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1. 发明授权

US08765082B2 Combined carbon dioxide and oxygen process for ethylbenzene dehydrogenation to styrene 失效
标题翻译：乙苯脱氢合成二氧化碳和氧气过程到苯乙烯
公开(公告)号：US08765082B2
公开(公告)日：2014-07-01
申请号：US13567207
申请日：2012-08-06
申请人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
发明人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
IPC分类号： B01J8/02 , C07C5/48
CPC分类号： C01B3/50 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/1252 , C01B2210/0046 , C01B2210/0053 , C07C5/48 , Y02P20/52 , C07C15/46 , C07C11/08 , C07C11/06 , C07C11/04 , C07C11/09 , C07C11/167
摘要： Processes for using a combination of carbon dioxide and oxygen in the dehydrogenation of hydrocarbons are provided. A hydrocarbon feedstock, carbon dioxide and oxygen are fed to an oxidative dehydrogenation reactor system containing one or more catalysts that promote dehydrogenation of the hydrocarbon feedstock to produce a dehydrogenated hydrocarbon product. The processes of the present invention may be used, for example, to produce styrene monomer by dehydrogenation of ethylbenzene using carbon dioxide and oxygen as oxidants.
摘要翻译：提供了在烃的脱氢中使用二氧化碳和氧气的组合的方法。将烃原料，二氧化碳和氧气进料到含有促进烃原料脱氢以产生脱氢烃产物的一种或多种催化剂的氧化脱氢反应器系统中。本发明的方法可以用于例如使用二氧化碳和氧气作为氧化剂使乙苯脱氢生产苯乙烯单体。

2. 发明授权

US07718568B2 Hydrothermally synthesized Mo-V-M-Nb-X oxide catalysts for the selective oxidation of hydrocarbons 失效
标题翻译：用于烃选择性氧化的水热合成Mo-V-M-Nb-X氧化物催化剂
公开(公告)号：US07718568B2
公开(公告)日：2010-05-18
申请号：US11389940
申请日：2006-03-27
申请人： Anne Mae Gaffney , Ruozhi Song
发明人： Anne Mae Gaffney , Ruozhi Song
IPC分类号： B01J23/24
CPC分类号： C07C51/215 , B01J23/002 , B01J23/02 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/14 , B01J23/20 , B01J23/24 , B01J23/28 , B01J23/34 , B01J23/64 , B01J23/6525 , B01J23/8877 , B01J27/0576 , B01J27/132 , B01J35/002 , B01J37/06 , B01J37/10 , B01J37/22 , B01J2523/00 , C07C253/24 , C07C253/26 , Y02P20/52 , C07C57/04 , B01J2523/44 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/67 , B01J2523/13 , B01J2523/3706 , B01J2523/845 , B01J2523/822 , B01J2523/842 , B01J2523/22 , B01J2523/33 , B01J2523/3737 , B01J2523/828 , B01J2523/824 , B01J2523/70 , B01J2523/72 , B01J2523/27 , B01J2523/11 , B01J2523/23 , B01J2523/847 , C07C255/08
摘要： Hydrothermally synthesized catalysts comprising a mixed metal oxide are utilized to produce unsaturated carboxylic acids by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, in the presence thereof; or to produce unsaturated nitrites by the vapor phase oxidation of an alkane, or a mixture of an alkane and an alkene, and ammonia in the presence thereof.
摘要翻译：包含混合金属氧化物的水热合成催化剂用于在存在下通过烷烃或烷烃和烯烃的混合物的气相氧化制备不饱和羧酸; 或通过烷烃或烷烃和烯烃的混合物以及氨的气相氧化产生不饱和腈。

3. 发明授权

US07304014B2 Modified catalysts and process 有权
标题翻译：改性催化剂和工艺
公开(公告)号：US07304014B2
公开(公告)日：2007-12-04
申请号：US11071137
申请日：2005-03-03
申请人： Fernando Antonio Pessoa Cavalcanti , Sanjay Chaturvedi , Anne Mae Gaffney , Scott Han , Ruozhi Song , Elsie Mae Vickery
发明人： Fernando Antonio Pessoa Cavalcanti , Sanjay Chaturvedi , Anne Mae Gaffney , Scott Han , Ruozhi Song , Elsie Mae Vickery
IPC分类号： B01J23/00 , B01J23/02 , B01J23/06
CPC分类号： B01J23/002 , B01J23/28 , B01J23/6484 , B01J23/6525 , B01J27/0576 , B01J35/0006 , B01J37/0036 , B01J37/0203 , B01J37/0236 , B01J37/06 , B01J37/34 , B01J2523/00 , C07C51/215 , C07C51/252 , Y02P20/582 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/824
摘要： Modified metal oxide catalysts are disclosed which have different chemical, physical and catalytic properties, when used for catalytic conversions of carbon based compounds, as compared to corresponding unmodified metal oxide catalysts. Methods for preparing the modified catalysts are described and their utility in catalytic process is described. Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared directly from corresponding alkanes, alkenes or alkanes and alkenes utilizing using one or more modified metal oxide catalysts.
摘要翻译：公开了当与相应的未改性的金属氧化物催化剂相比时，当用于碳基化合物的催化转化时，其具有不同的化学，物理和催化性质的改性金属氧化物催化剂。描述了制备改性催化剂的方法，并描述了它们在催化过程中的应用。使用一种或多种改性金属氧化物催化剂，直接从相应的烷烃，烯烃或烷烃和烯烃制备烯烃，不饱和饱和羧酸，饱和羧酸及其较高类似物。

4. 发明授权

US06407031B1 Promoted multi-metal oxide catalyst 失效
公开(公告)号：US06407031B1
公开(公告)日：2002-06-18
申请号：US09928030
申请日：2001-08-11
申请人： Sanjay Chaturvedi , Anne Mae Gaffney , Scott Han , Michele Doreen Heffner , Ruozhi Song
发明人： Sanjay Chaturvedi , Anne Mae Gaffney , Scott Han , Michele Doreen Heffner , Ruozhi Song
IPC分类号： B01J2322
CPC分类号： B01J23/002 , B01J23/22 , B01J23/28 , B01J27/0576 , B01J2523/00 , C07C51/215 , C07C51/252 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08 , B01J2523/3756 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/36 , B01J2523/35
摘要： A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.

5. 发明申请

US20120294776A1 Combined Carbon Dioxide and Oxygen Process for Ethylbenzene Dehydrogenation to Styrene 失效
标题翻译：用于乙苯脱氢至苯乙烯的二氧化碳和氧气的合成方法
公开(公告)号：US20120294776A1
公开(公告)日：2012-11-22
申请号：US13567207
申请日：2012-08-06
申请人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
发明人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
IPC分类号： B01J19/00
CPC分类号： C01B3/50 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/1252 , C01B2210/0046 , C01B2210/0053 , C07C5/48 , Y02P20/52 , C07C15/46 , C07C11/08 , C07C11/06 , C07C11/04 , C07C11/09 , C07C11/167
摘要： Processes for using a combination of carbon dioxide and oxygen in the dehydrogenation of hydrocarbons are provided. A hydrocarbon feedstock, carbon dioxide and oxygen are fed to an oxidative dehydrogenation reactor system containing one or more catalysts that promote dehydrogenation of the hydrocarbon feedstock to produce a dehydrogenated hydrocarbon product. The processes of the present invention may be used, for example, to produce styrene monomer by dehydrogenation of ethylbenzene using carbon dioxide and oxygen as oxidants.
摘要翻译：提供了在烃的脱氢中使用二氧化碳和氧气的组合的方法。将烃原料，二氧化碳和氧气进料到含有促进烃原料脱氢以产生脱氢烃产物的一种或多种催化剂的氧化脱氢反应器系统中。本发明的方法可以用于例如使用二氧化碳和氧气作为氧化剂使乙苯脱氢生产苯乙烯单体。

6. 发明授权

US08237000B2 Combined carbon dioxide and oxygen process for ethylbenzene dehydrogenation to styrene 失效
标题翻译：乙苯脱氢合成二氧化碳和氧气过程到苯乙烯
公开(公告)号：US08237000B2
公开(公告)日：2012-08-07
申请号：US12142738
申请日：2008-06-19
申请人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
发明人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
IPC分类号： C07C5/48
CPC分类号： C01B3/50 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/1252 , C01B2210/0046 , C01B2210/0053 , C07C5/48 , Y02P20/52 , C07C15/46 , C07C11/08 , C07C11/06 , C07C11/04 , C07C11/09 , C07C11/167
摘要： Processes for using a combination of carbon dioxide and oxygen in the dehydrogenation of hydrocarbons are provided. A hydrocarbon feedstock, carbon dioxide and oxygen are fed to an oxidative dehydrogenation reactor system containing one or more catalysts that promote dehydrogenation of the hydrocarbon feedstock to produce a dehydrogenated hydrocarbon product. The processes of the present invention may be used, for example, to produce styrene monomer by dehydrogenation of ethylbenzene using carbon dioxide and oxygen as oxidants.
摘要翻译：提供了在烃的脱氢中使用二氧化碳和氧气的组合的方法。将烃原料，二氧化碳和氧气进料到含有促进烃原料脱氢以产生脱氢烃产物的一种或多种催化剂的氧化脱氢反应器系统中。本发明的方法可以用于例如使用二氧化碳和氧气作为氧化剂使乙苯脱氢生产苯乙烯单体。

7. 发明申请

US20100256432A1 PROCESS FOR PRODUCING ETHYLENE VIA OXIDATIVE DEHYDROGENATION (ODH) OF ETHANE 有权
标题翻译：通过乙醛氧化脱氢（ODH）生产乙烯的方法
公开(公告)号：US20100256432A1
公开(公告)日：2010-10-07
申请号：US12417523
申请日：2009-04-02
申请人： Stephen Craig Arnold , Anne Mae Gaffney , Ruozhi Song , Chuen Yuan Yeh
发明人： Stephen Craig Arnold , Anne Mae Gaffney , Ruozhi Song , Chuen Yuan Yeh
IPC分类号： C07C5/333
CPC分类号： C07C5/48 , C07C2523/652 , Y02P20/52 , C07C11/04
摘要： A process for the oxidative dehydrogenation of ethane is disclosed. The process may include: contacting an ethane feed and an oxygen-containing gas in the presence of an oxidative dehydrogenation catalyst in an oxidative dehydrogenation reaction zone under conditions to oxidatively dehydrogenate at least a portion of the ethane to produce a product stream comprising ethylene, carbon oxides, water, and unreacted oxygen and ethane, wherein an oxygen concentration in the product stream is at least 0.1 mol %; contacting the product stream with an oxygen elimination catalyst in an oxygen elimination reaction zone to combust at least a portion of the oxygen; recovering from the oxygen elimination reaction zone an effluent having a reduced oxygen content; separating water from the effluent; separating carbon oxides and any non-condensable gas(es) from the ethylene and the unreacted ethane; and separating the ethylene from the unreacted ethane.
摘要翻译：公开了一种乙烷氧化脱氢方法。该方法可以包括：在氧化脱氢反应区中在氧化脱氢反应区存在下使乙烷进料和含氧气体接触，以使至少部分乙烷氧化脱氢以产生包含乙烯，碳氧化物，水和未反应的氧和乙烷，其中产物流中的氧浓度为至少0.1mol％; 使产物流与消氧反应区中的消除氧化催化剂接触以燃烧至少一部分氧; 从氧消除反应区回收具有降低的氧含量的流出物; 从流出物中分离水; 从乙烯和未反应的乙烷中分离碳氧化物和任何不可冷凝气体; 并将乙烯与未反应的乙烷分离。

8. 发明申请

US20100255985A1 PROCESS FOR MAKING CATALYSTS USEFUL FOR THE CONVERSION OF PARAFFINS TO OLEFINS 有权
标题翻译：制备催化剂用于将烯烃转化成烯烃的方法
公开(公告)号：US20100255985A1
公开(公告)日：2010-10-07
申请号：US12417488
申请日：2009-04-02
申请人： Anne Mae Gaffney , Ruma Ghosh , Ruozhi Song , Chuen Yuan Yeh , Tadeusz Langner
发明人： Anne Mae Gaffney , Ruma Ghosh , Ruozhi Song , Chuen Yuan Yeh , Tadeusz Langner
IPC分类号： B01J23/28 , B01J23/22
CPC分类号： B01J37/0036 , B01J23/002 , B01J23/28 , B01J23/8877 , B01J27/0576 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/036 , B01J37/06 , B01J2523/00 , C07C5/48 , C07C2521/02 , C07C2523/08 , C07C2523/18 , C07C2523/20 , C07C2523/22 , C07C2523/28 , C07C2523/30 , C07C2523/44 , C07C2523/755 , C07C2527/057 , Y02P20/52 , C07C11/04 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/847 , B01J2523/23
摘要： A process for forming a catalyst useful for the production of an olefin from a hydrocarbon is disclosed. The process may include: admixing at least one of elemental metals and compounds to form a multi-metal composition comprising Mo, V, Nb, Te and at least one of Ni and Sb; adjusting the pH of the multi-metal composition by adding nitric acid; drying the acidified multi-metal composition; calcining the dried multi-metal composition; and grinding the calcined multi-metal composition. The ground multi-metal composition may then be sized or shaped to form a mixed metal oxide catalyst. Alternatively, the ground multi-metal composition may be treated with an acid, optionally annealed, and sized or shaped to form a mixed metal oxide catalyst.
摘要翻译：公开了一种形成可用于从烃生产烯烃的催化剂的方法。该方法可以包括：将至少一种元素金属和化合物混合以形成包含Mo，V，Nb，Te和Ni和Sb中的至少一种的多金属组合物; 通过加入硝酸调节多金属组合物的pH值; 干燥酸化多金属组合物; 煅烧干燥的多金属组合物; 并研磨煅烧的多金属组合物。然后可以将研磨的多金属组合物的尺寸或成形尺寸形成混合的金属氧化物催化剂。或者，研磨的多金属组合物可以用酸处理，任选地退火，并且尺寸或成形形成混合的金属氧化物催化剂。

9. 发明申请

US20090318743A1 COMBINED CARBON DIOXIDE AND OXYGEN PROCESS FOR ETHYLBENZENE DEHYDROGENATION TO STYRENE 失效
标题翻译：联苯二氧化碳和氧化乙烯脱氢工艺用于苯乙烯
公开(公告)号：US20090318743A1
公开(公告)日：2009-12-24
申请号：US12142738
申请日：2008-06-19
申请人： STEPHEN C. ARNOLD , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
发明人： STEPHEN C. ARNOLD , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
IPC分类号： C07C5/327
CPC分类号： C01B3/50 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/1252 , C01B2210/0046 , C01B2210/0053 , C07C5/48 , Y02P20/52 , C07C15/46 , C07C11/08 , C07C11/06 , C07C11/04 , C07C11/09 , C07C11/167
摘要： Processes for using a combination of carbon dioxide and oxygen in the dehydrogenation of hydrocarbons are provided. A hydrocarbon feedstock, carbon dioxide and oxygen are fed to an oxidative dehydrogenation reactor system containing one or more catalysts that promote dehydrogenation of the hydrocarbon feedstock to produce a dehydrogenated hydrocarbon product. The processes of the present invention may be used, for example, to produce styrene monomer by dehydrogenation of ethylbenzene using carbon dioxide and oxygen as oxidants.
摘要翻译：提供了在烃的脱氢中使用二氧化碳和氧气的组合的方法。将烃原料，二氧化碳和氧气进料到含有促进烃原料脱氢以产生脱氢烃产物的一种或多种催化剂的氧化脱氢反应器系统中。本发明的方法可以用于例如使用二氧化碳和氧气作为氧化剂使乙苯脱氢生产苯乙烯单体。

10. 发明授权

US06943135B2 NOx treated mixed metal oxide catalyst 有权
公开(公告)号：US06943135B2
公开(公告)日：2005-09-13
申请号：US10731523
申请日：2003-12-09
申请人： Anne Mae Gaffney , Michele Doreen Heffner , Ruozhi Song
发明人： Anne Mae Gaffney , Michele Doreen Heffner , Ruozhi Song
IPC分类号： B01J23/00 , B01J23/20 , B01J23/28 , B01J23/652 , B01J27/057 , B01J35/00 , B01J37/08 , C07C51/215 , C07C51/25 , C07C253/24 , C07C255/08
CPC分类号： C07C51/252 , B01J23/002 , B01J23/20 , B01J23/28 , B01J23/6525 , B01J27/0576 , B01J35/002 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C253/24 , Y02P20/52 , C07C57/03 , C07C255/08 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/824 , C07C57/04
摘要： An improved catalyst comprising a mixed metal oxide, either promoted or not, is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.

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