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1. 发明授权

US09028794B2 Method for producing hydrogen with reduced CO2 emissions 有权
标题翻译：生产氢气减少二氧化碳排放的方法
公开(公告)号：US09028794B2
公开(公告)日：2015-05-12
申请号：US13637423
申请日：2011-03-16
申请人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
发明人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
IPC分类号： C01B3/02 , C01B3/38 , C01B3/48 , C01B3/56
CPC分类号： C01B3/38 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0288 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , Y02C10/04 , Y02P20/129 , Y02P30/30
摘要： The present invention relates to a method for producing hydrogen, with reduced carbon dioxide emissions, from a hydrocarbon mixture. In said method, the hydrocarbon mixture is reformed so as to produce a synthetic gas that is cooled, then treated in a shift reactor so as to be enriched with H2 and CO2. Optionally dried, said mixture is treated in a PSA hydrogen purification unit in order to produce hydrogen. The residue is treated by means of partial condensation with a view to capturing CO4 before said residue is sent as fuel to reforming.
摘要翻译：本发明涉及一种从碳氢化合物混合物中生产具有减少的二氧化碳排放的氢的方法。在所述方法中，将烃混合物重整以产生冷却的合成气体，然后在换档反应器中处理以富含H 2和CO 2。任选地干燥，所述混合物在PSA氢纯化装置中处理以产生氢气。残余物通过部分冷凝处理，以便在将所述残余物作为燃料送入重整之前捕获CO 4。

2. 发明申请

US20130017146A1 METHOD FOR PRODUCING HYDROGEN WITH REDUCED CO2 EMISSIONS 有权
标题翻译：用减少二氧化碳排放生产氢的方法
公开(公告)号：US20130017146A1
公开(公告)日：2013-01-17
申请号：US13637423
申请日：2011-03-16
申请人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
发明人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
IPC分类号： C01B3/02
CPC分类号： C01B3/38 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0288 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , Y02C10/04 , Y02P20/129 , Y02P30/30
摘要： The present invention relates to a method for producing hydrogen, with reduced carbon dioxide emissions, from a hydrocarbon mixture. In said method, the hydrocarbon mixture is reformed so as to produce a synthetic gas that is cooled, then treated in a shift reactor so as to be enriched with H2 and CO2. Optionally dried, said mixture is treated in a PSA hydrogen purification unit in order to produce hydrogen. The residue is treated by means of partial condensation with a view to capturing CO4 before said residue is sent as fuel to reforming.
摘要翻译：本发明涉及一种从碳氢化合物混合物中生产具有减少的二氧化碳排放的氢的方法。在所述方法中，将烃混合物重整以产生冷却的合成气体，然后在换档反应器中处理以富含H 2和CO 2。任选地干燥，所述混合物在PSA氢纯化装置中处理以产生氢气。残余物通过部分冷凝处理，以便在将所述残余物作为燃料送入重整之前捕获CO 4。

3. 发明授权

US08734569B2 Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture 有权
标题翻译：从含二氧化碳的气体混合物中获得二氧化碳的方法
公开(公告)号：US08734569B2
公开(公告)日：2014-05-27
申请号：US12828294
申请日：2010-07-01
申请人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
发明人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
IPC分类号： B01D53/22 , F25J3/06
CPC分类号： B01D53/229 , B01D53/002 , B01D2256/22 , B01D2257/504 , F23J15/06 , F23J2215/50 , F23J2900/15061 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2230/08 , F25J2230/30 , F25J2230/80 , F25J2235/80 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/06 , Y02C10/10 , Y02C10/12 , Y02C20/20 , Y02E20/326 , Y02E20/363
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
摘要翻译：公开了从含CO 2的气体混合物中获得二氧化碳的方法。该方法结合了气膜分离与低温温度的优点。

4. 发明授权

US08663364B2 Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture 有权
公开(公告)号：US08663364B2
公开(公告)日：2014-03-04
申请号：US12828295
申请日：2010-07-01
申请人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
发明人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
IPC分类号： B01D53/22 , F25J3/06
CPC分类号： B01D53/002 , B01D53/229 , B01D2256/22 , B01D2257/504 , F23J15/006 , F23J15/06 , F23J2215/50 , F23J2219/70 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2235/80 , F25J2240/02 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/04 , F25J2270/06 , Y02C10/10 , Y02C10/12 , Y02E20/326 , Y02E20/363
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.

5. 发明授权

US08617292B2 Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture 有权
标题翻译：从含二氧化碳的气体混合物中获得二氧化碳的方法
公开(公告)号：US08617292B2
公开(公告)日：2013-12-31
申请号：US12828293
申请日：2010-07-01
申请人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
发明人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
IPC分类号： B01D53/22 , B01D71/06 , F25J3/06
CPC分类号： B01D53/228 , B01D53/002 , B01D53/229 , B01D71/64 , B01D2257/504 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2230/08 , F25J2230/30 , F25J2230/80 , F25J2235/80 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/06 , Y02C10/10 , Y02C10/12
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
摘要翻译：公开了从含CO 2的气体混合物中获得二氧化碳的方法。该方法结合了气膜分离与低温温度的优点。

6. 发明申请

US20120145000A1 Drying Process For Flue Gas Treatment 审中-公开
标题翻译：烟气处理干燥过程
公开(公告)号：US20120145000A1
公开(公告)日：2012-06-14
申请号：US12965056
申请日：2010-12-10
申请人： Trapti Chaubey , Jean-Pierre Tranier , Paul Terrien
发明人： Trapti Chaubey , Jean-Pierre Tranier , Paul Terrien
IPC分类号： B01D53/02
CPC分类号： B01D53/261 , B01D53/002 , B01D53/06 , B01D2253/106 , B01D2253/116 , B01D2256/22 , B01D2257/504 , B01D2257/80 , B01D2258/0283 , B01D2259/4009 , Y02C10/08
摘要： An apparatus and method for drying a moist gas is provided. The apparatus includes a revolving desiccant rotor with at least an adsorption sector and a regeneration chamber; the regeneration chamber comprising at least a first dry gas sector, a hot regeneration sector, and a second dry gas sector, and optionally a cold regeneration sector. The method includes at least an adsorption sector and a regeneration chamber; the regeneration chamber comprising at least a first dry gas sector, a hot regeneration sector, and a second dry gas sector, and optionally a cold regeneration sector. This method includes the steps of; contacting a moist gas stream with the desiccant in the adsorption sector, thereby producing a dry gas stream; contacting a first dry gas stream with the desiccant in the first dry gas sector, thereby producing a first wet gas stream; contacting a hot partially wet gas stream with the desiccant in the hot regeneration sector, thereby producing a warm wet gas stream; contacting a dry regeneration gas stream with the desiccant in the second dry gas sector, thereby producing a wet regeneration gas stream, and contacting a regeneration purge gas stream with the desiccant in the cold regeneration sector, thereby producing a warm purge gas stream.
摘要翻译：提供了一种用于干燥潮湿气体的装置和方法。该装置包括至少具有吸附扇区和再生室的旋转干燥剂转子; 所述再生室包括至少第一干燥气体部分，热再生部分和第二干燥气体部分，以及任选的冷再生部分。该方法至少包括吸附扇区和再生室; 所述再生室包括至少第一干燥气体部分，热再生部分和第二干燥气体部分，以及任选的冷再生部分。该方法包括以下步骤：使湿气流与吸附部分中的干燥剂接触，从而产生干燥气流; 使第一干燥气流与第一干燥气体区段中的干燥剂接触，从而产生第一湿气流; 使热的部分湿气流与热再生扇区中的干燥剂接触，从而产生温暖的湿气流; 使干再生气体流与第二干燥气体区段中的干燥剂接触，从而产生湿再生气流，并使再生吹扫气流与冷再生扇区中的干燥剂接触，从而产生热的吹扫气流。

7. 发明申请

US20110247360A1 Method of Obtaining Carbon Dioxide From Carbon Dioxide-Containing Gas Mixture 有权
标题翻译：从含二氧化碳气体混合物获得二氧化碳的方法
公开(公告)号：US20110247360A1
公开(公告)日：2011-10-13
申请号：US12828293
申请日：2010-07-01
申请人： David J. HASSE , Sudhir S. KULKARNI , Edgar S. SANDERS, JR. , Jean-Pierre TRANIER , Paul Terrien
发明人： David J. HASSE , Sudhir S. KULKARNI , Edgar S. SANDERS, JR. , Jean-Pierre TRANIER , Paul Terrien
IPC分类号： F25J1/00
CPC分类号： B01D53/228 , B01D53/002 , B01D53/229 , B01D71/64 , B01D2257/504 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2230/08 , F25J2230/30 , F25J2230/80 , F25J2235/80 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/06 , Y02C10/10 , Y02C10/12
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
摘要翻译：公开了从含CO 2的气体混合物中获得二氧化碳的方法。该方法结合了气膜分离与低温温度的优点。

8. 发明申请

US20110239700A1 Method of Obtaining Carbon Dioxide From Carbon Dioxide-Containing Gas Mixture 有权
公开(公告)号：US20110239700A1
公开(公告)日：2011-10-06
申请号：US12828294
申请日：2010-07-01
申请人： David J. HASSE , Sudhir S. KULKARNI , Edgar S. SANDERS, JR. , Jean-Pierre TRANIER , Paul Terrien
发明人： David J. HASSE , Sudhir S. KULKARNI , Edgar S. SANDERS, JR. , Jean-Pierre TRANIER , Paul Terrien
IPC分类号： F25J3/00 , B01D53/22 , F02C7/00 , C01B31/20
CPC分类号： B01D53/229 , B01D53/002 , B01D2256/22 , B01D2257/504 , F23J15/06 , F23J2215/50 , F23J2900/15061 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2230/08 , F25J2230/30 , F25J2230/80 , F25J2235/80 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/06 , Y02C10/10 , Y02C10/12 , Y02C20/20 , Y02E20/326 , Y02E20/363
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.

9. 发明申请

US20120292574A1 Process For The Production Of Hydrogen And Carbon Dioxide 审中-公开
公开(公告)号：US20120292574A1
公开(公告)日：2012-11-22
申请号：US13169270
申请日：2011-06-27
申请人： Paul Terrien , Trapti Chaubey , Purushottam V. Shanbhag , Bhadra S. Grover , Dennis A. Vauk , Arthur Darde , Pascal Marty
发明人： Paul Terrien , Trapti Chaubey , Purushottam V. Shanbhag , Bhadra S. Grover , Dennis A. Vauk , Arthur Darde , Pascal Marty
IPC分类号： C01B3/32
摘要： This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 75%, and most preferably at least 90% of the carbon dioxide. The present invention further provides the design for capture of at least 80%, carbon dioxide from syngas that allows for the simultaneous production of medium to high amounts of hydrogen in the syngas as a part of the production of hydrogen in a hydrogen generation plant. By using the process of the present invention, especially in terms of a hydrogen generation plant, it is possible to increase recovery of hydrogen and capture of the carbon dioxide in the syngas stream by balancing the recycle of the hydrogen rich permeate from the hydrogen membrane separation units to the process unit and/or the water gas shift as capacity allows when a carbon dioxide separation unit, a carbon dioxide membrane separation unit and two hydrogen membrane separation units are utilized.

10. 发明申请

US20120118011A1 Process For The Production Of Hydrogen And Carbon Dioxide 审中-公开
标题翻译：氢和二氧化碳生产工艺
公开(公告)号：US20120118011A1
公开(公告)日：2012-05-17
申请号：US12974298
申请日：2010-12-21
申请人： Paul Terrien , Trapti Chaubey , Purushottam V. Shanbhag , Bhadra S. Grover , Dennis A. Vauk , Arthur Darde
发明人： Paul Terrien , Trapti Chaubey , Purushottam V. Shanbhag , Bhadra S. Grover , Dennis A. Vauk , Arthur Darde
IPC分类号： F25J3/02 , F25J3/08
CPC分类号： B01D53/002 , B01D53/226 , B01D2257/108 , B01D2257/504 , C01B3/38 , C01B3/48 , C01B3/501 , C01B3/506 , C01B3/56 , C01B2203/0205 , C01B2203/0233 , C01B2203/0283 , C01B2203/0294 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/147 , C01B2203/148 , F25J3/0223 , F25J3/0252 , F25J3/0266 , F25J3/0625 , F25J3/0655 , F25J3/067 , F25J2200/02 , F25J2205/04 , F25J2205/40 , F25J2205/60 , F25J2205/80 , F25J2215/04 , F25J2220/82 , F25J2230/30 , F25J2245/02 , F25J2270/90 , Y02C10/10 , Y02C10/12 , Y02P20/152 , Y02P30/30
摘要： The present invention provides a method to more efficiently recover hydrogen and carbon dioxide as well as a design for carbon dioxide capture from syngas that allows for the simultaneous production of medium to high amounts of hydrogen and the capture of at least 90% of the carbon dioxide in the syngas as a part of the production of hydrogen in a hydrogen generation plant. Through the use of a combination of hydrogen selective membranes and carbon dioxide selective membranes together with a carbon dioxide separation unit it is possible to increase recovery of hydrogen and carbon dioxide and improved process efficiency of the hydrogen generation plant.
摘要翻译：本发明提供了一种更有效地回收氢气和二氧化碳的方法以及从合成气中捕获二氧化碳的设计，其允许同时产生中等至大量的氢气并捕获至少90％的二氧化碳在合成气中作为氢气发电厂生产氢气的一部分。通过使用氢选择性膜和二氧化碳选择性膜与二氧化碳分离单元的组合，可以增加氢气和二氧化碳的回收率并提高氢气发生设备的工艺效率。

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