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1. 发明授权

US4985063A 3-aryl-pyrrolidine-2,4-diones 失效
标题翻译： 3-芳基 - 吡咯烷-2,4-二酮
公开(公告)号：US4985063A
公开(公告)日：1991-01-15
申请号：US391227
申请日：1989-08-08
申请人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Klaus Lurssen , Robert R. Schmidt , Hans-Joachim Santel , Benedikt Becker , Klaus Schaller , Wilhelm Stendel
发明人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Klaus Lurssen , Robert R. Schmidt , Hans-Joachim Santel , Benedikt Becker , Klaus Schaller , Wilhelm Stendel
IPC分类号： A01N43/90 , A01N47/06 , A01N53/00 , A61K31/395 , A61K31/40 , A61K31/435 , A61K31/55 , A61P31/04 , C07D207/16 , C07D211/60 , C07D223/06 , C07D471/04 , C07D487/04
CPC分类号： C07D471/04 , A01N43/90 , A01N47/06 , A01N53/00 , C07D207/16 , C07D211/60 , C07D223/06 , C07D487/04
摘要： A 3-aryl-pyrrolidine-2,4-dione (e) derivative of the formula (I) ##STR1## in which X represents alkyl, halogen and alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy and halogenoalkyl,Z represents alkyl, halogen and alkoxy,m represents a number from 1-4,n represents a number from 0-3, R represents hydrogen, ##STR2## or A where A represents a metal cation equivalent or represents an ammonium ion,R.sup.1 represents optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl and optionally substituted cycloalkyl which can be interrupted by hetero atoms, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl andR.sup.2 represents optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl and optionally substituted phenyl,as well as the pure enantiomeric forms of compounds of the formula (I). The compounds of formula (I) are effective as insecticidal, acaricidal, herbicidal and antimycotic agents.
摘要翻译：式（I）的3-芳基 - 吡咯烷-2,4-二酮（e）衍生物其中X代表烷基，卤素和烷氧基，Y代表氢，烷基，卤素，烷氧基和卤代烷基， Z表示烷基，卤素和烷氧基，m表示1-4以上的数，n表示0-3的数，R表示氢，IMA表示A表示金属阳离子当量或表示铵离子，R1表示任选被卤素取代的烷基，烯基，烷氧基烷基，烷硫基烷基，聚烷氧基烷基和可被杂原子间隔的任选取代的环烷基，或表示任选取代的苯基，任选取代的苯基烷基，取代的杂芳基，取代的苯氧基烷基和取代的羟基烷氧基烷基，烷基，环烷基，烯基，烷氧基烷基，聚烷氧基烷基和任选取代的苯基，以及式（I）化合物的纯对映体形式。式（I）的化合物作为杀虫剂，杀螨剂，除草剂和抗真菌剂是有效的。

2. 发明授权

US5091537A Intermediates for preparing 3-aryl-pyrrolidine-2,4-diones 失效
标题翻译：制备3-芳基 - 吡咯烷-2,4-二酮的中间体
公开(公告)号：US5091537A
公开(公告)日：1992-02-25
申请号：US564267
申请日：1990-08-08
申请人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Klaus Lurssen , Robert R. Schmidt , Hans-Joachim Santel , Benedikt Becker , Klaus Schaller , Wilhelm Stendel
发明人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Klaus Lurssen , Robert R. Schmidt , Hans-Joachim Santel , Benedikt Becker , Klaus Schaller , Wilhelm Stendel
IPC分类号： A01N43/90 , A01N47/06 , A01N53/00 , A01N53/04 , C07D207/16 , C07D211/60 , C07D223/06 , C07D471/04 , C07D487/04
CPC分类号： C07D471/04 , A01N43/90 , A01N47/06 , A01N53/00 , C07D207/16 , C07D211/60 , C07D223/06 , C07D487/04
摘要： A 3-aryl-pyrrolidine-2,4-dione (e) derivative of the formula (I) ##STR1## in which X represents alkyl, halogen and alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy and halogenoalkyl,Z represents alkyl, halogen and alkoxy,m represents a number from 1-4,n represents a number from 0-3,R represents hydrogen, ##STR2## or A, where A represents a metal cation equivalent or represents an ammonium ion,R.sup.1 represents optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl and optionally substituted cycloalkyl which can be interrupted by hetero atoms, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl andR.sup.2 represents optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl and optionally substituted phenyl,as well as the pure enantiomeric forms of compounds of the formula (I). The compounds of formula (I) are effective as insecticidal, acaricidal, herbicidal and antimycotic agents.
摘要翻译：式（I）的3-芳基 - 吡咯烷-2,4-二酮（e）衍生物其中X代表烷基，卤素和烷氧基，Y代表氢，烷基，卤素，烷氧基和卤代烷基， Z表示烷基，卤素和烷氧基，m表示1-4的数，n表示0-3的数，R表示氢，A表示金属阳离子当量或表示铵离子，R 1 代表任选取代的苯基烷基，取代的杂芳基，取代的苯氧基烷基和取代的噻唑烷氧基，R 2代表任意卤素取代的烷基，烯基，烷氧基烷基，烷基硫代烷基，聚烷氧基烷基和可被杂原子间隔的任选取代的环烷基，取代的烷基，环烷基，烯基，烷氧基烷基，聚烷氧基烷基和任选取代的苯基，以及式（I）化合物的纯对映体形式。式（I）的化合物作为杀虫剂，杀螨剂，除草剂和抗真菌剂是有效的。

3. 发明授权

US5116836A 3-phenyl-pyrrolidine-2,4-dione derivatives having pesticidal activity 失效
标题翻译：具有杀虫活性的3-苯基 - 吡咯烷-2,4-二酮衍生物
公开(公告)号：US5116836A
公开(公告)日：1992-05-26
申请号：US567872
申请日：1990-08-15
申请人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Benedikt Becker , Wilhelm Stendel , Christoph Erdelen
发明人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Benedikt Becker , Wilhelm Stendel , Christoph Erdelen
IPC分类号： A01N43/90 , A01N47/06 , C07D277/06 , C07D279/06 , C07D279/10 , C07D279/12 , C07D513/04
CPC分类号： C07D513/04 , A01N43/90 , A01N47/06 , C07D277/06 , C07D279/06 , C07D279/10
摘要： Novel 3-aryl-pyrrolidine 2,4-dione derivatives of the formula ##STR1## having pesticidal activity.
摘要翻译：新颖的具有杀虫活性的式（Ⅰ）的3-芳基 - 吡咯烷2,4-二酮衍生物。

4. 发明授权

US4777283A Process for the preparation of alkoxycarbonyl isocyanates 失效
标题翻译：烷氧基羰基异氰酸酯的制备方法
公开(公告)号：US4777283A
公开(公告)日：1988-10-11
申请号：US948215
申请日：1986-12-31
申请人： Andreas Krebs , Hermann Hagemann
发明人： Andreas Krebs , Hermann Hagemann
IPC分类号： C07B61/00 , B01J31/00 , C07C67/00 , C07C239/00 , C07C265/04 , C07C265/16 , C07C269/00 , C07C69/00
CPC分类号： C07C265/04 , C07C265/16
摘要： Alkoxycarbonyl isocyanates are prepared from carbamic acid esters by reacting these with phosgene and adding a catalyst.
摘要翻译：由氨基甲酸酯通过与光气反应并加入催化剂制备烷氧基羰基异氰酸酯。

5. 发明授权

US5142065A 3-aryl-pyrrolidine-2,4-diones 失效
标题翻译： 3-芳基 - 吡咯烷-2,4-二酮
公开(公告)号：US5142065A
公开(公告)日：1992-08-25
申请号：US710411
申请日：1991-06-05
申请人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Klaus Lurssen , Robert R. Schmidt , Hans-Joachim Santel , Benedikt Becker , Klaus Schaller , Wilhelm Stendel
发明人： Reiner Fischer , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Klaus Lurssen , Robert R. Schmidt , Hans-Joachim Santel , Benedikt Becker , Klaus Schaller , Wilhelm Stendel
IPC分类号： A01N43/90 , A01N47/06 , A01N53/00 , C07D207/16 , C07D211/60 , C07D223/06 , C07D471/04 , C07D487/04
CPC分类号： C07D471/04 , A01N43/90 , A01N47/06 , A01N53/00 , C07D207/16 , C07D211/60 , C07D223/06 , C07D487/04
摘要： An acylamino ester of the formula ##STR1## wherein X is C.sub.1-6 alkyl, or halogen,Y is hydrogen, C.sub.1-6 alkyl, halogen, or C.sub.1-3 halogenalkyl,Z is C.sub.1-6 alkyl, or halogen,n is 0 to 3,provided that when n is O,Y is not hydrogen, andR.sup.3 is C.sub.1-6 alkyl.
摘要翻译：其中X是C 1-6烷基或卤素，Y是氢，C 1-6烷基，卤素或C 1-3卤代烷基，Z是C 1-6烷基或卤素，n是0的酰基氨基酯至3，条件是当n为O时，Y不为氢，R 3为C 1-6烷基。

6. 发明授权

US5045560A Pesticidal tautomers of 3-aryl-pyrrolidine-2,4-diones and use thereas 失效
标题翻译： 3-芳基 - 吡咯烷-2,4-二酮的杀虫互变异构体
公开(公告)号：US5045560A
公开(公告)日：1991-09-03
申请号：US460208
申请日：1990-01-02
申请人： Reiner Fischer , Bernd Baasner , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Benedikt Becker , Klaus Schaller , Harry Strang
发明人： Reiner Fischer , Bernd Baasner , Hermann Hagemann , Andreas Krebs , Albrecht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Benedikt Becker , Klaus Schaller , Harry Strang
IPC分类号： A01N43/36 , A01N47/06 , C07D207/38 , C07D405/12
CPC分类号： C07D405/12 , A01N43/36 , A01N47/06 , C07D207/38
摘要： Insecticidal, acaricidal, herbicidal and antimycotic 3-aryl-pyrrolidine-2,4-diones of the formula ##STR1## in which X represents alkyl, halogen or alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl,Z represents alkyl, halogen or alkoxy,n represents a number from 0-3,R represents hydrogen or represents the groups --CO--R.sup.1 or --CO--O--R.sup.2, in whichR.sup.1 represents alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl which can be interrupted by hetero atoms, each of which radicals is optionally substituted by halogen, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl, andR.sup.2 represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or optionally substituted phenyl or cycloalkyl, each of which radicals is optionally substituted by halogen,A represents alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, or cycloalkyl which is optionally interrupted by a hetero atom, each of which radicals is optionally substituted by halogen, or represents arylalkyl which is optionally substituted by halogen, alkyl, halogenoalkyl, alkoxy or nitro,B and C* independently of one another represent hydrogen, alkyl or alkoxyalkyl.
摘要翻译：式（I）的杀虫，杀螨，除草和抗真菌性3-芳基 - 吡咯烷-2,4-二酮其中X代表烷基，卤素或烷氧基，Y代表氢，烷基，卤素，烷氧基或卤代烷基，Z 表示烷基，卤素或烷氧基，n表示0-3的数，R表示氢或表示基团-CO-R1或-CO-O-R2，其中R1表示烷基，烯基，烷氧基烷基，烷硫基烷基，聚烷氧基烷基或环烷基任何取代的苯基，取代的杂芳基，取代的苯氧基烷基或取代的噻唑烷基，或代表任意取代的苯基，任选取代的苯基烷基，取代的杂芳基，取代的苯氧基烷基和取代的硫代氧基烷基，R 2表示烷基，链烯基，烷氧基烷基，聚烷氧基烷基或任选取代的苯基或环烷基，各w 任选被卤素取代的基团，A代表烷基，链烯基，炔基，烷氧基烷基，聚烷氧基烷基，烷硫基烷基或环烷基，任选被杂原子间隔，每个基团任选被卤素取代，或表示任选取代的芳基烷基卤素，烷基，卤代烷基，烷氧基或硝基，B和C *彼此独立地表示氢，烷基或烷氧基烷基。

7. 发明授权

US4865641A Herbicidal new thiazolyl ether and thioether derivatives 失效
标题翻译：除草新的噻唑醚和硫醚衍生物
公开(公告)号：US4865641A
公开(公告)日：1989-09-12
申请号：US166137
申请日：1988-03-09
申请人： Klaus Sasse , Reiner Fischer , Hermann Hagemann , Andreas Krebs , Michael Schwamborn , Hans-Joachim Santel , Robert R. Schmidt , Robert H. Strang
发明人： Klaus Sasse , Reiner Fischer , Hermann Hagemann , Andreas Krebs , Michael Schwamborn , Hans-Joachim Santel , Robert R. Schmidt , Robert H. Strang
IPC分类号： C07D277/20 , A01N43/78 , C07D277/32 , C07D277/34 , C07D277/36 , C07D417/12
CPC分类号： C07D277/36 , A01N43/78 , C07D277/34
摘要： Herbicidally active compounds of the formula ##STR1## in which R.sup.1 represents hydrogen or alkyl,R.sup.2 represents hydrogen or alkyl,with the proviso that R.sup.1 and R.sup.2 do not simultaneously represent hydrogen,X represents oxygen or sulphur,R.sup.3 represents hydrogen, halogen, nitro, amino, cyano, alkyl, halogenoalkyl, alkoxy or halogenoalkoxy,wherein the radicals R.sup.3 can be identical or different,n represents a number from 1-4,U represents oxygen or sulphur,V represents a ##STR2## group, R.sup.4 and R.sup.5 independently of one another repreesnt hydrogen, alkyl, alkoxyalkyl or halogenoalkyl,W represents a radical ##STR3## D represents carbon or silicon, E represents oxygen or sulphur, andR.sup.6 through R.sup.12 can have various meanings.The starting materials wherein -U-V-W together are OH are also new.
摘要翻译： R1代表氢或烷基，R2代表氢或烷基，除了R1和R2不同时代表氢之外，其中R1代表氢或烷基，X代表氧或硫，R3代表氢，卤素，硝基，氨基，氰基，烷基，卤代烷基，烷氧基或卤代烷氧基，其中基团R3可以相同或不同，n表示1-4的数，U表示氧或硫，V表示基团，R4和R5独立地为另一个反应性氢，烷基，烷氧基烷基或卤代烷基，W表示基团，D表示碳或硅，E表示氧或硫，R6至R12可以具有各种含义。其中-U-V-W一起是OH的起始材料也是新的。

8. 发明授权

US08673818B2 C2-phenyl-substituted cyclic ketonols 有权
标题翻译： C2-苯基取代的环酮
公开(公告)号：US08673818B2
公开(公告)日：2014-03-18
申请号：US13455416
申请日：2012-04-25
申请人： Michael Ruther , Hermann Hagemann , Udo Schneider , Markus Dollinger , Peter Dahmen , Ulrike Wachendorff-Neumann , Reiner Fischer , Alan Graff , Thomas Bretschneider , Christoph Erdelen , Mark Wilhelm Drewes , Dieter Feucht , Folker Lieb
发明人： Michael Ruther , Hermann Hagemann , Udo Schneider , Markus Dollinger , Peter Dahmen , Ulrike Wachendorff-Neumann , Reiner Fischer , Alan Graff , Thomas Bretschneider , Christoph Erdelen , Mark Wilhelm Drewes , Dieter Feucht , Folker Lieb
IPC分类号： C07C49/597 , C07C69/003 , A01N35/06 , A01N37/10
CPC分类号： C07D491/10 , A01N43/06 , A01N43/12 , A01N43/16 , A01N43/36 , A01N43/38 , A01N43/90 , A01N47/06 , C07C45/46 , C07C49/657 , C07C49/747 , C07C69/013 , C07C69/612 , C07C69/738 , C07C69/757 , C07C233/51 , C07D207/38 , C07D209/54 , C07D307/94 , C07D309/14 , C07D309/38 , C07F7/081
摘要： The present invention relates to novel C2-phenyl-substituted cyclic ketoenols of the formula in which W is methyl, X is alkyl, alkenyl or alkinyl, Y is hydrogen, methyl, ethyl, i-propyl, alkenyl or alkinyl, and Z is hydrogen, alkyl, alkenyl or alkinyl, with the proviso that at least one of X, Y, or Z represents a chain having at least two carbon atoms and with the further proviso that X is not ethyl when Z is hydrogen and Y is methyl, and CKE represents the group in which B is hydrogen, alkyl or alkoxyalkyl, A and Q1 together are optionally substituted alkanediyl or alkenediyl, Q2 is represents hydrogen or C1-C4-alkyl, and G represents hydrogen or an acyl or acyl-like group, to a plurality of processes for their preparation and to their use as pesticides and herbicides.
摘要翻译：本发明涉及下式的新的C2-苯基取代的环酮酮：其中W是甲基，X是烷基，烯基或炔基，Y是氢，甲基，乙基，异丙基，烯基或炔基，Z是氢烷基，烯基或炔基，条件是X，Y或Z中的至少一个表示具有至少两个碳原子的链，另外条件是当Z是氢且Y是甲基时，X不是乙基，以及 CKE表示其中B为氢，烷基或烷氧基烷基的基团，A和Q1一起为任选取代的烷二基或亚烯基，Q2表示氢或C1-C4-烷基，G表示氢或酰基或酰基类，其制备方法和用作农药和除草剂的多种方法。

9. 发明授权

US08334300B2 C2-phenyl-substituted cyclic ketonols 有权
标题翻译： C2-苯基取代的环酮
公开(公告)号：US08334300B2
公开(公告)日：2012-12-18
申请号：US13071171
申请日：2011-03-24
申请人： Michael Ruther , Hermann Hagemann , Udo Schneider , Markus Dollinger , Peter Dahmen , Ulrike Wachendorff-Neumann , Reiner Fischer , Alan Graff , Thomas Bretschneider , Christophe Erdelen , Mark Wilhelm Drewes , Dieter Feucht , Folker Lieb
发明人： Michael Ruther , Hermann Hagemann , Udo Schneider , Markus Dollinger , Peter Dahmen , Ulrike Wachendorff-Neumann , Reiner Fischer , Alan Graff , Thomas Bretschneider , Christophe Erdelen , Mark Wilhelm Drewes , Dieter Feucht , Folker Lieb
IPC分类号： C07D207/38 , A01N43/36
CPC分类号： C07D491/10 , A01N43/06 , A01N43/12 , A01N43/16 , A01N43/36 , A01N43/38 , A01N43/90 , A01N47/06 , C07C45/46 , C07C49/657 , C07C49/747 , C07C69/013 , C07C69/612 , C07C69/738 , C07C69/757 , C07C233/51 , C07D207/38 , C07D209/54 , C07D307/94 , C07D309/14 , C07D309/38 , C07F7/081
摘要： The present invention relates to novel C2-phenyl-substituted cyclic ketoenols of the formula (I) in which W, X, Y, Z and CKE are as defined in the description, to processes for their preparation and to their use as pesticides and herbicides.
摘要翻译：本发明涉及式（I）的新的C2-苯基取代的环酮酮，其中W，X，Y，Z和CKE如说明书中所定义，其制备方法及其作为农药和除草剂的用途。

10. 发明申请

US20120238450A1 C2-PHENYL-SUBSTITUTED CYCLIC KETONOLS 有权
标题翻译： C2-苯基取代的环状酮
公开(公告)号：US20120238450A1
公开(公告)日：2012-09-20
申请号：US13455416
申请日：2012-04-25
申请人： Michael Ruther , Hermann Hagemann , Udo Schneider , Markus Dollinger , Peter Dahmen , Ulrike Wachendorff-Neumann , Reiner Fischer , Alan Graff , Thomas Bretschneider , Christoph Erdelen , Mark Wilhelm Drewes , Dieter Feucht , Folker Lieb
发明人： Michael Ruther , Hermann Hagemann , Udo Schneider , Markus Dollinger , Peter Dahmen , Ulrike Wachendorff-Neumann , Reiner Fischer , Alan Graff , Thomas Bretschneider , Christoph Erdelen , Mark Wilhelm Drewes , Dieter Feucht , Folker Lieb
IPC分类号： C07C49/597 , A01N35/06 , A01P15/00 , C07C69/003 , C07C45/67 , A01P13/00 , A01N37/10
CPC分类号： C07D491/10 , A01N43/06 , A01N43/12 , A01N43/16 , A01N43/36 , A01N43/38 , A01N43/90 , A01N47/06 , C07C45/46 , C07C49/657 , C07C49/747 , C07C69/013 , C07C69/612 , C07C69/738 , C07C69/757 , C07C233/51 , C07D207/38 , C07D209/54 , C07D307/94 , C07D309/14 , C07D309/38 , C07F7/081
摘要： The present invention relates to novel c2-phenyl-substituted cyclic ketoenols, to a plurality of processes for their preparation and to their use as pesticides as herbicides.
摘要翻译：本发明涉及新的c2-苯基取代的环酮酮，涉及多种制备方法及其作为除草剂杀虫剂的用途。

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