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1. 发明申请

US20110094149A1 METHOD OF HYDROTREATING FEEDS FROM RENEWABLE SOURCES WITH INDIRECT HEATING USING A CATALYST BASED ON MOLYBDENUM 审中-公开
标题翻译：使用基于钼的催化剂对具有间接加热的可再生来源的进料进行加氢的方法
公开(公告)号：US20110094149A1
公开(公告)日：2011-04-28
申请号：US12912025
申请日：2010-10-26
申请人： Wilfried Weiss , Laurent Bournay , Thierry Chapus , Antoine Daudin
发明人： Wilfried Weiss , Laurent Bournay , Thierry Chapus , Antoine Daudin
IPC分类号： C10L1/188
CPC分类号： C10G65/04 , C10G3/46 , C10G3/48 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/4006 , C10G2300/4081 , Y02P30/20
摘要： The invention describes a method of treating feeds from renewable sources comprising a hydrotreatment stage comprising at least two catalytic zones in which the entry stream comprising said feed mixed with at least a part of a hydrotreated liquid effluent from stage b) is introduced into the first catalytic zone at a temperature comprised between 150 and 260° C., and the effluent from the first catalytic zone is then introduced, mixed with at least a part of a hydrotreated liquid effluent from stage b) and preheated, into the following catalytic zone or zones at a temperature comprised between 260 and 320° C., and a stage of separation of the effluent from the hydrotreatment stage permitting the separation of a gaseous effluent and a hydrotreated liquid effluent of which at least a part is recycled at the top of each catalytic zone, said method using, in at least the catalytic zone or zones following the first, a bulk or supported catalyst comprising an active phase constituted by a sulphidized group VIB element, the group VIB element being molybdenum.
摘要翻译：本发明描述了一种处理来自可再生来源的饲料的方法，该方法包括加氢处理阶段，该加氢处理阶段包括至少两个催化区，其中将包含所述进料的进料与至少一部分来自步骤b）的加氢处理液体流出物混合进入第一催化剂区域，然后引入来自第一催化区域的流出物，与来自阶段b）的加氢处理的液体流出物的至少一部分混合并预热到以下催化区或区域在260至320℃之间的温度下，流出物与加氢处理阶段的分离阶段允许分离气态流出物和加氢处理的液体流出物，其中至少一部分在每个催化剂的顶部被再循环所述方法在至少在第一个催化区域之后使用主体或负载的催化剂，其包含由硫化VIB族元素，VIB族元素为钼。

2. 发明申请

US20110098494A1 METHOD OF HYDROTREATING FEEDS FROM RENEWABLE SOURCES WITH INDIRECT HEATING USING A CATALYST BASED ON NICKEL AND MOLYBDENUM HAVING A PARTICULAR ATOMIC RATIO 审中-公开
标题翻译：使用基于镍的催化剂和具有特定原子比的钼的间接加热从可再生来源进料的方法
公开(公告)号：US20110098494A1
公开(公告)日：2011-04-28
申请号：US12911983
申请日：2010-10-26
申请人： Wilfried WEISS , Laurent Bournay , Thierry Chapus , Antoine Daudin
发明人： Wilfried WEISS , Laurent Bournay , Thierry Chapus , Antoine Daudin
IPC分类号： C11B3/02
CPC分类号： C10G3/46 , C10G3/48 , C10G3/50 , C10G65/04 , C10G2300/1014 , C10G2300/1018 , C10G2300/4006 , C10G2300/4081 , Y02P30/20
摘要： The invention describes a method of treating feeds from renewable sources comprising a hydrotreatment stage comprising at least two catalytic zones in which the entry stream comprising said feed mixed with at least a part of a hydrotreated liquid effluent from stage b) is introduced into the first catalytic zone at a temperature comprised between 150 and 260° C., and the effluent from the first catalytic zone is then introduced, mixed with at least a part of a hydrotreated liquid effluent from stage b) and preheated, into the following catalytic zone or zones at a temperature comprised between 260 and 320° C., and a stage of separation of the effluent from the hydrotreatment stage permitting the separation of a gaseous effluent and a hydrotreated liquid effluent of which at least a part is recycled at the top of each catalytic zone, said method using, in at least the catalytic zone or zones following the first, a bulk or supported catalyst comprising an active phase constituted by at least one group VIB element and at least one group VIII element, said elements being in sulphide form and the atomic ratio of the group VIII metal to the group VIB metal being strictly greater than 0 and less than 0.095.
摘要翻译：本发明描述了一种处理来自可再生来源的饲料的方法，该方法包括加氢处理阶段，该加氢处理阶段包括至少两个催化区，其中将包含所述进料的进料与至少一部分来自步骤b）的加氢处理液体流出物混合进入第一催化剂区域，然后引入来自第一催化区域的流出物，与来自阶段b）的加氢处理的液体流出物的至少一部分混合并预热到以下催化区或区域在260至320℃之间的温度下，流出物与加氢处理阶段的分离阶段允许分离气态流出物和加氢处理的液体流出物，其中至少一部分在每个催化剂的顶部被再循环所述方法在至少在第一个催化区域之后使用本体或负载型催化剂，其包含由下式构成的活性相：至少一种VIB族元素和至少一种VIII族元素，所述元素为硫化物形式，并且VIII族金属与VIB族金属的原子比严格大于0且小于0.095。

3. 发明申请

US20100240942A1 PROCESS FOR HYDRODEOXYGENATION OF FEEDS DERIVED FROM RENEWABLE SOURCES WITH LIMITED DECARBOXYLATION CONVERSION USING A CATALYST BASED ON NICKEL AND MOLYBDENUM 有权
标题翻译：使用镍和钼的催化剂进行有限的脱羧转化的可再生来源进料的进料的氢化反应
公开(公告)号：US20100240942A1
公开(公告)日：2010-09-23
申请号：US12715836
申请日：2010-03-02
申请人： Antoine DAUDIN , Laurent Bournay , Thierry Chapus
发明人： Antoine DAUDIN , Laurent Bournay , Thierry Chapus
IPC分类号： C07C1/24
CPC分类号： C11C3/123 , B01J21/04 , B01J23/883 , B01J29/74 , B01J37/28 , B01J2229/20 , B01J2229/42 , C10G3/46 , C10G3/50 , C10G3/54 , C10G3/56 , C10G45/62 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C11C3/00 , Y02E50/13 , Y02P30/10 , Y02P30/20
摘要： The invention concerns a process for hydrodeoxygenation of feeds derived from renewable sources with conversion by decarboxylation/decarbonylation limited to at most 10%, using a bulk or supported catalyst comprising an active phase constituted by at least one element from group VIB and at least one element from group VIII, said elements being in the sulphide form, and the atomic ratio of the metal (or metals) from group VIII to the metal (or metals) from group VIB being strictly more than 0 and less than 0.095, said process being carried out at a temperature in the range 120° C. to 450° C., at a pressure in the range 1 MPa to 10 MPa, at an hourly space velocity in the range 0.1 h−1 to 10 h−1, and in the presence of a total quantity of hydrogen mixed with the feed such that the hydrogen/feed ratio is in the range 50 to 3000 Nm3 of hydrogen/m3 of feed.
摘要翻译：本发明涉及一种通过脱羧/脱羰转化而限制为至多10％的来自可再生来源的进料的加氢脱氧的方法，使用本体或负载型催化剂，其包含由至少一种来自VIB族的元素构成的活性相和至少一种元素来自VIII族的所述元素为硫化物形式，并且来自VIII族的金属（或金属）与VIB族金属（或金属）的原子比严格大于0且小于0.095，所述方法被携带在120℃至450℃的温度范围内，在1MPa至10MPa的压力下，以0.1h-1至10h-1的小时空速，在存在与进料混合的总量的氢，使得氢/进料比在50-3000Nm 3的氢/ m3进料的范围内。

4. 发明申请

US20100163458A1 METHOD OF CONVERTING EFFLUENTS OF RENEWABLE ORIGIN INTO FUEL OF EXCELLENT QUALITY BY USING A MOLYBDENUM-BASED CATALYST 有权
标题翻译：通过使用基于钼的催化剂将可再生原料转化为优质燃料的燃料的方法
公开(公告)号：US20100163458A1
公开(公告)日：2010-07-01
申请号：US12644710
申请日：2009-12-22
申请人： Antoine DAUDIN , Laurent Bournay , Thierry Chapus
发明人： Antoine DAUDIN , Laurent Bournay , Thierry Chapus
IPC分类号： C10G45/08 , B01J27/051 , B01J27/19 , B01J21/02 , B01J21/16
CPC分类号： B01J23/28 , B01J27/051 , B01J27/0515 , B01J27/19 , B01J29/74 , C10G3/44 , C10G3/48 , C10G3/50 , C10G3/54 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4018 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： The invention is concerned with a supported or unsupported catalyst comprising an active phase constituted by a sulfur-containing group VIB element, the group VIB element being molybdenum, and a hydrodeoxygenation process with a yield of hydrodeoxygenation product which is greater than or equal to 90% of charges from renewable sources using a catalyst according to the invention.
摘要翻译：本发明涉及负载或未负载的催化剂，其包含由含硫基团VIB元素，VIB族元素为钼构成的活性相和加氢脱氧方法，其加氢脱氧产物的产率大于或等于90％使用根据本发明的催化剂的可再生能源的电荷。

5. 发明授权

US08552235B2 Process for hydrodeoxygenation of feeds derived from renewable sources with limited decarboxylation conversion using a catalyst based on nickel and molybdenum 有权
标题翻译：使用基于镍和钼的催化剂进行有限脱羧转化的来自可再生能源的进料的加氢脱氧方法
公开(公告)号：US08552235B2
公开(公告)日：2013-10-08
申请号：US12715836
申请日：2010-03-02
申请人： Antoine Daudin , Laurent Bournay , Thierry Chapus
发明人： Antoine Daudin , Laurent Bournay , Thierry Chapus
IPC分类号： C07C1/00
CPC分类号： C11C3/123 , B01J21/04 , B01J23/883 , B01J29/74 , B01J37/28 , B01J2229/20 , B01J2229/42 , C10G3/46 , C10G3/50 , C10G3/54 , C10G3/56 , C10G45/62 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C11C3/00 , Y02E50/13 , Y02P30/10 , Y02P30/20
摘要： A process for hydrodeoxygenation of feeds derived from renewable sources with conversion by decarboxylation/decarbonylation limited to at most 10%, using a bulk or supported catalyst comprising an active phase constituted by at least one element from group VIB and at least one element from group VIII, said elements being in the sulphide form, and the atomic ratio of the metal (or metals) from group VIII to the metal (or metals) from group VIB being strictly more than 0 and less than 0.095, said process being carried out at a temperature in the range 120° C. to 450° C., at a pressure in the range 1 MPa to 10 MPa, at an hourly space velocity in the range 0.1 h−1 to 10 h−1, and in the presence of a total quantity of hydrogen mixed with the feed such that the hydrogen/feed ratio is in the range 50 to 3000 Nm3 of hydrogen/m3 of feed.
摘要翻译：通过脱羧/脱羰转化限制为至多10％的来自可再生来源的进料的加氢脱氧的方法，使用包含由至少一种来自VIB族元素和VIII族元素构成的活性相的本体或负载型催化剂所述元素为硫化物形式，并且来自VIB族的金属（或金属）与金属（或金属）的原子比严格大于0且小于0.095，所述方法在温度在120℃至450℃的范围内，在1MPa至10MPa的压力下，以0.1h-1至10h-1的小时空间速度，并且在与进料混合的氢气总量使得氢/进料比在50-3000Nm 3的氢/ m3进料的范围内。

6. 发明授权

US08546626B2 Method of converting effluents of renewable origin into fuel of excellent quality by using a molybdenum-based catalyst 有权
标题翻译：通过使用钼基催化剂将可再生原料的废水转化为优质燃料的方法
公开(公告)号：US08546626B2
公开(公告)日：2013-10-01
申请号：US12644710
申请日：2009-12-22
申请人： Antoine Daudin , Laurent Bournay , Thierry Chapus
发明人： Antoine Daudin , Laurent Bournay , Thierry Chapus
IPC分类号： C07C1/00
CPC分类号： B01J23/28 , B01J27/051 , B01J27/0515 , B01J27/19 , B01J29/74 , C10G3/44 , C10G3/48 , C10G3/50 , C10G3/54 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4018 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： The invention is concerned with a supported or unsupported catalyst comprising an active phase constituted by a sulfur-containing group VIB element, the group VIB element being molybdenum, and a hydrodeoxygenation process with a yield of hydrodeoxygenation product which is greater than or equal to 90% of charges from renewable sources using a catalyst according to the invention.
摘要翻译：本发明涉及负载或未负载的催化剂，其包含由含硫基团VIB元素，VIB族元素为钼构成的活性相和加氢脱氧方法，其加氢脱氧产物的产率大于或等于90％使用根据本发明的催化剂的可再生能源的电荷。

7. 发明申请

US20090326290A1 METHOD OF CONVERTING FEEDSTOCKS FROM RENEWABLE SOURCES TO GOOD-QUALITY DIESEL FUEL BASES USING A ZEOLITE CATALYST WITHOUT INTERMEDIATE GAS-LIQUID SEPARATION 有权
标题翻译：使用不具有中间气液分离的沸石催化剂将可再生来源的原料转化为优质柴油燃料的方法
公开(公告)号：US20090326290A1
公开(公告)日：2009-12-31
申请号：US12490647
申请日：2009-06-24
申请人： Christophe Bouchy , Antoine Daudin , Emmanuelle Guillon , Nathalie Dupassieux , Thierry Chapus
发明人： Christophe Bouchy , Antoine Daudin , Emmanuelle Guillon , Nathalie Dupassieux , Thierry Chapus
IPC分类号： C07C5/13
CPC分类号： C10G65/043 , C10G3/46 , C10G3/50 , C10G3/54 , C10G45/02 , C10G45/08 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , Y02P30/20
摘要： The invention relates to a method of treating feedstocks from renewable sources without intermediate gas-liquid separation in order to produce diesel fuel bases of excellent quality. The feedstocks used can be raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks.
摘要翻译：本发明涉及一种从可再生能源处理原料而不进行中间气液分离的方法，以生产质量优良的柴油燃料基料。所使用的原料可以是先前经受预精制阶段，动物脂肪或这些原料的混合物的生植物油或这种油。本发明涉及允许从这些原料获得高柴油燃料碱产率的方法。

8. 发明申请

US20090318740A1 METHOD OF CONVERTING FEEDSTOCKS FROM RENEWABLE SOURCES TO GOOD-QUALITY DIESEL FUEL BASES USING A ZEOLITE TYPE CATALYST 有权
标题翻译：使用沸石型催化剂将可再生来源的原料转化为优质柴油燃料的方法
公开(公告)号：US20090318740A1
公开(公告)日：2009-12-24
申请号：US12489885
申请日：2009-06-23
申请人： Emmanuelle GUILLON , Christophe Bouchy , Nathalie Dupassieux , Antoine Daudin , Thierry Chapus
发明人： Emmanuelle GUILLON , Christophe Bouchy , Nathalie Dupassieux , Antoine Daudin , Thierry Chapus
IPC分类号： C07C5/27
CPC分类号： C10G3/50 , B01J23/883 , B01J29/74 , B01J29/78 , B01J37/20 , B01J37/28 , C10G3/46 , C10G3/54 , C10G45/02 , C10G45/08 , C10G45/64 , C10G65/043 , C10G2300/1014 , C10G2300/1018 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , Y02P30/20
摘要： The invention relates to a method of treating feedstocks from renewable sources in order to produce diesel fuel bases of excellent quality. The feedstocks used can be, for example, raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks.
摘要翻译：本发明涉及一种从可再生能源处理原料以生产质量优良的柴油燃料基料的方法。所使用的原料可以是例如以前经受预精制阶段，动物脂肪或这些原料的混合物的生植物油或这种油。本发明涉及允许从这些原料获得高柴油燃料碱产率的方法。

9. 发明授权

US08877993B2 Process for ebullated bed hydroconversion of feeds of bio-renewable origin for the production of fuel bases 有权
标题翻译：用于生产燃料基地的生物可再生原料进料的沸腾床加氢转化方法
公开(公告)号：US08877993B2
公开(公告)日：2014-11-04
申请号：US12282910
申请日：2008-07-18
申请人： Thierry Chapus , Alain Quignard , Nathalie Dupassieux , Antoine Daudin
发明人： Thierry Chapus , Alain Quignard , Nathalie Dupassieux , Antoine Daudin
IPC分类号： C10G3/00 , C10G49/04 , C10G49/12
CPC分类号： C10G49/04 , C10G3/46 , C10G3/48 , C10G3/50 , C10G3/56 , C10G49/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/301 , C10G2300/4018 , C10G2400/06 , C10G2400/08 , Y02P30/20
摘要： The invention concerns a process for hydrotreatment and/or hydroconversion of a feed of bio-renewable origin containing triglyceride and/or fatty acid structures and wherein the fatty chains contain in the range 8 to 25 carbon atoms, said process comprising the following steps: a) hydrotreatment and/or hydroconversion of said bio-renewable feed in an ebullated bed reactor in the presence of a granular catalyst comprising, on an amorphous support, at least one metal or compound of a metal having a hydrodehydrogenating function, to produce a first effluent; b) sending the effluent produced in step a) to a distillation zone from which a gaseous fraction and at least one distillate cut the end point of which is less than 400° C.
摘要翻译：本发明涉及含有甘油三酯和/或脂肪酸结构的生物可再生来源的进料的加氢处理和/或加氢转化的方法，其中所述脂肪链含有8至25个碳原子，所述方法包括以下步骤：）在颗粒催化剂存在下在沸腾床反应器中加氢处理和/或加氢转化所述生物可再生进料，所述颗粒催化剂在无定形载体上包含至少一种具有脱氢功能的金属的金属或化合物，以产生第一流出物 ; b）将步骤a）中产生的流出物送到蒸馏区，蒸馏区中气态馏分和至少一个馏分切断其终点小于400℃。

10. 发明申请

US20120216450A1 METHOD OF CONVERTING FEEDS FROM RENEWABLE SOURCES IN CO-PROCESSING WITH A PETROLEUM FEED USING A CATALYST BASED ON NICKEL AND MOLYBDENUM 审中-公开
标题翻译：使用基于镍和钼的催化剂与石油进料共同加工的可再生来源转化进料的方法
公开(公告)号：US20120216450A1
公开(公告)日：2012-08-30
申请号：US13393050
申请日：2010-07-27
申请人： Nathalie Dupassieux , Antoine Daudin , Thierry Chapus
发明人： Nathalie Dupassieux , Antoine Daudin , Thierry Chapus
IPC分类号： C10L1/00
CPC分类号： B01J23/88 , C10G3/44 , C10G3/46 , C10G3/48 , C10G3/50 , C10G3/54 , C10G45/04 , C10G45/08 , C10G45/50 , C10G65/04 , C10G65/08 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10L1/04 , Y02P30/20
摘要： The invention relates to a method of hydrotreatment in co-processing of petroleum feeds, in a mixture with at least one feed obtained from renewable sources, for producing fuel bases (kerosene and/or gas oil) having a sulphur content below 10 ppm, said method comprising the following stages: a) a first hydrotreatment stage in which said feed passes through at least one first fixed-bed catalytic zone comprising at least one bulk or supported catalyst comprising an active phase constituted by at least one group VIB element and at least one group VIII element, said elements being in the form of sulphide and the atomic ratio of the group VIII metal (or metals) to group VIB metal (or metals) being strictly greater than 0 and less than 0.095, b) a second hydrotreatment stage into which the effluent from the first hydrotreatment stage is sent directly, and in which said effluent passes through at least one second fixed-bed catalytic zone comprising at least one hydrotreatment catalyst.
摘要翻译：本发明涉及一种在与至少一种从可再生来源获得的进料的混合物中与石油进料共同加工中加氢处理的方法，用于生产具有低于10ppm的硫含量的燃料基质（煤油和/或瓦斯油），所述方法包括以下阶段：a）第一加氢处理阶段，其中所述进料通过至少一个第一固定床催化区，所述至少一个第一固定床催化区包含至少一个本体或负载型催化剂，其包含由至少一组VIB元素构成的活性相和至少一种VIII族元素，所述元素为硫化物形式，Ⅷ族金属（或金属）与VIB族金属（或金属）的原子比严格大于0且小于0.095，b）第二加氢处理阶段来自第一加氢处理阶段的流出物直接送入其中，并且其中所述流出物通过包含至少一种加氢处理催化剂的至少一个第二固定床催化区。

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