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    • 1. 发明申请
    • USE OF THERMOELECTRIC MATERIALS FOR LOW TEMPERATURE THERMOELECTRIC PURPOSES
    • 热电材料用于低温热电场用途
    • US20100139730A1
    • 2010-06-10
    • US12517470
    • 2007-12-04
    • Anders BentienSimon JohnsenGeorg Kent Hellerup MadsenBo Brummerstedt IversenFrank Steglich
    • Anders BentienSimon JohnsenGeorg Kent Hellerup MadsenBo Brummerstedt IversenFrank Steglich
    • H01L35/20C01B19/00C22C12/00H01L35/34
    • H01L35/34C22C12/00C30B15/00C30B29/52H01L35/18
    • The invention relates to the use of a thermoelectric material for thermoelectric purposes at a temperature of 150 K or less, said thermoelectric material is a material corresponding to the stoichiometric formula FeSb2, wherein all or part of the Fe atoms optionally being substituted by one or more elements selected from the group comprising: Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, La, Hf, Ta, W, Re, Os, Tr, Pt, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and a vacancy; and wherein all or part of the Sb atoms optionally being substituted by one or more elements selected from the group comprising: P, As, Bi, S, Se, Te, B, Al, Ga, In, Tl, C, Si, Ge, Sn, Pb and a vacancy; with the proviso that neither one of the elements Fe and Sb in the formula FeSb2 is fully substituted with a vacancy, characterised in that said thermoelectric material exhibits a power factor (S2σ) of 25 μW/cmK2 or more at a temperature of 150 K or less. The invention also relates to thermoelectric materials per se falling within the above definition.
    • 本发明涉及在150K或更小的温度下用于热电目的的热电材料,所述热电材料是对应于化学计量式FeSb 2的材料,其中全部或部分Fe原子任选被一个或多个 选自包括Sc,Ti,V,Cr,Mn,Co,Ni,Cu,Zn,Y,Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,Cd,La,Hf,Ta ,W,Re,Os,Tr,Pt,Au,Hg,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu和空位; 并且其中全部或部分Sb原子任选被一种或多种选自以下的元素取代:P,As,Bi,S,Se,Te,B,Al,Ga,In,Tl,C,Si,Ge ,Sn,Pb和空位; 条件是式FeSb2中的元素Fe和Sb中的任一个都不完全被空位置换,其特征在于所述热电材料在150K的温度下表现出25μW/ cmK 2或更高的功率因数(S2&sgr) 或更少。 本发明还涉及属于上述定义的热电材料本身。