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1. 发明授权

US5304610A Amphoteric copolymer derived from vinylpyridine and acetoxystyrene 失效
标题翻译：衍生自乙烯基吡啶和乙酰氧基苯乙烯的两性共聚物
公开(公告)号：US5304610A
公开(公告)日：1994-04-19
申请号：US42358
申请日：1993-04-02
申请人： Apurba Bhattacharya , Kenneth G. Davenport , Michael T. Sheehan , James R. Sounik
发明人： Apurba Bhattacharya , Kenneth G. Davenport , Michael T. Sheehan , James R. Sounik
IPC分类号： G03F7/033 , A61K8/00 , A61K8/37 , A61K8/49 , A61K47/30 , A61Q5/02 , A61Q5/12 , B01F17/40 , B01F17/52 , C08F8/12 , C08F12/00 , C08F26/06 , C08F212/14 , C08F226/06 , C08L39/00 , C08L39/04 , C08L101/00 , C09D5/00 , C09K17/20 , C11D3/37
CPC分类号： C08F226/06 , C08F212/14 , C08F8/12 , G03C2001/0471
摘要： A unique polymer was synthesized via copolymerization of vinylpyridine and acetoxystyrene under radical-initiated conditions followed by acidic or basic hydrolysis of the acetoxy group to afford the corresponding hydroxy group. The built-in acid-base dual functionality (phenolic and pyridyl units) in this polymer backbone gives rise to its unique solubility properties over a wide pH range in both aqueous and non-aqueous media. Due to its amphoteric nature, this polymer finds application as an anti-stat, viscosity modifier, and/or ion-exchange resin.
摘要翻译：通过乙烯基吡啶和乙酰氧基苯乙烯在自由基引发条件下的共聚合，然后酸性或碱性水解乙酰氧基来合成独特的聚合物，得到相应的羟基。该聚合物骨架中的内置酸碱双官能团（酚类和吡啶基单元）在水性和非水性介质中都能在宽的pH范围内产生独特的溶解性。由于其两性性质，该聚合物可用作抗静电，粘度调节剂和/或离子交换树脂。

2. 发明授权

US5232995A Amphoteric copolymer derived from vinylpyridine and acetoxystyrene 失效
标题翻译：由乙烯基吡啶和乙氧基苯乙烯衍生的AMPHTERIC共聚物
公开(公告)号：US5232995A
公开(公告)日：1993-08-03
申请号：US3350
申请日：1993-01-12
申请人： Apurba Bhattacharya , Kenneth G. Davenport , Michael T. Sheehan , James R. Sounik
发明人： Apurba Bhattacharya , Kenneth G. Davenport , Michael T. Sheehan , James R. Sounik
IPC分类号： B01J43/00 , B01J45/00 , C08F8/12 , C08F212/14 , H01B1/12
CPC分类号： H01B1/122 , B01J43/00 , B01J45/00 , C08F212/14 , C08F8/12 , C08F2810/50 , G03C2001/0471
摘要： A unique polymer was synthesized via copolymerization of vinylpyridine and acetoxystyrene under radical-initiated conditions followed by acidic or basic hydrolysis of the acetoxy group to afford the corresponding hydroxy group. The built-in acid-base dual functionality (phenolic and pyridyl units) in this polymer backbone gives rise to its unique solubility properties over a wide pH range in both aqueous and non-aqueous media. Due to its amphoteric nature, this polymer finds application as an anti-stat, viscosity modifier, and/or ion-exchange resin.
摘要翻译：通过乙烯基吡啶和乙酰氧基苯乙烯在自由基引发条件下的共聚合，然后酸性或碱性水解乙酰氧基来合成独特的聚合物，得到相应的羟基。该聚合物骨架中的内置酸碱双官能团（酚类和吡啶基单元）在水性和非水性介质中都能在宽的pH范围内产生独特的溶解性。由于其两性性质，该聚合物可用作抗静电，粘度调节剂和/或离子交换树脂。

3. 发明授权

US5210149A Amphoteric copolymer derived from vinylpyridine and acetoxystyrene 失效
标题翻译：衍生自乙烯基吡啶和乙酰氧基苯乙烯的两性共聚物
公开(公告)号：US5210149A
公开(公告)日：1993-05-11
申请号：US968741
申请日：1992-10-30
申请人： Apurba Bhattacharya , Kenneth G. Davenport , Michael T. Sheehan , James R. Sounik
发明人： Apurba Bhattacharya , Kenneth G. Davenport , Michael T. Sheehan , James R. Sounik
IPC分类号： B01J43/00 , B01J45/00 , C08F8/12 , C08F212/14 , H01B1/12
CPC分类号： H01B1/122 , B01J43/00 , B01J45/00 , C08F212/14 , C08F8/12 , C08F2810/50 , G03C2001/0471
摘要： A unique polymer was synthesized via copolymerization of vinylpyridine and acetoxystyrene under radical-initiated conditions followed by acidic or basic hydrolysis of the acetoxy group to afford the corresponding hydroxy group. The built-in acid-base dual functionality (phenolic and pyridyl units) in this polymer backbone gives rise to its unique solubility properties over a wide pH range in both aqueous and non-aqueous media. Due to its amphoteric nature, this polymer finds application as an anti-stat, viscosity modifier, and/or ion-exchange resin.
摘要翻译：通过乙烯基吡啶和乙酰氧基苯乙烯在自由基引发条件下的共聚合，然后酸性或碱性水解乙酰氧基来合成独特的聚合物，得到相应的羟基。该聚合物骨架中的内置酸碱双官能团（酚类和吡啶基单元）在水性和非水性介质中都能在宽的pH范围内产生独特的溶解性。由于其两性性质，该聚合物可用作抗静电，粘度调节剂和/或离子交换树脂。

4. 发明授权

US5739295A Photoactive coumarin sulfonate compounds 失效
标题翻译：光敏香豆素磺酸盐化合物
公开(公告)号：US5739295A
公开(公告)日：1998-04-14
申请号：US813099
申请日：1997-03-07
申请人： Mohammad Aslam , Michael T. Sheehan , George Kvakovszky , Kenneth G. Davenport , Douglas J. Gordon
发明人： Mohammad Aslam , Michael T. Sheehan , George Kvakovszky , Kenneth G. Davenport , Douglas J. Gordon
IPC分类号： C07D311/56 , C07D335/06 , C08F12/30 , C08G8/28 , C07D311/20
CPC分类号： C07D335/06 , C07D311/56
摘要： A new class of 3-diazo-3,4-dihydrocoumarin compounds which are useful as photoactive compounds in a wide variety of applications including photoresists and other opto-electronic applications are disclosed and claimed. Preferred embodiments include 6-sulfonyl-3-diazo-4-oxo-3,4-dihydrocoumarin esters. These compounds exhibit very high photosensitivity in the deep ultraviolet (DUV) region (ca. 250 nm), and therefore, are useful as photoactive compounds in DUV photoresist formulations.
摘要翻译：公开和要求保护的新类型的可用作光活性化合物的3-重氮-3,4-二氢香豆素化合物，包括光致抗蚀剂和其他光电子应用。优选的实施方案包括6-磺酰基-3-重氮基-4-氧代-3,4-二氢香豆素酯。这些化合物在深紫外（DUV）区域（约250nm）中表现出非常高的光敏性，因此可用作DUV光致抗蚀剂制剂中的光活性化合物。

5. 发明授权

US5041666A Method for the production of 3,3'4,4'-tetraaminobiphenyl 失效
标题翻译：制备3,3'4,4'-四氨基联苯的方法
公开(公告)号：US5041666A
公开(公告)日：1991-08-20
申请号：US82265
申请日：1987-08-06
申请人： Bennett C. Ward , Wilson B. Ray , Charles B. Hilton , Anthony J. East , Kenneth G. Davenport
发明人： Bennett C. Ward , Wilson B. Ray , Charles B. Hilton , Anthony J. East , Kenneth G. Davenport
IPC分类号： C07C211/50
CPC分类号： C07C211/50
摘要： A method is provided for the production of 3,3', 4,4'-tetraaminobiphenyl (TAB) from biphenyl comprising the following steps:1) acetylating the biphenyl in the presence of an appropriate Friedel-Crafts catalyst to obtain 4,4'-diacetylbiphenyl (DAcB);2) oximating the DAcB to form DAcB dioxime;3) subjecting the dioxime to a double Beckmann rearrangement to obtain N,N-diacetylbenzidine (DiAcBz);4) nitrating the DiAcBz to obtain 3,3'-dinitro-N,N-diacetylbenzidine (DNAcBz)5) removing the acetyl groups of the DNAcBz by basic hydrolysis to form 3,3'-dinitrobenzidine (DNB); and6) reducing the nitrate groups of the DNB to form TAB.
摘要翻译：提供从联苯制备3,3 + 40,4,4'-四氨基联苯（TAB）的方法，包括以下步骤：1）在合适的Friedel-Crafts催化剂存在下使联苯乙酰化得到4,4 ' - 乙酰基联苯（DAcB）; 2）使DAcB肟化形成DAcB二肟; 3）使二肟双重Beckmann重排，得到N，N-二乙酰基联苯胺（DiAcBz）; 4）硝化DiAcBz得到3,3'-二硝基-N，N-二乙酰基联苯胺（DNAcBz）5）通过碱水解除去DNAcBz的乙酰基，形成3,3'-二硝基联苯胺（DNB）; 和6）减少DNB的硝酸盐基团形成TAB。

6. 发明授权

US4692546A Process for producing acyloxy aromatic carboxylic acids 失效
标题翻译：制备酰氧基芳族羧酸的方法
公开(公告)号：US4692546A
公开(公告)日：1987-09-08
申请号：US779893
申请日：1985-09-25
申请人： Kenneth G. Davenport
发明人： Kenneth G. Davenport
IPC分类号： C07C45/46 , C07C45/54 , C07C51/09 , C07C65/03 , C07B41/08 , C07C51/245 , C07C59/52 , C07C69/017
CPC分类号： C07C65/03 , C07C45/46 , C07C45/54 , C07C51/09
摘要： Acyloxy aromatic carboxylic acids, e.g., 4-acetoxybenzoic acid, are prepared by oxidizing with oxygen an acyloxy aromatic ketone, e.g., 4-acetoxyacetophenone in the presence of manganese cations and a lower-carboxylic acid anhydride as catalyst and a co-reductant or promoter. The acyloxy aromatic ketone may be prepared by acylating a hydroxy aromatic ketone, e.g., 4-hydroxyacetophenone, which has the effect of "masking" the hydroxyl group of the ketone in a manner necessary to effect the subsequent transition-metal catalyzed oxidation of the ketone to the acyloxy aromatic carboxylic acid.
摘要翻译：芳氧基芳族羧酸，例如4-乙酰氧基苯甲酸，通过在氧阳离子和低级羧酸酐作为催化剂和共还原剂或促进剂的存在下，用氧气氧化芳族酮例如4-乙酰氧基苯乙酮来制备。酰氧基芳族酮可以通过酰化羟基芳族酮，例如4-羟基苯乙酮来制备，所述羟基芳族酮具有以掩蔽所述酮的羟基的方式的作用，所述方式是为了进行随后的酮的过渡金属催化氧化所必需的与酰氧基芳族羧酸反应。

7. 发明授权

US5466869A Process for perparing 4-hydroxyacetophenone oxime 失效
标题翻译：制备4-羟基苯乙酮肟的方法
公开(公告)号：US5466869A
公开(公告)日：1995-11-14
申请号：US332240
申请日：1994-10-31
申请人： Kenneth G. Davenport , Roger A. Sheldon , Joel Le Bars , Werner H. Mueller
发明人： Kenneth G. Davenport , Roger A. Sheldon , Joel Le Bars , Werner H. Mueller
IPC分类号： C07C249/04
CPC分类号： C07C249/04
摘要： A catalytic process for preparing 4-hydroxyacetophenone oxime by reacting 4-hydroxyacetophenone with NH.sub.3 and H.sub.2 O.sub.2 in the liquid phase, in the presence of a catalyst substantially consisting of a titanium-containing molecular sieve such as a highly crystalline substance, containing SiO.sub.2 and having a zeolitic structure.
摘要翻译：在催化剂存在下，通过使4-羟基苯乙酮与NH 3和H 2 O 2在液相中反应制备4-羟基苯乙酮肟的催化方法，催化剂基本上由含钛的含钛分子筛沸石结构。

8. 发明授权

US5072025A Process for the production of 3,5-disubstituted-4-acetoxystyrene 失效
标题翻译：制备3,5-二取代-4-乙酰氧基苯乙烯的方法
公开(公告)号：US5072025A
公开(公告)日：1991-12-10
申请号：US559759
申请日：1990-07-26
申请人： Richard Vicari , Mohammad Aslam , Wilson B. Ray , Kenneth G. Davenport , Ralph Dammel , Juergen Lingnau , Karl-Friedrich Doessel
发明人： Richard Vicari , Mohammad Aslam , Wilson B. Ray , Kenneth G. Davenport , Ralph Dammel , Juergen Lingnau , Karl-Friedrich Doessel
IPC分类号： C07C39/373 , C07C45/54 , C07C45/63 , C07C49/825 , G03F7/038
CPC分类号： G03F7/038 , C07C39/373 , C07C45/54 , C07C45/63 , C07C49/825
摘要： 3-substituted-4-hydroxy- and 4-acetoxystyrene compounds, especially 3,5-di(methyl, bromo or chloro)-4-acetoxystyrene as well as a process for its preparation. 2,6-dimethylphenol is acylated with acetic anhydride and HF catalyzed to produce 3,5-dimethyl-4-hydroxy-acetophenone. After subsequent esterification with acetic anhydride and catalyzed hydrogenation to form 1-(3',5'-dimethyl-4'-acetoxyphenyl)ethanol, this intermediate is then dehydrated with an acid and a polymerization inhibitor to produce 3,5-dimethyl-4-acetoxystyrene.
摘要翻译： 3-取代-4-羟基 - 和4-乙酰氧基苯乙烯化合物，特别是3,5-二（甲基，溴或氯）-4-乙酰氧基苯乙烯以及其制备方法。 2,6-二甲基苯酚用乙酸酐进行酰化，HF催化反应生成3,5-二甲基-4-羟基苯乙酮。在用乙酸酐进行酯化和催化氢化后，形成1-（3'，5'-二甲基-4'-乙酰氧基苯基）乙醇，然后将该中间体用酸和阻聚剂脱水，得到3,5-二甲基-4 乙酰氧基苯乙烯

9. 发明授权

US4981995A Method for producing ibuprofen 失效
标题翻译：生产布洛芬的方法
公开(公告)号：US4981995A
公开(公告)日：1991-01-01
申请号：US500645
申请日：1990-03-28
申请人： Varadaraj Elango , Mark A. Murphy , Brad L. Smith , Kenneth G. Davenport , Graham N. Mott , Edward G. Zey , Gary L. Moss
发明人： Varadaraj Elango , Mark A. Murphy , Brad L. Smith , Kenneth G. Davenport , Graham N. Mott , Edward G. Zey , Gary L. Moss
IPC分类号： B01J31/24 , C07C45/46 , C07C51/12 , C07C57/30
CPC分类号： B01J31/2404 , B01J31/24 , C07C45/46 , C07C51/12 , B01J2231/34 , B01J2531/824 , Y02P20/584
摘要： A method is provided for the preparation of ibuprofen by carbonylating 1-(4'-isobutylphenyl)ethanol (IBPE) with carbon monoxide in an acidic aqueous medium, e.g. containing at least 10% of water based on the weight of IBPE initially added, at a temperature of at least about 10.degree. C. and a carbon monoxide pressure of at least about 500 psig, and in the presence of (1) a catalyst complex consisting essentially of a palladium compound in which the palladium has a valence of zero to 2 and is complexed with at least one monodentate phosphine ligand miscible with the organic phase of the reaction medium, the phosphorus/palladium mole ratio in said palladium compound and ligand being at least about 2:1 when the palladium/IBPE mole ratio is such that palladium=1 and IBPE=10,000 or more; (2) dissociated hydrogen ions from an acid which is substantially completely ionizable in dilute aqueous solution such that the mole ratio of hydrogen ions to IBPE added to the reaction zone is at least about 0.15; and, (3) dissociated halide ions such that the mole ratio of halide ions to IBPE added to the reaction zone is at least about 0.15. Advantageously, a hydrogen halide is the source of hydrogen ions and halide ions. The carbonylation is preferably integrated with a method of producing IBPE from isobutylbenzene wherein the latter compound is subjected to Friedel-Crafts reaction with an acetylating agent to produce 4-isobutylacetophenone, which is then reduced with hydrogen in the presence of a hydrogenation catalyst, or with a reducing agent containing available hydrogen, to obtain IBPE. The palladium catalyst complex can be precipitated from an organic phase of the carbonylation reaction which typically includes the ibuprofen product. The precipitated catalyst complex can be recycled without further treatment.
摘要翻译：提供了一种通过在酸性水性介质中将1-（4'-异丁基苯基）乙醇（IBPE）与一氧化碳羰基化来制备布洛芬的方法，例如，在至少约10℃的温度和至少约500psig的一氧化碳压力下，在（1）催化剂络合物的存在下，基于最初加入的IBPE的重量，含有至少10％的水基本上由钯化合物组成，其中钯的价数为0至2，并且与至少一种与反应介质的有机相可混溶的单齿膦配体络合，所述钯化合物和配体中的磷/钯摩尔比为当钯/ IBPE摩尔比使得钯= 1和IBPE = 10,000或更高时，至少约2:1; （2）从在稀水溶液中基本完全可离子化的酸离解氢离子使得加入到反应区中的氢离子与IBPE的摩尔比至少为约0.15; 和（3）离解的卤离子使得加入反应区的卤离子与IBPE的摩尔比至少为约0.15。有利地，卤化氢是氢离子和卤离子的来源。羰基化优选与从异丁基苯生产IBPE的方法相结合，其中后一种化合物与乙酰化剂进行Friedel-Crafts反应以产生4-异丁基苯乙酮，然后在氢化催化剂存在下用氢还原，或与含有可用氢的还原剂，以获得IBPE。钯催化剂络合物可以从通常包括布洛芬产物的羰基化反应的有机相中沉淀出来。沉淀的催化剂络合物可以循环使用，无需进一步处理。

10. 发明授权

US4908476A Synthesis of 2-(4-hydroxyphenoxy)alkanoic acids 失效
标题翻译： 2-（4-羟基苯氧基）链烷酸的合成
公开(公告)号：US4908476A
公开(公告)日：1990-03-13
申请号：US170728
申请日：1988-03-21
申请人： Varadaraj Elango , Kenneth G. Davenport
发明人： Varadaraj Elango , Kenneth G. Davenport
IPC分类号： C07C51/00 , C07C51/09 , C07C51/367 , C07C59/125 , C07C59/64 , C07C67/00
CPC分类号： C07C51/09 , C07C51/367
摘要： A method for synthesizing 2-(4-hydroxyphenoxy)alkanoic acids by reacting a hydroxyaromatic ketone derivative with a 2-substituted alkanoic acid under basic conditions and thereafter oxidizing the intermediate with subsequent hydrolysis.

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