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1. 发明申请

US20120308727A1 CLEANER COMPOSITION FOR FORMED METAL ARTICLES 有权
标题翻译：用于形成金属制品的清洁剂组合物
公开(公告)号：US20120308727A1
公开(公告)日：2012-12-06
申请号：US13544070
申请日：2012-07-09
申请人： Andrew M. Hatch , Gary Rochfort , Richard D. Banaszak
发明人： Andrew M. Hatch , Gary Rochfort , Richard D. Banaszak
IPC分类号： C23G5/032 , B08B3/08 , B05D3/10 , B08B9/28
CPC分类号： C23G1/125 , B05D3/10 , B08B3/00 , B08B3/02 , B08B3/04 , B08B3/08 , B08B9/00 , B08B9/08 , B08B9/0804 , B08B9/0813 , C11D1/66 , C11D1/72 , C11D17/00 , C23G1/22 , C23G5/032 , Y10T428/12
摘要： The present invention discloses an improved cleaning composition for cleaning metal surfaces such as aluminum and aluminum-containing alloys. The cleaning composition of the present invention comprises water and an ethoxylate of an alcohol having Formula R1—OH wherein R1 is a saturated or unsaturated, straight-chain or branched aliphatic having from 12 to 80 carbon atoms; an inorganic pH adjusting component; and at least one surfactant that is different than the ethoxylate set forth above. The cleaning composition of the present invention also has an average water-break-free percent reduction of less than 50% after 7 days aging of a working composition prepared from the cleaning composition. The present invention also provides a method of cleaning a metal surface with the cleaning composition of the invention.
摘要翻译：本发明公开了一种用于清洁金属表面的改进的清洁组合物，例如铝和含铝合金。本发明的清洁组合物包含水和具有式R1-OH的醇的乙氧基化物，其中R1是具有12至80个碳原子的饱和或不饱和的直链或支链脂族; 无机pH调节组分; 和至少一种不同于上述乙氧基化物的表面活性剂。本发明的清洁组合物在由清洁组合物制备的工作组合物老化7天后，还具有小于50％的平均无水脱水率。本发明还提供了用本发明的清洁组合物清洗金属表面的方法。

2. 发明授权

US09447507B2 Cleaner composition for formed metal articles 有权
标题翻译：成型金属制品的清洁组合物
公开(公告)号：US09447507B2
公开(公告)日：2016-09-20
申请号：US13544070
申请日：2012-07-09
申请人： Andrew M. Hatch , Gary Rochfort , Richard D. Banaszak
发明人： Andrew M. Hatch , Gary Rochfort , Richard D. Banaszak
IPC分类号： B08B3/00 , C23G1/12 , C23G1/22 , C23G5/032 , C11D17/00 , C11D1/72 , C11D1/66 , B08B3/08 , B08B3/04 , B08B3/02 , B08B9/00 , B08B9/08 , B05D3/10
CPC分类号： C23G1/125 , B05D3/10 , B08B3/00 , B08B3/02 , B08B3/04 , B08B3/08 , B08B9/00 , B08B9/08 , B08B9/0804 , B08B9/0813 , C11D1/66 , C11D1/72 , C11D17/00 , C23G1/22 , C23G5/032 , Y10T428/12
摘要： The present invention discloses an improved cleaning composition for cleaning metal surfaces such as aluminum and aluminum-containing alloys. The cleaning composition of the present invention comprises water and an ethoxylate of an alcohol having Formula R1—OH wherein R1 is a saturated or unsaturated, straight-chain or branched aliphatic having from 12 to 80 carbon atoms; an inorganic pH adjusting component; and at least one surfactant that is different than the ethoxylate set forth above. The cleaning composition of the present invention also has an average water-break-free percent reduction of less than 50% after 7 days aging of a working composition prepared from the cleaning composition. The present invention also provides a method of cleaning a metal surface with the cleaning composition of the invention.
摘要翻译：本发明公开了一种用于清洁金属表面的改进的清洁组合物，例如铝和含铝合金。本发明的清洁组合物包含水和具有式R1-OH的醇的乙氧基化物，其中R1是具有12至80个碳原子的饱和或不饱和的直链或支链脂族; 无机pH调节组分; 和至少一种不同于上述乙氧基化物的表面活性剂。本发明的清洁组合物在由清洁组合物制备的工作组合物老化7天后，还具有小于50％的平均无水脱水率。本发明还提供了用本发明的清洁组合物清洗金属表面的方法。

3. 发明授权

US08273695B2 Lubricant and surface conditioner for formed metal surfaces 有权
标题翻译：用于形成金属表面的润滑剂和表面处理剂
公开(公告)号：US08273695B2
公开(公告)日：2012-09-25
申请号：US11348100
申请日：2006-02-06
申请人： Gary L. Rochfort , Richard D. Banaszak , Andrew M. Hatch
发明人： Gary L. Rochfort , Richard D. Banaszak , Andrew M. Hatch
IPC分类号： C10M129/70 , C10M129/16
CPC分类号： C10M173/02 , C10M2201/02 , C10M2209/104 , C10M2209/105 , C10M2209/107 , C10M2209/108 , C10M2209/109 , C10N2230/06 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , C10N2270/02 , C23C22/56 , C23C22/58 , C23C22/83
摘要： Improved lubricant and surface conditioner forming composition containing oxa acids and their methyl esters corresponding to general formula (I): H3C—(CH2)n—CH═CH—(CH2)m—O—(CH2CH2O)x—CH2—C(═O)—OR (I) where each of m, n and x, which may be the same or different, is a positive integer and R represents H or CH3, when dissolved and/or dispersed in water is effective in reducing COF values on substrates that have been contacted with such a lubricant and surface conditioner forming composition and subsequently dried, even when the substrates have been conversion coated and rinsed before any contact with the lubricant and surface conditioner forming composition. Materials according to general formula (I) may be used together with other surfactants, including some constituents of previously known lubricant and surface conditioner forming compositions to provide improvements in COF, waterbreak performance, water drainage and resistance to dry-off of the conditioner.
摘要翻译：改进的润滑剂和表面调理剂形成组合物，其含有对应于通式（I）的含氧酸及其甲酯：H3C-（CH2）n-CH = CH-（CH2）m-O-（CH2CH2O）x-CH2-C（= O）-OR（I）其中可以相同或不同的m，n和x各自为正整数，R表示H或CH 3，当溶解和/或分散在水中时有效降低COF值已经与这种润滑剂和表面调理剂形成组合物接触并随后干燥的基底，即使当在与润滑剂和表面调理剂形成组合物接触之前基底已被转化涂覆和漂洗时。根据通式（I）的材料可以与其它表面活性剂一起使用，包括先前已知的润滑剂和表面调理剂形成组合物的一些组分，以提供COF，防水性能，排水性能和耐干燥剂的改善。

4. 发明授权

US08216992B2 Cleaner composition for formed metal articles 有权
标题翻译：成型金属制品的清洁组合物
公开(公告)号：US08216992B2
公开(公告)日：2012-07-10
申请号：US10763438
申请日：2004-01-23
申请人： Andrew M. Hatch , Gary L. Rochfort , Richard D. Banaszak
发明人： Andrew M. Hatch , Gary L. Rochfort , Richard D. Banaszak
IPC分类号： C11D1/72 , C11D1/66 , C11D3/04
CPC分类号： C23G1/125 , B05D3/10 , B08B3/00 , B08B3/02 , B08B3/04 , B08B3/08 , B08B9/00 , B08B9/08 , B08B9/0804 , B08B9/0813 , C11D1/66 , C11D1/72 , C11D17/00 , C23G1/22 , C23G5/032 , Y10T428/12
摘要： The present invention discloses an improved cleaning composition for cleaning metal surfaces such as aluminum and aluminum-containing alloys. The cleaning composition of the present invention comprises water and an ethoxylate of an alcohol having Formula R1—OH wherein R1 is a saturated or unsaturated, straight-chain or branched aliphatic having from 12 to 80 carbon atoms; an inorganic pH adjusting component; and at least one surfactant that is different than the ethoxylate set forth above. The cleaning composition of the present invention also has an average water-break-free percent reduction of less than 50% after 7 days aging of a working composition prepared from the cleaning composition. The present invention also provides a method of cleaning a metal surface with the cleaning composition of the invention.
摘要翻译：本发明公开了一种用于清洁金属表面的改进的清洁组合物，例如铝和含铝合金。本发明的清洁组合物包含水和具有式R1-OH的醇的乙氧基化物，其中R1是具有12至80个碳原子的饱和或不饱和的直链或支链脂族; 无机pH调节组分; 和至少一种不同于上述乙氧基化物的表面活性剂。本发明的清洁组合物在由清洁组合物制备的工作组合物老化7天后，还具有小于50％的平均无水脱水率。本发明还提供了用本发明的清洁组合物清洗金属表面的方法。

5. 发明授权

US06558480B1 Process and composition for conversion coating with improved heat stability 失效
标题翻译：具有改善热稳定性的转化涂层的工艺和组成
公开(公告)号：US06558480B1
公开(公告)日：2003-05-06
申请号：US09807159
申请日：2001-07-23
申请人： Gary L. Rochfort , Timm L. Kelly , Richard D. Banaszak
发明人： Gary L. Rochfort , Timm L. Kelly , Richard D. Banaszak
IPC分类号： C23C2200
CPC分类号： C23C22/34
摘要： A conversion coating that does not substantially diminish the luster of a metal surface on which it is coated nor impair adhesion to the surface of lacquers and printing inks commonly used on beverage containers may be provided by contacting the metal surface with an aqueous liquid composition comprising water and at least the following components: (A) a component of one or more dissolved transition metal compounds that contain zirconium and may also include titanium, provided that zirconium constitutes more than 30% of the moles of the total moles or zirconium and titanium; (B) a component of at least one dissolved compound that contains inorganically bonded fluorine and is not part of component (A); and (C) a component of dissolved organic polymer molecules.
摘要翻译：可以通过使金属表面与包含水的水性液体组合物接触来提供不会显着降低其上涂覆的金属表面的光泽或损害对表面和通常用于饮料容器上的印刷油墨的表面的转化涂层和至少以下组分：（A）含有锆的一种或多种溶解的过渡金属化合物的组分，并且还可以包括钛，条件是锆占总摩尔数的30％以上或锆和钛; （B）至少一种含有无机结合的氟并且不是组分（A）的一部分的溶解化合物的组分; 和（C）溶解的有机聚合物分子的组分。

6. 发明授权

US5584943A Cleaning and surface conditioning of formed metal surfaces 失效
标题翻译：形成金属表面的清洁和表面处理
公开(公告)号：US5584943A
公开(公告)日：1996-12-17
申请号：US362687
申请日：1994-12-22
申请人： Richard D. Banaszak , Timm L. Kelly , Gary L. Rochfort
发明人： Richard D. Banaszak , Timm L. Kelly , Gary L. Rochfort
IPC分类号： C10M105/22 , C10M105/32 , C10M105/68 , C10M105/74 , C10M107/34 , C10M107/48 , C10M173/02 , C11D3/02 , C11D11/00 , C23C22/34 , C23G1/12 , C10M173/00 , B65D75/00
CPC分类号： C11D3/046 , C10M105/22 , C10M105/32 , C10M105/68 , C10M105/74 , C10M107/34 , C10M107/48 , C10M173/02 , C11D11/0029 , C11D3/02 , C23C22/34 , C23G1/125 , C10M2201/00 , C10M2201/02 , C10M2201/05 , C10M2201/06 , C10M2201/08 , C10M2201/081 , C10M2201/082 , C10M2201/084 , C10M2201/18 , C10M2207/021 , C10M2207/022 , C10M2207/023 , C10M2207/04 , C10M2207/046 , C10M2207/103 , C10M2207/123 , C10M2207/124 , C10M2207/125 , C10M2207/126 , C10M2207/128 , C10M2207/129 , C10M2207/14 , C10M2207/142 , C10M2207/22 , C10M2207/2606 , C10M2207/2623 , C10M2207/2805 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/284 , C10M2207/285 , C10M2207/286 , C10M2207/345 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/04 , C10M2209/06 , C10M2209/062 , C10M2209/082 , C10M2209/084 , C10M2209/086 , C10M2209/1033 , C10M2209/104 , C10M2209/1045 , C10M2209/105 , C10M2209/1055 , C10M2209/106 , C10M2209/1065 , C10M2209/107 , C10M2209/1075 , C10M2209/108 , C10M2209/1085 , C10M2209/109 , C10M2209/1095 , C10M2209/12 , C10M2211/044 , C10M2211/06 , C10M2215/04 , C10M2215/042 , C10M2215/06 , C10M2215/08 , C10M2215/0806 , C10M2215/082 , C10M2215/086 , C10M2215/1006 , C10M2215/12 , C10M2215/122 , C10M2215/204 , C10M2215/26 , C10M2215/28 , C10M2215/285 , C10M2217/00 , C10M2217/02 , C10M2217/04 , C10M2219/04 , C10M2219/042 , C10M2219/044 , C10M2223/02 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/049 , C10M2223/06 , C10M2223/061 , C10M2223/065 , C10M2223/10 , C10M2225/00 , C10M2225/003 , C10M2225/02 , C10M2225/025 , C10M2225/0405 , C10M2227/061 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/40 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02 , C10N2250/121 , C10N2270/00
摘要： A lubricant and surface conditioner for formed metal surfaces, particularly beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. An aqueous composition for forming the conditioner by contact with metal surfaces includes a water-soluble organic material selected from a phosphate ester, alcohol, fatty acid including mono-, di-, tri-, and polyacids; fatty acid derivatives such as salts, hydroxy acids, amides, esters, ethers and derivatives thereof; and mixtures thereof and at least one of the elements selected from zirconium, titanium, cerium, aluminum, iron, tin, vanadium, tantalum, niobium, molybdenum, tungsten, and hafnium in metallic or ionic form. In order to avoid formation of sludge in the aqueous lubricant and surface conditioner forming composition, the composition should contain as little as possible of materials containing phenanthrene rings, such as conventional surfactants made by ethoxylating rosin. In order to assure the minimization of such surfactants in the aqueous lubricant and surface conditioner forming composition, surfactants containing phenanthrene rings should also be avoided or minimized in earlier cleaning stages.
摘要翻译：用于形成的金属表面，特别是饮料容器的润滑剂和表面调节剂降低了所述金属表面的静摩擦系数，并且能够在较低温度下干燥所述金属表面。用于通过与金属表面接触形成护发素的水性组合物包括选自磷酸酯，醇，包括单 - ，二 - ，三 - 和多酸的脂肪酸的水溶性有机材料; 脂肪酸衍生物如盐，羟基酸，酰胺，酯，醚和衍生物; 以及选自锆，钛，铈，铝，铁，锡，钒，钽，铌，钼，钨和铪中的至少一种元素的金属或离子形式。为了避免在水性润滑剂和表面调理剂形成组合物中形成污泥，组合物应尽可能少含有含有菲环的材料，例如通过乙氧基化松香制备的常规表面活性剂。为了确保水性润滑剂和表面调理剂形成组合物中这些表面活性剂的最小化，在早期的清洗阶段中也应避免或最小化含有菲环的表面活性剂。

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