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1. 发明授权

US06875303B2 Method of bonding a window to a substrate without a primer 有权
标题翻译：将窗口粘合到没有底漆的基材上的方法
公开(公告)号：US06875303B2
公开(公告)日：2005-04-05
申请号：US10304425
申请日：2002-11-26
申请人： Andon Samurkas , Ziyan Wu , Sean C. Tobin , Daniel P. Heberer
发明人： Andon Samurkas , Ziyan Wu , Sean C. Tobin , Daniel P. Heberer
IPC分类号： B60J1/02 , B08B7/00 , B32B17/10 , C03C27/04 , C08L75/04 , C09J5/02 , C09J175/04 , C09J201/00 , H05H1/24
CPC分类号： C09J5/02 , B08B7/00 , C03C27/048 , C08L75/04 , C09J2400/143 , C09J2475/00
摘要： The invention is a process for bonding glass to a substrate without the need to prime the surface of the substrate. The process comprises, first, treating the surface of the substrate with air plasma, applying to the surface of the substrate or to the surface of the glass an adhesive capable of bonding to the treated substrate and glass, and contacting the glass and the substrate with the adhesive disposed between the substrate and the glass, and allowing the adhesive to cure. Preferably the substrate is coated with a coating. Preferred adhesives are polyurethane or silane functional elastomeric adhesives.The process of the invention allows bonding of glass to a substrate without the need to use a primer on the substrate prior to application of the adhesive. The process is especially effective in facilitating the bonding of glass to coated substrates, especially substrates coated with acid resistant coatings such as PPG's carbamate coating or DuPont's Gen III, IV and VI coatings.
摘要翻译：本发明是一种将玻璃粘合到基材上的方法，而不需要填充基材的表面。该方法包括：首先用空气等离子体处理衬底的表面，向衬底的表面或玻璃表面施加能够与经处理的衬底和玻璃结合的粘合剂，并将玻璃和衬底与粘合剂设置在基板和玻璃之间，并允许粘合剂固化。优选地，用涂层涂覆基材。优选的粘合剂是聚氨酯或硅烷官能的弹性体粘合剂。本发明的方法允许将玻璃粘合到基材上，而不需要在施加粘合剂之前在基材上使用底漆。该方法在促进玻璃与涂覆的基材，特别是涂覆有耐酸涂层如PPG的氨基甲酸酯涂层或DuPont的Gen III，IV和VI涂层的基材之间特别有效。

2. 发明授权

US06649016B2 Silane functional adhesive composition and method of bonding a window to a substrate without a primer 有权
标题翻译：硅烷功能性粘合剂组合物和将窗口粘合到没有底漆的基材上的方法
公开(公告)号：US06649016B2
公开(公告)日：2003-11-18
申请号：US10090848
申请日：2002-03-04
申请人： Ziyan Wu , Daniel P. Heberer
发明人： Ziyan Wu , Daniel P. Heberer
IPC分类号： C09J18316
CPC分类号： C09J171/02 , C08G65/336 , C08L2666/54 , C09J201/10
摘要： This invention relates to silane functional adhesive composition and to a method of bonding a window to a painted substrate using the adhesive without the need for a primer for the painted substrate. In one embodiment, the invention is a method of bonding glass to a painted substrate, such as a window in a vehicle. The process comprises applying to the glass or the unprimed painted substrate an adhesive as described herein; contacting the glass with the unprimed painted substrate wherein the adhesive is located between the window and the substrate; and allowing the adhesive to cure.
摘要翻译：本发明涉及硅烷功能性粘合剂组合物以及使用粘合剂将窗口粘合到涂漆基材上的方法，而不需要用于涂漆基材的底漆。在一个实施方案中，本发明是将玻璃粘合到涂漆的基材，例如车辆中的窗口的方法。该方法包括将如本文所述的粘合剂施加到玻璃或未经染色的基材上; 使玻璃与未涂漆的基材接触，其中粘合剂位于窗和基材之间; 并使粘合剂固化。

3. 发明授权

US07708853B2 System for bonding glass into a structure 有权
标题翻译：将玻璃粘结成结构的系统
公开(公告)号：US07708853B2
公开(公告)日：2010-05-04
申请号：US12195648
申请日：2008-08-21
申请人： Ziyan Wu , Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam
发明人： Ziyan Wu , Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam
IPC分类号： C09J5/02 , B60J10/02
CPC分类号： C03C27/048 , C03C27/10 , C09D5/002 , C09J5/02
摘要： The invention is a bonding process using a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.
摘要翻译：本发明是使用组合物的粘合方法，该组合物包含a）一种或多种具有四种配体的有机钛酸酯或锆酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷的杂原子的官能团，硫，其中两个或更多个配体可以形成环状结构，条件是配体之一具有酸性部分; 一种或多种强有机酸或其混合物; b）一种或多种烷氧基硅烷; c）任选的一种或多种高分子量树脂; 和d）溶解组合物组分的溶剂。该组合物在下文中称为透明底漆。优选地，组合物包含有机钛酸盐或锆酸盐和强酸。

4. 发明申请

US20090205769A1 SYSTEM FOR BONDING GLASS INTO A STRUCTURE 有权
标题翻译：将玻璃粘结成结构的系统
公开(公告)号：US20090205769A1
公开(公告)日：2009-08-20
申请号：US12195648
申请日：2008-08-21
申请人： Ziyan Wu , Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam
发明人： Ziyan Wu , Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam
IPC分类号： B32B37/12
CPC分类号： C03C27/048 , C03C27/10 , C09D5/002 , C09J5/02
摘要： The invention is a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.
摘要翻译：本发明是一种组合物，其包含a）一种或多种具有四种配体的有机钛酸酯或锆酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷和硫的杂原子的官能团，其中两个或更多的配体可以形成环状结构，条件是配体之一具有酸性部分; 一种或多种强有机酸或其混合物; b）一种或多种烷氧基硅烷; c）任选的一种或多种高分子量树脂; 和d）溶解组合物组分的溶剂。该组合物在下文中称为透明底漆。优选地，组合物包含有机钛酸盐或锆酸盐和强酸。

5. 发明授权

US07494540B2 System for bonding glass into a structure 有权
标题翻译：将玻璃粘结成结构的系统
公开(公告)号：US07494540B2
公开(公告)日：2009-02-24
申请号：US11012606
申请日：2004-12-15
申请人： Ziyan Wu , Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam
发明人： Ziyan Wu , Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam
IPC分类号： C09J5/02 , C09J175/00
CPC分类号： C03C27/048 , C03C27/10 , C09D5/002 , C09J5/02
摘要： The invention is a composition comprising a) one or more organotitanates or zirconates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure with the proviso that one of the ligands has an acidic moiety; one or more strong organic acids or a mixture thereof; b) one or more alkoxysilanes; c) optionally one or more high molecular weight resins; and d) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. Preferably, the composition comprises both an organotitanate or zirconate and a strong acid.
摘要翻译：本发明是一种组合物，其包含a）一种或多种具有四种配体的有机钛酸酯或锆酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷和硫的杂原子的官能团，其中两个或更多的配体可以形成环状结构，条件是配体之一具有酸性部分; 一种或多种强有机酸或其混合物; b）一种或多种烷氧基硅烷; c）任选的一种或多种高分子量树脂; 和d）溶解组合物组分的溶剂。该组合物在下文中称为透明底漆。优选地，组合物包含有机钛酸盐或锆酸盐和强酸。

6. 发明授权

US07416599B2 System for bonding glass into a structure 有权
标题翻译：将玻璃粘结成结构的系统
公开(公告)号：US07416599B2
公开(公告)日：2008-08-26
申请号：US11008426
申请日：2004-12-10
申请人： Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam , Ziyan Wu
发明人： Harry W. Hsieh , Daniel P. Heberer , Dominic J. Allam , Ziyan Wu
IPC分类号： E06B3/56 , C09J5/02 , C09J175/00
CPC分类号： C09J175/04 , C03C27/048 , C08G18/10 , C08G18/307
摘要： The invention is a composition comprising a) one or more organotitanates having four ligands wherein the ligands are hydrocarbyl, optionally containing one or more functional groups having one or more heteroatoms selected from the group comprising oxygen, nitrogen, phosphorus and sulfur wherein two or more of the ligands may form a cyclic structure; b) one or more mercaptosilanes; c) one or more polyaminosilanes; d) one or more secondary aminosilanes; and e) a solvent which dissolves the components of the composition. This composition is referred to as a clear primer hereinafter. In another embodiment the invention is a system for bonding glass to a substrate which comprises a clear primer according to the invention; and an adhesive comprising an isocyanate functional prepolymer and a catalyst for the cure of the isocyanate functional prepolymer.
摘要翻译：本发明是一种组合物，其包含a）一种或多种具有四种配体的有机钛酸盐，其中配体是烃基，任选地含有一个或多个具有一个或多个选自氧，氮，磷和硫的杂原子的官能团，其中两个或多个配体可以形成环状结构; b）一种或多种巯基硅烷; c）一种或多种聚氨基硅烷; d）一种或多种仲氨基硅烷; 和e）溶解组合物组分的溶剂。该组合物在下文中称为透明底漆。在另一个实施方案中，本发明是用于将玻璃粘合到基底上的系统，其包含根据本发明的透明底漆; 以及包含异氰酸酯官能预聚物和用于固化异氰酸酯官能预聚物的催化剂的粘合剂。

7. 发明申请

US20080185098A1 ADHESIVE USEFUL FOR INSTALLING VEHICLE WINDOWS 审中-公开
标题翻译：粘合有用的安装车窗
公开(公告)号：US20080185098A1
公开(公告)日：2008-08-07
申请号：US12024819
申请日：2008-02-01
申请人： Ziyan Wu , Lirong Zhou , Daniel P. Heberer
发明人： Ziyan Wu , Lirong Zhou , Daniel P. Heberer
IPC分类号： C09J175/04 , C08G18/00 , C08K5/51 , C08K5/43 , C08K5/42 , C08K5/10
CPC分类号： C09J175/04 , C08G18/10 , C08G18/12 , C08G18/4009 , C08G18/409 , C08G18/4812 , C08G18/4841 , C08G18/708 , C08K5/0016 , C08K2201/014 , C08G18/792 , C08G18/307 , C08G18/7664 , C08L75/08
摘要： The invention is a composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more low polar plasticizers; c) one or more high polar plasticizers d) one or more carbon blacks; and e) one or more catalysts for the reaction of isocyanate moieties with hydroxyl groups.In another embodiment the invention is a method of bonding two or more substrates together which comprises contacting the two or more substrates together with a composition according to this invention disposed along at least a portion of the area wherein the substrates are in contact.In yet another embodiment the invention is a method of replacing a window of a vehicle comprising: i) removing the window from the vehicle; ii) applying a composition according to the invention to a replacement window or to the flange of the vehicle adapted to hold the window into the vehicle; iii) contacting the flange of the vehicle and the replacement window with the composition disclosed between the replacement window and the flange of the vehicle; and iv) allowing the adhesive to cure.
摘要翻译：本发明是一种组合物，其包含a）一种或多种异氰酸酯官能的聚醚基预聚物; b）一种或多种低极性增塑剂; c）一种或多种高极性增塑剂d）一种或多种炭黑; 和e）用于使异氰酸酯部分与羟基反应的一种或多种催化剂。在另一个实施方案中，本发明是一种将两个或更多个基底结合在一起的方法，其包括使两个或更多个基底与沿着其中基底接触的区域的至少一部分布置的根据本发明的组合物接触。在另一个实施例中，本发明是一种替换车辆的窗户的方法，包括：i）从车辆移除窗户; ii）将根据本发明的组合物施加到适于将窗户保持在车辆中的更换窗口或车辆的凸缘; iii）使车辆的凸缘与更换窗口接触，其中所述组合物在更换窗和车辆的凸缘之间公开; 和iv）允许粘合剂固化。

8. 发明授权

US5681919A Magnetic recording binder containing aminoalkylphosphonate salt 失效
标题翻译：含有氨基烷基膦酸盐的磁记录粘合剂
公开(公告)号：US5681919A
公开(公告)日：1997-10-28
申请号：US453150
申请日：1995-05-30
申请人： Charles J. Amirsakis , David E. Vietti , Daniel P. Heberer , Louis C. Dolmon , Lawrence Picchiotti
发明人： Charles J. Amirsakis , David E. Vietti , Daniel P. Heberer , Louis C. Dolmon , Lawrence Picchiotti
IPC分类号： C08G63/685 , C07F9/38 , C08G18/08 , C08G18/30 , C08G63/692 , C09D5/23 , G11B5/702
CPC分类号： C08G18/0819 , C08G63/6926 , G11B5/7021 , Y10S428/90 , Y10T428/25 , Y10T428/31609 , Y10T428/31786
摘要： A magnetic recording medium is prepared by applying a magnetic coating composition onto a non-magnetic support and curing said composition, said coating composition containing ferromagnetic particles dispersed in a binder comprising a thermoplastic resin selected from the group consisting of polyurethanes and polyester wherein there is chemically bonded to said resin at least one aminoalkylphosphonate represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different oxyalkyl radicals having from 2 to 12 carbon atoms, R.sup.3 is an alkylene radical having from 1 to 12 carbon atoms, or an aralkylene radical having from 7 to 10 carbon atoms R.sup.4 is an alkyl radical having from 1 to 12 carbon atoms, a cycloalkyl radical having from 5 to 12 carbon atoms, or an aryl radical having from 6 to 12 carbon atoms wherein the aryl radical may contain a halogen atom, a hydroxyl group, or an amino group, and M.sup.+ is a metal ion or an ammonium ion.
摘要翻译：通过将磁性涂料组合物施加到非磁性载体上并固化所述组合物来制备磁记录介质，所述涂料组合物含有分散在粘合剂中的铁磁颗粒，所述粘合剂包含选自聚氨酯和聚酯的热塑性树脂，其中存在化学与所述树脂键合至少一种由下式表示的氨基烷基膦酸酯：其中R 1和R 2是相同或不同的具有2至12个碳原子的氧烷基，R 3是具有1至12个碳原子的亚烷基，或具有7至10个碳原子的亚芳基R 4是具有1至12个碳原子的烷基，具有5至12个碳原子的环烷基或具有6至12个碳原子的芳基，其中芳基可以含有卤素原子，羟基或氨基，M +是金属离子或铵离子。

9. 发明授权

US07834102B2 Composition useful as an adhesive for installing vehicle windows 有权
标题翻译：用作安装车窗的粘合剂的组合物
公开(公告)号：US07834102B2
公开(公告)日：2010-11-16
申请号：US11510234
申请日：2006-08-25
申请人： Lirong Zhou , Daniel P. Heberer
发明人： Lirong Zhou , Daniel P. Heberer
IPC分类号： C08F20/00 , C08G73/00 , C08G18/00
CPC分类号： C09J175/04 , B60J10/34 , B60J10/45 , C08G18/10 , C08G18/12 , C08G18/163 , C08G18/4072 , C08G18/7664 , C08G18/792
摘要： The invention is an composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of from about 45 to about 59° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more nonconductive carbon blacks; e) one or more catalysts for the reaction of isocyanates moieties with hydroxyl groups. In a preferred embodiment the composition of the invention further comprises one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of about 60 to about 90° C.
摘要翻译：本发明是一种组合物，其包含a）一种或多种异氰酸酯官能的聚醚基预聚物; b）一种或多种异氰酸酯官能聚酯预聚物，其中所述一种或多种聚酯用于制备熔点为约45至约59℃的预聚物; c）一种或多种具有约3或更大的标称官能度的多异氰酸酯; d）一种或多种非导电炭黑; e）用于使具有羟基的异氰酸酯部分反应的一种或多种催化剂。在优选的实施方案中，本发明的组合物还包含一种或多种异氰酸酯官能的聚酯预聚物，其中所述一种或多种聚酯用于制备熔点为约60至约90℃的预聚物。

10. 发明授权

US5556698A Magnetic recording medium having a binder containing aminoalkylphosphonate salt functional groups 失效
标题翻译：具有含有氨基烷基膦酸盐官能团的粘合剂的磁记录介质
公开(公告)号：US5556698A
公开(公告)日：1996-09-17
申请号：US452804
申请日：1995-05-30
申请人： Charles J. Amirsakis , David E. Vietti , Daniel P. Heberer , Louis C. Dolmon , Lawrence Picchiotti
发明人： Charles J. Amirsakis , David E. Vietti , Daniel P. Heberer , Louis C. Dolmon , Lawrence Picchiotti
IPC分类号： C08G63/685 , C07F9/38 , C08G18/08 , C08G18/30 , C08G63/692 , C09D5/23 , G11B5/702
CPC分类号： C08G18/0819 , C08G63/6926 , G11B5/7021 , Y10S428/90 , Y10T428/25 , Y10T428/31609 , Y10T428/31786
摘要： A magnetic recording medium is prepared by applying a magnetic coating composition onto a non-magnetic support and curing said composition, said coating composition containing ferromagnetic particles dispersed in a binder comprising a thermoplastic resin selected from the group consisting of polyurethanes and polyester wherein there is chemically bonded to said resin at least one aminoalkylphosphonate represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different oxyalkyl radicals having from 2 to 12 carbon atoms, R.sup.3 is an alkylene radical having from 1 to 12 carbon atoms, or an aralkylene radical having from 7 to 10 carbon atoms R.sup.4 is an alkyl radical having from 1 to 12 carbon atoms, a cycloalkyl radical having from 5 to 12 carbon atoms, or an aryl radical having from 6 to 12 carbon atoms wherein the aryl radical may contain a halogen atom, a hydroxyl group, or an amino group, and M.sup.+ is a metal ion or an ammonium ion.
摘要翻译：通过将磁性涂料组合物施加到非磁性载体上并固化所述组合物来制备磁记录介质，所述涂料组合物含有分散在粘合剂中的铁磁颗粒，所述粘合剂包含选自聚氨酯和聚酯的热塑性树脂，其中存在化学与所述树脂键合至少一种由下式表示的氨基烷基膦酸酯：其中R 1和R 2是相同或不同的具有2至12个碳原子的氧烷基，R 3是具有1至12个碳原子的亚烷基，或具有7至10个碳原子的亚芳基R 4是具有1至12个碳原子的烷基，具有5至12个碳原子的环烷基或具有6至12个碳原子的芳基，其中芳基可以含有卤素原子，羟基或氨基，M +是金属离子或铵离子。

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