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    • 1. 发明申请
    • NANOSTRUCTURED SI-C-COMPOSITE FOR ELECTRODE APPLICATIONS
    • 用于电极应用的纳米结构的SI-C复合材料
    • US20120156493A1
    • 2012-06-21
    • US13384417
    • 2010-05-18
    • Arkadi MaiselsYves Gorat StommelFrank StengerMartin MiessenJutta ZimmermannManfred DannehlPeter Pilgram
    • Arkadi MaiselsYves Gorat StommelFrank StengerMartin MiessenJutta ZimmermannManfred DannehlPeter Pilgram
    • B32B5/16H01B1/04B82Y30/00
    • H01M4/386C01P2004/61C01P2006/14H01M4/133H01M4/134H01M10/052Y10T428/2982
    • The invention relates to a process for producing nanostructured silicon-carbon composites, comprising the (A) introduction of at least one of components (a1) mono- and/or polyhydroxyaromatic compound, and (a2) an aldehyde, and (a3) a catalyst, into a reactor to obtain a composition in which the components react with one another in the presence of the catalyst at a reaction temperature T of 75 to 200° C., and at a pressure of 80 to 2400 kPa, and over a period to of 0.001 to 1 000 000 s, which gives a preliminary gel, and (B) introduction of at least one component (b1) sub-micron silicon powder, in crystalline or amorphous form, into the composition obtained during or after step (A), and then (C) introduction of the product obtained after step (B) into a neutralizing agent selected from an acid if (a3) is a basic catalyst, or an alkali if (a3) is an acidic catalyst, which gives a finely divided product, and (D) drying the product obtained during or after step (C) and then (E) carbonizing the product obtained after step (D) at a temperature of 500 to 1200° C., to the composites themselves, to the use thereof as an anode material for lithium ion cells and batteries, and to the lithium ion cells and batteries.
    • 本发明涉及一种生产纳米结构的硅 - 碳复合材料的方法,包括(A)引入组分(a1)单 - 和/或多羟基芳族化合物中的至少一种,和(a2)醛,和(a3)催化剂 在反应温度T为75〜200℃,压力为80〜2400kPa的条件下,在催化剂的存在下,使成分彼此反应的组合物,并在一段时间内, 0.001至1 000 000秒,其产生初步凝胶,和(B)将至少一种(b)亚微米硅粉末以结晶或无定形形式引入到步骤(A)期间或之后获得的组合物中, ,然后(C)将(a3)为碱性催化剂,或(a3)为酸性催化剂的碱,如果(a3)为酸性催化剂,则将步骤(B)后得到的产物引入选自酸的中和剂, 产品,和(D)干燥步骤(C)期间或之后获得的产物,然后(E)碳氮化物 在步骤(D)后获得的产物在500-1200℃的温度下,作为锂离子电池和电池的负极材料,以及锂离子电池和电池,使用它们本身。