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    • 1. 发明授权
    • Nonlinear optical material
    • 非线性光学材料
    • US5202891A
    • 1993-04-13
    • US813211
    • 1991-12-23
    • Arthur W. SleightJinfan Huang
    • Arthur W. SleightJinfan Huang
    • G02F1/355
    • G02F1/3551
    • Nonlinear optical materials having the general formula Ca.sub.1.40-X M.sub.X V.sub.0.98.+-.0.05 O.sub.4.00.+-.0.08 wherein X is 0.07 to 0.43 and M is selected from the group consisting of Bi, La, Ce, Y, Pm, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc, and mixtures thereof are described. Compositions satisfying this formula belong to the space group R3c wherein a=b=10.8.+-.0.1 .ANG., and c=38.0.+-.0.3 .ANG.. These NLO compositions are capable of doubling the frequency of light at about 0.1 to about 3.3 times the efficiency of KH.sub.2 PO.sub.4 (KDP). No damage to the NLO material is observed when they are exposed to high-power lasers.
    • 具有通式Ca1.40-XMXV0.98 +/- 0.05O4.00 +/- 0.08的非线性光学材料,其中X为0.07至0.43,M选自Bi,La,Ce,Y,Pm, Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Sc及其混合物。 满足该式的组合物属于空间群R3c,其中a = b = 10.8 +/- 0.1 ANGSTROM,c = 38.0 +/- 0.3 ANGSTROM。 这些NLO组合物能够将光的频率加倍至KH2PO4(KDP)效率的约0.1至约3.3倍。 当暴露于高功率激光器时,不会观察到NLO材料的损坏。