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1. 发明申请

US20120237436A1 Catalyst For The Growth Of Carbon Single-Walled Nanotubes 审中-公开
标题翻译：用于碳单壁纳米管生长的催化剂
公开(公告)号：US20120237436A1
公开(公告)日：2012-09-20
申请号：US13429309
申请日：2012-03-23
申请人： Avetik R. Harutyunyan , Toshio Tokune , Elena Mora
发明人： Avetik R. Harutyunyan , Toshio Tokune , Elena Mora
IPC分类号： D01F9/127 , B82Y40/00 , B82Y30/00
CPC分类号： B01J35/0013 , B01J21/185 , B01J23/28 , B01J23/44 , B01J23/74 , B01J37/0211 , B01J37/343 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , Y10S977/843
摘要： Methods and processes for synthesizing single-wall carbon nanotubes are provided. A carbon precursor gas is contacted with metal catalysts deposited on a support material. The metal catalysts are preferably nanoparticles having diameters less than about 3 nm. The reaction temperature is selected such that it is near the eutectic point of the mixture of metal catalyst particles and carbon. Further, the rate at which hydrocarbons are fed into the reactor is equivalent to the rate at which the hydrocarbons react for given synthesis temperature. The methods produce carbon single-walled nanotubes having longer lengths.
摘要翻译：提供了合成单壁碳纳米管的方法和方法。碳前体气体与沉积在载体材料上的金属催化剂接触。金属催化剂优选直径小于约3nm的纳米颗粒。选择反应温度使其接近金属催化剂颗粒和碳的混合物的共晶点。此外，烃进料到反应器中的速率等于烃在给定合成温度下反应的速率。该方法产生长度较长的碳单壁碳纳米管。

2. 发明授权

US08728430B2 Low temperature single-wall carbon nanotube synthesis 有权
标题翻译：低温单壁碳纳米管合成
公开(公告)号：US08728430B2
公开(公告)日：2014-05-20
申请号：US12487324
申请日：2009-06-18
申请人： Elena Mora , John M. Pigos , Avetik R. Harutyunyan
发明人： Elena Mora , John M. Pigos , Avetik R. Harutyunyan
IPC分类号： D01F9/12
CPC分类号： C01B31/0233 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02
摘要： The present disclosure is directed to a method for producing SWCNT from endothermic carbon-containing feedstock, such as, methane gas, using an activated alumina supported Fe:Mo catalyst. The SWCNT growth temperature is less than about 560° C., and the catalyst is activated by exposure to a reducing atmosphere at a temperature greater than about 900° C.
摘要翻译：本公开涉及一种使用活性氧化铝负载的Fe：Mo催化剂从含吸热碳原料（如甲烷气）生产SWCNT的方法。 SWCNT生长温度低于约560℃，并且催化剂通过在大于约900℃的温度下暴露于还原性气氛而被活化。

3. 发明授权

US08163263B2 Catalyst for the growth of carbon single-walled nanotubes 有权
标题翻译：用于生长碳单壁纳米管的催化剂
公开(公告)号：US08163263B2
公开(公告)日：2012-04-24
申请号：US11669128
申请日：2007-01-30
申请人： Avetik R. Harutyunyan , Toshio Tokune , Elena Mora
发明人： Avetik R. Harutyunyan , Toshio Tokune , Elena Mora
IPC分类号： D01F9/12
CPC分类号： B01J35/0013 , B01J21/185 , B01J23/28 , B01J23/44 , B01J23/74 , B01J37/0211 , B01J37/343 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , Y10S977/843
摘要： Methods and processes for synthesizing single-wall carbon nanotubes are provided. A carbon precursor gas is contacted with metal catalysts deposited on a support material. The metal catalysts are preferably nanoparticles having diameters less than about 3 nm. The reaction temperature is selected such that it is near the eutectic point of the mixture of metal catalyst particles and carbon. Further, the rate at which hydrocarbons are fed into the reactor is equivalent to the rate at which the hydrocarbons react for given synthesis temperature. The methods produce carbon single-walled nanotubes having longer lengths.
摘要翻译：提供了合成单壁碳纳米管的方法和方法。碳前体气体与沉积在载体材料上的金属催化剂接触。金属催化剂优选直径小于约3nm的纳米颗粒。选择反应温度使其接近金属催化剂颗粒和碳的混合物的共晶点。此外，烃进料到反应器中的速率等于烃在给定合成温度下反应的速率。该方法产生长度较长的碳单壁碳纳米管。

4. 发明申请

US20090324484A1 Effect Of Hydrocarbon And Transport Gas Feedstock On Efficiency And Quality Of Grown Single-Walled Nanotubes 有权
标题翻译：烃和运输气体原料对生长单壁纳米管的效率和质量的影响
公开(公告)号：US20090324484A1
公开(公告)日：2009-12-31
申请号：US12113814
申请日：2008-05-01
申请人： Avetik R. Harutyunyan , Elena Mora
发明人： Avetik R. Harutyunyan , Elena Mora
IPC分类号： D01F9/12
CPC分类号： D01F9/127 , B82Y30/00 , D01F9/1272 , D01F9/133
摘要： Methods and processes for synthesizing high quality carbon single-walled nanotubes (SWNTs) are provided. The method provides the means for optimization of amount of carbon precursor and transport gas per unit weight of catalyst. Efficiencies of about 20% can be achieved when contacting the catalyst deposited on a support with a carbon precursor gas with a flow rates of about 4.2×10−3 mol CH4/sec·g (Fe) at 780 ° C. Hydrocarbon flow rates of about 1.7 10−2 mol CH4/sec·g (Fe) and higher result in faster carbon SWNTs growth with improved quality. Slower rates of carbon atoms supply (˜4.5×1020 C atoms/s·g Fe or 6.4×10−4 mol CH4/sec·g (Fe)) result in the formation of more defective nanotubes.
摘要翻译：提供了合成高品质碳单壁纳米管（SWNT）的方法和工艺。该方法提供了用于优化碳前体和每单位重量催化剂的运输气体的量的方法。当沉积在载体上的催化剂与碳前体气体接触时，在780℃下流速约为4.2×10-3 mol CH4 / sec.g（Fe），可以实现约20％的效率。 1.7 10-2 mol CH4 / sec.g（Fe）和更高的速度导致更快的碳SWNTs生长，质量提高。碳原子供应速度越来越慢（约4.5x1020 C原子/秒，Fe或6.4×10-4摩尔CH4 / sec.g（Fe））导致形成更多的有缺陷的纳米管。

5. 发明授权

US08591858B2 Effect of hydrocarbon and transport gas feedstock on efficiency and quality of grown single-walled nanotubes 有权
标题翻译：碳氢化合物和运输气体原料对生长的单壁纳米管的效率和质量的影响
公开(公告)号：US08591858B2
公开(公告)日：2013-11-26
申请号：US12113814
申请日：2008-05-01
申请人： Avetik R. Harutyunyan , Elena Mora
发明人： Avetik R. Harutyunyan , Elena Mora
IPC分类号： C01B31/02 , D01C5/00 , D01F9/12 , B01J19/08 , C09C1/56 , B32B9/00 , B32B17/08
CPC分类号： D01F9/127 , B82Y30/00 , D01F9/1272 , D01F9/133
摘要： Methods and processes for synthesizing high quality carbon single-walled nanotubes (SWNTs) are provided. The method provides the means for optimization of amount of carbon precursor and transport gas per unit weight of catalyst. In certain aspects, methods are provided wherein a supported metal catalyst is contacted with a carbon precursor gas at about one atmosphere pressure, wherein SWNTs are synthesized at a growth rate of about 0.002 μm/sec to about 0.003 μm/sec and the SWNTs have a ratio of G-band to D-band in Raman spectra (IG:ID) of greater than about 4. Efficiencies of about 20% can be achieved when contacting the catalyst deposited on a support with a carbon precursor gas with a flow rates of about 4.2×10−3 mol CH4/sec·g (Fe) at 780° C. Hydrocarbon flow rates of about 1.7 10−2 mol CH4/sec·g (Fe) and higher result in faster carbon SWNTs growth with improved quality. Slower rates of carbon atoms supply (˜4.5×1020 C atoms/s·g Fe or 6.4×10−4 mol CH4/sec·g (Fe)) result in the formation of more defective nanotubes.
摘要翻译：提供了合成高质量碳单壁纳米管（SWNT）的方法和工艺。该方法提供了用于优化碳前体和每单位重量催化剂的运输气体的量的方法。在某些方面，提供了一种方法，其中负载金属催化剂在大约一个大气压下与碳前体气体接触，其中以约0.002mum / sec至约0.003mum / sec的生长速率合成SWNT，并且SWNT具有将拉伸光谱中的G带与D带的比例（IG：ID）大于约4.当将沉积在载体上的催化剂与碳前体气体接触，流速约为约20％时，可实现约20％的效率 4.2×10-3 mol CH4 / sec·g（Fe）在780°C。烃流量约为1.7×10-2 mol CH4 / sec·g（Fe）和更高，导致更快的碳SWNTs生长，质量提高。碳原子供应速度较慢（〜4.5×1020 C原子/ s·g Fe或6.4×10-4 mol CH4 / sec·g（Fe））导致形成更多缺陷的纳米管。

6. 发明申请

US20130259795A1 LOW TEMPERATURE SINGLE-WALL CARBON NANOTUBE SYNTHESIS 有权
标题翻译：低温单壁碳纳米管合成
公开(公告)号：US20130259795A1
公开(公告)日：2013-10-03
申请号：US12487324
申请日：2009-06-18
申请人： Elena Mora , John M. Pigos , Avetik R. Harutyunyan
发明人： Elena Mora , John M. Pigos , Avetik R. Harutyunyan
IPC分类号： C01B31/02
CPC分类号： C01B31/0233 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02
摘要： The present disclosure is directed to a method for producing SWCNT from endothermic carbon-containing feedstock, such as, methane gas, using an activated alumina supported Fe:Mo catalyst. The SWCNT growth temperature is less than about 560° C., and the catalyst is activated by exposure to a reducing atmosphere at a temperature greater than about 900° C.
摘要翻译：本公开涉及一种使用活性氧化铝负载的Fe：Mo催化剂从含吸热碳原料（如甲烷气）生产SWCNT的方法。 SWCNT生长温度低于约560℃，并且催化剂通过在大于约900℃的温度下暴露于还原性气氛而被活化。

7. 发明申请

US20070281087A1 Catalyst for the Growth of Carbon Single-Walled Nanotubes 有权
标题翻译：碳单壁纳米管生长催化剂
公开(公告)号：US20070281087A1
公开(公告)日：2007-12-06
申请号：US11669128
申请日：2007-01-30
申请人： Avetik Harutyunyan , Toshio Tokune , Elena Mora
发明人： Avetik Harutyunyan , Toshio Tokune , Elena Mora
IPC分类号： C23C16/26
CPC分类号： B01J35/0013 , B01J21/185 , B01J23/28 , B01J23/44 , B01J23/74 , B01J37/0211 , B01J37/343 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , Y10S977/843
摘要： Methods and processes for synthesizing single-wall carbon nanotubes are provided. A carbon precursor gas is contacted with metal catalysts deposited on a support material. The metal catalysts are preferably nanoparticles having diameters less than about 3 nm. The reaction temperature is selected such that it is near the eutectic point of the mixture of metal catalyst particles and carbon. Further, the rate at which hydrocarbons are fed into the reactor is equivalent to the rate at which the hydrocarbons react for given synthesis temperature. The methods produce carbon single-walled nanotubes having longer lengths.
摘要翻译：提供了合成单壁碳纳米管的方法和方法。碳前体气体与沉积在载体材料上的金属催化剂接触。金属催化剂优选直径小于约3nm的纳米颗粒。选择反应温度使其接近金属催化剂颗粒和碳的混合物的共晶点。此外，烃进料到反应器中的速率等于烃在给定合成温度下反应的速率。该方法产生长度较长的碳单壁碳纳米管。

8. 发明授权

US08026100B2 Method of determining lifetime of a nanotube-producing catalyst 有权
标题翻译：确定纳米管生产催化剂寿命的方法
公开(公告)号：US08026100B2
公开(公告)日：2011-09-27
申请号：US12108566
申请日：2008-04-24
申请人： Elena Mora , Avetik Harutyunyan
发明人： Elena Mora , Avetik Harutyunyan
IPC分类号： G01N23/00
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/02
摘要： The present teachings are directed toward methods of determining the lifetime of a catalyst for producing carbon nanotubes. The methods include providing different isotopically-labeled reaction components, primarily hydrocarbon sources containing different carbon isotopes, to the catalyst and measuring the Raman spectra of the carbon nanotubes produced with the different hydrocarbon sources.
摘要翻译：本教导涉及确定用于生产碳纳米管的催化剂的寿命的方法。这些方法包括向催化剂提供不同的同位素标记的反应组分，主要是含有不同碳同位素的烃源，并测量用不同烃源生产的碳纳米管的拉曼光谱。

9. 发明申请

US20080292532A1 Method of Determining Lifetime of a Nanotube-Producing Catalyst 有权
标题翻译：确定纳米管生产催化剂寿命的方法
公开(公告)号：US20080292532A1
公开(公告)日：2008-11-27
申请号：US12108566
申请日：2008-04-24
申请人： Elena Mora , Avetik Harutyunyan
发明人： Elena Mora , Avetik Harutyunyan
IPC分类号： G01N31/10 , D01F9/127
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162 , C01B2202/02
摘要： The present teachings are directed toward methods of determining the lifetime of a catalyst for producing carbon nanotubes. The methods include providing different isotopically-labeled reaction components, primarily hydrocarbon sources containing different carbon isotopes, to the catalyst and measuring the Raman spectra of the carbon nanotubes produced with the different hydrocarbon sources.
摘要翻译：本教导涉及确定用于生产碳纳米管的催化剂的寿命的方法。这些方法包括向催化剂提供不同的同位素标记的反应组分，主要是含有不同碳同位素的烃源，并测量用不同烃源生产的碳纳米管的拉曼光谱。

10. 发明授权

US08124043B2 Method of preparing carbon nanotube containing electrodes 有权
标题翻译：制备含有碳纳米管的电极的方法
公开(公告)号：US08124043B2
公开(公告)日：2012-02-28
申请号：US11723185
申请日：2007-03-16
申请人： Avetik Harutyunyan , Elena Mora
发明人： Avetik Harutyunyan , Elena Mora
IPC分类号： D01F9/12 , B01J23/00 , H01B1/06
CPC分类号： H01M8/0234 , B82Y30/00 , B82Y40/00 , C01B32/162 , H01M4/90 , H01M4/9083 , H01M4/92 , H01M4/926 , Y10S977/742
摘要： The present teachings are directed toward a matrix containing nanosized metal components and carbon nanotubes, with the carbon nanotubes being produced in situ by the nanosized metal components upon the contacting of the nanosized metal components with a carbon source under conditions sufficient to produce the carbon nanotubes. Also disclosed are methods of producing the matrix containing the nanosized metal components and carbon nanotubes.
摘要翻译：本教导涉及含有纳米尺寸金属组分和碳纳米管的基质，其中在纳米金属组分与碳源在足以产生碳纳米管的条件下接触时，纳米金属组分原位产生碳纳米管。还公开了制备含有纳米尺寸金属组分和碳纳米管的基质的方法。

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