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1. 发明授权

US5631372A Process for the manufacture of 1-substituted-4-fluoro-1,4-diazoniabicyclo[2.] octane salts 失效
标题翻译： 1-取代-4-氟-1,4-二氮杂双环[2.2.2]辛烷盐的制备方法
公开(公告)号：US5631372A
公开(公告)日：1997-05-20
申请号：US642994
申请日：1996-05-06
申请人： Andrew J. Poss , George A. Shia , Dennis M. Lavery
发明人： Andrew J. Poss , George A. Shia , Dennis M. Lavery
IPC分类号： C07D487/08 , C07D247/00 , C07D243/14 , C07D245/04 , C07F9/06
CPC分类号： C07D487/08
摘要： A process for producing 1-substituted-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts having the formula ##STR1## wherein the Z substituent is OH, OR, OC(O)R, SO.sub.3, SO.sub.2 R, NO.sub.2, NO, or PO(OR).sub.2, wherein R is an aryl or C.sub.1 -C.sub.8 alkyl group; n is 0, 1 or 2; each of R.sub.1, R.sub.2, R.sub.3, P.sub.4 and R.sub.5 independently represent hydrogen, C.sub.1 to C.sub.8 alkyl, or aryl 1-substituted-1,4-diazoniabicyclo[2.2.2]octane or 1,4-diazoniabicyclo[2.2.2]octane mono-N-oxide is reacted to attach the Z group and then the result is reacted with molecular fluorine in the presence of a solvent that substantially does not react with fluorine and a fluoride scavenger that results in an X counter ion. These compounds are useful as fluorinating agents for the introduction of fluorine into organic compounds.
摘要翻译：一种制备具有式“IMAGE”的1-取代-4-氟-1,4-二氮鎓双环[2.2.2]辛烷盐的方法，其中Z取代基是OH，OR，OC（O）R，SO 3，SO 2 R，NO 2 ，NO或PO（OR）2，其中R是芳基或C 1 -C 8烷基; n为0,1或2; R1，R2，R3，P4和R5各自独立地表示氢，C1至C8烷基或芳基1-取代-1,4-二氮鎓双环[2.2.2]辛烷或1,4-二氮鎓双环[2.2.2]辛烷单 N-氧化物反应以连接Z基团，然后在基本上不与氟反应的溶剂和导致X抗衡离子的氟化物清除剂的存在下，使分子氟与分子氟反应。这些化合物可用作将氟引入有机化合物中的氟化剂。

2. 发明授权

US5552533A Preparation of (8S)-8-fluoroerythromycins with N-F fluorinating agents 失效
标题翻译：用N-F氟化剂制备（8S）-8-氟尿嘧啶
公开(公告)号：US5552533A
公开(公告)日：1996-09-03
申请号：US305626
申请日：1994-09-14
申请人： Andrew J. Poss , George A. Shia
发明人： Andrew J. Poss , George A. Shia
IPC分类号： C07H17/08 , C07H15/24
CPC分类号： C07H17/08
摘要： (8S)-8-fluoroerythromycins are prepared by reacting 8,9-anhydroerythromycin 6,9-hemiacetals or an N-oxide thereof with a carboxylic acid and an N-F fluorinating agent. The anhydro starting material may be prepared in situ from erythromycins or an N-oxide derivative thereof. The (8S)-8-fluoroerythromycin products are useful antibacterial agents.
摘要翻译：（8S）-8-氟尿嘧啶通过使8,9-脱水红霉素6,9-半缩醛或其N-氧化物与羧酸和N-F氟化剂反应来制备。脱水原料可以从红霉素或其N-氧化物衍生物原位制备。（8S）-8-氟红霉素产品是有用的抗菌剂。

3. 发明授权

US5403957A Method for preparing N-fluorosulfonimides 失效
标题翻译：制备N-氟磺酰亚胺的方法
公开(公告)号：US5403957A
公开(公告)日：1995-04-04
申请号：US963870
申请日：1992-10-20
申请人： William J. Wagner , George A. Shia , Andrew J. Poss
发明人： William J. Wagner , George A. Shia , Andrew J. Poss
IPC分类号： C07D285/14 , C07C303/34 , C07C303/40 , C07C311/48 , C07D285/00 , C07D285/01 , C07C311/15 , C07C311/00 , C07C311/21 , C07D291/04
CPC分类号： C07D285/01 , C07C303/40
摘要： The present invention relates to a process of preparing N-benzenesulfonimides comprising reacting an alkali metal salt of a sulfonimide with fluorine in the presence of water or water/organic solvent mixtures. N-fluorosulfonimides are useful as fluorinating agents. The N-fluorosulfonimides allow the introduction of fluorine into organic compounds under mild conditions.
摘要翻译：本发明涉及一种制备N-苯磺酰亚胺的方法，包括在水或水/有机溶剂混合物的存在下使磺酰亚胺的碱金属盐与氟反应。 N-氟磺酰亚胺可用作氟化剂。 N-氟磺酰亚胺允许在温和条件下将氟引入有机化合物。

4. 发明授权

US08383867B2 Method for producing fluorinated organic compounds 有权
标题翻译：氟化有机化合物的制备方法
公开(公告)号：US08383867B2
公开(公告)日：2013-02-26
申请号：US11592476
申请日：2006-11-03
申请人： Sudip Mukhopadhyay , Haridasan K. Nair , Rajesh K. Dubey , Rajiv R. Singh , George A. Shia
发明人： Sudip Mukhopadhyay , Haridasan K. Nair , Rajesh K. Dubey , Rajiv R. Singh , George A. Shia
IPC分类号： C07C17/25 , C07C19/08 , C07C21/18 , C07C17/00 , C07C23/00 , C07C25/13 , C07C22/00
CPC分类号： C07C17/278 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/10
摘要： Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, F, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a Cl addition agent under conditions effective to produce a compound of formula (I).
摘要翻译：公开了一种制备氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：CF 3 CF n CH m X a-m（I）转化为至少一种式（II）CF 3 CZCHZ（II）化合物。其中每个X独立地为Cl，F，I或Br; 每个Z独立地为H或F; n为1或2; m为1,2或3，条件是当n为1时，m为1或2; a为2或3，a-m≥0。某些实施方案包括在有效产生式（I）化合物的条件下，将氟化C 2烯烃如四氟乙烯与Cl加成剂反应的步骤。

5. 发明授权

US5243080A Method of fluorinating by using N-fluoropyridinium pyridine heptafluorodiborate 失效
标题翻译：使用N-氟吡啶鎓吡啶七氟二硼酸酯进行氟化的方法
公开(公告)号：US5243080A
公开(公告)日：1993-09-07
申请号：US910461
申请日：1992-07-08
申请人： Michael Van Der Puy , David Nalewajek , George A. Shia , William J. Wagner
发明人： Michael Van Der Puy , David Nalewajek , George A. Shia , William J. Wagner
IPC分类号： C07D213/89 , C07F5/02
CPC分类号： C07D213/89 , C07F5/022
摘要： The present invention provides a novel compound represented as ##STR1## The present novel compound is prepared by reacting fluorine with pyridine-boron trifluoride and is useful as a fluorinating agent in the fluorination of organic compounds.
摘要翻译：本发明提供了一种新化合物，其表示为本发明的新化合物，其通过氟与吡啶 - 三氟化硼反应制备，并且可用作有机化合物的氟化中的氟化剂。

6. 发明授权

US4935519A N-fluoropyridinium pyridine heptafluorodiborate 失效
标题翻译： N-氟吡啶鎓吡啶七氟二硼酸酯
公开(公告)号：US4935519A
公开(公告)日：1990-06-19
申请号：US406659
申请日：1989-09-13
申请人： Michael Van Der Puy , David Nalewajek , George A. Shia , William J. Wagner
发明人： Michael Van Der Puy , David Nalewajek , George A. Shia , William J. Wagner
IPC分类号： C07D213/89 , C07F5/02
CPC分类号： C07D213/89 , C07F5/022
摘要： The present invention provides a novel compound represented as ##STR1## The present novel compound is prepared by reacting fluorine with pyridine-boron trifluoride and is useful as a fluorinating agent in the fluorination of organic compounds.
摘要翻译：本发明提供了一种新化合物，其表示为本发明的新化合物，其通过氟与吡啶 - 三氟化硼反应制备，并且可用作有机化合物的氟化中的氟化剂。

7. 发明授权

US4791038A Inhibiting voltage suppression in lithium/fluorinated carbon batteries 失效
标题翻译：抑制锂/氟化碳电池中的电压抑制
公开(公告)号：US4791038A
公开(公告)日：1988-12-13
申请号：US917455
申请日：1986-10-09
申请人： George A. Shia , David Nalewajek , Michael F. Pyszczek
发明人： George A. Shia , David Nalewajek , Michael F. Pyszczek
IPC分类号： H01M4/06 , H01M4/58 , H01M4/583
CPC分类号： H01M4/583 , H01M4/5835
摘要： Voltage suppression is an important problem in the Li/CF.sub.x battery system. The voltage that a Li/CF.sub.x battery will deliver just after the circuit has been closed can be as low as the voltage near the end of battery life. Electronic circuitry powered by Li/CF.sub.x batteries are complicated by the need to design around this problem.The processing of fluorinated carbon (CF.sub.x) to lower the initial voltage suppression is disclosed wherein fluorinated carbon is treated with a Group IA metal-alkyl or -aryl compound. The reaction between these compounds (e.g., n-butyl lithium) and the fluorinated carbon produces a battery grade product which undergoes reduced to almost no suppression of the initial closed circuit voltage.
摘要翻译：电压抑制是Li / CFx电池系统中的一个重要问题。在电路闭合后，Li / CFx电池将传递的电压可能低于电池寿命结束时的电压。由于需要围绕这个问题设计，由Li / CFx电池供电的电子电路很复杂。公开了氟化碳（CFx）降低初始电压抑制的处理，其中用IA族金属 - 烷基或芳基化合物处理氟化碳。这些化合物（例如正丁基锂）和氟化碳之间的反应产生电池级产品，其几乎不会抑制初始闭路电压。

8. 发明授权

US4556618A Battery electrode and method of making 失效
标题翻译：电池电极及其制作方法
公开(公告)号：US4556618A
公开(公告)日：1985-12-03
申请号：US556826
申请日：1983-12-01
申请人： George A. Shia
发明人： George A. Shia
IPC分类号： H01M4/62 , H01M4/06 , H01M4/08 , H01M4/88 , H01M4/58
CPC分类号： H01M4/8875 , H01M4/08 , H01M4/1393 , H01M4/8605 , H01M4/8668 , H01M4/8673 , H01M4/96
摘要： An improvement is provided for the manufacture of perhalogenated polymer, e.g., PTFE, bonded electrodes.The formulation comprises a mixture of an active material is carbon monofluoride (otherwise known as fluorinated graphite or fluorinated carbon or CF.sub.x or (C.sub.2 F).sub.n); a conductive carbon additive, such as acetylene black or graphite; and polytetrafluoroethylene (PTFE).The process comprises high shear mixing to cause the PTFE to fibrillate. The mixture is then wet with a non-polymeric pore-former to make the mixture more pliable and to create micropores in the electrode when the solution is removed by evaporation. The wet mixture is then sequentially suitably formed into a, e.g., extruded, or calendered or pressed to flatten the mixture to a thin sheet and rolled up and folded and pressed out again until a uniform sheet is obtained and the like.The resulting product affords a sheet which is relatively flexible, and stronger and allows a lower PTFE loading than has been obtained with other electrode sheet materials formed with fibrillatable polymers. The higher the PTFE content, the higher the voltage losses for the electrode.
摘要翻译：提供了用于制造全卤化聚合物例如PTFE，键合电极的改进。该制剂包括活性物质的混合物是单氟化碳（另外称为氟化石墨或氟化碳或CF x或（C 2 F）n）; 导电碳添加剂，如乙炔黑或石墨; 和聚四氟乙烯（PTFE）。该方法包括高剪切混合以使PTFE原纤化。然后将混合物用非聚合物成孔剂湿润以使混合物更柔韧，并且当通过蒸发除去溶液时在电极中产生微孔。然后将湿混合物依次适当地形成为例如挤出的或压延的或压制的以使混合物平坦化成薄片，并卷起并折叠并再次压出直到获得均匀的片材等。所得到的产品提供相对柔性的片材，并且比通过可原纤化的聚合物形成的其它电极片材料获得的PTFE负载更低。 PTFE含量越高，电极的电压损失越高。

9. 发明授权

US4765968A Fluorinated carbon composition for use in fabricating a Li/CF.sub.x battery cathode 失效
标题翻译：用于制造Li / CFx电池阴极的氟化碳组合物
公开(公告)号：US4765968A
公开(公告)日：1988-08-23
申请号：US59456
申请日：1987-06-08
申请人： George A. Shia , David J. Friedland
发明人： George A. Shia , David J. Friedland
IPC分类号： H01M4/58 , H01M4/583 , C01B31/00 , H01M4/60
CPC分类号： H01M4/583 , H01M4/5835 , H01M6/16
摘要： A means to eliminate the suppression of the closed circuit voltage of a Li/CF.sub.x battery during the initial part of its discharge is effected by blending an additive CF.sub.x which does not show significant voltage suppression with the (bulk) CF.sub.x that is normally used in fabricating cathodes for such batteries. Blending is used to get a mixture which has substantially minimized voltage suppression and has good capacity.The closed circuit voltage of a Li/CF.sub.x battery during the initial 10% of discharge is known to be lower than the closed circuit voltage during the later stages. This characteristic adversely impacts applications since the voltage at beginning of life is as low as the voltage indicating end of life, complicating design of circuitry to indicate end of life.In the disclosure, the material with no significant voltage suppression discharges preferentially at the beginning of discharge leading to higher voltage and no suppression. The bulk material also discharges to some extent during this early stage of discharge. When the small percentage of coke-based CF.sub.x additive is depleted, the bulk CF.sub.x has discharged to the point that it no longer shows voltage suppression.
摘要翻译：通过将不显示显着电压抑制的添加剂CFx与制造中通常使用的（体积）CFx混合来消除在其初始部分放电期间抑制Li / CF x电池的闭路电压的手段这种电池的阴极。混合用于获得基本上最小化电压抑制并具有良好容量的混合物。在最初的10％放电期间，Li / CFx电池的闭路电压已知低于后期阶段的闭路电压。该特性对应用有不利的影响，因为寿命开始时的电压与指示寿命终止的电压一样低，使电路的设计复杂化，从而表明寿命终止。在本公开中，没有明显的电压抑制的材料在放电开始时优先放电导致更高的电压并且没有抑制。散装材料在放电初期也会有一定程度的放电。当少量的焦炭基CFx添加剂耗尽时，体积CFx已经放电到不再显示电压抑制的程度。

10. 发明授权

US4686161A Method of inhibiting voltage suppression lithium/fluorinated carbon batteries 失效
标题翻译：抑制电压抑制锂/氟化碳电池的方法
公开(公告)号：US4686161A
公开(公告)日：1987-08-11
申请号：US776546
申请日：1985-09-16
申请人： George A. Shia , David J. Friedland
发明人： George A. Shia , David J. Friedland
IPC分类号： H01M4/06 , H01M4/08 , H01M4/58 , H01M10/44
CPC分类号： H01M4/5835
摘要： A means to eliminate the suppression of the closed circuit voltage of a Li/CF.sub.x battery during the initial part of its discharge is effected by blending an additive CF.sub.x which does not show significant voltage suppression with the (bulk) CF.sub.x that is normally used in fabricating cathodes for such batteries. Blending is used to get a mixture which has substantially minimized voltage suppression and has good capacity.The closed circuit voltage of a Li/CF.sub.x battery during the initial 10% of discharge is known to be lower than the closed circuit voltage during the later stages. This characteristic adversely impacts applications since the voltage at beginning of life is as low as the voltage indicating end of life, complicating design of circuitry to indicate end of life.In the disclosure, the material with no significant voltage suppression discharge, preferentially at the beginning of discharge leading to higher voltage and no suppression. The bulk material also discharges to some extent during this early stage of discharge. When the small percentage of coke-based CF.sub.x additive is depleted, the bulk CF.sub.x has discharged to the point that it no longer shows voltage suppression.
摘要翻译：通过将不显示显着电压抑制的添加剂CFx与制造中通常使用的（体积）CFx混合来消除在其初始部分放电期间抑制Li / CF x电池的闭路电压的手段这种电池的阴极。混合用于获得基本上最小化电压抑制并具有良好容量的混合物。在最初的10％放电期间，Li / CFx电池的闭路电压已知低于后期阶段的闭路电压。该特性对应用有不利的影响，因为寿命开始时的电压与指示寿命终止的电压一样低，使电路的设计复杂化，从而表明寿命终止。在本公开中，材料没有明显的电压抑制放电，优先在放电开始时导致较高的电压而不受抑制。散装材料在放电初期也会有一定程度的放电。当少量的焦炭基CFx添加剂耗尽时，体积CFx已经放电到不再显示电压抑制的程度。

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