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    • 5. 发明申请
    • Annealed and promoted catalyst
    • 退火和促进催化剂
    • US20080103331A1
    • 2008-05-01
    • US12002821
    • 2007-12-19
    • Anne GaffneyMichele HeffnerRuozhi Song
    • Anne GaffneyMichele HeffnerRuozhi Song
    • C07C29/00
    • C07C51/215C07C51/252C07C57/04
    • A mixed metal oxide, which may be an orthorhombic phase material, is improved as a catalyst for the production of unsaturated carboxylic acids, or unsaturated nitrites, from alkanes, or mixtures of alkanes and alkenes, by: contacting with a liquid contact member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; recovering insoluble material from the contact mixture; calcining the recovered insoluble material in a non-oxidizing atmosphere; admixing the calcined recovered insoluble material with (i) at least one promoter element or compound thereof and (ii) at least one solvent for the at least one promoter element or compound thereof; removing the at least one solvent to form a catalyst precursor; and calcining the catalyst precursor.
    • 可以是斜方相材料的混合金属氧化物作为用于从烷烃或烷烃和烯烃的混合物生产不饱和羧酸或不饱和亚硝酸盐的催化剂,通过以下方式改进:与选自 由有机酸,醇,无机酸和过氧化氢组成的组合形成接触混合物; 从接触混合物中回收不溶物质; 在非氧化性气氛中煅烧回收的不溶物; 将煅烧回收的不溶物与(i)至少一种助催化剂元件或其化合物和(ii)至少一种用于至少一种助催化剂元件或其化合物的溶剂混合; 除去所述至少一种溶剂以形成催化剂前体; 并煅烧催化剂前体。