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1. 发明授权

US09334398B2 Aqueous polymer dispersion obtainable by free-radically initiated emulsion polymerization in the presence of lignosulfonate 有权
标题翻译：在木质素磺酸盐存在下通过自由引发的乳液聚合得到的聚合物水分散体
公开(公告)号：US09334398B2
公开(公告)日：2016-05-10
申请号：US14375937
申请日：2013-02-11
申请人： BASF SE
发明人： Rabie Al-Hellani , Carmen-Elena Cimpeanu , Juergen Schmidt-Thuemmes , Dirk Lawrenz , Kristina Georgieva , Anja Song
IPC分类号： C08L25/14 , C08F2/22 , C08F2/44 , C08L33/08 , C09D4/06 , C09D7/12 , D21H19/56
CPC分类号： C08L25/14 , C08F2/22 , C08F2/44 , C08L33/08 , C09D4/06 , C09D7/65 , D21H19/56 , Y10T428/31906
摘要： Described is an aqueous polymer dispersion comprising a chain growth addition polymer obtainable via free-radically initiated emulsion polymerization from ethylenically unsaturated, free-radically polymerizable monomers, wherein the chain growth addition polymer is formed to an extent of not less than 60 wt % from primary monomers selected from vinylaromatic compounds, conjugated aliphatic dienes, vinyl esters of saturated C1- to C20-carboxylic acids, esters of acrylic acid or of methacrylic acid with monohydric C1- to C20-alcohols, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, or mixtures thereof, wherein the monomers are polymerized in the presence of lignosulfonate and wherein the chain growth addition polymer is branched or crosslinked. Also described is a process for preparing the aqueous polymer dispersion. The polymer dispersion is useful for preparing paper coating compositions.
摘要翻译：描述了一种含水聚合物分散体，其包含通过烯键式不饱和的可自由基聚合的单体经由自由基引发的乳液聚合而获得的链增长加成聚合物，其中链生长加成聚合物形成至少不少于60重量％选自乙烯基芳族化合物，共轭脂族二烯，饱和C 1〜C 20羧酸的乙烯基酯，丙烯酸或甲基丙烯酸与一元C 1〜C 20醇的酯，碳原子数2〜8的脂肪族烃和1〜两个双键或其混合物，其中所述单体在木素磺酸盐存在下聚合，并且其中链生长加成聚合物是支链或交联的。还描述了制备聚合物水分散体的方法。聚合物分散体可用于制备纸涂料组合物。

2. 发明授权

US09315943B2 Finely divided, starch-containing polymer dispersions, processes for their preparation and use as sizes in papermaking 有权
标题翻译：细分，含淀粉的聚合物分散体，其制备方法和用作造纸中的尺寸
公开(公告)号：US09315943B2
公开(公告)日：2016-04-19
申请号：US14350467
申请日：2012-10-11
申请人： BASF SE
发明人： Carmen-Elena Cimpeanu , Holger Kern , Petra Arnold , Christoph Hamers
IPC分类号： C08L25/14 , C08L3/00 , C08K3/10 , D21H21/16 , C08F212/08 , C08F2/24 , D21H17/28 , D21H17/34 , D21H19/20 , C08F2/26 , C08F251/00 , C08F220/18
CPC分类号： D21H21/16 , C08F2/24 , C08F2/26 , C08F212/08 , C08F220/18 , C08F251/00 , D21H17/28 , D21H17/34 , D21H19/20 , C08F2220/1825 , C08F236/20 , C08F2/44
摘要： A finely divided, starch-containing polymer dispersion which is obtainable by free radical emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one redox initiator and starch, wherein (a) from 0 to less than 40% by weight of at least one optionally substituted styrene, (b) from greater than 60 to 100% by weight of at least one C1-C12-alkyl acrylate and/or C1-C12-alkyl methacrylate, (c) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer, are used as the ethylenically unsaturated monomers, the sum (a)+(b)+(c) being 100% and being based on the active monomer content and (d) from 15 to 40% by weight of at least one degraded starch which has a molar mass Mw of from 1000 to 65 000 g/mol, based on the total weight of solids content of components (a)+(b)+(c)+(d), are used as the starch, and the polymerization being carried out in the presence of at least 0.01% by weight, based on the monomers used, of at least one terpene containing chain-transfer agent, and in which the polymer dispersion optionally comprises an aluminum compound. The use of the finely divided, starch-containing polymer dispersions as sizes for paper, board and cardboard is also claimed.
摘要翻译：一种细分散的含淀粉的聚合物分散体，其可通过烯属不饱和单体在至少一种氧化还原引发剂和淀粉的存在下的自由基乳液聚合而获得，其中（a）0至小于40重量％的至少一种任选取代的苯乙烯，（b）大于60至100重量％的至少一种丙烯酸C1-C12烷基酯和/或甲基丙烯酸C1-C12-烷基酯，（c）0至10重量％的至少一种其他烯键式不饱和可共聚单体用作烯键式不饱和单体，总和（a）+（b）+（c）为100％，基于活性单体含量，（d）15〜40重量％使用基于组分（a）+（b）+（c）+（d）的固体含量的总重量，摩尔质量Mw为1000至65000g / mol的至少一种降解淀粉用作淀粉，并且所述聚合在至少基于所用单体的至少0.01重量％存在下进行，至少在萜烯含链转移剂，其中聚合物分散体任选地包含铝化合物。还要求使用细碎的含淀粉聚合物分散体作为纸，纸板和纸板的尺寸。

3. 发明授权

US09328247B2 Paper coating slip additive comprising acid monomer, associative monomer and nonionic monomer 有权
标题翻译：包含酸单体，缔合单体和非离子单体的纸涂料滑爽添加剂
公开(公告)号：US09328247B2
公开(公告)日：2016-05-03
申请号：US14356530
申请日：2012-11-07
申请人： BASF SE
发明人： Hermann Seyffer , Carmen-Elena Cimpeanu , Anja Song , Thomas Steinmacher , Joerg Claussen , Philipp Zacharias , Vijay Immanuel Raman , Petra Schoecker
IPC分类号： C09D7/12 , C09D4/06 , C08F20/28
CPC分类号： C09D7/1216 , C08F20/28 , C09D4/06 , C09D7/61 , Y10T428/31906
摘要： A paper coating slip additive obtainable by free-radical polymerization, its preparation and its use in paper coating compositions are described. The additive is formed from (a) acid monomers selected from ethylenically unsaturated C3 to C8 carboxylic acids, (b) associative monomers of the general formula H2C═CR1—COO-(EO)n—(PO)m—R2 where R1 is hydrogen or methyl, n is at least two, m is from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30 alkyl group or a C8-C30 alkaryl group, and (c) nonionic copolymerizable monomers other than a) and b), wherein said additive has a weight average molecular weight of below 200 000 and wherein tert-dodecyl mercaptan is used as chain transfer agent.
摘要翻译：描述了通过自由基聚合获得的纸张涂布滑爽剂，其制备方法及其在纸涂料组合物中的用途。添加剂由（a）选自烯属不饱和C3至C8羧酸的酸单体形成，（b）通式为H 2 C = CR 1 -COO-（EO）n - （PO）m -R 2的缔合单体，其中R 1为氢或甲基，n为至少两个，m为0至50，EO为环氧乙烷基团，PO为环氧丙烷基团，R 2为C 8 -C 30烷基或C 8 -C 30烷芳基，（c）除a）和b）以外的非离子共聚单体，其中所述添加剂的重均分子量低于200000，其中叔十二烷基硫醇用作链转移剂。

4. 发明申请

US20140275415A1 FINELY DIVIDED, STARCH-CONTAINING POLYMER DISPERSIONS, PROCESSES FOR THEIR PREPARATION AND USE AS SIZES IN PAPERMAKING 有权
标题翻译：精细分散，含淀粉的聚合物分散体，其制备方法和用于造纸中的尺寸
公开(公告)号：US20140275415A1
公开(公告)日：2014-09-18
申请号：US14350467
申请日：2012-10-11
申请人： BASF SE
发明人： Carmen-Elena Cimpeanu , Holger Kern , Petra Arnold , Christoph Hamers
IPC分类号： D21H21/16 , D21H19/20
CPC分类号： D21H21/16 , C08F2/24 , C08F2/26 , C08F212/08 , C08F220/18 , C08F251/00 , D21H17/28 , D21H17/34 , D21H19/20 , C08F2220/1825 , C08F236/20 , C08F2/44
摘要： A finely divided, starch-containing polymer dispersion which is obtainable by free radical emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one redox initiator and starch, wherein (a) from 0 to less than 40% by weight of at least one optionally substituted styrene, (b) from greater than 60 to 100% by weight of at least one C1-C12-alkyl acrylate and/or C1-C12-alkyl methacrylate, (c) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer, are used as the ethylenically unsaturated monomers, the sum (a)+(b)+(c) being 100% and being based on the active monomer content and (d) from 15 to 40% by weight of at least one degraded starch which has a molar mass Mw of from 1000 to 65000 g/mol, based on the total weight of solids content of components (a)+(b)+(c)+(d), are used as the starch, and the polymerization being carried out in the presence of at least 0.01% by weight, based on the monomers used, of at least one terpene containing chain-transfer agent, and in which the polymer dispersion optionally comprises an aluminium compound. The use of the finely divided, starch-containing polymer dispersions as sizes for paper, board and cardboard is also claimed.
摘要翻译：一种细分散的含淀粉的聚合物分散体，其可通过烯属不饱和单体在至少一种氧化还原引发剂和淀粉的存在下的自由基乳液聚合而获得，其中（a）0至小于40重量％的至少一种任选取代的苯乙烯，（b）大于60至100重量％的至少一种丙烯酸C1-C12烷基酯和/或甲基丙烯酸C1-C12-烷基酯，（c）0至10重量％的至少一种其他烯键式不饱和可共聚单体用作烯键式不饱和单体，总和（a）+（b）+（c）为100％，基于活性单体含量，（d）15〜40重量％使用基于组分（a）+（b）+（c）+（d）的固体含量的总重量，摩尔质量Mw为1000至65000g / mol的至少一种降解淀粉作为淀粉，并且所述聚合在至少一种基于所用单体的至少0.01重量％存在下进行萜烯含链转移剂，其中聚合物分散体任选地包含铝化合物。还要求使用细碎的含淀粉聚合物分散体作为纸，纸板和纸板的尺寸。

5. 发明授权

US09950502B2 Paper and cardboard packaging with barrier coating 有权
公开(公告)号：US09950502B2
公开(公告)日：2018-04-24
申请号：US14360803
申请日：2012-12-03
申请人： BASF SE
发明人： Hermann Seyffer , Carmen-Elena Cimpeanu , Heiko Diehl , Darijo Mijolovic , Andre Van Meer , Jan Van Delft , Christof Van Sluijs
IPC分类号： B32B27/10 , D21H19/12 , B65D5/18 , B65D5/36 , B65D5/20 , B65D5/02 , B65D5/00 , B65D5/40 , B65D5/42 , B32B27/30 , B65D5/56 , B32B29/00 , B32B1/02 , C08F2/22 , D21H19/16 , D21H19/20 , D21H19/52 , D21H19/54 , D21H27/10 , D21H11/14 , D21H19/34 , D21H19/58 , B65D30/00 , B65D65/42 , B65D85/00
CPC分类号： B32B27/10 , B32B1/02 , B32B27/30 , B32B27/308 , B32B29/00 , B32B29/002 , B65D5/00 , B65D5/02 , B65D5/18 , B65D5/20 , B65D5/36 , B65D5/40 , B65D5/42 , B65D5/56 , B65D5/563 , B65D31/00 , B65D65/42 , B65D85/70 , B65D2565/383 , B65D2577/04 , C08F2/22 , D21H11/14 , D21H19/12 , D21H19/16 , D21H19/20 , D21H19/34 , D21H19/52 , D21H19/54 , D21H19/58 , D21H27/10 , Y10T428/1303 , Y10T428/1307 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/264 , Y10T428/31906
摘要： Described is paper or cardboard packaging produced from mineral oil contaminated, (e.g., recycled) paper, wherein the packaging includes a barrier layer obtainable by applying an aqueous polymer dispersion comprising a copolymer obtainable by emulsion polymerization of C1-C4 alkyl (meth)acrylates, acid monomers, e.g., acrylic acid or methacrylic acid, 0-20 wt % of acrylonitrile and 0 to 10 wt % of further monomers in an aqueous medium in the presence of a carbohydrate compound, preferably in the form of a degraded starch, wherein the glass transition temperature of the copolymer is in the range from +10 to +45° C. The barrier layer may be situated on one of the surfaces of the packaging or form one of multiple layers of a multilayered packaging coating or be situated as a coating on one side of an inner bag situated within the packaging.

6. 发明申请

US20160083909A1 FINELY DIVIDED, STARCH-CONTAINING POLYMER DISPERSIONS, PROCESSES FOR THEIR PREPARATION AND USE AS SIZES IN PAPERMAKING 审中-公开
标题翻译：精细分散，含淀粉的聚合物分散体，其制备方法和用于造纸中的尺寸
公开(公告)号：US20160083909A1
公开(公告)日：2016-03-24
申请号：US14959118
申请日：2015-12-04
申请人： BASF SE
发明人： Carmen-Elena Cimpeanu , Holger Kern , Petra Arnold , Christoph Hamers
IPC分类号： D21H21/16 , D21H19/20
CPC分类号： D21H21/16 , C08F2/24 , C08F2/26 , C08F212/08 , C08F220/18 , C08F251/00 , D21H17/28 , D21H17/34 , D21H19/20 , C08F2220/1825 , C08F236/20 , C08F2/44
摘要： A finely divided, starch-containing polymer dispersion which is obtainable by free radical emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one redox initiator and starch, wherein (a) from 0 to less than 40% by weight of at least one optionally substituted styrene, (b) from greater than 60 to 100% by weight of at least one C1-C12-alkyl acrylate and/or C1-C12-alkyl methacrylate, (c) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer, are used as the ethylenically unsaturated monomers, the sum (a)−(b)+(c) being 100% and being based on the active monomer content and (d) from 15 to 40% by weight of at least one degraded starch which has a molar mass Mw of from 1000 to 65 000 g/mol, based on the total weight of solids content of components (a)+(b)+(c)+(d), are used as the starch, and the polymerization being carried out in the presence of at least 0.01% by weight, based on the monomers used, of at least one terpene containing chain-transfer agent, and in which the polymer dispersion optionally comprises an aluminium compound. The use of the finely divided, starch-containing polymer dispersions as sizes for paper, board and cardboard is also claimed.
摘要翻译：一种细分散的含淀粉的聚合物分散体，其可通过烯属不饱和单体在至少一种氧化还原引发剂和淀粉的存在下的自由基乳液聚合而获得，其中（a）0至小于40重量％的至少一种任选取代的苯乙烯，（b）大于60至100重量％的至少一种丙烯酸C1-C12烷基酯和/或甲基丙烯酸C1-C12-烷基酯，（c）0至10重量％的至少一种其他烯键式不饱和可共聚单体用作烯键式不饱和单体，总和（a） - （b）+（c）为100％，基于活性单体含量，（d）15至40重量％使用基于组分（a）+（b）+（c）+（d）的固体含量的总重量，摩尔质量Mw为1000至65000g / mol的至少一种降解淀粉用作淀粉，并且所述聚合在至少基于所用单体的至少0.01重量％的存在下进行一种含萜烯的链转移剂，其中聚合物分散体任选地包含铝化合物。还要求使用细碎的含淀粉聚合物分散体作为纸，纸板和纸板的尺寸。

7. 发明申请

US20140342171A1 AQUEOUS POLYMER DISPERSION OBTAINABLE BY FREE-RADICALLY INITIATED EMULSION POLYMERIZATION IN THE PRESENCE OF LIGNOSULFONATE 有权
标题翻译：水合聚合物分散体，可以通过免疫原性乳化聚合获得，
公开(公告)号：US20140342171A1
公开(公告)日：2014-11-20
申请号：US14375937
申请日：2013-02-11
申请人： BASF SE
发明人： Rabie Al-Hellani , Carmen-Elena Cimpeanu , Juergen Schmidt-Thuemmes , Dirk Lawrenz , Kristina Georgieva , Anja Song
IPC分类号： C08L25/14 , D21H19/56 , C09D7/12 , C08L33/08 , C09D4/06
CPC分类号： C08L25/14 , C08F2/22 , C08F2/44 , C08L33/08 , C09D4/06 , C09D7/65 , D21H19/56 , Y10T428/31906
摘要： Described is an aqueous polymer dispersion comprising a chain growth addition polymer obtainable via free-radically initiated emulsion polymerization from ethylenically unsaturated, free-radically polymerizable monomers, wherein the chain growth addition polymer is formed to an extent of not less than 60 wt % from primary monomers selected from vinylaromatic compounds, conjugated aliphatic dienes, vinyl esters of saturated C1- to C20-carboxylic acids, esters of acrylic acid or of methacrylic acid with monohydric C1- to C20-alcohols, aliphatic hydrocarbons having 2 to 8 carbon atoms and one or two double bonds, or mixtures thereof, wherein the monomers are polymerized in the presence of lignosulfonate and wherein the chain growth addition polymer is branched or crosslinked. Also described is a process for preparing the aqueous polymer dispersion. The polymer dispersion is useful for preparing paper coating compositions.
摘要翻译：描述了一种含水聚合物分散体，其包含通过烯键式不饱和的可自由基聚合的单体经由自由基引发的乳液聚合而获得的链增长加成聚合物，其中链生长加成聚合物形成至少不少于60重量％选自乙烯基芳族化合物，共轭脂族二烯，饱和C 1〜C 20羧酸的乙烯基酯，丙烯酸或甲基丙烯酸与一元C 1〜C 20醇的酯，碳原子数2〜8的脂肪族烃和1〜两个双键或其混合物，其中所述单体在木素磺酸盐存在下聚合，并且其中链生长加成聚合物是支链或交联的。还描述了制备聚合物水分散体的方法。聚合物分散体可用于制备纸涂料组合物。

8. 发明申请

US20140302335A1 PAPER COATING SLIP ADDITIVE COMPRISING ACID MONOMER, ASSOCIATIVE MONOMER AND NONIONIC MONOMER 有权
标题翻译：包装酸性单体，相关单体和非离子单体的纸涂层滑水添加剂
公开(公告)号：US20140302335A1
公开(公告)日：2014-10-09
申请号：US14356530
申请日：2012-11-07
申请人： BASF SE
发明人： Hermann Seyffer , Carmen-Elena Cimpeanu , Anja Song , Thomas Steinmacher , Joerg Claussen , Philipp Zacharias , Vijay Raman , Petra Schoecker
IPC分类号： C09D7/12 , C08F20/28
CPC分类号： C09D7/1216 , C08F20/28 , C09D4/06 , C09D7/61 , Y10T428/31906
摘要： A paper coating slip additive obtainable by free-radical polymerization, its preparation and its use in paper coating compositions are described. The additive is formed from (a) acid monomers selected from ethylenically unsaturated C3 to C8 carboxylic acids, (b) associative monomers of the general formula H2C═CR1—COO-(EO)n—(PO)m—R2 where R1 is hydrogen or methyl, n is at least two, m is from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R 2 is a C8-C30 alkyl group or a C8-C30 alkaryl group, and (c) nonionic copolymerizable monomers other than a) and b), wherein said additive has a weight average molecular weight of below 200 000 and wherein tert-dodecyl mercaptan is used as chain transfer agent.
摘要翻译：描述了通过自由基聚合获得的纸张涂布滑爽剂，其制备方法及其在纸涂料组合物中的用途。添加剂由（a）选自烯属不饱和C3至C8羧酸的酸单体形成，（b）通式为H 2 C = CR 1 -COO-（EO）n - （PO）m -R 2的缔合单体，其中R 1为氢或甲基，n为至少两个，m为0至50，EO为环氧乙烷基团，PO为环氧丙烷基团，R 2为C 8 -C 30烷基或C 8 -C 30烷芳基，（c ）除a）和b）以外的非离子可共聚单体，其中所述添加剂的重均分子量低于200000，并且其中使用叔十二烷基硫醇作为链转移剂。

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