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1. 发明授权

US08450478B2 Cyclic guanidine ionic liquid 有权
标题翻译：环状胍离子液体
公开(公告)号：US08450478B2
公开(公告)日：2013-05-28
申请号：US13358491
申请日：2012-01-25
申请人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
发明人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
IPC分类号： C07D401/04 , C07D413/04 , C07D417/04 , C07D403/04
CPC分类号： H01M10/0568 , C07D233/44 , C07D233/48 , C07D239/12 , C07D239/14 , C07D401/04 , C07D403/04 , C07D417/04 , H01G9/038 , H01G9/2013 , H01G9/2031 , H01G9/2059 , H01G11/58 , H01G11/62 , H01M14/005 , Y02E10/542 , Y02E60/13 , Y02P70/521
摘要： Disclosed is an ionic liquid which is stable over a wide potential range and exhibits a high ionic conductivity. The ionic liquid comprises a cyclic guanidine salt represented by the following formula (1): wherein R1 and R2 each is independently an alkyl group or an alkoxyalkyl group, X is a methylene group, an oxygen atom, a sulfur atom, or R3N; R3 is an alkyl group, an alkoxyalkyl group, or an acyl group; l, m, and n each is an integer in the range of 1-6; Y− is a monovalent anion such as (R4SO2)2N−, R4SO3−, R4COO−, BF4−, PF6−, NO3−, (CN)2N−, (CHO)2N−, NCS−, R4OSO3−, R4SO2S−, and a halogen ion. The ionic liquid is useful for a variety of electrolytes, particularly for electrolytes of electrochemical cells.
摘要翻译：公开了一种离子液体，其在宽电势范围内是稳定的并且表现出高离子导电性。离子液体包含由下式（1）表示的环状胍盐：其中R1和R2各自独立地为烷基或烷氧基烷基，X为亚甲基，氧原子，硫原子或R3N; R3是烷基，烷氧基烷基或酰基; l，m和n分别为1-6的整数; Y-是一价阴离子如（R4SO2）2N-，R4SO3-，R4COO-，BF4-，PF6-，NO3-，（CN）2N-，（CHO）2N-，NCS-，R4OSO3-，R4SO2S-，和卤素离子。离子液体可用于各种电解质，特别是用于电化学电池的电解质。

2. 发明授权

US08129543B2 Cyclic guanidine ionic liquid 有权
标题翻译：环状胍离子液体
公开(公告)号：US08129543B2
公开(公告)日：2012-03-06
申请号：US12529590
申请日：2008-02-26
申请人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
发明人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
IPC分类号： C07D403/02
CPC分类号： H01M10/0568 , C07D233/44 , C07D233/48 , C07D239/12 , C07D239/14 , C07D401/04 , C07D403/04 , C07D417/04 , H01G9/038 , H01G9/2013 , H01G9/2031 , H01G9/2059 , H01G11/58 , H01G11/62 , H01M14/005 , Y02E10/542 , Y02E60/13 , Y02P70/521
摘要： Disclosed is an ionic liquid which is stable over a wide potential range and exhibits a high ionic conductivity. The ionic liquid comprises a cyclic guanidine salt represented by the following formula (1): wherein R1 and R2 each is independently an alkyl group or an alkoxyalkyl group, X is a methylene group, an oxygen atom, a sulfur atom, or R3N; R3 is an alkyl group, an alkoxyalkyl group, or an acyl group; l, m, and n each is an integer in the range of 1-6; Y− is a monovalent anion such as (R4SO2)2N−, R4SO3−, R4COO−, BF4−, PF6−, NO3−, (CN)2N−, (CHO)2N−, NCS−, R4OSO3−, R4SO2S−, and a halogen ion. The ionic liquid is useful for a variety of electrolytes, particularly for electrolytes of electrochemical cells.
摘要翻译：公开了一种离子液体，其在宽电势范围内是稳定的并且表现出高离子导电性。离子液体包含由下式（1）表示的环状胍盐：其中R1和R2各自独立地为烷基或烷氧基烷基，X为亚甲基，氧原子，硫原子或R3N; R3是烷基，烷氧基烷基或酰基; l，m和n分别为1-6的整数; Y-是一价阴离子如（R4SO2）2N-，R4SO3-，R4COO-，BF4-，PF6-，NO3-，（CN）2N-，（CHO）2N-，NCS-，R4OSO3-，R4SO2S-，和卤素离子。离子液体可用于各种电解质，特别是用于电化学电池的电解质。

3. 发明授权

US08198387B2 Proton-conducting compound and proton-conducting polymer 有权
标题翻译：质子导电化合物和质子传导性聚合物
公开(公告)号：US08198387B2
公开(公告)日：2012-06-12
申请号：US12312031
申请日：2007-10-30
申请人： Atsushi Kawada , Aya Tashiro
发明人： Atsushi Kawada , Aya Tashiro
IPC分类号： C08F26/06 , C07D251/54
CPC分类号： C08F20/34 , C07D251/70 , C08G73/0644 , C08G73/065 , C08G73/0655 , C08G73/0661 , H01M8/103 , H01M8/1048 , H01M8/1072 , H01M2300/0082 , H01M2300/0085 , H01M2300/0091 , Y02P70/56
摘要： Provided is a proton-conducting compound which provides proton conductivity without humidification and is suitable for electrochemical device materials such as solid electrolytes for fuel cells and electrolytes for batteries. Provided also is a proton-conducting polymer. The proton-conducting compound is composed of a melamine compound salt obtained from a melamine compound represented by the following formula (1) and a Bronsted acid and the proton-conducting polymer is obtained by homopolymerizing or copolymerizing the melamine compound salt. In formula (1), R1, R2, R3, R4, and R5 each is independently an alkyl group, an aryl group, an alkenyl group, a heterocyclic group, or a hydrogen atom; at least one of them is a group other than hydrogen; R2 and R3 or R4 and R5 may join together to form a heterocyclic structure; and the alkyl group, the aryl group, the alkenyl group, or the heterocyclic group may have a substituent. A melamine compound salt wherein R1 is CH2═CR6—CO—O(CH2)n— polymerizes to yield a proton-conducting polymer. In this particular R1 group, R6 is hydrogen or an alkyl group and n is an integer equal to or larger than 1.
摘要翻译：提供了一种质子传导性化合物，其在不加湿的情况下提供质子传导性，并且适用于电化学装置材料，例如用于燃料电池的固体电解质和用于电池的电解质。还提供了一种质子传导性聚合物。质子传导性化合物由通过下式（1）表示的三聚氰胺化合物和布朗斯台德酸获得的三聚氰胺化合物盐和通过均聚或共聚三聚氰胺化合物盐得到的质子传导性聚合物组成。在式（1）中，R 1，R 2，R 3，R 4和R 5各自独立地为烷基，芳基，烯基，杂环基或氢原子; 它们中的至少一个是氢以外的基团; R2和R3或R4和R5可以连接在一起形成杂环结构; 并且烷基，芳基，烯基或杂环基可以具有取代基。其中R1为CH2 = CR6-CO-O（CH2）n-）的三聚氰胺化合物盐为聚合物以产生质子传导聚合物。在该特定的R 1基团中，R 6是氢或烷基，n是等于或大于1的整数。

4. 发明申请

US20120123115A1 CYCLIC GUANIDINE IONIC LIQUID 有权
标题翻译：循环管理离子液体
公开(公告)号：US20120123115A1
公开(公告)日：2012-05-17
申请号：US13358491
申请日：2012-01-25
申请人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
发明人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
IPC分类号： C07D401/04 , C07D413/04 , C07D417/04 , C07D403/04
CPC分类号： H01M10/0568 , C07D233/44 , C07D233/48 , C07D239/12 , C07D239/14 , C07D401/04 , C07D403/04 , C07D417/04 , H01G9/038 , H01G9/2013 , H01G9/2031 , H01G9/2059 , H01G11/58 , H01G11/62 , H01M14/005 , Y02E10/542 , Y02E60/13 , Y02P70/521
摘要： Disclosed is an ionic liquid which is stable over a wide potential range and exhibits a high ionic conductivity. The ionic liquid comprises a cyclic guanidine salt represented by the following formula (1): wherein R1 and R2 each is independently an alkyl group or an alkoxyalkyl group, X is a methylene group, an oxygen atom, a sulfur atom, or R3N; R3 is an alkyl group, an alkoxyalkyl group, or an acyl group; l, m, and n each is an integer in the range of 1-6; Y− is a monovalent anion such as (R4SO2)2N−, R4SO3−, R4COO−, BF4−, PF6−, NO3−, (CN)2N−, (CHO)2N−, NCS−, R4OSO3−, R4SO2S−, and a halogen ion. The ionic liquid is useful for a variety of electrolytes, particularly for electrolytes of electrochemical cells.
摘要翻译：公开了一种离子液体，其在宽电势范围内是稳定的并且表现出高离子导电性。离子液体包含由下式（1）表示的环状胍盐：其中R1和R2各自独立地为烷基或烷氧基烷基，X为亚甲基，氧原子，硫原子或R3N; R3是烷基，烷氧基烷基或酰基; l，m和n分别为1-6的整数; Y-是一价阴离子如（R4SO2）2N-，R4SO3-，R4COO-，BF4-，PF6-，NO3-，（CN）2N-，（CHO）2N-，NCS-，R4OSO3-，R4SO2S-，和卤素离子。离子液体可用于各种电解质，特别是用于电化学电池的电解质。

5. 发明申请

US20100121074A1 CYCLIC GUANIDINE IONIC LIQUID 有权
标题翻译：循环管理离子液体
公开(公告)号：US20100121074A1
公开(公告)日：2010-05-13
申请号：US12529590
申请日：2008-02-26
申请人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
发明人： Atsushi Kawada , Aya Tashiro , Toshihiro Kumagai
IPC分类号： C07D403/02
CPC分类号： H01M10/0568 , C07D233/44 , C07D233/48 , C07D239/12 , C07D239/14 , C07D401/04 , C07D403/04 , C07D417/04 , H01G9/038 , H01G9/2013 , H01G9/2031 , H01G9/2059 , H01G11/58 , H01G11/62 , H01M14/005 , Y02E10/542 , Y02E60/13 , Y02P70/521
摘要： Disclosed is an ionic liquid which is stable over a wide potential range and exhibits a high ionic conductivity. The ionic liquid comprises a cyclic guanidine salt represented by the following formula (1): wherein R1 and R2 each is independently an alkyl group or an alkoxyalkyl group, X is a methylene group, an oxygen atom, a sulfur atom, or R3N; R3 is an alkyl group, an alkoxyalkyl group, or an acyl group; l, m, and n each is an integer in the range of 1-6; Y− is a monovalent anion such as (R4SO2)2N−, R4SO3−, R4COO−, BF4−, PF6−, NO3−, (CN)2N−, (CHO)2N−, NCS−, R4OSO3−, R4SO2S−, and a halogen ion. The ionic liquid is useful for a variety of electrolytes, particularly for electrolytes of electrochemical cells.
摘要翻译：公开了一种离子液体，其在宽电势范围内是稳定的并且表现出高离子导电性。离子液体包含由下式（1）表示的环状胍盐：其中R1和R2各自独立地为烷基或烷氧基烷基，X为亚甲基，氧原子，硫原子或R3N; R3是烷基，烷氧基烷基或酰基; l，m和n分别为1-6的整数; Y-是一价阴离子如（R4SO2）2N-，R4SO3-，R4COO-，BF4-，PF6-，NO3-，（CN）2N-，（CHO）2N-，NCS-，R4OSO3-，R4SO2S-，和卤素离子。离子液体可用于各种电解质，特别是用于电化学电池的电解质。

6. 发明申请

US20100063249A1 PROTON-CONDUCTING COMPOUND AND PROTON-CONDUCTING POLYMER 有权
标题翻译：导电化合物和导电聚合物
公开(公告)号：US20100063249A1
公开(公告)日：2010-03-11
申请号：US12312031
申请日：2007-10-30
申请人： Atsushi Kawada , Aya Tashiro
发明人： Atsushi Kawada , Aya Tashiro
IPC分类号： C08G73/00 , C07D403/04 , C07D251/54 , C07D413/04 , C08G67/00
CPC分类号： C08F20/34 , C07D251/70 , C08G73/0644 , C08G73/065 , C08G73/0655 , C08G73/0661 , H01M8/103 , H01M8/1048 , H01M8/1072 , H01M2300/0082 , H01M2300/0085 , H01M2300/0091 , Y02P70/56
摘要： Provided is a proton-conducting compound which provides proton conductivity without humidification and is suitable for electrochemical device materials such as solid electrolytes for fuel cells and electrolytes for batteries. Provided also is a proton-conducting polymer. The proton-conducting compound is composed of a melamine compound salt obtained from a melamine compound represented by the following formula (1) and a Bronsted acid and the proton-conducting polymer is obtained by homopolymerizing or copolymerizing the melamine compound salt. In formula (1), R1, R2, R3, R4, and R5 each is independently an alkyl group, an aryl group, an alkenyl group, a heterocyclic group, or a hydrogen atom; at least one of them is a group other than hydrogen; R2 and R3 or R4 and R5 may join together to form a heterocyclic structure; and the alkyl group, the aryl group, the alkenyl group, or the heterocyclic group may have a substituent. A melamine compound salt wherein R1 is CH2═CR6—CO—O(CH2)n— polymerizes to yield a proton-conducting polymer. In this particular R1 group, R6 is hydrogen or an alkyl group and n is an integer equal to or larger than 1.
摘要翻译：提供了一种质子传导性化合物，其在不加湿的情况下提供质子传导性，并且适用于电化学装置材料，例如用于燃料电池的固体电解质和用于电池的电解质。还提供了一种质子传导性聚合物。质子传导性化合物由通过下式（1）表示的三聚氰胺化合物和布朗斯台德酸获得的三聚氰胺化合物盐和通过均聚或共聚三聚氰胺化合物盐得到的质子传导性聚合物组成。在式（1）中，R 1，R 2，R 3，R 4和R 5各自独立地为烷基，芳基，烯基，杂环基或氢原子; 它们中的至少一个是氢以外的基团; R2和R3或R4和R5可以连接在一起形成杂环结构; 并且烷基，芳基，烯基或杂环基可以具有取代基。其中R1为CH2 = CR6-CO-O（CH2）n-）的三聚氰胺化合物盐为聚合物以产生质子传导聚合物。在该特定的R 1基团中，R 6是氢或烷基，n是等于或大于1的整数。

7. 发明申请

US20130150576A1 NITROGEN-CONTAINING AROMATIC COMPOUND, ORGANIC SEMICONDUCTOR MATERIAL, AND ORGANIC ELECTRONIC DEVICE 有权
标题翻译：含氮的芳族化合物，有机半导体材料和有机电子器件
公开(公告)号：US20130150576A1
公开(公告)日：2013-06-13
申请号：US13818685
申请日：2011-07-07
申请人： Masanori Hotta , Yuichi Sawada , Atsushi Kawada , Masana Jikumaru , Megumi Matsumoto
发明人： Masanori Hotta , Yuichi Sawada , Atsushi Kawada , Masana Jikumaru , Megumi Matsumoto
IPC分类号： H01L51/00
CPC分类号： H01L51/0071 , C07D487/04 , C07D491/048 , C07D495/04 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1059 , C09K2211/1088 , C09K2211/1092 , C09K2211/1096 , H01L51/0072 , H01L51/0087 , H01L51/0512 , H01L51/0558 , H01L51/5016 , Y02E10/549
摘要： Provided are a nitrogen-containing aromatic heterocyclic compound useful as an organic semiconductor material and an organic electronic device using this compound. The nitrogen-containing aromatic heterocyclic compound has a fused indole skeleton represented by the following formula (1), the organic semiconductor material contains the said compound, and the organic electronic device uses the said organic semiconductor material. In general formula (1), X is N-A′, O, S, or Se; A is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group exclusive of a fused heterocycle consisting of 4 rings or more; and R is a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group exclusive of a fused heterocycle consisting of 4 rings or more.
摘要翻译：提供可用作有机半导体材料的含氮芳族杂环化合物和使用该化合物的有机电子器件。含氮芳族杂环化合物具有由下式（1）表示的稠合吲哚骨架，有机半导体材料包含所述化合物，有机电子器件使用所述有机半导体材料。通式（1）中，X为N-A'，O，S或Se; A是不大于4个环以上的稠合杂环的烷基，环烷基，烯基，炔基，芳香族烃基或芳香族杂环基; R是氢原子，烷基，环烷基，链烯基，炔基，芳香族烃基或不包括4环以上的稠合杂环的芳香族杂环基。

8. 发明授权

US08766248B2 Nitrogen-containing aromatic compound, organic semiconductor material, and organic electronic device 有权
标题翻译：含氮芳香族化合物，有机半导体材料和有机电子器件
公开(公告)号：US08766248B2
公开(公告)日：2014-07-01
申请号：US13818685
申请日：2011-07-07
申请人： Masanori Hotta , Yuichi Sawada , Atsushi Kawada , Masana Jikumaru , Megumi Matsumoto
发明人： Masanori Hotta , Yuichi Sawada , Atsushi Kawada , Masana Jikumaru , Megumi Matsumoto
IPC分类号： C07D487/02 , C07D491/048 , C07D495/04
CPC分类号： H01L51/0071 , C07D487/04 , C07D491/048 , C07D495/04 , C09K11/06 , C09K2211/1007 , C09K2211/1029 , C09K2211/1059 , C09K2211/1088 , C09K2211/1092 , C09K2211/1096 , H01L51/0072 , H01L51/0087 , H01L51/0512 , H01L51/0558 , H01L51/5016 , Y02E10/549
摘要： Provided are a nitrogen-containing aromatic heterocyclic compound useful as an organic semiconductor material and an organic electronic device using this compound. The nitrogen-containing aromatic heterocyclic compound has a fused indole skeleton represented by the following formula (1), the organic semiconductor material contains the compound, and the organic electronic device uses the organic semiconductor material. In general formula (1), X is N-A′, O, S, or Se; A is an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group exclusive of a fused heterocycle consisting of 4 rings or more; and R is a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aromatic hydrocarbon group, or an aromatic heterocyclic group exclusive of a fused heterocycle consisting of 4 rings or more.
摘要翻译：提供可用作有机半导体材料的含氮芳族杂环化合物和使用该化合物的有机电子器件。含氮芳族杂环化合物具有由下式（1）表示的稠合吲哚骨架，有机半导体材料含有化合物，有机电子器件使用有机半导体材料。通式（1）中，X为N-A'，O，S或Se; A是不大于4个环以上的稠合杂环的烷基，环烷基，烯基，炔基，芳香族烃基或芳香族杂环基; R是氢原子，烷基，环烷基，链烯基，炔基，芳香族烃基或不包括4环以上的稠合杂环的芳香族杂环基。

9. 发明申请

US20120241732A1 ORGANIC LIGHT-EMITTING MATERIAL AND ORGANIC LIGHT-EMITTING ELEMENT 有权
标题翻译：有机发光材料和有机发光元件
公开(公告)号：US20120241732A1
公开(公告)日：2012-09-27
申请号：US13514248
申请日：2010-12-02
申请人： Ayataka Endo , Chihaya Adachi , Kazuaki Yoshimura , Atsushi Kawada , Hiroshi Miyazaki , Takahiro Kai
发明人： Ayataka Endo , Chihaya Adachi , Kazuaki Yoshimura , Atsushi Kawada , Hiroshi Miyazaki , Takahiro Kai
IPC分类号： H01L51/54
CPC分类号： C09K11/06 , C07D209/86 , C07D487/04 , C09B57/00 , C09K2211/1007 , C09K2211/1011 , C09K2211/1018 , C09K2211/1029 , C09K2211/1044 , C09K2211/1059 , H01L51/0072 , H01L51/5012 , H05B33/10 , Y10S428/917
摘要： Fluorescence-emitting material which improves luminous efficiency of an organic light-emitting element such as an organic EL element or an organic PL element and an organic light-emitting element using the fluorescence-emitting material. The fluorescence-emitting material includes a compound having an indolocarbazole skeleton represented by the following general formula (1), as defined in the specification. The organic light-emitting element includes an organic EL element including: a substrate; an anode; a cathode; and a light-emitting layer, the anode and the cathode being laminated on the substrate and the light-emitting layer being sandwiched between the anode and the cathode, in which the light-emitting layer includes: the organic light-emitting material; and as a host material, an organic compound having excited triplet energy higher than that of the organic light-emitting material.
摘要翻译：使用荧光发射材料提高诸如有机EL元件或有机PL元件的有机发光元件和有机发光元件的发光效率的荧光发射材料。荧光发射材料包括具有如说明书中定义的由以下通式（1）表示的吲哚咔唑骨架的化合物。有机发光元件包括：有机EL元件，包括：基板; 阳极; 阴极和发光层，阳极和阴极层压在基板上，发光层夹在阳极和阴极之间，其中发光层包括：有机发光材料; 作为主体材料，具有比有机发光材料高的激发三重态能量的有机化合物。

10. 发明授权

US08993129B2 Fluorescence and delayed fluorescence-type organic light-emitting material and element 有权
标题翻译：荧光和延迟荧光型有机发光材料和元素
公开(公告)号：US08993129B2
公开(公告)日：2015-03-31
申请号：US13514248
申请日：2010-12-02
申请人： Ayataka Endo , Chihaya Adachi , Kazuaki Yoshimura , Atsushi Kawada , Hiroshi Miyazaki , Takahiro Kai
发明人： Ayataka Endo , Chihaya Adachi , Kazuaki Yoshimura , Atsushi Kawada , Hiroshi Miyazaki , Takahiro Kai
IPC分类号： H01L51/54 , C09K11/06 , H05B33/10 , C09B57/00 , H01L51/00 , H01L51/50
CPC分类号： C09K11/06 , C07D209/86 , C07D487/04 , C09B57/00 , C09K2211/1007 , C09K2211/1011 , C09K2211/1018 , C09K2211/1029 , C09K2211/1044 , C09K2211/1059 , H01L51/0072 , H01L51/5012 , H05B33/10 , Y10S428/917
摘要： Fluorescence-emitting material which improves luminous efficiency of an organic light-emitting element such as an organic EL element or an organic PL element and an organic light-emitting element using the fluorescence-emitting material. The fluorescence-emitting material includes a compound having an indolocarbazole skeleton represented by the following general formula (1), as defined in the specification. The organic light-emitting element includes an organic EL element including: a substrate; an anode; a cathode; and a light-emitting layer, the anode and the cathode being laminated on the substrate and the light-emitting layer being sandwiched between the anode and the cathode, in which the light-emitting layer includes: the organic light-emitting material; and as a host material, an organic compound having excited triplet energy higher than that of the organic light-emitting material.
摘要翻译：使用荧光发射材料提高诸如有机EL元件或有机PL元件的有机发光元件和有机发光元件的发光效率的荧光发射材料。荧光发射材料包括具有如说明书中定义的由以下通式（1）表示的吲哚咔唑骨架的化合物。有机发光元件包括：有机EL元件，包括：基板; 阳极; 阴极和发光层，阳极和阴极层压在基板上，发光层夹在阳极和阴极之间，其中发光层包括：有机发光材料; 作为主体材料，具有比有机发光材料高的激发三重态能量的有机化合物。

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