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    • 4. 发明授权
    • Shale hydration inhibition agent and method of use
    • 页岩水化抑制剂及其使用方法
    • US07084092B2
    • 2006-08-01
    • US10647830
    • 2003-08-25
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • C09K8/12
    • C09K8/06C09K8/22C09K2208/12Y10S507/922
    • A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing a shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid includes, an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which A is independently selected from H and CH2CH2CH2NH2; and in which B is independently selected from H, CH2CH2OH, CH2CH2OCH2CH2CH2NH2 and CH2CH2CH2NH2. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art. The fluids may also be used in the disposal by reinjection of drilling cutting into a selected subterranean disposal formation.
    • 一种用于通过含有在水存在下膨胀的页岩的地层的钻井,固井,修井,压裂和放弃地下井的水基流体。 在一个说明性实施例中,钻井流体包括水基连续相,加重剂和页岩水合抑制剂。 页岩水化抑制剂应具有以下通式:其中A独立地选自H和CH 2 CH 2 CH 2 H 2 N 2 并且其中B独立地选自H,CH 2 CH 2 OH,CH 2 CH 2 OCH 2, 2> 2 CH 2 2 CH 2 NH 2和CH 2 CH 2 2 < / 2 NH 2。 页岩水化抑制剂以足够的浓度存在,以在与钻井液接触时基本上减少页岩钻屑的膨胀。 钻井液可以被配制成包括水基钻井液的各种各样的组分,例如加重剂,流体损失控制剂,悬浮剂,增粘剂,流变控制剂,以及其它化合物和材料 艺术技能 流体还可以通过将钻削切割注入到选定的地下处理层中而用于处理。
    • 5. 发明授权
    • High performance water based drilling mud and method of use
    • 高性能水基钻井泥浆及其使用方法
    • US06831043B2
    • 2004-12-14
    • US10062071
    • 2002-01-31
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • C09K702
    • C09K8/22C09K8/24C09K2208/12
    • A water-base fluid for use in drilling wells and other drilling operation includes a shale clay which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: wherein R and R′ are independently selectable alkylene groups having 2 to 4 carbon atoms, and wherein x and y have independently selected values such that the sum of x and y is at least 1. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale clay. The fluid may be used for formulating drilling fluids such as water-base drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shale clays.
    • 用于钻井和其他钻井操作的水基流体包括在水存在下膨胀的页岩粘土。 流体优选包括:基于水性的连续相和具有下式的页岩水化抑制剂:其中R和R'独立地是可选择的具有2至4个碳原子的亚烷基,并且其中x和y具有独立选择的值,使得 x和y之和至少为1.页岩水化抑制剂应以足够的浓度存在,以减少页岩粘土的溶胀。 流体可以用于配制钻井液,例如水基钻井泥浆或透明盐水钻井液。 该流体也可用于含有可溶胀的粘土或页岩粘土的钻屑的脱气和处理。
    • 6. 发明授权
    • High performance water based drilling fluids and method of use
    • 高性能水基钻井液及其使用方法
    • US07250390B2
    • 2007-07-31
    • US11008008
    • 2004-12-09
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • Arvind D. PatelEmanuel StamatakisEric DavisJim Friedheim
    • C09K8/04
    • C09K8/22C09K8/24C09K2208/12
    • A water-base fluid for use in drilling wells and other drilling operation includes a shale clay which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: H—(OR)x—[—NH—CH2—CH2—CH2—O—CH2—CH2—NH—]—(R′O)y—H wherein R and R′ are independently selectable alkylene groups having 2 to 4 carbon atoms, and wherein x and y have independently selected values such that the sum of x and y is at least 1. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale clay. The fluid may be used for formulating drilling fluids such as water-base drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shale clays.
    • 用于钻井和其他钻井操作的水基流体包括在水存在下膨胀的页岩粘土。 流体优选包括:基于水的连续相和具有下式的页岩水合抑制剂:<?in-line-formula description =“In-line Formulas”end =“lead”?> H(OR) - - - - - - - - - - - CH 2 -CH 2 CH 2 -CH 2 CH 2 - -N 2 - (R'O) - - - - (R'O)y -H-α-in-line-formula description =“In-line Formulas”end =“ 尾“→其中R和R'独立地是可选择的具有2至4个碳原子的亚烷基,并且其中x和y具有独立选择的值,使得x和y之和至少为1.页岩水化抑制剂应为 以足够的浓度存在,以减少页岩粘土的膨胀。 流体可以用于配制钻井液,例如水基钻井泥浆或透明盐水钻井液。 该流体也可用于含有可溶胀的粘土或页岩粘土的钻屑的脱气和处理。
    • 7. 发明授权
    • High performance water-based drilling mud and method of use
    • 高性能水泥钻井泥浆及其使用方法
    • US07192907B2
    • 2007-03-20
    • US10654505
    • 2003-09-03
    • Arvind D. PatelEmanuel StamatakisSteve Young
    • Arvind D. PatelEmanuel StamatakisSteve Young
    • C09K8/00E21B43/00
    • C09K8/24C09K2208/12
    • A water based drilling fluid for use in drilling a subterranean well through a subterranean formation that swells in the presence of water, the drilling fluid is formulated to include: an aqueous based continuous phase; a weigh material; a shale encapsulator and an optional shale hydration inhibition agent. The shale encapsulator has the formula: which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1–C6 alkyl, C2–C6 ether or amide; R, R′ and R″ are independently selectable C1–C3 alkyl; and B− is a charge balancing anion to the quaternary amine. The shale encapsulator and the optional shale hydration inhibition agent may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water. Conventional additives may be included into the formulation of the drilling fluid, such conventional additives may include: fluid loss control agents, alkaline reserve and other pH control agents, bridging agents, lubricants, anti-bit balling agents, corrosion inhibition agents, surfactants and solids suspending agents as well as mixtures and combination of these and similar compounds that should be known to one of skill in the art.
    • 一种水基钻井液,用于通过在水存在下膨胀的地下地层钻探地下井,将钻井液配制为包括:基于水的连续相; 称重材料; 页岩封装剂和可选的页岩水化抑制剂。 页岩封装器具有下式:其中x和y具有使得阳离子的分子量在约10,000至约200,000AMU范围内的值; A选自C 1 -C 6烷基,C 2 -C 6 - 醚或酰胺; R,R'和R“独立地选自C 1 -C 3烷基; 并且B + - 是与季胺的电荷平衡阴离子。 页岩封装剂和任选的页岩水化抑制剂可以以足够的浓度存在,以在水的存在下减少地层的溶胀。 常规的添加剂可以包括在钻井液的配方中,这种常规的添加剂可以包括:流体损失控制剂,碱性储备和其它pH控制剂,桥联剂,润滑剂,抗磨损球剂,腐蚀抑制剂,表面活性剂和固体 悬浮剂以及这些和本领域技术人员已知的类似化合物的混合物和组合。
    • 8. 发明授权
    • High performance water-based drilling mud and method of use
    • 高性能水泥钻井泥浆及其使用方法
    • US07497262B2
    • 2009-03-03
    • US11672847
    • 2007-02-08
    • Arvind D. PatelEmanuel StamatakisSteve Young
    • Arvind D. PatelEmanuel StamatakisSteve Young
    • E21B43/16C09K8/03C09K8/035C09K8/04
    • C09K8/24C09K2208/12
    • A method of forming a subterranean well and a method of reducing the swelling of shale clay during the drilling of the subterranean well. The method features the use of a water based drilling fluid, wherein the drilling fluid is formulated to include: an aqueous based continuous phase; a weight material; an optional shale hydration inhibition agent and a shale encapsulator. The shale encapsulator has the formula: in which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1-C6 alkyl, C2-C6 ether or C2-C6 amide; R, R′and R″are independently selectable C1-C3 alkyl; and B−is a charge balancing anion to the quaternary amine. The shale hydration inhibition agent and the shale encapsulator may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water. Conventional additives may be included into the formulation of the drilling fluid, including: fluid loss control agents, alkaline reserve and other pH control agents, bridging agents, lubricants, anti-bit balling agents, corrosion inhibition agents, surfactants, solids suspending agents, and mixtures and combinations of these and other similar additives.
    • 一种形成地下井的方法和在地下井的钻探期间减少页岩粘土的膨胀的方法。 该方法的特征在于使用水基钻井液,其中钻井液被配制为包括:基于水的连续相; 重物料; 可选的页岩水化抑制剂和页岩封隔器。 页岩封装剂具有下式:其中x和y具有使阳离子的分子量在约10,000至约200,000AMU范围内的值; A选自C 1 -C 6烷基,C 2 -C 6醚或C 2 -C 6酰胺; R,R'和R'可独立选择的C 1 -C 3烷基; 而B是与季胺的电荷平衡阴离子。 页岩水化抑制剂和页岩封壳剂可以以足够的浓度存在,以在水的存在下减少地层的溶胀。 常规的添加剂可以包括在钻井液的配方中,包括:流体损失控制剂,碱性储备和其它pH控制剂,桥联剂,润滑剂,抗钻头球磨剂,腐蚀抑制剂,表面活性剂,固体悬浮剂和 这些和其他类似添加剂的混合物和组合。
    • 9. 发明授权
    • Shale hydration inhibition agent and method of use
    • 页岩水化抑制剂及其使用方法
    • US07572756B2
    • 2009-08-11
    • US11936570
    • 2007-11-07
    • Arvind D. PatelEmanuel Stamatakis
    • Arvind D. PatelEmanuel Stamatakis
    • C09K8/35
    • C09K8/22C09K8/20C09K8/24C09K8/68C09K2208/12
    • A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid is composed of an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which R and R′ independently selected from hydrogen, methyl, ethyl or propyl, and X has a value from 1 to 6. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art. The fluids may also be used in fracturing and the disposal by reinjection of drilling cutting into a selected subterranean disposal formation.
    • 一种用于钻井,固井,修井,压裂和放弃地下井的水基流体,通过含有在水存在下膨胀的页岩的地层。 在一个说明性实施例中,钻井流体由基于水的连续相,加重剂和页岩水化抑制剂组成。 页岩水化抑制剂应具有以下通式:其中R和R'独立地选自氢,甲基,乙基或丙基,X具有1至6的值。页岩水化抑制剂以足够的浓度存在至基本上 在与钻井液接触时减少页岩钻屑的膨胀。 钻井液可以被配制成包括水基钻井液的各种各样的组分,例如加重剂,流体损失控制剂,悬浮剂,增粘剂,流变控制剂,以及其它化合物和材料 艺术技能 流体也可以用于压裂和通过将钻削切割注入到选定的地下处理层中来进行处理。
    • 10. 发明授权
    • Shale hydration inhibition agent and method of use
    • 页岩水化抑制剂及其使用方法
    • US07521398B2
    • 2009-04-21
    • US11123396
    • 2005-05-06
    • Arvind D. PatelEmanuel Stamatakis
    • Arvind D. PatelEmanuel Stamatakis
    • C09K8/035
    • C09K8/22C09K8/20C09K8/24C09K8/68C09K2208/12
    • A method of using a water-base wellbore fluid in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. Further the shale hydration inhibition agent may be present in the form of a free-base or in the form of an acid salt of the disclosed amine compounds. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the fluid.
    • 一种在地下井中使用水基井眼流体的方法,其渗透包含在水存在下溶胀的页岩的地下地层。 井眼流体包括水基连续相和页岩水化抑制剂。 一种说明性的页岩水化抑制剂优选是芳族胺与醛,优选甲醛的反应产物的氢化反应的反应产物。 或者,页岩水化抑制剂可以是苯胺和甲醛的反应产物的氢化反应的反应产物。 在一个说明性实施方案中,页岩水化抑制剂选自称为多环脂族胺的化合物类别。 此外,页岩水化抑制剂可以以游离碱的形式或所公开的胺化合物的酸式的形式存在。 页岩水化抑制剂以足够的浓度存在,以在与流体接触时大大减少页岩钻屑的膨胀。