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1. 发明授权

US6153089A Upgradation of undesirable olefinic liquid hydrocarbon streams 有权
标题翻译：不期望的烯烃液态烃流的升级
公开(公告)号：US6153089A
公开(公告)日：2000-11-28
申请号：US282174
申请日：1999-03-31
申请人： Asit Kumar Das , Sukumar Mandal , Sobhan Ghosh , Debasis Bhattacharyya , Ganga Shanker Mishra , Jagdev Kumar Dixit , Arvind Pratap Singh , Ashok Kumar Tewari , Satish Makhija , Manoranjan Santra , Latoor Lal Saroya , Shankar Sharma , Satyen Kumar Das
发明人： Asit Kumar Das , Sukumar Mandal , Sobhan Ghosh , Debasis Bhattacharyya , Ganga Shanker Mishra , Jagdev Kumar Dixit , Arvind Pratap Singh , Ashok Kumar Tewari , Satish Makhija , Manoranjan Santra , Latoor Lal Saroya , Shankar Sharma , Satyen Kumar Das
IPC分类号： C10G11/05 , C10G11/18 , C10G35/095
CPC分类号： C10G35/095 , C10G11/05 , C10G11/18 , Y02P30/446
摘要： A process for converting undesirable olefinic hydrocarbon streams to hydrogen and petrochemical feedstock e.g. light olefins in C.sub.2 -C.sub.4 range and aromatics especially toluene and xylenes, which comprises simultaneous cracking and reforming at olefin rich hydrocarbons using a catalyst consisting of dehydrogenating metal components, shape selective zeolite components and large pore acidic components in different proportions in a circulating fluidized bed reactor-regenerator system having reactor temperature within 450-750.degree. C. and WHSV of 0.1-60 hour.sup.-1.
摘要翻译：将不期望的烯烃流转化为氢和石化原料的方法，例如在C2-C4范围内的轻质烯烃和芳族化合物，特别是甲苯和二甲苯，其包括在富含烯烃的烃中同时裂化和重整，所述催化剂在循环流化床中使用由脱氢金属组分，形状选择性沸石组分和不同比例的大孔酸性组分组成的催化剂反应器 - 再生器系统，反应器温度在450-750℃，WHSV为0.1-60小时-1。

2. 发明授权

US5846402A Process for catalytic cracking of petroleum based feed stocks 失效
标题翻译：石油基原料催化裂化工艺
公开(公告)号：US5846402A
公开(公告)日：1998-12-08
申请号：US855946
申请日：1997-05-14
申请人： Sukumar Mandal , Suresh Kumarshah , Debasis Bhattacharyya , Vutukuru Lakshmi Narasimha Murthy , Asit Kumar Das , Sanjeev Singh , Ram Mohan Thakur , Shankar Sharma , Jagdev Kumar Dixit , Sobhan Ghosh , Satyen Kumar Das , Manoranjan Santra , Latoor Lal Saroya , Marri Rama Rao , Ganga Shanker Mishra , Satish Makhija
发明人： Sukumar Mandal , Suresh Kumarshah , Debasis Bhattacharyya , Vutukuru Lakshmi Narasimha Murthy , Asit Kumar Das , Sanjeev Singh , Ram Mohan Thakur , Shankar Sharma , Jagdev Kumar Dixit , Sobhan Ghosh , Satyen Kumar Das , Manoranjan Santra , Latoor Lal Saroya , Marri Rama Rao , Ganga Shanker Mishra , Satish Makhija
IPC分类号： B01J29/80 , C10G11/05 , C10G11/18 , C10G11/00
CPC分类号： B01J29/80 , C10G2400/20 , C10G2400/28
摘要： A process for selective catalytic cracking of a petroleum-based feedstock to produce a product having a high yield of liquified petroleum gas (LPG) and light olefins having 3 to 4 carbons includes providing a fluidized bed reactor which is a high velocity riser, continuously circulating fluidized bed reactor; providing a solid acidic catalyst comprised of: from 1 to 6% by wt. of ultra stable Y-zeolite; from 8-25% by wt. of Pentasil zeolite which is shape selective; from 0-8% by wt. of an active material which is bottom selective; from 0-1% by wt. of rare earth constituents; and from 91 to 60% by wt. of nonacidic constituents and binder; charging the fluidized bed reactor with the solid acidic catalyst and the petroleum-based feedstock; and cracking the petroleum-based feedstock in the presence of the solid acidic catalyst in the fluidized bed reactor. The reactor is operated at a Weight Hourly Space Velocity (WHSV) ranging from 40 to 120 hr.sup.-1, a ratio of solid acidic catalyst to petroleum-based feedstock ranging from 15 to 25, a temperature at the top of the high velocity riser ranging from 530.degree. C. to 600.degree. C., recycled riser products ranging from 0 to 40%, a pressure in the fluidized bed reactor ranging from 1.0 to 4.0 kg/cm.sup.2 g, and an amount of steam for dilution and quenching of hydrocarbons ranging from 3 to 50 wt. % of the petroleum-based feedstock. The Pentasil zeolite has a pore size ranging from 5 to 6 .ANG. so that the catalyst is highly selective for LPG and C.sub.4 light olefins with minimum dry gas and coke make, and so that the vanadium tolerance of the catalyst is increased and ranges up to 21,000 PPM. The process produces a LPG yield ranging up to 40 to 65 wt. % of the fresh petroleum-based feedstock, a selectivity for the light olefins of at least 40 wt. %, and a selectivity for the LPG of at least 45 wt.
摘要翻译：选择性催化裂化石油基原料以生产具有高产率的液化石油气（LPG）和具有3至4个碳原子的轻质烯烃的产物的方法包括提供流化床反应器，其为高速提升管，连续循环流化床反应器; 提供固体酸性催化剂，其包含：1至6重量％的超稳定Y型沸石; 8-25重量％。具有形状选择性的pentasil沸石; 0-8重量％的底部选择性活性物质; 0-1重量％的稀土成分; 和91〜60重量％。的非酸成分和粘合剂; 用固体酸性催化剂和石油基原料装入流化床反应器; 并在流化床反应器中在固体酸性催化剂存在下裂化石油基原料。反应器以40至120小时-1的重量小时空间速度（WHSV）运行，固体酸性催化剂与石油基原料的比例为15至25，高速提升管顶部的温度范围从530℃至600℃，循环的提升产品的范围为0至40％，流化床反应器的压力范围为1.0至4.0kg / cm2g，以及用于稀释和猝灭烃的蒸汽量 3〜50重量％％的石油基原料。 Pentasil沸石的孔径范围为5至6安格姆，使得催化剂对于具有最少干燥气体和焦炭的LPG和C4轻质烯烃具有高选择性，并且使得催化剂的耐钒性增加并且范围高达21,000 PPM。该方法产生高达40至65重量％的LPG产率。％的新鲜石油基原料，轻质烯烃的选择性至少为40wt。％，并且LPG的选择性至少为45wt。

3. 发明授权

US07029571B1 Multi stage selective catalytic cracking process and a system for producing high yield of middle distillate products from heavy hydrocarbon feedstocks 有权
标题翻译：多阶段选择性催化裂解工艺和从重质烃原料生产高产率的中间馏分产物的系统
公开(公告)号：US07029571B1
公开(公告)日：2006-04-18
申请号：US09937850
申请日：2000-02-16
申请人： Debasis Bhattacharyya , Asit Kumar Das , Arumugam Velayutham Karthikeyani , Satyen Kumar Das , Pankaj Kasliwal , Manoranjan Santra , Latoor Lal Saroya , Jagdev Kumar Dixit , Ganga Sanker Mishra , Jai Prakash Singh , Satish Makhija , Sobhan Ghosh
发明人： Debasis Bhattacharyya , Asit Kumar Das , Arumugam Velayutham Karthikeyani , Satyen Kumar Das , Pankaj Kasliwal , Manoranjan Santra , Latoor Lal Saroya , Jagdev Kumar Dixit , Ganga Sanker Mishra , Jai Prakash Singh , Satish Makhija , Sobhan Ghosh
IPC分类号： C10G51/02 , B01J8/08
CPC分类号： C10G11/18 , C10G51/026
摘要： According to this invention, there is provided a process and apparatus for catalytic cracking of various petroleum based heavy feed stocks in the presence of solid zeolite catalyst and high pore size acidic components for selective bottom cracking and mixtures thereof, in multiple riser type continuously circulating fluidized bed reactors operated at different severities to produce high yield of middle distillates, in the range of 50–65 wt % of fresh feed.
摘要翻译：根据本发明，提供了一种用于在固体沸石催化剂和用于选择性底部裂解的高孔径酸性组分及其混合物存在下各种石油基重原料的催化裂化的方法和装置，在多个立管型连续循环流化床床反应器运行在不同的严重程度以产生高产率的中间馏分，在新鲜进料的50-65重量％的范围内。

4. 发明授权

US07462275B2 Process for conversion of hydrocarbons to saturated LPG and high octane gasoline 有权
标题翻译：将碳氢化合物转化为饱和LPG和高辛烷值汽油的方法
公开(公告)号：US07462275B2
公开(公告)日：2008-12-09
申请号：US10894341
申请日：2004-07-20
申请人： Asit Kumar Das , Debasis Bhattacharyya , Gadari Saidulu , Satayen Kumar Das , Bandaru Venkata Hari P. Gupta , Ramakrishnan Ramanarayanan , Latoor Lal Saroya , Konduri Lakshminarayana , Marri Rama Rao , Vinod Ramchandra Upadhyay , Sukumar Mandal , Deepa Meghavathu , Arumugam Velayutham Karthikeyani , Wadharwa Ram Kalsi , Arvind Pratap Singh , Veena Bansal , Ashok Kumar Tiwari , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raghunath Raje
发明人： Asit Kumar Das , Debasis Bhattacharyya , Gadari Saidulu , Satayen Kumar Das , Bandaru Venkata Hari P. Gupta , Ramakrishnan Ramanarayanan , Latoor Lal Saroya , Konduri Lakshminarayana , Marri Rama Rao , Vinod Ramchandra Upadhyay , Sukumar Mandal , Deepa Meghavathu , Arumugam Velayutham Karthikeyani , Wadharwa Ram Kalsi , Arvind Pratap Singh , Veena Bansal , Ashok Kumar Tiwari , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raghunath Raje
IPC分类号： C10G67/00
CPC分类号： C10G11/05 , C10G2400/28
摘要： The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2 (g) and weight hourly space velocity in range of 0.1 to 20 hour−1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.
摘要翻译：本发明涉及一种将95％真实沸点低于400℃的烃流转化成非常高产率的进料和高辛烷值汽油的45-65重量％的液化石油气的方法，所述方法包括使用固体可流化催化剂催化裂化烃，所述固体可流化催化剂包含具有或不具有Y-沸石的中孔结晶铝硅酸盐，非结晶酸性物质或其组合，其在400至550℃的温度范围内操作的流化密床反应器 ℃，压力范围为2至20kg / cm2（g）和0.1至20小时-1范围内的重时空速，其中所述致密床反应器与用于连续的催化剂汽提塔和再生器流动连通在存在空气和/或含氧气体的情况下再生焦化的催化剂，催化剂在反应器 - 再生器系统之间连续循环。

5. 发明授权

US07604731B2 Process for the production of needle coke 有权
标题翻译：生产针状焦的工艺
公开(公告)号：US07604731B2
公开(公告)日：2009-10-20
申请号：US10892024
申请日：2004-07-15
申请人： Debasis Bhattacharyya , Satheesh Vetterkunnel Kumaran , Bandaru Venkata Hari Prasad Gupta , Pramod Kumar , Asit Kumar Das , Gadari Saidulu , Satyen Kumar Das , Gurpreet Singh Kapur , Veena Bansal , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raghunath Raje
发明人： Debasis Bhattacharyya , Satheesh Vetterkunnel Kumaran , Bandaru Venkata Hari Prasad Gupta , Pramod Kumar , Asit Kumar Das , Gadari Saidulu , Satyen Kumar Das , Gurpreet Singh Kapur , Veena Bansal , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raghunath Raje
IPC分类号： C10G51/02 , C10G9/00
CPC分类号： C10G9/005 , C10B55/00 , C10G51/023
摘要： A process is disclosed for producing needle coke from heavy atmospheric distillation residues having sulfur no more than 0.7 wt %, which process involves the steps of heating the feedstock to a temperature in the range of 440 to 520° C. for thermal cracking in a soaking column under pressure in the range of 1 to 10 kg/cm2 to separate the easily cokable material, separating the cracked products in a quench column and a distillation column and then subjecting the hydrocarbon fraction from the bottom of the quench column and a hydrocarbon fraction having a boiling point in the range of 380 to 480° C. from the distillation column and/or any other suitable heavier hydrocarbon streams in a definite ratio depending on certain characteristic parameters to thermal cracking in a second soaking column at a temperature of 460 to 540° C., pressure in the range of 2 to 20 kg/cm2 in presence of added quantity of steam for formation of a mesophase carbonaceous structure which on steam stripping and cooling forms a solid crystalline coke suitable for manufacturing of graphite electrode of large diameter having co-efficient of thermal expansion lower than 1.1×10−6/° C. measured on graphite artifact in the temperature range of 25 to 525° C.
摘要翻译：公开了一种用于从具有不超过0.7重量％的硫的重大气压蒸馏残余物生产针状焦炭的方法，该方法包括将原料加热至440-520℃范围内的温度以进行浸泡中的热裂解柱在1至10kg / cm2的压力范围内以分离容易结合的材料，将裂化产物在骤冷塔和蒸馏塔中分离，然后对来自骤冷塔的底部的烃馏分和具有取决于某些特征参数与第二个均热塔中的热裂解在460至540℃的温度下，从蒸馏塔和/或任何其它合适的较重烃流中的沸点在380至480℃范围内在蒸汽的形成中间相含碳结构的添加量存在下，在2至20kg / cm2的范围内的压力，在汽提和冷却形成适用于制造热膨胀系数小于1.1×10 -6 /℃的大直径石墨电极的固体结晶焦炭，在25至525℃的温度范围内测量石墨伪影。

6. 发明授权

US6149875A Fluidized catalytic cracking process and apparatus 有权
标题翻译：流化催化裂化工艺及装置
公开(公告)号：US6149875A
公开(公告)日：2000-11-21
申请号：US219459
申请日：1998-12-23
申请人： Marri Rama Rao , Vutukuru Lakshmi Narasimha Murthy , Sanjeev Singh , Asit Kumar Das , Sobhan Ghosh , Debasis Bhattacharyya , Satish Makhija , Sukumar Mandal
发明人： Marri Rama Rao , Vutukuru Lakshmi Narasimha Murthy , Sanjeev Singh , Asit Kumar Das , Sobhan Ghosh , Debasis Bhattacharyya , Satish Makhija , Sukumar Mandal
IPC分类号： C10G11/05 , C10G11/18 , B01J8/26
CPC分类号： C10G11/18 , C10G11/05
摘要： A fluidized catalytic cracking apparatus includes a riser containing a regenerated catalyst and adsorbant, and has a first inlet for introduction of high velocity steam, a second inlet for introduction of a feed stream containing heavy residual fractions with high concentrations of conradson coke, metals including vanadium and nickel, and additional poisons including nitrogen, a third inlet for introduction of an adsorbent, and a fourth inlet disposed above the third inlet means for introduction of a regenerated catalyst, the adsorbent having a particle size which is larger than that of the regenerated catalyst. A stripper is provided into which the riser extends for causing separation of a hydrocarbon fraction from spent catalyst and adsorbent, and a separator is connected to the stripper and has a base, an inlet at the base for introduction of steam in the upward direction so as to provide a transport velocity in the upward direction for the spent catalyst and cause a separation of the particles of the spent catalyst from the adsorbent in use. A regenerator is connected to the separator and has an outlet and is in flow communication with the fourth inlet for introduction of the regenerated catalyst into the riser. A burner is provided for receiving the adsorbent from the separator and for causing a regeneration thereof, the burner having an inlet for introduction of oxygen containing gas and an outlet in flow communication with the third inlet for introduction of the adsorbent into the riser. A lift line is connected between the separator and the regenerator for allowing a flow of the spent catalyst from the separator into the regenerator while leaving the adsorbent within the separator in a fluidized condition the lift line having a plurality of steam inlets disposed at different elevations along its length for introduction of steam to provide said transport velocity.
摘要翻译：流化催化裂化装置包括含有再生催化剂和吸附剂的提升管，并且具有用于引入高速蒸汽的第一入口，用于引入含有高浓度康拉多焦炭的重残余馏分的进料流的第二入口，包括钒的金属和镍，以及包括氮的附加毒物，用于引入吸附剂的第三入口，以及设置在第三入口装置上方以引入再生催化剂的第四入口，所述吸附剂的粒度大于再生催化剂的粒径。提供了一种汽提器，其中提升管延伸用于使烃馏分与废催化剂和吸附剂分离，并且分离器连接到汽提器并具有基座，底部是用于沿向上方向引入蒸汽的入口，以便为废催化剂向上提供输送速度，并在使用中引起废催化剂颗粒与吸附剂的分离。再生器连接到分离器并且具有出口并且与第四入口流动连通以将再生催化剂引入提升管。提供燃烧器用于从分离器接收吸附剂并引起其再生，燃烧器具有用于引入含氧气体的入口和与第三入口流动连通的出口，用于将吸附剂引入提升管中。升降线连接在分离器和再生器之间，用于允许废催化剂从分离器流入再生器，同时在分离器内留下吸附剂处于流化状态，提升管线具有沿着不同高度设置的多个蒸汽入口其引入蒸汽的长度以提供所述输送速度。

7. 发明授权

US6114267A Process for the preparation of fluidized catalytic cracking (FCC) catalyst 失效
标题翻译：流化催化裂化（FCC）催化剂的制备方法
公开(公告)号：US6114267A
公开(公告)日：2000-09-05
申请号：US80201
申请日：1998-05-18
申请人： Sobhan Ghosh , Satish Makhija , Mohan Prabhu Kuvettu , Ventachalam Krishnan , Sanjay Kumar Ray , Manoranjan Santra , Ram Mohan Thakur , Jagdev Kumar Dixit
发明人： Sobhan Ghosh , Satish Makhija , Mohan Prabhu Kuvettu , Ventachalam Krishnan , Sanjay Kumar Ray , Manoranjan Santra , Ram Mohan Thakur , Jagdev Kumar Dixit
IPC分类号： B01J29/08 , C10G11/05 , B01J29/06
CPC分类号： C10G11/05 , B01J29/084
摘要： A process for preparation of fluidized catalytic cracking (FCC) catalyst, comprising silicon stabilized large crystallite sized synthetic faujasite zeolite, aluminum depleted and normal kaolin clay, alumina and silica. The cracking catalyst is highly active and selective for bottom upgradation, it produces less coke and higher gasoline and total cycle oil (TCO) and possesses improved metal tolerance properties when evaluated and compared with a commercial catalyst under conditions of a typical FCC unit in a petroleum refinery.
摘要翻译：一种制备流化催化裂化（FCC）催化剂的方法，包括硅稳定的大晶粒大小的合成八面沸石沸石，贫铝和正常的高岭土，氧化铝和二氧化硅。裂解催化剂对于底部升级具有高度活性和选择性，它在较低的焦炭和更高的汽油和全周期循环油（TCO）时产生较少的金属耐受性，并且在石油中典型的FCC装置条件下与商业催化剂进行比较炼油厂

8. 发明授权

US06540904B1 Process for the upgradation of petroleum residue 有权
标题翻译：石油残渣升级过程
公开(公告)号：US06540904B1
公开(公告)日：2003-04-01
申请号：US09518413
申请日：2000-03-03
申请人： Suhas Ranjan Gun , Priya Bandhu Chowdhury , Kashi Nath Bhattacharya , Achinta Kumar Roy , Umanand Sharma , Swapan Kumar Ghosh , Awadhesh Kumar Sinha , Santosh Kumar Chanda , Sukumar Mandal , Sanjay Kumar Ray , Asit Kumar Das , Satish Makhija , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
发明人： Suhas Ranjan Gun , Priya Bandhu Chowdhury , Kashi Nath Bhattacharya , Achinta Kumar Roy , Umanand Sharma , Swapan Kumar Ghosh , Awadhesh Kumar Sinha , Santosh Kumar Chanda , Sukumar Mandal , Sanjay Kumar Ray , Asit Kumar Das , Satish Makhija , Sobhan Ghosh , Akhilesh Kumar Bhatnagar
IPC分类号： C10G1102
CPC分类号： C10G11/02 , C10G2300/107
摘要： The present invention provides a process for the upgradation of petroleum residue into useful fractions by subjecting petroleum residue in the presence of a solvent and ferrous sulphate catalyst to a pressure in the range of 10 atm. to 120 atm., temperature in the range of 380-420° C., for a period in the range of 0-120 minutes, in a reactor vessel, in an inert atmosphere. The charge is then cooled to room temperature and the product gas released through scrubbers. The residue is re-heated, if required, for free flow of liquid product. The resulting liquid product is distilled to obtain useful fractions.
摘要翻译：本发明提供了一种通过在溶剂和硫酸亚铁催化剂存在下将石油残余物在10atm范围内的压力下将石油残渣升级为有用级分的方法。温度在380-420℃的范围内，在0-120分钟的时间内，在反应器容器中，在惰性气氛中。然后将电荷冷却至室温，并通过洗涤器释放产物气体。如果需要，残余物被重新加热，用于液体产品的自由流动。将所得液体产物蒸馏以获得有用的级分。

9. 发明申请

US20060016725A1 Process for conversion of hydrocarbons to saturated LPG and high octane gasoline 有权
标题翻译：将碳氢化合物转化为饱和LPG和高辛烷值汽油的方法
公开(公告)号：US20060016725A1
公开(公告)日：2006-01-26
申请号：US10894341
申请日：2004-07-20
申请人： Asit Das , Debasis Bhattacharyya , Gadari Saidulu , Satayen Das , Bandaru Gupta , Ramakrishnan Ramanarayanan , Latoor Saroya , Konduri Lakshminarayana , Marri Rao , Vinod Upadhyay , Sukumar Mandal , Deepa Meghavathu , Arumugam Karthikeyani , Wadharwa Kalsi , Arvind Singh , Veena Bansal , Ashok Tiwari , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raje
发明人： Asit Das , Debasis Bhattacharyya , Gadari Saidulu , Satayen Das , Bandaru Gupta , Ramakrishnan Ramanarayanan , Latoor Saroya , Konduri Lakshminarayana , Marri Rao , Vinod Upadhyay , Sukumar Mandal , Deepa Meghavathu , Arumugam Karthikeyani , Wadharwa Kalsi , Arvind Singh , Veena Bansal , Ashok Tiwari , Venkatachalam Krishnan , Satish Makhija , Sobhan Ghosh , Niranjan Raje
IPC分类号： C10G67/00
CPC分类号： C10G11/05 , C10G2400/28
摘要： The present invention relates to a process for the conversion of hydrocarbon streams with 95% true boiling point less than 400° C. to very high yield of liquefied petroleum gas in the range of 45-65 wt % of feed and high octane gasoline, the said process comprises catalytic cracking of the hydrocarbons using a solid fluidizable catalyst comprising a medium pore crystalline alumino-silicates with or without Y-zeolite, non crystalline acidic materials or combinations thereof in a fluidized dense bed reactor operating at a temperature range of 400 to 550° C., pressure range of 2 to 20 kg/cm2(g) and weight hourly space velocity in range of 0.1 to 20 hour−1, wherein the said dense bed reactor is in flow communication to a catalyst stripper and a regenerator for continuous regeneration of the coked catalyst in presence of air and or oxygen containing gases, the catalyst being continuously circulated between the reactor-regenerator system.
摘要翻译：本发明涉及一种将95％真实沸点低于400℃的烃流转化成非常高产率的进料和高辛烷值汽油的45-65重量％的液化石油气的方法，所述方法包括使用固体可流化催化剂催化裂化烃，所述固体可流化催化剂包含具有或不具有Y-沸石的中孔结晶铝硅酸盐，非结晶酸性物质或其组合，其在400至550℃的温度范围内操作的流化密床反应器 ℃，压力范围为2至20kg / cm 2（g），重时空速为0.1至20小时的范围，其中所述致密的床反应器与催化剂汽提器和再生器流动连通，用于在存在空气和/或含氧气体的情况下连续再生焦化催化剂，催化剂在反应器 - 再生器系统之间连续循环。

10. 发明授权

US06284218B1 Process for preparing an hydrothermally stable, large crystallite sized, highly crystallite sized, highly crystalline synthetic faujasite zeolite 有权
标题翻译：制备水热稳定，大晶粒尺寸，高度微晶尺寸，高度结晶的合成八面沸石沸石的方法
公开(公告)号：US06284218B1
公开(公告)日：2001-09-04
申请号：US09158817
申请日：1998-09-23
申请人： Mohan Prabhu Kuvettu , Manoranjan Santra , Venkatachalam Krishnan , Sanjay Kumar Ray , Christopher J , Ganga Shanker Mishra , Ram Mohan Thakur , Satish Makhija , Soban Ghosh
发明人： Mohan Prabhu Kuvettu , Manoranjan Santra , Venkatachalam Krishnan , Sanjay Kumar Ray , Christopher J , Ganga Shanker Mishra , Ram Mohan Thakur , Satish Makhija , Soban Ghosh
IPC分类号： C01B3920
CPC分类号： C01B39/20 , Y10S423/21
摘要： A synthetic faujasite zeolite and a process for preparing the same which includes forming a reaction mixture consisting essentially of water, a source of silica, a source of alumina, Na2O nd nucleation centers, wherein the reaction mixture has molar ratios of constituents including Na2O/SiO2, 0.4-0.9; SiO2/Al2O3, 7-13; and H2O/Na2O, 30-45, and wherein the nucleation centers have molar ratios of constituents including Na2O/SiO2, 0.5-2.0; SiO2/Al203, 10-20; and H2O/Na2O, 10-40; and heating the reaction mixture to a temperature ranging from 90 to 110° C. for a time period ranging from 23 to 29 hours to obtain the synthetic faujasite zeolite, wherein the synthetic faujasite zeolite has a crystallite size ranging from 1500 to 2000 Å, a particle size ranging from 4000 to 8000 Å, and a retention of surface of more than 70% of that of a parent zeolite, when exchanged with ammonia and subjected to hydrothermal treatment at 650° C. for 3 hours and with 100% steam.
摘要翻译：合成八面沸石及其制备方法，其包括形成基本上由水，二氧化硅源，氧化铝源，Na 2 O和成核中心组成的反应混合物，其中反应混合物具有包括Na 2 O / SiO 2 ，0.4-0.9; SiO2 / Al2O3,7-13; 和H 2 O / Na 2 O，30-45，并且其中成核中心具有包括Na 2 O / SiO 2，0.5-2.0的组成的摩尔比; SiO2 / Al2O3,10-20; 和H2O / Na2O，10-40; 并将反应混合物加热到90〜110℃的温度，时间为23〜29小时，得到合成八面沸石沸石，其中合成八面沸石沸石的微晶尺寸为1500〜2000，颗粒尺寸范围为4000至8000，并且当与氨交换时，保留表面超过母体沸石的70％，并在650℃下进行水热处理3小时，并用100％蒸汽进行水热处理。

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