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1. 发明申请

US20160200843A1 TIN-FREE CATALYST-CONTAINING COMPOSITION FOR A MONOSIL PROCESS WITH OPTIMIZED PROCESS PROPERTIES 审中-公开
标题翻译：具有优化工艺特性的单层工艺的无含催化剂的组合物
公开(公告)号：US20160200843A1
公开(公告)日：2016-07-14
申请号：US14912710
申请日：2014-07-29
申请人： Aristidis IOANNIDIS , Ioana-Elena MIHAILESCU , Bastian BIELAWSKI , Helmut MACK , Kerstin WEISSENBACH
发明人： Aristidis IOANNIDIS , Ioaba-Ekeba MIHAILESCU , Bastian BIELAWSKI , Helmut MACK , Kerstin WEISSENBACH
IPC分类号： C08F210/02 , B29C47/00
CPC分类号： C08F210/02 , B29C47/0004 , B29K2023/00 , B29L2031/00 , C08K5/0025 , C08K5/005 , C08K5/09 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08L23/00
摘要： The invention relates to a composition for use in a Monosil process for the crosslinking of thermoplastic polyolefins which comprises (i) from 5 to 60% by weight content of 2-ethyl hexanoic acid [H3C(CH2)3CH(C2H5)COOH], (ii) content of at least one monounsaturated organofunctional alkoxysilane of the general formula I A-SiR2x(OR1)3-x (I), where R1 is mutually independently a linear or branched hydrocarbon moiety having from 1 to 4 C atoms, R2 is methyl and x is 0 or 1 and A is a monovalent olefin group of the formula (R3)2C=C(R3)-Mk-, where k is 0 or 1, in which groups R3 are identical or different and R3 is a hydrogen atom or a methyl group and the group M is a group from the following list: —CH2—, —(CH2)2—, —(CH2)3— and —C(O)O—(CH2)3—, (iii) content of at least one free-radical generator and (iv) optionally content of at least one other component, where the entirety of all components (i) to (iv) gives 100% by weight. The present invention further relates to a production process, and also to mouldings or products obtainable thereby based on thermoplastic polyolefins, where a composition of the invention is reacted together with at least one thermoplastic polyolefin in a Monosil process. The invention further relates to the use of a composition of the invention in the Monosil process for the crosslinking of thermoplastic polyolefins during the production of products moulded by means of extrusion, based on thermoplastic polyolefins.
摘要翻译：本发明涉及一种用于交联热塑性聚烯烃的Monosil方法的组合物，其包含（i）5-60重量％的2-乙基己酸[H3C（CH2）3CH（C2H5）COOH]，（ ii）至少一种通式I A-SiR 2 x（OR 1）3-x（I）的单不饱和有机官能烷氧基硅烷的含量，其中R 1相互独立地为具有1至4个C原子的直链或支链烃部分，R2为甲基并且x为0或1，A为式（R3）2C = C（R3）-Mk-的单价烯烃基，其中k为0或1，其中基团R3相同或不同，R3为氢原子或-CH 2 - ， - （CH 2）2 - ， - （CH 2）3 - 和-C（O）O-（CH 2）3 - ，（iii）至少一种自由基发生剂的含量和（iv）任选的至少一种其它组分的含量，其中所有组分（i）至（iv）的全部为100重量％。本发明还涉及一种制备方法，还涉及基于热塑性聚烯烃可得到的成型品或产品，其中本发明的组合物与Monosil方法中的至少一种热塑性聚烯烃一起反应。本发明还涉及本发明的组合物在Monosil方法中用于在通过基于热塑性聚烯烃的挤出成型的产品生产期间交联热塑性聚烯烃。

2. 发明申请

US20160200852A1 TIN-FREE COMPOSITION FOR CROSSLINKING THERMOPLASTIC POLYOLEFINS 审中-公开
标题翻译：用于交联热塑性聚烯烃的无铅组合物
公开(公告)号：US20160200852A1
公开(公告)日：2016-07-14
申请号：US14913236
申请日：2014-07-29
申请人： Aristidis IOANNIDIS , Ioana-Elena MIHAILESCU , Bastlan BIELAWSKI , Kerstin WEISSENBACH
发明人： Aristidis IOANNIDIS , Ioana-Elena MIHAILESCU , Bastian BIELAWSKI , Kerstin WEISSENBACH
IPC分类号： C08F255/02
CPC分类号： C08F255/02 , C08K5/0025 , C08K5/09 , C08L23/06 , C08K5/14 , C08K5/5425
摘要： The invention relates to a composition for use in a Monosil process for the crosslinking of thermoplastic polyolefins which comprises(i) from 5 to 60% by weight content of caprylic acid (H3C(CH2)6COOH), (ii) content of at least one monounsaturated organofunctional alkoxysilane of the general formula I A-SiR2x(OR1)3-x (I), where R1 is mutually independently a linear or branched hydrocarbon moiety having from 1 to 4 C atoms, R2 is methyl and x is 0 or 1 and A is a monovalent olefin group of the formula (R3)2C═C(R3)-Mk-, where k is 0 or 1, in which groups R3 are identical or different and R3 is a hydrogen atom or a methyl group and the group M is a group from this list: —CH2—, —(CH2)2—, —(CH2)3— and C(O)O—(CH2)3—, (iii) content of at least one free-radical generator and (iv) optionally content of at least one other component, where the entirety of all components (i) to (iv) gives 100% by weight. The present invention further relates to production processes and to mouldings or, respectively, products obtained therefrom, based on thermoplastic polyolefins, where a composition of the invention is reacted together with at least one thermoplastic polyolefin in a Monosil process. The invention further relates to the use of a composition of the invention in the Monosil process for the crosslinking of thermoplastic polyolefins during the production of products moulded by means of extrusion, based on thermoplastic polyolefins.
摘要翻译：本发明涉及用于交联热塑性聚烯烃的Monosil方法的组合物，其包含（i）5至60重量％的辛酸（H3C（CH2）6COOH）含量，（ii）至少一种通式I A-SiR 2 x（OR 1）3-x（I）的单不饱和有机官能烷氧基硅烷，其中R 1相互独立地为具有1至4个C原子的直链或支链烃部分，R 2为甲基且x为0或1， A是式（R3）2C = C（R3）-Mk-的一价烯烃基，其中k是0或1，其中基团R3相同或不同，R3是氢原子或甲基，基团 M是该列表中的基团：-CH 2 - ， - （CH 2）2 - ， - （CH 2）3 - 和C（O）O-（CH 2）3 - ，（iii）至少一种自由基发生剂和（iv）至少一种其它组分的任选含量，其中所有组分（i）至（iv）的全部量为100重量％。本发明进一步涉及制备方法，以及基于热塑性聚烯烃从其获得的成型品或其制品，其中本发明的组合物与Monosil方法中的至少一种热塑性聚烯烃一起反应。本发明还涉及本发明的组合物在Monosil方法中用于在通过基于热塑性聚烯烃的挤出成型的产品生产期间交联热塑性聚烯烃。

3. 发明申请

US20130253144A1 SILANOL CONDENSATION CATALYSTS FOR THE CROSS-LINKING OF FILLED AND UNFILLED POLYMER COMPOUNDS 审中-公开
标题翻译：用于填充和未充分聚合物化合物交联的硅烷醇缩合催化剂
公开(公告)号：US20130253144A1
公开(公告)日：2013-09-26
申请号：US13903594
申请日：2013-05-28
申请人： Kerstin WEISSENBACH , Aristidis IOANNIDIS , Bastian BIELAWSKI
发明人： Kerstin WEISSENBACH , Aristidis IOANNIDIS , Bastian BIELAWSKI
IPC分类号： C08F110/02
CPC分类号： C08F110/02 , C07F7/1896 , C08F230/08 , C08K5/5419
摘要： The invention relates to a composition of an organofunctional silane compound, particularly of a mono-unsaturated silane compound, and of an organic acid or a precursor compound which releases said organic acid, and to a method for the production of polymer compounds such as granulates and/or finished products from thermoplastic base polymers and/or monomers and/or prepolymers of the thermoplastic base polymer utilizing the composition, the organic acid, or the precursor compound which releases said organic acid. The invention also relates to the produced polymers, filled plastics such as, for example, granulates, finished products, molded bodies and/or articles such as pipes or cables. In addition, the invention relates to a kit containing the composition.
摘要翻译：本发明涉及有机官能硅烷化合物，特别是单不饱和硅烷化合物的组合物，有机酸或前体化合物的释放所述有机酸的组合物，以及制备高分子化合物如颗粒和 /或使用所述组合物，有机酸或释放所述有机酸的前体化合物的热塑性基础聚合物和/或热塑性基础聚合物的单体和/或预聚物的成品。本发明还涉及生产的聚合物，填充塑料，例如颗粒，成品，成型体和/或诸如管道或电缆的物品。此外，本发明涉及含有该组合物的试剂盒。

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