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    • 4. 发明授权
    • Process for producing sulfones
    • 生产砜的方法
    • US4151050A
    • 1979-04-24
    • US923328
    • 1978-07-10
    • Bertel KasteningDierk Knittel
    • Bertel KasteningDierk Knittel
    • C07D333/72C25B3/00C25B3/04
    • C25B3/04C07D333/72C25B3/00
    • A process for producing sulfones in which sulfur dioxide is electrolytically transformed into SO.sub.2.sup.- ions and caused to react with organic compounds having functional groups replaceable by SO.sub.2.sup.-, in an aprotic organic solvent, to produce the corresponding organosulfone. According to the present improvement a phosphoric acid triester such as phosphoric acid tribenzyl ester, is added to the solvent as an organic compound capable of reacting with halogen ions of a salt, such as tetraalkylammoniumhalogenide or tetraalkylphosphoniumhalogenide, introduced into the solvent as a conductivity-promoting agent.
    • 一种生产砜的方法,其中二氧化硫被电解转化成SO 2 - 离子,并使其与有机化合物反应,所述有机化合物具有在非质子有机溶剂中可被SO 2 - 可置换的官能团,以产生相应的有机砜。 根据目前的改进,将磷酸三酯如磷酸三苄酯作为有机化合物加入到溶剂中,该有机化合物作为导电促进剂引入到溶剂中作为卤素离子的卤素离子,例如四烷基卤化铵或四烷基碘鎓卤化物 代理商