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1. 发明授权

US5206417A Radiation-sensitive, ethylenically unsaturated copolymerizable compounds and their preparation 失效
标题翻译：辐射敏感，烯属不饱和可共聚化合物及其制备方法
公开(公告)号：US5206417A
公开(公告)日：1993-04-27
申请号：US810348
申请日：1991-12-18
申请人： Andreas Boettcher , Gerd Rehmer
发明人： Andreas Boettcher , Gerd Rehmer
IPC分类号： C07C267/00 , C07C271/48 , C08F20/36
CPC分类号： C08F20/36 , C07C267/00 , C07C271/48
摘要： The ethylenically unsaturated organic compounds are of the general formula ##STR1## where R is alkyl, aryl or a radical R.sup.1, and R.sup.1 is a radical ##STR2## where R.sup.2 to R.sup.6 are each H, alkyl, OH, Oalkyl, SH, Salkyl, halogen, N(alkyl).sub.2 or N(alkyl)(aryl), and not less than one but not more than three of the radicals R.sup.2 to R.sup.6 are each a radical ##STR3## where X is alkylene or oxaalkylene, each of 2 to 10 carbon atoms, and Y is H or CH.sub.3. These compounds have particularly high photochemical reactivity in the medium-wavelength to relatively long-wavelength UV range.
摘要翻译：烯属不饱和有机化合物具有通式“IMAGE”，其中R是烷基，芳基或基团R 1，R 1是基团，其中R 2至R 6各自为H，烷基，OH，O烷基，SH，S烷基，卤素，N（烷基）2或N（烷基）（芳基），并且不少于一个但不多于3个基团R 2至R 6各自为基团，其中X为亚烷基或氧杂亚烷基，每个为2至 10个碳原子，Y是H或CH3。这些化合物在中波长到相对较长波长的UV范围内具有特别高的光化学反应性。

2. 发明授权

US5294688A UV-crosslinkable copolymers 失效
标题翻译：紫外线交联共聚物
公开(公告)号：US5294688A
公开(公告)日：1994-03-15
申请号：US974818
申请日：1992-11-16
申请人： Gerd Rehmer , Gerhard Auchter , Andreas Boettcher , Lothar Franz , Helmut Jaeger
发明人： Gerd Rehmer , Gerhard Auchter , Andreas Boettcher , Lothar Franz , Helmut Jaeger
IPC分类号： C08F2/04 , C08F224/00 , C08F226/06 , C08F228/06 , C08F246/00 , C08J3/28
CPC分类号： C08F226/06 , C08F224/00 , C08F228/06 , C08F246/00 , Y10S522/904 , Y10S522/905
摘要： The invention relates to UV-crosslinkable copolymers built up fromA) from 99.5 to 75% by weight of olefinically unsaturated monomers,B) from 0.5 to 25% by weight of unsaturated compounds of the formula I ##STR1## and C) from 0.01 to 10% by weight of copolymerizable, olefinically unsaturated acetophenone and/or benzophenone derivatives containing no phenyl group having a free hydroxyl group in the ortho-position to the carbonyl group, whereX is O, S or NR.sup.1 andR is unsubstituted or substituted C.sub.2 - to C.sub.6 -alkylene, andR.sup.1 is C.sub.1 - to C.sub.8 -alkyl or phenyl.The copolymers according to the invention are suitable, after crosslinking, as coating agents, impregnants or adhesives and in particular as contact adhesives.
摘要翻译：本发明涉及由A）为99.5-75重量％的烯属不饱和单体组成的UV-可交联共聚物，B）0.5-25重量％的式I的不饱和化合物（*化学结构*）和C） 0.01〜10重量％的可与羰基邻位不含苯基的可共聚的烯属不饱和苯乙酮和/或二苯甲酮衍生物，其中X为O，S或NR1，R为未取代的或未取代的取代的C 2 -C 6亚烷基，R 1是C 1 -C 8烷基或苯基。根据本发明的共聚物在交联后适合作为包衣剂，浸渍剂或粘合剂，特别是作为接触粘合剂。

3. 发明授权

US5248805A Radiation-senstive, ethylenically unsaturated, copolymerizable compounds and their preparation 失效
标题翻译：辐射敏感性，烯键式不饱和，可共聚化合物及其制备方法
公开(公告)号：US5248805A
公开(公告)日：1993-09-28
申请号：US841767
申请日：1992-03-02
申请人： Andreas Boettcher , Gerd Rehmer
发明人： Andreas Boettcher , Gerd Rehmer
IPC分类号： C08F2/50 , C08G65/331 , G03F7/027
CPC分类号： C08G65/331 , G03F7/027 , Y10S522/904 , Y10S522/905
摘要： Radiation-sensitive, ethylenically unsaturated compounds and a process for their preparation. The ethylenically unsaturated organic compounds are of the general formula ##STR1## where R is alkyl, aryl or a radical R.sup.1 andR.sup.1 is a radical ##STR2## where R.sup.2 to R.sup.6 are each H, alkyl, OH, OAlkyl, SH, SAlkyl, halogen, N (Alkyl).sub.2 or N (Alkyl) (Aryl) and at least one but not more than three of the radicals R.sup.2 to R.sup.6 is or are a radical ##STR3## where X is alkylene, cycloalkylene, oxaalkylene or arylene, Y is H or CH.sub.3 -- and Z is O or NY.The novel radiation-sensitive ethylenically unsaturated compounds are suitable for the preparation of polymeric radiation-sensitive compounds.
摘要翻译：辐射敏感的烯属不饱和化合物及其制备方法。烯键式不饱和有机化合物具有通式“IMAGE”，其中R是烷基，芳基或基团R 1，R 1是基团，其中R 2至R 6各自为H，烷基，OH，O烷基，SH，烷基，卤素，N（烷基）2或N（烷基）（芳基），并且至少一个但不多于三个基团R 2至R 6为或为基团，其中X为亚烷基，亚环烷基，氧杂亚烷基或亚芳基 Y为H或CH 3 - ，Z为O或NY。新型辐射敏感烯属不饱和化合物适用于制备聚合物辐射敏感化合物。

4. 发明授权

US5389699A (Meth)acrylate copolymer based UV-crosslinkable materials 失效
标题翻译：（甲基）丙烯酸酯共聚物的紫外线交联材料
公开(公告)号：US5389699A
公开(公告)日：1995-02-14
申请号：US88736
申请日：1993-07-08
申请人： Gerd Rehmer , Andreas Boettcher , Michael Portugall
发明人： Gerd Rehmer , Andreas Boettcher , Michael Portugall
IPC分类号： C08F2/46 , C08F220/36 , C08F246/00 , C09D133/14 , C09D157/04 , C09J133/14 , C09J157/04
CPC分类号： C09J157/04 , C08F220/36 , C08F246/00 , C09D133/14 , C09D157/04 , C09J133/14 , Y10S522/904 , Y10S522/905
摘要： UV-crosslinkable materials based on (meth)acrylate copolymers and containing from 0.01 to 10% by weight, based on the copolymer, of copolymerized monomers of the formula I ##STR1## where x is alkyl of 1 to 3 carbon atoms or is phenyl which is unsubstituted or substituted by n Y groups, Y is --H, --CF.sub.3, --O-- alkyl and/or alkyl-COO--, where alkyl in each case is of 1 to 4 carbon atoms, halogen, --CH, --COOH or a non-ortho --OH group, n is from 0 to 4 and Z is a group of the formula ##STR2## where R is H or C.sub.1 -C.sub.4 -alkyl and A is an alkylene, oxaalkylene or polyoxaalkylene radical of 2 to 12 carbon atoms are used as hotmelt adhesives, for coating sheet-like mineral substrates and as surface coatings.
摘要翻译：基于（甲基）丙烯酸酯共聚物的紫外线交联材料，基于共聚物含有0.01至10重量％的式I的共聚单体，其中x是1至3个碳原子的烷基，或是苯基， Y是-H，-CF 3，-O-烷基和/或烷基-COO-，其中每种情况下的烷基具有1至4个碳原子，卤素，-CH，-COOH或非邻位-OH基团，n为0至4，并且Z为下式的基团：其中R为H或C 1 -C 4 - 烷基，A为亚烷基，亚氧基亚烷基或聚氧亚烷基， 2至12个碳原子用作热熔粘合剂，用于涂覆片状矿物基材和表面涂层。

5. 发明授权

US5180756A Agents curable by ultraviolet radiation 失效
标题翻译：可通过紫外线辐射固化的药剂
公开(公告)号：US5180756A
公开(公告)日：1993-01-19
申请号：US505729
申请日：1990-04-06
申请人： Gerd Rehmer , Andreas Boettcher
发明人： Gerd Rehmer , Andreas Boettcher
IPC分类号： C08F2/48 , C08F2/50 , C08F291/00 , C09J4/06
CPC分类号： C09J4/06
摘要： Agents which are curable by ultraviolet radiation are based on a binder formulation of (1) from 99.0 to 20% by weight of a copolymer, (2) from 1.0 to 80% by weight of monoolefinically unsaturated compounds and (3) from 0.0 to 20% by weight of polyolefinically unsaturated compounds. The agents contain copolymers (1) which are obtainable by subjecting a mixture of (A) from 80 to 99.9% by weight of olefinically unsaturated monomers, (B) from 0 to 10% by weight of a copolymerizable olefinically unsaturated photoinitiator and (C) from 0 to 10% by weight of a polymerization-regulating photoinitiator to free radical polymerization, the sum of (B) and (C) being not less than 0.1% by weight and the stated percentages by weight being based on the sum of the weights of (A)+(B)+(C).
摘要翻译：可通过紫外线辐射固化的试剂基于（1）99.0-20％重量的共聚物的粘合剂制剂，（2）1.0至80％重量的单烯属不饱和化合物和（3）0.0至20 重量％的聚烯烃不饱和化合物。这些试剂含有共聚物（1），其可通过使（A）80-99.9重量％的烯属不饱和单体，（B）0-10重量％的可共聚的烯属不饱和光引发剂和（C） 0〜10重量％的聚合调节光引发剂进行自由基聚合时，（B）和（C）之和不小于0.1重量％，所述重量百分比基于重量的总和（A）+（B）+（C）。

6. 发明授权

US5073611A Copolymers crosslinkable by ultraviolet radiation in the atmosphere 失效
标题翻译：通过紫外线辐射在大气中交联的共聚物
公开(公告)号：US5073611A
公开(公告)日：1991-12-17
申请号：US692796
申请日：1991-04-29
申请人： Gerd Rehmer , Andreas Boettcher
发明人： Gerd Rehmer , Andreas Boettcher
IPC分类号： C08L57/00 , C08F2/38 , C08F2/44 , C08F2/48 , C08F246/00 , C08K5/17
CPC分类号： C08F246/00 , Y10S522/904 , Y10S522/905
摘要： Copolymers which are curable by ultraviolet radiation in the air are prepared by a process in which a mixture of (A) from 80 to 99.9% by weight of olefinically unsaturated monomers, (B) from 0 to 10% by weight of a copolymerizable olefinically unsaturated, photoreactive compound which, in the excited state produced by UV radiation, is capable of abstracting hydrogen and (C) from 0 to 10% by weight of a polymerization-regulating photoreactive compound which, in the excited state, is capable of abstracting hydrogen is subjected to free radical polymerization, the sum of (B) and (C) being not less than 0.1% by weight and the stated percentages by weight being based on the sum of the weights of (A)+(B)+(C).
摘要翻译：可通过空气中的紫外线辐射固化的共聚物通过以下方法制备：（A）80-99.9重量％的烯属不饱和单体，（B）0-10重量％的可共聚的烯属不饱和单体，在由UV辐射产生的激发态中能够提取氢的（C）0至10重量％的聚合调节光反应性化合物，其在激发态能够提取氢的光反应性化合物是进行自由基聚合时，（B）和（C）之和不小于0.1重量％，所述重量百分比基于（A）+（B）+（C）的重量之和，。

7. 发明授权

US5264533A Benzophenone derivatives and their preparation 失效
标题翻译：二苯甲酮衍生物及其制备方法
公开(公告)号：US5264533A
公开(公告)日：1993-11-23
申请号：US742163
申请日：1991-08-01
申请人： Gerd Rehmer , Andreas Boettcher , Michael Portugall
发明人： Gerd Rehmer , Andreas Boettcher , Michael Portugall
IPC分类号： C08F2/46 , C08F220/36 , C08F246/00 , C09D133/14 , C09D157/04 , C09J133/14 , C09J157/04 , C08F126/02 , C08F2/50 , C08F226/02 , C08F271/00
CPC分类号： C09J157/04 , C08F220/36 , C08F246/00 , C09D133/14 , C09D157/04 , C09J133/14 , Y10S522/904 , Y10S522/905
摘要： UV-crosslinkable materials based on (meth)acrylate copolymers and containing special modified unsaturated benzophenone derivatives as copolymerized units are used as hotmelt adhesives, for coating sheet-like mineral substrates and as surface coatings.
摘要翻译：使用基于（甲基）丙烯酸酯共聚物并含有特殊改性的不饱和二苯甲酮衍生物作为共聚单元的紫外线交联材料用作热熔粘合剂，用于涂覆片状矿物基材和表面涂层。

8. 发明授权

US5026806A UV-crosslinkable materials based on isoamyl (meth)acrylate copolymers 失效
标题翻译：基于（甲基）丙烯酸异戊酯共聚物的紫外线交联材料
公开(公告)号：US5026806A
公开(公告)日：1991-06-25
申请号：US417698
申请日：1989-10-05
申请人： Gerd Rehmer , Andreas Boettcher , Peter Pfoehler , Oral Aydin , Gerhard Nestler
发明人： Gerd Rehmer , Andreas Boettcher , Peter Pfoehler , Oral Aydin , Gerhard Nestler
IPC分类号： C08J5/18 , C08F220/18 , C08L23/00 , C08L33/04 , C08L33/06 , C09J133/06
CPC分类号： C09J133/062 , C08F220/18 , C09J2201/606
摘要： Materials which are cross-linkable by ultraviolet radiation under atmospheric oxygen and are based on (meth)acrylate copolymers having a K value of from 10 to 100 are obtained by free radical polymerization, in the presence or absence of a solvent, ofa) from 5% to 97.4% by weight of isoamyl acrylate and/or isoamyl methacrylate,b) from 9% to 89.9% by weight of (methacrylates whose homopolymers have a glass transition temperature below -30.degree. C.,c) from 2.5% to 30% by weight of .alpha.,.beta.-monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature above -30.degree. C.,d) from 0% to 10% by weight of monoolefinically unsaturated acids and/or their anhydrides ande) from 0% to 20% by weight of further olefinically unsaturated monomers having one or more of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary and tertiary amine and ether groups, andf) from 0.1% to 5% by weight of a copolymerizable benzophenone derivative or acetophenone derivative,the sum of the percentages by weight X (=a+b+c+d+f) being 100 in each case.
摘要翻译：通过在大气氧下通过紫外线辐射可交联并且基于具有10至100的K值的（甲基）丙烯酸酯共聚物的材料通过自由基聚合在溶剂存在或不存在下通过a） 5％至97.4％的丙烯酸异戊酯和/或甲基丙烯酸异戊酯，b）9％至89.9％（重量）（甲基丙烯酸酯的均聚物的玻璃化转变温度低于-30℃，c）为2.5％至30％重量％的α，β-单烯烃不饱和化合物，其均聚物具有高于-30℃的玻璃化转变温度，d）0重量％至10重量％的单烯属不饱和酸和/或其酸酐，和e）0％至20重量％的具有一个或多个以下官能团的其它烯属不饱和单体：羟基，酰胺，环氧化物，醚，酯，氨基甲酸酯，脲，伯，仲和叔胺和醚基，以及f）0.1％至5重量％的可共聚的b 烯苯酯衍生物或苯乙酮衍生物，每种情况下，重量百分比X（= a + b + c + d + f）之和为100。

9. 发明授权

US08053457B2 3-imidazolyl-indoles for the treatment of proliferative diseases 失效
标题翻译： 3-咪唑基 - 吲哚，用于治疗增殖性疾病
公开(公告)号：US08053457B2
公开(公告)日：2011-11-08
申请号：US12593721
申请日：2008-03-27
申请人： Andreas Boettcher , Nicole Buschmann , Pascal Furet , Jean-Marc Groell , Jorg Kallen , Joanna Hergovich Lisztwan , Keiichi Masuya , Lorenz Mayr , Andrea Vaupel
发明人： Andreas Boettcher , Nicole Buschmann , Pascal Furet , Jean-Marc Groell , Jorg Kallen , Joanna Hergovich Lisztwan , Keiichi Masuya , Lorenz Mayr , Andrea Vaupel
IPC分类号： A61K31/397 , A61K31/5377 , A61K31/496 , A61K31/506 , C07D401/14 , C07D403/14
CPC分类号： C07D403/04
摘要： The invention relates to 3-heterocyclyl indolyl compounds of formula I capable of inhibiting the interaction between p53, or variants thereof, and MDM2 and/or MDM4, or variants thereof, respectively: wherein R1, R2, R3, R4, RA, Y and Y are as defined in the specification. Due to their activity, the compounds are useful in the treatment of various disorders and diseases mediated by the activity of MDM2 and/or MDM4, or variants thereof, such as inflammatory or proliferative diseases or in the protection of cells.
摘要翻译：本发明涉及能够分别抑制p53或其变体和MDM2和/或MDM4或其变体之间的相互作用的式I的3-杂环基吲哚基化合物：其中R1，R2，R3，R4，RA，Y和 Y如说明书中所定义。由于它们的活性，所述化合物可用于治疗由MDM2和/或MDM4或其变体如炎性或增殖性疾病或保护细胞的活性介导的各种疾病和疾病。

10. 发明授权

US5220037A Sulfonium salts and use thereof 失效
标题翻译：锍盐及其用途
公开(公告)号：US5220037A
公开(公告)日：1993-06-15
申请号：US825752
申请日：1992-01-27
申请人： Reinhold Schwalm , Andreas Boettcher
发明人： Reinhold Schwalm , Andreas Boettcher
IPC分类号： C07C381/12 , G03F7/029
CPC分类号： C07C381/12 , G03F7/029
摘要： Novel sulfonium salts useful as photoinitiators for cationic polymerization and for producing relief patterns and relief images have the general formula (I) ##STR1## where A.sup..crclbar. is a non-nucleophilic counterion,x is 1, 2 or 3,R is a hydrocarbon radicalR' is arylene or substituted arylene, andR" is ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl or monohalogenated or polyhalogenated alkyl orR.sup.1 and R.sup.2 are each hydrogen or alkyl, and R.sup.3 is phenyl, alkenyl or cycloalkenyl, orR.sup.1 is hydrogen, and R.sup.2 and R.sup.3 form ethylenically unsaturated ring, orR.sup.1 and R.sup.2 are each hydrogen, alkyl, cycloalkyl or aryl, and R.sup.3 is alkoxy orR.sup.1 is hydrogen or alkyl and R.sup.2 and R.sup.3 are each alkoxy, aryloxy or substituted aryloxy.
摘要翻译：用作阳离子聚合和产生浮雕图案和浮雕图像的光引发剂的新型锍盐具有通式（I）其中A（ - ）是非亲核抗衡离子，x为1,2或3， R是烃基，R'是亚芳基或取代的亚芳基，R“是其中R 1，R 2和R 3各自是烷基或单卤代或多卤代烷基或R 1和R 2各自是氢或烷基，R 3是苯基，烯基或环烯基，或R 1为氢，R 2和R 3为烯键式不饱和环，或者R 1和R 2各自为氢，烷基，环烷基或芳基，R 3为烷氧基或R 1为氢或烷基，R 2和R 3为烷氧基，芳氧基或取代的芳氧基。

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