS
    • 制备乙烯和合成气的方法
    • US20130334464A1
    • 2013-12-19
    • US13902175
    • 2013-05-24
    • BASF SE
    • Maximilian VICARIChristian WEICHERTDirk GROSSSCHMIDTMichael RUSSMirko HAIDERHorst NEUHAUSERMichael L. HAYES
    • C01B3/36C07C4/02
    • C01B3/36C01B2203/0255C07C2/78C07C4/025C07C11/24
    • A process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen, is disclosed. The process consists of separately preheating and then mixing a first input stream containing a hydrocarbon and a second input stream containing oxygen, supplying the first input stream and the second input stream via a burner block to a firing space, quenching a cracking gas obtained to produce a process water stream and a product gas stream, cooling the product gas stream in a cooling column by direct heat exchange with cooling water, depleting soot in an electrostatic filter, combining all process water streams and passing through soot channels, subjecting the combined process water stream to a cleaning operation by partial vaporization in a one-stage flash vessel to obtain a cleaned process water stream, and recycling the cleaned process water stream into the process.
    • 公开了通过用氧气分解氧化烃来制备乙炔和合成气的方法。 该方法包括单独地预热,然后混合含有烃的第一输入流和含有氧的第二输入流,经由燃烧器块将第一输入流和第二输入流提供到燃烧空间,淬火产生的裂解气 工艺水流和产物气流,通过与冷却水直接热交换在冷却塔中冷却产物气流,在静电过滤器中消除烟灰,将所有工艺水流合并通过烟灰通道,对组合的工艺水 通过在一级闪蒸容器中部分蒸发而进行清洁操作以获得清洁的工艺水流,并将清洁的工艺水流循环到该过程中。
    • 2. 发明申请
    • APPARATUS AND PROCESS FOR PREPARING ACETYLENE AND SYNTHESIS GAS
    • 制备乙烯和合成气体的装置和方法
    • US20160207767A1
    • 2016-07-21
    • US14912809
    • 2014-08-28
    • BASF SE
    • Matthias KERNMichael RUSSPeter RENZEMaximilian VICARI
    • C01B3/36C07C2/78B01J19/24
    • C01B3/36B01J4/002B01J19/24B01J2219/24C01B2203/0255C01B2203/062C01B2203/1235C07C2/78C07C11/24
    • An apparatus (10) for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is proposed, comprising a mixing unit (12), a mixing section and a mixing diffuser (16). The mixing unit (12) has a feed orifice (18) for supply of a hydrocarbonaceous stream, a feed orifice (20) for supply of an oxygenous stream, a swirl register and a distributor plate (24). The distributor plate (24) is disposed between the mixing section (14) and the feed orifice (18) for supply of a hydrocarbonaceous stream. The distributor plate (24) has orifices (28). The swirl register (22) is disposed between the feed orifice (20) for supply of an oxygenous stream and the mixing section (14). The mixing diffuser (16) is connected to the mixing section (14).There is a further proposal of a process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen.
    • 提出了一种用于通过用氧气分解氧化烃来制备乙炔和合成气的装置(10),包括混合单元(12),混合段和混合扩散器(16)。 混合单元(12)具有用于供应烃流的进料孔(18),用于供应氧气流的进料孔(20),涡流定位器和分配板(24)。 分配板(24)设置在混合部分(14)和进料孔(18)之间,用于供应烃流。 分配板(24)具有孔(28)。 旋流寄存器(22)设置在供给孔(20)之间,用于供应氧气流和混合部分(14)。 混合扩散器(16)连接到混合部分(14)。 还有一个进一步的建议是通过用氧气对烃进行部分氧化制备乙炔和合成气的方法。
    • 3. 发明申请
    • PROCESS FOR PREPARING 1,3-BUTADIENE FROM N-BUTENES BY OXIDATIVE DEHYDROGENATION
    • US20180002254A1
    • 2018-01-04
    • US15514077
    • 2015-09-14
    • BASF SELinde AG
    • Jan Pablo JOSCHPhilipp GRÜNERegina BENFERMaximilian VICARIAndre BIEGNERGergor BLOCHHeinz BOELTHendrik REYNEKEChristine TOEGELUlrike WENNING
    • C07C5/48B01D3/40
    • C07C5/48B01D3/40C07C5/333C07C7/005C07C7/05C07C7/08C07C7/11C07C11/167
    • The invention relates to a process for preparing butadiene from n-butenes, comprising the steps of: A) providing an input gas stream a comprising n-butenes, B) feeding the input gas stream a comprising n-butenes and a gas containing at least oxygen into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene, giving a product gas stream b comprising butadiene, unconverted n-butenes, water vapor, oxygen, low-boiling hydrocarbons and high-boiling secondary components, with or without carbon oxides and with or without inert gases; Ca) cooling the product gas stream b by contacting with a cooling medium in at least one cooling zone, the cooling medium being at least partly recycled and having an aqueous phase and an organic phase, Cb) compressing the cooled product gas stream b which may have been depleted of high-boiling secondary components in at least one compression stage, giving at least one aqueous condensate stream c1 and one gas stream c2 comprising butadiene, n-butenes, water vapor, oxygen and low-boiling hydrocarbons, with or without carbon oxides and with or without inert gases; D) removing uncondensable and low-boiling gas constituents comprising oxygen and low-boiling hydrocarbons, with or without carbon oxides and with or without inert gases, as gas stream d2 from the gas stream c2 by absorbing the C4 hydrocarbons comprising butadiene and n-butenes in an absorbent, giving an absorbent stream laden with C4 hydrocarbons and the gas stream d2, and then desorbing the C4 hydrocarbons from the laden absorbent stream, giving a C4 product gas stream d1, E) separating the C4 product stream d1 by extractive distillation with a butadiene-selective solvent into a stream e1 comprising butadiene and the selective solvent and a stream e2 comprising n-butenes; F) distilling the stream e1 comprising butadiene and the selective solvent into a stream f1 consisting essentially of the selective solvent and a stream f2 comprising butadiene, wherein stage Cb) comprises at least two compression stages Cba) and at least two cooling stages Cbb) configured in the form of quench columns, the cooling in the cooling stages being effected by direct contacting with a biphasic cooling medium having an aqueous phase and an organic phase.
    • 5. 发明申请
    • METHOD FOR PRODUCING ACETYLENES AND SYNGAS
    • US20150336858A1
    • 2015-11-26
    • US14758649
    • 2014-01-15
    • BASF SE
    • Maximilian VICARIChristian WEICHERTDirk GROSSSCHMIDTMichael RUSSKai Rainer EHRHARDTHorst NEUHAUSERMichael L. HAYES
    • C07C2/78C01B3/36
    • C01B3/36C01B2203/025C01B2203/0255C01B2203/062C01B2203/0877C01B2203/0894C01B2203/1235C01B2203/148C07C2/78C07C11/24
    • The invention relates to a continuous method for producing acetylenes and syngas by partially oxidizing hydrocarbons with oxygen. A first feed stream (1) containing one or more hydrocarbons and a second feed stream (2) containing oxygen are mixed in a ratio of the mass flows of the second feed stream (2) to the first feed stream (1) corresponding to an oxygen number of less than or equal to 0.31, said streams being heated separately from each other, and fed to a combustion chamber (FR) via a burner block (BR), the partial oxidation of the hydrocarbons being carried out in said combustion chamber, thereby obtaining a first cracked gas stream Ig. The invention is characterized in that the first cracked gas stream Ig is precooled to a temperature ranging from 100 to 1000° C. in a prequench region (H), thereby obtaining a second cracked gas stream IIg, 50 to 90% of the solids contained in the second cracked gas stream IIg are separated therefrom in a solid-gas separating device (A), thereby obtaining a solid stream If and a third cracked gas stream IIIg, the third cracked gas stream IIIg is cooled to 80 to 90 ° C. by injecting water in a total quench region (B), thereby obtaining a fourth cracked gas stream IVg and a first process water stream Iliq, the fourth cracked gas stream IVg undergoes a fine separation of solids in one or more scrubbing devices (C, D), thereby obtaining one or more process water streams IIliq, IIIliq and a product gas stream VIg, the process water streams Iliq, IIliq, IIIliq are merged into a combined process water stream IVliq, the combined process water stream IVliq is partly recirculated, as stream Vliq, into the total quench region (B) and otherwise undergoes a cleaning process, as stream VIliq, by means of a partial evaporation process, thereby obtaining a cleaned process water stream VIIliq, which is cooled by a recooling device (F), partially recycled, as stream VIIIliq, into the method, and otherwise discharged, as stream IXliq.
    • 9. 发明申请
    • APPARATUS AND PROCESS FOR THE PREPARATION OF ACETYLENE AND SYNTHESIS GAS
    • US20180170829A1
    • 2018-06-21
    • US15129094
    • 2015-03-25
    • BASF SE
    • Maximilian VICARISusanne BRITZIUSLilian KARA-HIPPENMichael RUSSMatthias KERNChristian WEICHERT
    • C07C2/78C01B3/36C07C11/24B01D3/14C07D207/267
    • C07C2/78B01D3/14B01J2219/00006C01B3/36C07C9/04C07C9/06C07C9/14C07C11/04C07C11/24C07C15/04C07C15/06C07C15/073C07C15/08C07C15/58C07D207/267
    • An apparatus (10) for the preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is proposed. The apparatus (10) comprises a reactor (12), wherein the reactor (12) comprises a burner block (14) with a furnace chamber for the preparation of a composition C1 comprising at least acetylene and substituted acetylene, a first scrubber (22) which is constructed for adding a solvent to the composition C1 to obtain a composition C2, a second scrubber (26) which is constructed for adding the solvent to the composition C2 to obtain a composition C3, a first stripper (36) which is constructed for stripping the composition C3 to obtain a composition C4 comprising the substituted acetylene, acetylene and the solvent and for separating off the acetylene, a first column (46) which is constructed for partial degassing of the composition C4 under a pressure of from 1.0 bar to 1.5 bar to obtain a composition C5 and a first amount A1 of the solvent, a second stripper (56) to which the composition C5 can be fed for stripping a composition C9 to obtain a second amount A2 of the solvent and a composition C6, a third stripper (68) which is constructed for stripping the solvent from the first scrubber (22) to obtain a composition C9, wherein the third striper (68) is connected to the second stripper (56) for feeding the composition C9 to the second stripper (56), an apparatus (72) for adding a diluting gas to the composition C5, which is arranged between the first column (46) and the second stripper (56), a second column (76) which is constructed for adding water to the composition C6 to obtain a composition C7 comprising a third amount A3 of the solvent and water and to obtain a composition C8 comprising the substituted acetylene, and a mixing condenser (82) which is constructed for adding water to the composition C8 to obtain a composition C11 comprising the substituted acetylene.A process for the preparation of acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is further proposed.