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    • 7. 发明申请
    • Permanent chemical marker and identification of information in polymers
    • 永久化学标记和聚合物信息的识别
    • US20100003762A1
    • 2010-01-07
    • US12446770
    • 2007-10-23
    • Axel KolbeHardy Markwitz
    • Axel KolbeHardy Markwitz
    • G01N33/44C08F283/02
    • C08K5/0008C08K3/01
    • The invention relates to a process for chemical marking and identification of information in polymers and additives, such as ageing additives, thermal stabilizer additives, light stabilizer additives, plasticizer additives or flame retardant additives and dyes and other high-value additives. The marking is effected by the use of defined atomic masses in the form of isotopes of suitable elements in chemical compounds which are incorporated into the polymer matrix and anchored during the production. The result is a chemical code which can be recalled over the entire product life without adversely affecting the properties of the polymer through high concentrations of extraneous substances. It is possible by this process to trace back the origin of a polymer, to detect possible mixtures with chemically identical products from other manufacturers, or to clarify at a later stage whether an additive has been added in the concentration specified.
    • 本发明涉及聚合物和添加剂中的信息化学标记和鉴定方法,例如老化添加剂,热稳定剂添加剂,光稳定剂添加剂,增塑剂添加剂或阻燃添加剂以及染料和其它高价值添加剂。 标记通过使用在化学化合物中合适元素的同位素形式的限定原子团块来实现,所述化合物被掺入到聚合物基质中并在生产过程中锚定。 结果是可以在整个产品寿命内回收的化学代码,而不会通过高浓度的外来物质不利地影响聚合物的性能。 通过该方法可以追溯聚合物的来源,检测来自其他制造商的化学相同产品的可能混合物,或者在稍后阶段澄清是否以规定的浓度添加添加剂。
    • 8. 发明申请
    • Method for stabilizing the spinning solution for production of cellulose composite molded bodies
    • 用于稳定纺丝溶液以生产纤维素复合成型体的方法
    • US20090309256A1
    • 2009-12-17
    • US12373971
    • 2007-07-16
    • Axel KolbeHardy MarkwitzFrank WendlerMichael Mooz
    • Axel KolbeHardy MarkwitzFrank WendlerMichael Mooz
    • B29C47/06
    • D01F2/00D01F1/10
    • The invention stabilizes spinning solutions used to produce cellulose composite molded bodies incorporating functional materials by the dry-wet extrusion method. The invention incorporates active materials detrimentally affecting the spinning process and materials which are unstable in the cellulose spinning solution, using separate active material and cellulose streams. The active material stream is produced, stabilized and stored separately and mixed with the cellulose stream directly before the forming apparatus, for example, a spinning bar. The active material stream includes amine oxide, functional materials, additives and water. The cellulose stream includes cellulose in amine oxide. The inventive method avoids heat build-up in the moulding or spinning solution, produces cellulose molded bodies with an adequately high degree of polymerisation and excellent functional properties and restricts the decomposition of the amine oxide. The interactions between cellulose and additive are restricted and storage life for the additive suspension improved.
    • 本发明通过干式湿式挤出法稳定了用于生产掺有功能材料的纤维素复合成型体的纺丝溶液。 本发明使用不利地影响纺丝工艺的活性材料和在纤维素纺丝溶液中不稳定的材料,使用分开的活性材料和纤维素流。 生产活性物质流,分离储存并与纤维素流混合,直接在成形装置例如纺丝棒之前。 活性物质流包括氧化胺,功能材料,添加剂和水。 纤维素流包括氧化胺中的纤维素。 本发明的方法避免了在模制或纺丝溶液中的热积聚,产生具有足够高的聚合度和优异的功能性能的纤维素模塑体并限制了氧化胺的分解。 纤维素和添加剂之间的相互作用受到限制,添加剂悬浮液的储存寿命得到改善。