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1. 发明授权

US5179180A Process for the gas-phase homo- or copolymerization of alpha-olefin with a pretreated catalyst system 失效
标题翻译： α-烯烃与预处理催化剂体系气相均聚或共聚的方法
公开(公告)号：US5179180A
公开(公告)日：1993-01-12
申请号：US429025
申请日：1989-10-30
申请人： Antero Ahvenainen , Hannu Salminen , Jari Tervonen , Tarja Soderberg
发明人： Antero Ahvenainen , Hannu Salminen , Jari Tervonen , Tarja Soderberg
IPC分类号： C08F4/62 , C08F2/34 , C08F4/60 , C08F4/646 , C08F4/654 , C08F10/00 , C08F10/04 , C08F110/06 , C08F110/08
CPC分类号： C08F10/04 , C08F10/00 , C08F110/06 , C08F110/08 , Y10S526/901 , Y10S526/904 , Y10S526/907
摘要： The polymerization of certain alpha-olefins in a gas phase involves the problem of agglomeration of the product into particles disadvantageous from the viewpoint of its handling. In the present invention this problem has been solved by means of a new type of process for the homo- or copolymerization of alpha-olefins. In the process the catalyst system is pretreated by contacting and reacting a transition-metal compound which is solid or on a solid carrier with an organoaluminum compound, and possibly an electron donor, in a liquid medium, and by drying the thus formed reaction product to produce a solid catalyst system. The thus pretreated solid and active catalyst system is then fed together with an alpha-olefin in the gaseous state into a gas-phase reactor, and polymerization is carried out by contacting them with each other. By feeding a dry and active catalyst system into the gas-phase reactor, it is possible to avoid the agglomeration of the product which occurs in conventional processes in which an organoaluminum compound and possibly an electron donor are fed in a liquid medium into the reactor.
摘要翻译：在气相中某些α-烯烃的聚合涉及从其处理的观点来看，不利于产物聚集成颗粒的问题。在本发明中，这个问题已经通过用于α-烯烃均聚或共聚的新型方法来解决。在该方法中，催化剂体系通过在液体介质中使固体或固体载体上的过渡金属化合物与有机铝化合物和可能的电子给体接触并使其反应，并将由此形成的反应产物干燥产生固体催化剂体系。然后将如此预处理的固体和活性催化剂体系与气态的α-烯烃一起进料到气相反应器中，并通过使它们彼此接触进行聚合。通过将干燥和活性的催化剂体系进料到气相反应器中，可以避免在有机铝化合物和可能的电子给体在液体介质中进料到反应器中的常规方法中发生的产物的聚集。

2. 发明授权

US06291590B1 Extrusion coating structure 有权
标题翻译：挤出涂层结构
公开(公告)号：US06291590B1
公开(公告)日：2001-09-18
申请号：US09341426
申请日：1999-09-07
申请人： Markku Sainio , Erkki Laiho , Martti Vähälä , Hannu Salminen
发明人： Markku Sainio , Erkki Laiho , Martti Vähälä , Hannu Salminen
IPC分类号： C08L2308
CPC分类号： B32B27/10 , B32B15/085 , B32B15/20 , B32B27/08 , B32B27/32 , B32B2311/24 , B32B2317/12 , B32B2323/04 , C08L23/0815 , C08L2205/02 , Y10T428/31725 , Y10T428/31743 , Y10T428/31746 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855 , Y10T428/3188 , Y10T428/31895 , Y10T428/31971 , Y10T428/31982 , Y10T428/31993 , C08L2666/04
摘要： Extrusion coating structure in which at least one layer is made of a polymer composition comprising a multimodal ethylene polymer, which contains from 80 to 100% by weight of ethylene repeating u nits and from 0 to 20% by weight of C3-C10 alpha-olefin repeating units, has a density of between 0.920 and 0.960 kg/m3, and which is a blend of at least two different ethylene polymers.
摘要翻译：挤压涂层结构，其中至少一层由包含多元乙烯聚合物的聚合物组合物制成，所述多峰乙烯聚合物含有80-100重量％的乙烯重复单元和0-20重量％的C 3 -C 10α-烯烃重复单元的密度为0.920至0.960kg / m 3，并且是至少两种不同乙烯聚合物的共混物。

3. 发明授权

US07048882B2 Process for producing a polyethylene coating on a substrate 有权
标题翻译：在基材上生产聚乙烯涂层的方法
公开(公告)号：US07048882B2
公开(公告)日：2006-05-23
申请号：US10204321
申请日：2001-02-19
申请人： Martti Vähälä , Hannu Salminen , Arja Lehtinen
发明人： Martti Vähälä , Hannu Salminen , Arja Lehtinen
IPC分类号： B28B3/20 , C08F8/00 , C08F2/00 , B32B27/10
CPC分类号： C08F297/083 , B29C47/0021 , B29C47/02 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F10/02 , C08F210/16 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/06 , Y10T428/31895 , Y10T428/31931 , Y10T428/31938 , C08F4/65916 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F2500/05 , C08F2500/13 , C08F2500/26
摘要： This invention concerns a process for coating a substrate, and an extrusion coating structure. According to the present process, the coating is provided by producing a bimodal polyethylene composition by subjecting ethylene, optionally with hydrogen and/or comonomers to polymerization or copolymerization reactions in a multistage polymerization sequence of successive polymerization stages. The polymerization reactions are carried out in the presence of a single site catalyst capable of forming a composition which comprises a low molecular weight component with an MFR2 of 20 g/10 min or more and a density higher than the density of the composition, and a high molecular weight component, said composition having a melt flow rate MFR2 of 5 g/10 min or more and a density of 915–960 kg/m3. The composition is extruded on the substrate as such or by adding 10 wt-% or less, calculated from the total weight of the coating, of high pressure PE-LD by blending into the extrusion composition or by coextrusion.
摘要翻译：本发明涉及一种涂覆基材和挤出涂布结构的方法。根据本发明的方法，通过在连续聚合阶段的多级聚合顺序中使乙烯（任选地与氢和/或共聚单体）进行聚合或共聚反应来制备双峰聚乙烯组合物来提供涂层。聚合反应在能够形成组合物的单中心催化剂的存在下进行，所述组合物包含20分钟/ 10分钟以上的MFR 2的低分子量组分，密度高于所述组合物的密度和高分子量组分，所述组合物具有5g / 10min以上的熔体流动速率MFR 2和915-960kg / m 2的密度， 3 。将该组合物原样挤出到基材上，或者通过混合到挤出组合物中或通过共挤出，通过加入由涂层的总重量计算的10重量％或更少的高压PE-LD。

4. 发明授权

US06921799B1 Olefin polymerization process 有权
标题翻译：烯烃聚合工艺
公开(公告)号：US06921799B1
公开(公告)日：2005-07-26
申请号：US09457574
申请日：1999-12-09
申请人： Arild Follestad , Hannu Salminen
发明人： Arild Follestad , Hannu Salminen
IPC分类号： C08F4/60 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/00 , C08F210/16 , G08F2/38
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , Y10S526/901 , Y10S526/905 , Y10S526/943 , C08F4/65925 , C08F2/00 , C08F2/001 , C08F2500/12 , C08F2500/04 , C08F2500/07 , C08F2500/26 , C08F2500/03 , C08F210/14
摘要： The invention relates to a process for the preparation of an olefin polymer comprising at least two polymerization stage in the presence of an olefin polymerization catalyst material, an olefin polymer produced by such process, and the use of such polymers for the production of fibres, pipes, films, moulded products and products for wire and cable applications.
摘要翻译：本发明涉及一种制备烯烃聚合物的方法，其包括在烯烃聚合催化剂材料存在下的至少两个聚合阶段，通过这种方法生产的烯烃聚合物，以及这些聚合物用于生产纤维，管道，电影，模制产品和电线电缆应用产品。

5. 发明授权

US06627706B1 Olefin polymerization process 失效
标题翻译：烯烃聚合工艺
公开(公告)号：US06627706B1
公开(公告)日：2003-09-30
申请号：US09719794
申请日：2001-02-14
申请人： Arild Follestad , Hannu Salminen
发明人： Arild Follestad , Hannu Salminen
IPC分类号： C08F234
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y02P20/582 , Y10S526/901 , Y10S526/905 , Y10S526/943 , C08F2/001 , C08F4/65916 , C08F2/38 , C08F210/14 , C08F2500/12
摘要： This invention relates to a process for the preparation of olefin polymers, preferably a multi-stage process, in which hydrogen is used to control the molecular weight of the olefin polymer produced in a continuous reactor, in particular a process wherein a metallocene or other single site catalyst is present in the polymerization reaction mixture, as well as to olefin polymers produced thereby.
摘要翻译：本发明涉及一种用于制备烯烃聚合物的方法，优选多阶段方法，其中使用氢气来控制在连续反应器中生产的烯烃聚合物的分子量，特别是其中茂金属或其它单体聚合反应混合物中存在现场催化剂，以及由此产生的烯烃聚合物。

6. 发明授权

US5986021A Process for manufacturing LLDPE polymers 失效
标题翻译：制造LLDPE聚合物的方法
公开(公告)号：US5986021A
公开(公告)日：1999-11-16
申请号：US930696
申请日：1998-02-10
申请人： Harri Hokkanen , Hannu Salminen , Kalle Kallio , Hilkka Knuuttila , Ari Palmroos
发明人： Harri Hokkanen , Hannu Salminen , Kalle Kallio , Hilkka Knuuttila , Ari Palmroos
IPC分类号： C08F2/00 , C08F2/06 , C08F2/34 , C08F4/642 , C08F210/00 , C08F210/02 , C08F210/16 , C08G85/00
CPC分类号： C08F210/16 , Y10S526/904 , Y10S526/943
摘要： Process for manufacturing ethylene copolymers by polymerizing ethylene and a minor amount of C.sub.3 -C.sub.6 alphaolefins in particle form in slurry reactor in the presence of an ethylene polymerizing catalyst. According to the invention the polymerization is carried out in propane diluent by using a metallocene catalyst activated with an alumoxane compound.
摘要翻译： PCT No.PCT / FI96 / 00240 Sec。 371日期1998年2月10日 102（e）1998年2月10日PCT 1996年4月30日PCT PCT。第WO96 / 34895号公报日期1996年11月7日在乙烯聚合催化剂存在下，通过在淤浆反应器中聚合乙烯和少量C3-C6α-烯烃制备乙烯共聚物的方法。根据本发明，通过使用由铝氧烷化合物活化的茂金属催化剂在丙烷稀释剂中进行聚合。

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